CN107311162A - A kind of continuous production graphene device - Google Patents

A kind of continuous production graphene device Download PDF

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Publication number
CN107311162A
CN107311162A CN201710522934.5A CN201710522934A CN107311162A CN 107311162 A CN107311162 A CN 107311162A CN 201710522934 A CN201710522934 A CN 201710522934A CN 107311162 A CN107311162 A CN 107311162A
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CN
China
Prior art keywords
bistrique
box
stationary
condenser
continuous production
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Granted
Application number
CN201710522934.5A
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Chinese (zh)
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CN107311162B (en
Inventor
杜文达
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Shanghai Diba Electronic Technology Co Ltd
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Shanghai Diba Electronic Technology Co Ltd
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Priority to CN201710522934.5A priority Critical patent/CN107311162B/en
Publication of CN107311162A publication Critical patent/CN107311162A/en
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Publication of CN107311162B publication Critical patent/CN107311162B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/18Use of auxiliary physical effects, e.g. ultrasonics, irradiation, for disintegrating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/18Adding fluid, other than for crushing or disintegrating by fluid energy
    • B02C23/36Adding fluid, other than for crushing or disintegrating by fluid energy the crushing or disintegrating zone being submerged in liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C7/00Crushing or disintegrating by disc mills
    • B02C7/02Crushing or disintegrating by disc mills with coaxial discs
    • B02C7/08Crushing or disintegrating by disc mills with coaxial discs with vertical axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C7/00Crushing or disintegrating by disc mills
    • B02C7/11Details
    • B02C7/12Shape or construction of discs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/18Use of auxiliary physical effects, e.g. ultrasonics, irradiation, for disintegrating
    • B02C2019/183Crushing by discharge of high electrical energy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00Structure or properties of graphene
    • C01B2204/02Single layer graphene

Abstract

The invention discloses a kind of continuous production graphene device, including frame, once mounting has motor to the machine frame inside from the bottom to top, separator box, charging box and condenser box, insulating lid is provided with the top of the separator box, centrifugal pan is provided with inside the separator box, the centrifugal pan is provided with rotary bistrique, stationary bistrique is provided with the top of the rotary bistrique, the stationary bistrique is fixedly mounted on insulating lid, and junction is provided with No. two sealing rings, the stationary bistrique lower end is in taper hole shape, the rotary bistrique upper end is in axis of cone shape, and the taper of the axis of cone and the taper of taper hole are equal, the axis of cone of the rotary bistrique upper end is additionally provided with the even liquid bath of rotary bistrique, gland is provided with the top of the stationary bistrique, fluid injection pore is offered inside the stationary bistrique, connection ascending pipe at the top of the fluid injection pore, the ascending pipe runs through gland.Apparatus of the present invention overall structure is simple and convenient to operate, and less energy consumption, yield are high, lightweight, non-environmental-pollution, can realize graphene separation, the continuous production of purification.

