CN107311670A - A kind of novel fire resistant material - Google Patents

A kind of novel fire resistant material Download PDF

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Publication number
CN107311670A
CN107311670A CN201710520662.5A CN201710520662A CN107311670A CN 107311670 A CN107311670 A CN 107311670A CN 201710520662 A CN201710520662 A CN 201710520662A CN 107311670 A CN107311670 A CN 107311670A
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CN
China
Prior art keywords
parts
zinc oxide
antioxidant
carborundum
silica
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Pending
Application number
CN201710520662.5A
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Chinese (zh)
Inventor
吴树全
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Xuzhou Su Brand High Temperature New Material Co Ltd
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Xuzhou Su Brand High Temperature New Material Co Ltd
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Priority to CN201710520662.5A priority Critical patent/CN107311670A/en
Publication of CN107311670A publication Critical patent/CN107311670A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3284Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3821Boron carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon
    • C04B2235/427Diamond
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
    • C04B2235/524Non-oxidic, e.g. borides, carbides, silicides or nitrides
    • C04B2235/5248Carbon, e.g. graphite

Abstract

The invention discloses a kind of novel fire resistant material, the material is mainly made up of following parts by weight of component:20 37 parts of 10 13 parts of peptide cyanines resin, 15 17 parts of boron carbide, 58 parts of antioxidant, 8 10 parts of zinc oxide, 58 parts of carborundum, 10 12 parts of diamond, 0 12 parts of silica 1,20 37 parts of glass fibre or carbon fiber.Preparation method is as follows:Sorting, milling, mixing, drying, high temperature melt, coating, cooling.The high-temperature material that the present invention is produced, hardness is high, the manufacture of large scale equipment can be used for alternative metals, superhigh temperature resistant and comparison to be light, and price is low, it will not be corroded and get rusty, it is manufactured into after high temperature resistant equipment, due to inherently exotic material, so exotic material need not be smeared, the working time of staff is saved, while also saving raw tea cost for enterprise.Manufacture craft of the present invention is simple, it is easy to make.

