CN107311603A - Purify antimicrobial form diatom ooze wall material - Google Patents

Purify antimicrobial form diatom ooze wall material Download PDF

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Publication number
CN107311603A
CN107311603A CN201710534993.4A CN201710534993A CN107311603A CN 107311603 A CN107311603 A CN 107311603A CN 201710534993 A CN201710534993 A CN 201710534993A CN 107311603 A CN107311603 A CN 107311603A
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CN
China
Prior art keywords
wall material
diatom ooze
antimicrobial form
parts
ooze wall
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710534993.4A
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Chinese (zh)
Inventor
谢敏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changan Dongguan Fertile Soil Decoration Materials Store
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Changan Dongguan Fertile Soil Decoration Materials Store
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Changan Dongguan Fertile Soil Decoration Materials Store filed Critical Changan Dongguan Fertile Soil Decoration Materials Store
Priority to CN201710534993.4A priority Critical patent/CN107311603A/en
Publication of CN107311603A publication Critical patent/CN107311603A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2092Resistance against biological degradation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

Antimicrobial form diatom ooze wall material is purified the present invention relates to one kind.The purification antimicrobial form diatom ooze wall material includes the component of following parts by weight:30~45 parts of calcium carbonate;5~15 parts of magnesium carbonate;3~12 parts of talcum powder;12~24 parts of diatomite;2~18 parts of bactericide containing zinc;0.1~1 part of hydroxypropyl methyl cellulose ether;0.1~1 part of hydroxypropyl starch ether;0.05~0.1 part of polyvinyl alcohol;1~2 part of bentonite;23~25 parts of calcium hydroxide;1~2 part of redispersable latex powder.The purification antimicrobial form diatom ooze wall material of the present invention can not only have certain inner wall decoration effect, the pernicious gases such as formaldehyde, benzene, ammonia in indoor air can also effectively be dispelled, purifying air improves human respiratory, beneficial health, and with being firmly bonded, produce it is simple, the features such as facilitate.

Description

Purify antimicrobial form diatom ooze wall material
Technical field
The present invention relates to construction engineering technical field, and in particular to one kind purification antimicrobial form diatom ooze wall material.
Background technology
With the development of the society, requirement of the people to finishing yet more and more higher, do not require nothing more than beautiful attractive in appearance, also require environmental protection Health.After finishing, some peculiar smell are had indoors and the gas being detrimental to health is present, such as formaldehyde.Generally use The method of windowing ventilation comes discharge of noxious gases and peculiar smell, or reduces indoor dirt using methods such as adsorbent, cultivation flowers and plants Dye, but above-mentioned method can not be inherently eliminated pollution, and efficiency is low, and cost is high, and the operating time is longer.
Diatom ooze is as a kind of new environment friendly inorganic interior decoration wall material, and it has, and density is low, specific surface area is big, hole Rate is high, adsorptive liquid ability is strong, chemical stability is high, fusing point is high, matter is soft, sound insulation, many excellent properties such as wear-resisting, heat-resisting, Main function in coating is absorption and regulation humidity, can effectively adsorb the harmful substances such as formaldehyde, benzene, ammonia free in air, And it can purify in air because of the peculiar smell of the generations such as pet, smoking, rubbish.
In conventional art, using nano titanium oxide as photochemical catalyst in most diatom ooze wall material, in illumination bar Harmful substance under part including catalytic decomposition absorption, but titanium dioxide has that photocatalysis efficiency is low, only issued in ultraviolet light conditions Photocatalysis is waved, the shortcomings of poor to the spectral response of visible ray, also poor to the adsorptivity of harmful substance, causes diatom ooze wall Material purification air effect can not ensure, therefore most of such diatom ooze wall materials can only achieve partial adsorbates harmful substance, decompose Harmful substance ability is weak, and antibacterial ability is also weaker, and automatic humidifying ability is undesirable, it is difficult to meets people and is adsorbed for persistent high efficiency The active demand of the harmful substances such as decomposing formaldehyde.