Description

A kind of continuous production graphene device
Technical field
The present invention relates to technical field of novel materials, more particularly to a kind of continuous production graphene device.
Background technology
The production of graphene, traditional handicraft has mechanical stripping method, expanded graphite graft process;Mechanical stripping method workload is big, Efficiency is low, and production graphene cost is high, and graphene can not be widely applied.Expanded graphite graft process produces graphene, production technology Numerous rope, in expanded graphite production process, intercalator is done using strong corrosive material, is produced in enormous quantities, and local environment is polluted It is larger, it is impossible to popularization and application.Therefore, a kind of it is proposed that continuous production graphene device.
The content of the invention
It is a primary object of the present invention to provide a kind of continuous production graphene device, effectively it can solve in background technology The problem of.
To achieve the above object, the technical scheme taken of the present invention is:
A kind of continuous production graphene device, including frame, once mounting has motor, separation to the machine frame inside from the bottom to top Be provided with the top of case, charging box and condenser box, the separator box inside insulating lid, the separator box and be provided with centrifugal pan, it is described from Cartridge is provided with the top of rotary bistrique, the rotary bistrique and is provided with stationary bistrique, and the stationary bistrique is fixedly mounted on insulating lid, and connection Place is provided with No. two sealing rings, and the stationary bistrique lower end is in taper hole shape, and the rotary bistrique upper end is in axis of cone shape, and the cone of the axis of cone Degree is equal with the taper of taper hole, and the axis of cone of the rotary bistrique upper end, which is additionally provided with the top of the even liquid bath of rotary bistrique, the stationary bistrique, to be provided with Connection ascending pipe at the top of fluid injection pore, the fluid injection pore is offered inside gland, the stationary bistrique, the ascending pipe is through pressure Lid, the gland is fixed on insulating lid by two groups of screw mandrels, and the part that the ascending pipe is located at gland bottom is equipped with spring, Connection return duct on the inside of the ascending pipe, one end of the return duct connects the bottom of side, the one of the remote fluid injection pore End connection suction line, the side of described suction line one end connection separator box bottom, the insulating lid provided with charging pore, it is described enter Expects pipe hole is connected with charging box by pipeline, and internal described in condenser box to be provided with condenser pipe, described condenser pipe one end is run through and prolonged Extend inside separator box, the condenser pipe other end connects condensator outlet, the centrifugation tray bottom is connected with motor output shaft, And junction, provided with a sealing ring, the motor output shaft outside is provided with slip ring.
Further, the stationary bistrique is connected with an electrode wires, and the rotary bistrique is connected with conductor wire, the conductor wire One end connects No. two electrode wires, the machine frame inside and is provided with carbon brush with slip ring correspondence position.
Further, the Pipe installing has a valve, and the ascending pipe is provided with No. three valves, the suction line peace Equipped with circulating pump, the return duct is provided with No. two valves.
Further, the side of the separator box bottom is provided with drainage tube, and the side is provided with capping, described and capping Connection is screwed, and junction is provided with leak-proof washer.
Further, it is provided with inside the charging box at the top of mixed liquor, the charging box and is provided with charge door, the condenser Cooling fluid is housed, the part that the condenser pipe is located inside condenser box is provided with fin inside case.
Compared with prior art, the present invention has the advantages that:Apparatus of the present invention overall structure is simple, operation side Just, and less energy consumption, yield is high, lightweight, non-environmental-pollution, graphene separation, the continuous production of purification can be realized.
Brief description of the drawings
Fig. 1 is a kind of overall structure diagram of continuous production graphene device of the present invention.
Fig. 2 is a kind of internal structure schematic diagram of continuous production graphene device of the present invention.
In figure:1st, frame;2nd, charge door;3rd, charging box;4th, mixed liquor;5th, pipeline;6th, a valve;7th, an electrode Line;8th, stationary bistrique;9th, insulating lid;10th, pore is fed;11st, fluid injection pore;12nd, separator box;13rd, rotary bistrique;14th, centrifugal pan; 15th, drainage tube;16th, a sealing ring;17th, conductor wire;18th, slip ring;19th, motor;20th, carbon brush;21st, No. two electrode wires;22nd, two Number valve;23rd, the even liquid bath of rotary bistrique;24th, cover;25th, condenser pipe;26th, circulating pump;27th, No. two sealing rings;28th, screw mandrel;29、 Spring;30th, gland;31st, ascending pipe;32nd, condensator outlet;33rd, fin;34th, cooling fluid;35th, condenser box;36th, No. three Valve;37th, suction line;38th, return duct.
Embodiment
To be easy to understand the technical means, the inventive features, the objects and the advantages of the present invention, with reference to Embodiment, is expanded on further the present invention.
As shown in Figure 1-2, from the bottom to top one inside a kind of continuous production graphene device, including frame 1, the frame 1 Secondary to be provided with motor 19, separator box 12, charging box 3 and condenser box 35, the top of separator box 12 is provided with insulating lid 9, described The inside of separator box 12 is provided with centrifugal pan 14, and the centrifugal pan 14 is provided with rotary bistrique 13, and the top of rotary bistrique 13 is provided with fixed mill First 8, the stationary bistrique 8 is fixedly mounted on insulating lid 9, and junction, provided with No. two sealing rings 27, the lower end of stationary bistrique 8 is in Taper hole shape, the upper end of rotary bistrique 13 is in axis of cone shape, and the taper of the axis of cone and the taper of taper hole are equal, the rotary bistrique 13 The axis of cone of upper end is additionally provided with the even liquid bath 23 of rotary bistrique, and the top of stationary bistrique 8, which is provided with inside gland 30, the stationary bistrique 8, to be opened up There is fluid injection pore 11, the top of the fluid injection pore 11 connection ascending pipe 31, the ascending pipe 31 runs through gland 30, the gland 30 It is fixed on by two groups of screw mandrels 28 on insulating lid 9, the part that the ascending pipe 31 is located at the bottom of gland 30 is equipped with spring 29, institute The inner side of ascending pipe 31 connection return duct 38 is stated, one end of the return duct 38 connects the bottom of 12 sides, and described 31 away from fluid injection One end connection suction line 37 of pore 11, the side of the one end of suction line 37 connection separator box 12 bottom, the insulating lid 9 is set There is charging pore 10, the charging pore 10 is connected with charging box 3 by pipeline 5, and 35 inside are provided with condensation described in condenser box Pipe 25, described one end of condenser pipe 25 is through 9 and extends to inside separator box 12, and the other end of the condenser pipe 25 connection condenser goes out Mouth 32, the bottom of centrifugal pan 14 is connected with the output shaft of motor 19, and junction, provided with a sealing ring 16, the motor 19 is defeated Slip ring 18 is provided with the outside of shaft.