Description

A kind of novel fire resistant material
Technical field
The present invention is specifically a kind of novel fire resistant material, belongs to exotic material technical field.
Background technology
During high temperature production, used equipment is mostly that metal is made, yet with Strength of Metallic Materials Greatly, it is chronically in high-temperature operation, is easily corroded and gets rusty, it is necessary to periodic cleaning, otherwise can influence the product quality produced, Increase the workload of staff, be unfavorable for the raising of production efficiency.In order to further protect hardware, it can typically take Hardware inner surface smears the measure of high-temperature material, cumbersome, and needs also exist for periodically smearing high-temperature material and consolidated.
The content of the invention
The technical problem existed for above-mentioned background technology, the present invention provides a novel fire resistant material, with superelevation Hardness and high intensity hardness ratio, can be directly prepared into high-temperature service, without smearing high-temperature material again, and lightweight, and price is low, It will not be corroded and get rusty, without periodic cleaning.
To achieve these goals, a kind of novel fire resistant material of the invention, the material is main by following parts by weight of component Composition:10-13 parts of peptide cyanines resin, 15-17 parts of boron carbide, 5-8 parts of antioxidant, 8-10 parts of zinc oxide, 5-8 parts of carborundum, gold 20-37 parts of 10-12 parts of hard rock, 0-12 parts of silica 1,20-37 parts of glass fibre or carbon fiber.
Preferably, the material is mainly made up of following parts by weight of component:It is 10 parts of peptide cyanines resin, 15 parts of boron carbide, anti-oxidant 37 parts of 5 parts of agent, 8 parts of zinc oxide, 5 parts of carborundum, 10 parts of diamond, 0 part of silica 1,37 parts of glass fibre or carbon fiber.
Preferably, the material is mainly made up of following parts by weight of component:It is 13 parts of peptide cyanines resin, 17 parts of boron carbide, anti-oxidant 20 parts of 8 parts of agent, 10 parts of zinc oxide, 8 parts of carborundum, 12 parts of diamond, 2 parts of silica 1,20 parts of glass fibre or carbon fiber.
Preferably, the material is mainly made up of following parts by weight of component:11.5 parts of peptide cyanines resin, 16 parts of boron carbide, antioxygen 6.5 parts of agent, 9 parts of zinc oxide, 6.5 parts of carborundum, 11 parts of diamond, 1 part of silica 1,28.5 parts of glass fibre or carbon are fine 28.5 parts of dimension.
A kind of preparation method of novel fire resistant material is as follows:
A. raw material is chosen according to parts by weight;
B. antioxidant and zinc oxide are mixed and wears into 150-300 mesh, obtain the powder mixing of antioxidant and zinc oxide Thing;
C. the mixture of powders that will be obtained in peptide cyanines resin, boron carbide, carborundum, diamond, silica and step b It is put into ball mill, through wet mixed ball milling 20h-25h, obtains mixed material;
D. the mixture in step c is dried into 6-10h at a temperature of 150-200 DEG C;
F. dried mixture is placed in high temperature furnace and melted, after thawing, is coated on glass fibre or carbon fiber, it is cold But to room temperature, you can.
Compared with prior art, peptide cyanines resin of the present invention has anti-high oxidation in itself, the features such as self-extinguishment, with carbon fiber or Glass fibre is solidified into fiber-reinforced resin, then with boron carbide, antioxidant, zinc oxide, carborundum, diamond, silica After chemically reacting, the high-temperature material produced, hardness is high, and the manufacture of large scale equipment, resistance to superelevation can be used for alternative metals Warm and relatively light, price is low, will not be corroded and get rusty, and is manufactured into after high temperature resistant equipment, due to inherently exotic material, institute So that exotic material need not be smeared, the working time of staff is saved, while also saving raw tea cost for enterprise.This hair Bright manufacture craft is simple, it is easy to make.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1:
The present embodiment manufactures the exotic material 100kg, is mainly made up of following parts by weight of component:Peptide cyanines resin 10kg, boron carbide 15kg, antioxidant 5kg, zinc oxide 8kg, carborundum 5kg, diamond 10kg, silica 1 0kg, glass Fiber 37kg or carbon fiber 37kg.
Preparation method is as follows:
A. raw material is chosen according to parts by weight;
B. antioxidant and zinc oxide are mixed and wears into 150 mesh, obtain the mixture of powders of antioxidant and zinc oxide;
C. the mixture of powders that will be obtained in peptide cyanines resin, boron carbide, carborundum, diamond, silica and step b It is put into ball mill, through wet mixed ball milling 20h, obtains mixed material;
D. the mixture in step c is dried into 6h at a temperature of 150 DEG C;
F. dried mixture is placed in high temperature furnace and melted, after thawing, is coated on glass fibre or carbon fiber, it is cold But to room temperature, you can.
Embodiment 2:
The present embodiment manufactures the exotic material 100kg, is mainly made up of following parts by weight of component:Peptide cyanines resin 13kg, boron carbide 17kg, antioxidant 8kg, zinc oxide 10kg, carborundum 8kg, diamond 12kg, silica 1 2kg, glass Fiber 20kg or carbon fiber 20kg.
Preparation method is as follows:
A. raw material is chosen according to parts by weight;
B. antioxidant and zinc oxide are mixed and wears into 300 mesh, obtain the mixture of powders of antioxidant and zinc oxide;
C. the mixture of powders that will be obtained in peptide cyanines resin, boron carbide, carborundum, diamond, silica and step b It is put into ball mill, through wet mixed ball milling 25h, obtains mixed material;
D. the mixture in step c is dried into 10h at a temperature of 200 DEG C;
F. dried mixture is placed in high temperature furnace and melted, after thawing, is coated on glass fibre or carbon fiber, it is cold But to room temperature, you can.
Embodiment 3:
The present embodiment manufactures the exotic material 100kg, is mainly made up of following parts by weight of component:Peptide cyanines resin 11.5kg, boron carbide 16kg, antioxidant 6.5kg, zinc oxide 9kg, carborundum 6.5kg, diamond 11kg, silica 11kg, glass fibre 28.5kg or carbon fiber 28.5kg.
Preparation method is as follows:
A. raw material is chosen according to parts by weight;
B. antioxidant and zinc oxide are mixed and wears into 200 mesh, obtain the mixture of powders of antioxidant and zinc oxide;
C. the mixture of powders that will be obtained in peptide cyanines resin, boron carbide, carborundum, diamond, silica and step b It is put into ball mill, through wet mixed ball milling 22.5h, obtains mixed material;
D. the mixture in step c is dried into 7.5h at a temperature of 180 DEG C;
F. dried mixture is placed in high temperature furnace and melted, after thawing, is coated on glass fibre or carbon fiber, it is cold But to room temperature, you can.