The content of the invention
Based on this, a kind of adsorption-decomposition function harmful substance ability of present invention offer is strong, strong antibacterial, automatic humidifying, heatproof The multi-functional purification antimicrobial form diatom ooze wall material such as fire prevention, environment friendly and pollution-free.
In order to realize the purpose of the present invention, the present invention uses following technical scheme:
One kind purification antimicrobial form diatom ooze wall material, includes the component of following parts by weight:
The purification antimicrobial form diatom ooze wall material of the present invention can not only have certain inner wall decoration effect, can also be effectively Dispel the pernicious gases such as formaldehyde, benzene, ammonia in indoor air, purification air improves human respiratory, beneficial health, and And with being firmly bonded, produce it is simple, the features such as facilitate.The wall material of the present invention is compared with traditional wall material, its production brushed Product quality not chip off-falling not alice, not mouldy, bubble, not colour-fast, fire-retardant, and the same day brushes, and the same day is moved in without formaldehyde, VOC etc. Noxious material, nonpoisonous and tasteless, service life is more than 20 years.
Wherein, diatom soil pores is more, specific surface area is high, and adsorptivity is strong, can play elimination peculiar smell, be harmful in adsorption cleaning room The effect of gas.Calcium carbonate and magnesium carbonate play a part of binder materials, and the use of both materials can also ensure wall material Later strength, reduces the usage amount of organic cementing material.Re-dispersible glue powder can improve mobility, improve workability, change Kind cohesive force, extension open hour and enhancing water-retaining property, can make wall material have enough cohesive forces to ensure that upper wall is constructed, simultaneously It ensure that adhesive strength of the slurry at initial stage on wall.On the basis of re-dispersible glue powder, then added with calcium hydroxide and Polyvinyl alcohol, three coordinates jointly has deferred action to hydrated cementitious, helps to extend the operable time of mortar.Hydroxypropyl Methyl cellulose ether can improve the water-retaining property of mixed slurry, and with the effect of thickening, can improve application property, and hydroxypropyl Starch ether has cracking resistance effect, with cellulose ether collective effect, plays a part of thickening, thickening.
Nano-Zinc loses bacterium mass flow, admittedly with very strong sterilization and anti-microbial property, the cell membrane that can be destroyed in bacterium Change virus protein, while exterminating bacterium, moreover it is possible to the harmful compound discharged in bacterium residuum is decomposed, due to Nano-Zinc Physical property itself, oxidizable, made moist easy caking, and therefore, Nano-Zinc is protected added with iron oxide and calcium oxide, so that Nano-Zinc can play its sterilization, antibacterial functions to greatest extent.Bentonite uses six alkyl trimethyl ammonium bromides, hexadecane bromide Change the materials such as pyridine, hexadecyltrimethylammonium chloride to be modified, make it have except formaldehyde, except benzene, except purification functions such as ammonia, Modified alta-mud combination diatomite, Nano-Zinc make the purification antimicrobial form diatom ooze wall material of the present invention have multiple sterilization, antibacterial Effect and adsorption-decomposition function harmful substance ability are strong, the fire prevention of strong antibacterial, automatic humidifying, heatproof, many work(such as environment friendly and pollution-free Energy.
In wherein some embodiments, include the component of following parts by weight:
In wherein some embodiments, include the component of following parts by weight:
In wherein some embodiments, the diatomite is the diatomite of 300~900 mesh.
In wherein some embodiments, the diatomaceous moisture content is less than 0.5%;The diatomaceous specific surface area is 40~65m2/g。
In wherein some embodiments, the particle size range of the Nano-Zinc is 10~50nm.
In wherein some embodiments, the bentonite is modified alta-mud.
In wherein some embodiments, the viscosity for stating modified alta-mud is 300~1800mPa.s.
In wherein some embodiments, six alkyl trimethyl ammonium bromides, hexadecane bromide are contained in the modified alta-mud Change pyridine and hexadecyltrimethylammonium chloride.