A kind of continuous production graphene device of the invention, during work, by an electrode wires 7, No. two electrode wires 21 and motor 19 switch on power, can normal work, mixed liquor 4 is added in charging box 3 by charge door 2, number valve 6 of turn will Mixed liquor 4 adds separator box 12 by pipeline 5, and a number valve 6 of adjustment makes mixed liquor 4 enter the flow of separator box 12 and graphene stream Go out the flow of separator box 12 impartial, start circulating pump 26 4 point of two tunnel of mixed liquor in separator box 12, graphite stationary bistrique is injected all the way 8, spray in the crack between graphite stationary bistrique 8 and graphite rotary bistrique 13, another road enters return duct 38 and rinses stirring separation Mixed liquor 4 in case 12, starts the motor 19 of graphite rotary bistrique 13, makes graphite rotary bistrique 13 in the tapered hole of graphite stationary bistrique 8 Rotate at a high speed, using one group of graphite rotary bistrique 13, the stationary bistrique 8 of close contact, fluid injection pore 11 is drilled with stationary bistrique 8, from Fluid injection pore 11 pressurization injection graphite solution, rotary bistrique 13 add power drive under rotate at a high speed, by graphite rotary bistrique 13, Apply electric field respectively in stationary bistrique 8, the graphite particle in graphite solution is continuously broken up using the electric arc in electric field, is broken The centrifugal pan 14 that graphite particle is installed by rotary bistrique 13 rotates at a high speed the centrifugal force separate of generation, the larger graphite of particle diameter The fluid injection pore 11 that powder solution injects stationary bistrique 8 through circulating pump 26 enters to be continued to break up in the crack of two bistriques, and electric arc is broken up The condensed pipe 25 of the less gaseous state thing of graphite particle diameter flows into container, and the liquid that condensed pipe 25 is flowed into container after liquefying is just Single-layer graphene mixed solution, in the continuous cyclic process of graphite solution, by rotary bistrique 13 centrifuge out it is thick Graphene mixture can be bonded at the inwall of separator box 12, be bonded at the inwall of separator box 12 it is thick be exactly graphite and graphene mixing Thing, graphite and multi-layer graphene mixture are rinsed through high pressure reflow mixed liquor, the graphite particle in the graphite solution not being breached Stationary bistrique 8 is again introduced into through circulating pump 26 to continue to break up, breaking up graphite particle and multi-layer graphene with multi-layer graphene relic During relic, multi-layer graphene relic is smaller because of resistance, in rotary bistrique 13, the electric field crack of stationary bistrique 8, the electric field being subject to Power is maximum, breaks up speed and breaks up speed more than graphite particle, until the graphite particle in graphite solution is converted to multilayer -- Single-layer graphene solution, while in sealing container inwall formation multi-layer graphene paste, completing graphite and directly producing graphene Flow.
Wherein, the stationary bistrique 8 is connected with an electrode wires 7, and the rotary bistrique 13 is connected with conductor wire 17, the conduction The one end of line 17 connects No. two electrode wires 21, the inside of the frame 1 and is provided with carbon brush 20 with the correspondence position of slip ring 18, by by one Number electrode wires 7 and No. two electrode wires 21 switch on power, and make stationary bistrique 8 and the formation electric field of rotary bistrique 13.
Wherein, the pipeline 5 is provided with a valve 6, and the ascending pipe 31 is provided with No. three valves 36, the suction line 37 are provided with circulating pump 26, and the return duct 38 is provided with No. two valves 22, adjust a valve 6, make a flow of valve 6 and Condensator outlet 32 keeps impartial, No. two valves 22 of adjustment, the flow of No. three valves 36, makes graphite stationary bistrique 8 and the dynamic mill of graphite Solution pressure and the pressure of spring 29 between first 13 keep impartial.
Wherein, the side of the bottom of separator box 12 is provided with drainage tube 15, and 12 side is provided with capping 24, described 12 Connection is screwed with capping 24, and junction is provided with leak-proof washer.
Wherein, the inside of charging box 3 is provided with mixed liquor 4, and the top of charging box 3 is provided with charge door 2, the condenser The inside of case 35 is equipped with cooling fluid 34, and the part that the condenser pipe 25 is located inside condenser box 35 is provided with fin 33.
In the present invention, graphite stationary bistrique 8 and the friction contact surface of graphite rotary bistrique 13 make planar shaped, live meaning taper angle Shape, has no effect on the application of the technology of the present invention.
In the present invention, graphite stationary bistrique 8 and the installation site of graphite rotary bistrique 13 are exchanged, and have no effect on the technology of the present invention Using.
In the present invention, graphite stationary bistrique 8 and graphite rotary bistrique 13 installation direction in machine frame are arbitrarily selected, not Influence the application of the technology of the present invention.
In the present invention, the graphite powder in mixed liquor 4, can select the graphite that any carbon structure is constituted, has no effect on The application of the technology of the present invention.
In the present invention, the solution in mixed liquor 4, can select aqueous, oiliness, organic matter, inorganic matter, has no effect on this hair The application of bright technology.
In the present invention, the concentration of mixed liquor 4 is large and small, and the pressure that circulating pump 26 is produced is high and low, has no effect on the present invention The application of technology.
In the present invention, the electric field between graphite stationary bistrique 8 and graphite rotary bistrique 13, can select alternating current, direct current, change Frequency electricity, electrostatic, have no effect on the application of the technology of the present invention.
In the present invention, from the intensity of electric field, graphite rotary bistrique 13 between graphite stationary bistrique 8 and graphite rotary bistrique 13 Rotating speed speed, has no effect on the application of the technology of the present invention.
In the present invention, rotary bistrique 13 used, stationary bistrique 8 can select graphite material, metal material, have no effect on this hair The application of bright technology.
In the present invention, rotary bistrique 13 used, stationary bistrique 8 can single group work, can also it is multigroup with one heart, combine work side by side Make, have no effect on the application of the technology of the present invention.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