Claims (5)

1. a kind of novel fire resistant material, it is characterised in that the material is mainly made up of following parts by weight of component:Peptide cyanines resin 10-13 parts, 15-17 parts of boron carbide, 5-8 parts of antioxidant, 8-10 parts of zinc oxide, 5-8 parts of carborundum, 10-12 parts of diamond, two 20-37 parts of 10-12 parts of silica, 20-37 parts of glass fibre or carbon fiber.
2. a kind of novel fire resistant material according to claim 1, it is characterised in that the material is main by following parts by weight Component is constituted:10 parts of peptide cyanines resin, 15 parts of boron carbide, 5 parts of antioxidant, 8 parts of zinc oxide, 5 parts of carborundum, 10 parts of diamond, 37 parts of 0 part of silica 1,37 parts of glass fibre or carbon fiber.
3. a kind of novel fire resistant material according to claim 1, it is characterised in that the material is main by following parts by weight Component is constituted:13 parts of peptide cyanines resin, 17 parts of boron carbide, 8 parts of antioxidant, 10 parts of zinc oxide, 8 parts of carborundum, 12 parts of diamond, 20 parts of 2 parts of silica 1,20 parts of glass fibre or carbon fiber.
4. a kind of novel fire resistant material according to claim 1, it is characterised in that the material is main by following parts by weight Component is constituted:11.5 parts of peptide cyanines resin, 16 parts of boron carbide, 6.5 parts of antioxidant, 9 parts of zinc oxide, 6.5 parts of carborundum, diamond 28.5 parts of 11 parts, 1 part of silica 1,28.5 parts of glass fibre or carbon fiber.
5. a kind of novel fire resistant material according to claim any one of 1-4, it is characterised in that the making side of the material Method is as follows:
A. raw material is chosen according to parts by weight;
B. antioxidant and zinc oxide are mixed and wears into 150-300 mesh, obtain the mixture of powders of antioxidant and zinc oxide;
C. the mixture of powders obtained in peptide cyanines resin, boron carbide, carborundum, diamond, silica and step b is put into In ball mill, through wet mixed ball milling 20h-25h, mixed material is obtained;
D. the mixture in step c is dried into 6-10h at a temperature of 150-200 DEG C;
F. dried mixture is placed in high temperature furnace and melted, after thawing, be coated on glass fibre or carbon fiber, be cooled to Room temperature, you can.
CN201710520662.5A 2017-06-30 2017-06-30 A kind of novel fire resistant material Pending CN107311670A (en)

Priority Applications (1)

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CN201710520662.5A CN107311670A (en) 2017-06-30 2017-06-30 A kind of novel fire resistant material

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CN107311670A true CN107311670A (en) 2017-11-03

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108359298A (en) * 2018-03-02 2018-08-03 合肥铭佑高温技术有限公司 A kind of fiber reinforcement peptide cyanines resin heat-resisting material and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105585773A (en) * 2014-11-12 2016-05-18 王洪珠 Heat-resistant anti-aging automobile bumper

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105585773A (en) * 2014-11-12 2016-05-18 王洪珠 Heat-resistant anti-aging automobile bumper

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108359298A (en) * 2018-03-02 2018-08-03 合肥铭佑高温技术有限公司 A kind of fiber reinforcement peptide cyanines resin heat-resisting material and preparation method thereof

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Application publication date: 20171103