In wherein some embodiments, in addition to appropriate pigment.
Embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But, the present invention can be with perhaps More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make Understanding to the disclosure is more thorough comprehensive.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.
One kind purification antimicrobial form diatom ooze wall material, includes the component of following parts by weight:
In wherein some embodiments, include the component of following parts by weight:
In wherein some embodiments, include the component of following parts by weight:
In wherein some embodiments, the diatomite is the diatomite of 300~900 mesh.
In wherein some embodiments, the diatomaceous moisture content is less than 0.5%;The diatomaceous specific surface area is 40~65m2/g。
In wherein some embodiments, the particle size range of the Nano-Zinc is 10~50nm.
In wherein some embodiments, the bentonite is modified alta-mud.
In wherein some embodiments, the viscosity for stating modified alta-mud is 300~1800mPa.s.
In wherein some embodiments, six alkyl trimethyl ammonium bromides, hexadecane bromide are contained in the modified alta-mud Change pyridine and hexadecyltrimethylammonium chloride.
The purification antimicrobial form diatom ooze wall material of the present invention can not only have certain inner wall decoration effect, can also be effectively Dispel the pernicious gases such as formaldehyde, benzene, ammonia in indoor air, purification air improves human respiratory, beneficial health, and And with being firmly bonded, produce it is simple, the features such as facilitate.The wall material of the present invention is compared with traditional wall material, its production brushed Product quality not chip off-falling not alice, not mouldy, bubble, not colour-fast, fire-retardant, and the same day brushes, and the same day is moved in without formaldehyde, VOC etc. Noxious material, nonpoisonous and tasteless, service life is more than 20 years.
Wherein, diatom soil pores is more, specific surface area is high, and adsorptivity is strong, can play elimination peculiar smell, be harmful in adsorption cleaning room The effect of gas.Calcium carbonate and magnesium carbonate play a part of binder materials, and the use of both materials can also ensure wall material Later strength, reduces the usage amount of organic cementing material.Re-dispersible glue powder can improve mobility, improve workability, change Kind cohesive force, extension open hour and enhancing water-retaining property, can make wall material have enough cohesive forces to ensure that upper wall is constructed, simultaneously It ensure that adhesive strength of the slurry at initial stage on wall.On the basis of re-dispersible glue powder, then added with calcium hydroxide and Polyvinyl alcohol, three coordinates jointly has deferred action to hydrated cementitious, helps to extend the operable time of mortar.Hydroxypropyl Methyl cellulose ether can improve the water-retaining property of mixed slurry, and with the effect of thickening, can improve application property, and hydroxypropyl Starch ether has cracking resistance effect, with cellulose ether collective effect, plays a part of thickening, thickening.
Nano-Zinc loses bacterium mass flow, admittedly with very strong sterilization and anti-microbial property, the cell membrane that can be destroyed in bacterium Change virus protein, while exterminating bacterium, moreover it is possible to the harmful compound discharged in bacterium residuum is decomposed, due to Nano-Zinc Physical property itself, oxidizable, made moist easy caking, and therefore, Nano-Zinc is protected added with iron oxide and calcium oxide, so that Nano-Zinc can play its sterilization, antibacterial functions to greatest extent.Bentonite uses six alkyl trimethyl ammonium bromides, hexadecane bromide Change the materials such as pyridine, hexadecyltrimethylammonium chloride to be modified, make it have except formaldehyde, except benzene, except purification functions such as ammonia, Modified alta-mud combination diatomite, Nano-Zinc make the purification antimicrobial form diatom ooze wall material of the present invention have multiple sterilization, antibacterial Effect and adsorption-decomposition function harmful substance ability are strong, the fire prevention of strong antibacterial, automatic humidifying, heatproof, many work(such as environment friendly and pollution-free Energy.