1. a kind of continuous production graphene device, including frame(1), it is characterised in that:The frame(1)Internal from the bottom to top one It is secondary that motor is installed(19), separator box(12), charging box(3)And condenser box(35), the separator box(12)Top is provided with exhausted Edge lid(9), the separator box(12)Inside is provided with centrifugal pan(14), the centrifugal pan(14)Rotary bistrique is installed(13), it is described Rotary bistrique(13)Top is provided with stationary bistrique(8), the stationary bistrique(8)It is fixedly mounted on insulating lid(9)On, and junction is provided with two Number sealing ring(27), the stationary bistrique(8)Lower end is in taper hole shape, the rotary bistrique(13)Upper end is in axis of cone shape, and the axis of cone Taper and taper hole taper it is equal, the rotary bistrique(13)The axis of cone of upper end is additionally provided with the even liquid bath of rotary bistrique(23), it is described fixed Bistrique(8)Top is provided with gland(30), the stationary bistrique(8)Inside offers fluid injection pore(11), the fluid injection pore(11) Top connects ascending pipe(31), the ascending pipe(31)Through gland(30), the gland(30)Pass through two groups of screw mandrels(28)Gu It is scheduled on insulating lid(9)On, the ascending pipe(31)Positioned at gland(30)The part of bottom is equipped with spring(29), the ascending pipe (31)Inner side connects return duct(38), the return duct(38)One end connection(12)The bottom of side, it is described(31)Away from note Liquid pipe hole(11)One end connection suction line(37), the suction line(37)One end connects separator box(12)The side of bottom, institute State insulating lid(9)Provided with charging pore(10), the charging pore(10)And charging box(3)Pass through pipeline(5)It is connected, condenser Described in case(35)Inside is provided with condenser pipe(25), the condenser pipe(25)One end is run through(9)And extend to separator box(12)Inside, The condenser pipe(25)The other end connects condensator outlet(32), the centrifugal pan(14)Bottom and motor(19)Output shaft connects Connect, and junction is provided with a sealing ring(16), the motor(19)Slip ring is provided with the outside of output shaft(18).
2. a kind of continuous production graphene device according to claim 1, it is characterised in that:The stationary bistrique(8)Connection There are an electrode wires(7), the rotary bistrique(13)It is connected with conductor wire(17), the conductor wire(17)One end connects No. two electrodes Line(21), the frame(1)Internal and and slip ring(18)Correspondence position is provided with carbon brush(20).
3. a kind of continuous production graphene device according to claim 1, it is characterised in that:The pipeline(5)It is provided with A number valve(6), the ascending pipe(31)No. three valves are installed(36), the suction line(37)Circulating pump is installed(26), The return duct(38)No. two valves are installed(22).
4. a kind of continuous production graphene device according to claim 1, it is characterised in that:The separator box(12)Bottom Side drainage tube is installed(15), it is described(12)Side is provided with capping(24), it is described(12)And capping(24)It is solid by screw Fixed connection, and junction is provided with leak-proof washer.
5. a kind of continuous production graphene device according to claim 1, it is characterised in that:The charging box(3)It is internal Provided with mixed liquor(4), the charging box(3)Top is provided with charge door(2), the condenser box(35)Inside is equipped with cooling fluid (34), the condenser pipe(25)Positioned at condenser box(35)Internal part is provided with fin(33).
CN201710522934.5A 2017-06-30 2017-06-30 A kind of continuous production graphene device Active CN107311162B (en)