A kind of preparation method for purifying antimicrobial form diatom ooze wall material, comprises the following steps:
First calcium carbonate, magnesium carbonate are dissolved in water, are stirred in greenhouse to dissolving, then sequentially add into above-mentioned solution hydroxypropyl first Base cellulose ether, hydroxypropyl starch ether, polyvinyl alcohol, redispersable latex powder, calcium hydroxide, stir, and then add silicon Diatomaceous earth and bentonite, stir, then add bactericide containing zinc to above-mentioned solution, are eventually adding talcum powder, stir mediation viscosity, The color needed further according to product, adds corresponding appropriate pigment.
The solution of the present invention will be further illustrated by several embodiments below.
Embodiment one:
Purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight:
30 parts of calcium carbonate;5 parts of magnesium carbonate;3 parts of talcum powder;24 parts of diatomite;2 parts of bactericide containing zinc;Hydroxypropyl methyl is fine Plain 0.1 part of the ether of dimension;0.1 part of hydroxypropyl starch ether;0.05 part of polyvinyl alcohol;1 part of bentonite;23 parts of calcium hydroxide;It is redispersible 1 part of latex powder;Appropriate pigment.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is:First calcium carbonate, magnesium carbonate are dissolved in water, are stirred in greenhouse Mix to dissolving, then sequentially add into above-mentioned solution hydroxypropyl methyl cellulose ether, hydroxypropyl starch ether, polyvinyl alcohol, can be again Dispersed latex powder, calcium hydroxide, stir, and then add diatomite and bentonite, stir, then are added to above-mentioned solution Bactericide containing zinc, is eventually adding talcum powder, and stirring reconciles viscosity, the color needed further according to product, adds corresponding appropriate Pigment.
Embodiment two:
Purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight:
40 parts of calcium carbonate;10 parts of magnesium carbonate;8 parts of talcum powder;18 parts of diatomite;10 parts of bactericide containing zinc;Hydroxypropyl methyl 0.5 part of cellulose ether;0.5 part of hydroxypropyl starch ether;0.08 part of polyvinyl alcohol;1.5 parts of bentonite;24 parts of calcium hydroxide;Can be again 1.5 parts of dispersed latex powder;Appropriate pigment.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is:First calcium carbonate, magnesium carbonate are dissolved in water, are stirred in greenhouse Mix to dissolving, then sequentially add into above-mentioned solution hydroxypropyl methyl cellulose ether, hydroxypropyl starch ether, polyvinyl alcohol, can be again Dispersed latex powder, calcium hydroxide, stir, and then add diatomite and bentonite, stir, then are added to above-mentioned solution Bactericide containing zinc, is eventually adding talcum powder, and stirring reconciles viscosity, the color needed further according to product, adds corresponding appropriate Pigment.
Embodiment three:
Purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight:
45 parts of calcium carbonate;15 parts of magnesium carbonate;12 parts of talcum powder;12 parts of diatomite;18 parts of bactericide containing zinc;Hydroxypropyl methyl 1 part of cellulose ether;1 part of hydroxypropyl starch ether;0.1 part of polyvinyl alcohol;2 parts of bentonite;25 parts of calcium hydroxide;Redispersable latex 2 parts of powder;Appropriate pigment.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is:First calcium carbonate, magnesium carbonate are dissolved in water, are stirred in greenhouse Mix to dissolving, then sequentially add into above-mentioned solution hydroxypropyl methyl cellulose ether, hydroxypropyl starch ether, polyvinyl alcohol, can be again Dispersed latex powder, calcium hydroxide, stir, and then add diatomite and bentonite, stir, then are added to above-mentioned solution Bactericide containing zinc, is eventually adding talcum powder, and stirring reconciles viscosity, the color needed further according to product, adds corresponding appropriate Pigment.
Example IV:
Purification antimicrobial form diatom ooze wall material of the present invention, it includes the component of following parts by weight:
38 parts of calcium carbonate;8 parts of magnesium carbonate;6 parts of talcum powder;20 parts of diatomite;15 parts of bactericide containing zinc;Hydroxypropyl methyl is fine Plain 0.3 part of the ether of dimension;0.6 part of hydroxypropyl starch ether;0.06 part of polyvinyl alcohol;1.2 parts of bentonite;23 parts of calcium hydroxide;It can divide again Dissipate 2 parts of latex powder.
The method for preparing above-mentioned purification antimicrobial form diatom ooze wall material is:First calcium carbonate, magnesium carbonate are dissolved in water, are stirred in greenhouse Mix to dissolving, then sequentially add into above-mentioned solution hydroxypropyl methyl cellulose ether, hydroxypropyl starch ether, polyvinyl alcohol, can be again Dispersed latex powder, calcium hydroxide, stir, and then add diatomite and bentonite, stir, then are added to above-mentioned solution Bactericide containing zinc, is eventually adding talcum powder, stirring mediation viscosity.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

1. one kind purification antimicrobial form diatom ooze wall material, it is characterised in that include the component of following parts by weight:
2. purification antimicrobial form diatom ooze wall material according to claim 1, it is characterised in that include the group of following parts by weight Point:
3. purification antimicrobial form diatom ooze wall material according to claim 2, it is characterised in that include the group of following parts by weight Point:
4. purification antimicrobial form diatom ooze wall material according to claim 3, it is characterised in that the diatomite is 300~900 Purpose diatomite.
5. purification antimicrobial form diatom ooze wall material according to claim 4, it is characterised in that the diatomaceous moisture content is small In 0.5%;The diatomaceous specific surface area is 40~65m2/g。
6. purification antimicrobial form diatom ooze wall material according to claim 3, it is characterised in that the particle size range of the Nano-Zinc For 10~50nm.
7. purification antimicrobial form diatom ooze wall material according to claim 3, it is characterised in that the bentonite is bentone Soil.
8. purification antimicrobial form diatom ooze wall material according to claim 7, it is characterised in that the viscosity of the modified alta-mud For 300~1800mPa.s.
9. purification antimicrobial form diatom ooze wall material according to claim 8, it is characterised in that contain in the modified alta-mud Six alkyl trimethyl ammonium bromides, cetyl pyridinium bromide and hexadecyltrimethylammonium chloride.
10. the purification antimicrobial form diatom ooze wall material according to any one of claim 1 to 9, it is characterised in that also include Appropriate pigment.
CN201710534993.4A 2017-07-03 2017-07-03 Purify antimicrobial form diatom ooze wall material Pending CN107311603A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549375A (en) * 2021-08-10 2021-10-26 北京城建智投建设集团有限公司 Novel coating without formaldehyde and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104446283A (en) * 2014-12-18 2015-03-25 辽宁东奥非金属材料开发有限公司 Diatom ooze wall material capable of efficiently purifying air or resisting against bacteria or automatically humidifying and preparation method of diatom ooze wall material
CN104496358A (en) * 2014-12-30 2015-04-08 北京大津硅藻新材料股份有限公司 Indoor anti-mildew and antibacterial diatom ooze decorative wall material
CN105176232A (en) * 2015-08-31 2015-12-23 天长市银狐漆业有限公司 Weather-resistant and waterproof exterior wall emulsion paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104446283A (en) * 2014-12-18 2015-03-25 辽宁东奥非金属材料开发有限公司 Diatom ooze wall material capable of efficiently purifying air or resisting against bacteria or automatically humidifying and preparation method of diatom ooze wall material
CN104496358A (en) * 2014-12-30 2015-04-08 北京大津硅藻新材料股份有限公司 Indoor anti-mildew and antibacterial diatom ooze decorative wall material
CN105176232A (en) * 2015-08-31 2015-12-23 天长市银狐漆业有限公司 Weather-resistant and waterproof exterior wall emulsion paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549375A (en) * 2021-08-10 2021-10-26 北京城建智投建设集团有限公司 Novel coating without formaldehyde and preparation method thereof

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Application publication date: 20171103