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CN107892294A (en) * 2017-12-31 2018-04-10 周思齐 The method and apparatus that high purity graphite rod produces graphene
CN108238598A (en) * 2018-04-20 2018-07-03 上海地霸电子科技有限公司 A kind of mechanical device of continuous production graphene
CN109809395A (en) * 2019-01-22 2019-05-28 上海地霸电子科技有限公司 A kind of graphite directly produces the method and device of graphene composite particulate material
CN111320163A (en) * 2018-12-17 2020-06-23 上海地霸电子科技有限公司 Graphene mixed solution preparation device and method and mixed solution
CN111318242A (en) * 2018-12-17 2020-06-23 上海地霸电子科技有限公司 Graphene composite material preparation device and method and composite material
CN112236026A (en) * 2020-09-30 2021-01-15 扬州斯帕克实业有限公司 Graphene composite wave-absorbing preparation device and coating agent prepared by using same
CN114014309A (en) * 2021-12-13 2022-02-08 哈尔滨盛世康虹生物技术有限公司 Water-soluble graphene production equipment and method based on electric field melting
WO2023115152A1 (en) * 2021-12-23 2023-06-29 2MS Mining Pty Ltd Apparatus and process for processing materials

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107892294A (en) * 2017-12-31 2018-04-10 周思齐 The method and apparatus that high purity graphite rod produces graphene
CN108238598A (en) * 2018-04-20 2018-07-03 上海地霸电子科技有限公司 A kind of mechanical device of continuous production graphene
CN111320163A (en) * 2018-12-17 2020-06-23 上海地霸电子科技有限公司 Graphene mixed solution preparation device and method and mixed solution
CN111318242A (en) * 2018-12-17 2020-06-23 上海地霸电子科技有限公司 Graphene composite material preparation device and method and composite material
CN109809395A (en) * 2019-01-22 2019-05-28 上海地霸电子科技有限公司 A kind of graphite directly produces the method and device of graphene composite particulate material
CN112236026A (en) * 2020-09-30 2021-01-15 扬州斯帕克实业有限公司 Graphene composite wave-absorbing preparation device and coating agent prepared by using same
CN114014309A (en) * 2021-12-13 2022-02-08 哈尔滨盛世康虹生物技术有限公司 Water-soluble graphene production equipment and method based on electric field melting
WO2023115152A1 (en) * 2021-12-23 2023-06-29 2MS Mining Pty Ltd Apparatus and process for processing materials

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