CN107308724A - A kind of dedusting denitrification integral filtrate aftertreatment fluid and its preparation method and application - Google Patents

A kind of dedusting denitrification integral filtrate aftertreatment fluid and its preparation method and application Download PDF

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Publication number
CN107308724A
CN107308724A CN201710763336.7A CN201710763336A CN107308724A CN 107308724 A CN107308724 A CN 107308724A CN 201710763336 A CN201710763336 A CN 201710763336A CN 107308724 A CN107308724 A CN 107308724A
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filtrate
aftertreatment fluid
parts
dedusting
preparation
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CN201710763336.7A
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Chinese (zh)
Inventor
陆勤伟
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Anhui Yuanchen Environmental Protection Science and Technology Co Ltd
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Anhui Yuanchen Environmental Protection Science and Technology Co Ltd
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Priority to CN201710763336.7A priority Critical patent/CN107308724A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/08Filter cloth, i.e. woven, knitted or interlaced material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0464Impregnants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0471Surface coating material
    • B01D2239/0492Surface coating material on fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filtering Materials (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of dedusting denitrification integral filtrate aftertreatment fluid, following component is included:Manganese nitrate solution, cerous nitrate, ammonium metavanadate, ammonium paratungstate, stearic acid and polyethylene glycol oxide.In addition, present invention also offers the preparation method and application of the filtrate aftertreatment fluid.It can make filtrate while having dedusting and denitration function after the filtrate aftertreatment fluid processing filtrate that the present invention is provided, improve filter efficiency and the service life of filtrate, and flue gas purification system can be simplified, save substantial amounts of human and material resources resource.

Description

A kind of dedusting denitrification integral filtrate aftertreatment fluid and its preparation method and application
Technical field
The present invention relates to a kind of filtrate processing technology field, a kind of dedusting denitrification integral filtrate post processing is more particularly to Liquid and its preparation method and application.
Background technology
Atmosphere pollution is essentially from the burning of the fuel such as coal-burning power plant, cement plant, waste incineration, wherein pollution products bag Include dust, NOx, SOx etc..The tail flue gas cleaning system of traditional large-scale fuel burner is by dust arrester, flue gas desulfurization Device and equipment for denitrifying flue gas composition.Generally, dust arrester is only used for chalk dust removing, and flue gas desulfurization device is only used for removing SOx, Equipment for denitrifying flue gas is only used for removing NOx, and this flue gas purification system being made up of a variety of simple function devices will necessarily be made Into the defect such as instrument and equipment is complicated, fund input is big, operation expense is high.
Sack cleaner is a kind of efficient dedusting technology, and in China, cement industry is used widely, and is mainly used to mend The non-fiber dust that collection is tiny, dry;The filtrate of sack cleaner can use various material, wherein PTFE (polytetrafluoroethyl-nes Alkene) with PPS (polyphenylene sulfide) composite filtering material it is a kind of cost performance very high conventional filtrate.Low-temperature selective catalytic reduction denitration skill Art (low temperature NH3-SCR technologies) is a kind of potential gas denitrifying technology, is used at present by many manufacturing enterprises.Low temperature NH3- SCR technology is typically disposed in before sack cleaner, in catalyst denitrification process, and the escaping of ammonia phenomenon occurs once in a while, causes NOx It is diffused into bag-type dust link;Simultaneously when humidity of flue gas is higher, the oxidizing gas in flue gas is easily combined with water, in conduct The fiber surface of the filter bag of the core component of sack cleaner condenses into sour dew, paste bag phenomenon occurs, so that deashing inconvenience is caused, Filter efficiency is influenceed, shortens the service life of filtrate.
The content of the invention
The technical problems to be solved by the invention, which are the provision of one kind, can make filtrate while having dedusting and denitration function Dedusting denitrification integral filtrate aftertreatment fluid, its preparation method and application are also provided.
The present invention is to solve above-mentioned technical problem by the following technical programs:
On the one hand, the present invention provides a kind of dedusting denitrification integral filtrate aftertreatment fluid, and the aftertreatment fluid includes such as the following group Point:Manganese nitrate solution, cerous nitrate, ammonium metavanadate, ammonium paratungstate, stearic acid and polyethylene glycol oxide.
Preferably, according to mass fraction meter, the aftertreatment fluid includes following component:30-100 parts of manganese nitrate solution, nitre Sour cerium 10-50 parts, 5-20 parts of ammonium metavanadate, 10-30 parts of ammonium paratungstate, 5-15 parts of stearic acid, 0.5-5 parts of polyethylene glycol oxide.
Preferably, according to mass fraction meter, the aftertreatment fluid includes following component:65 parts of manganese nitrate solution, cerous nitrate 30 parts, 12 parts of ammonium metavanadate, 20 parts of ammonium paratungstate, 10 parts of stearic acid, 3 parts of polyethylene glycol oxide.
On the other hand, the present invention also provides the preparation method of above-mentioned filtrate aftertreatment fluid, and the preparation method includes:
At 20-30 DEG C, cerous nitrate, ammonium metavanadate, ammonium paratungstate, stearic acid are sequentially added into manganese nitrate solution and is gathered Ethylene oxide, is then well mixed, and filtrate aftertreatment fluid is made.
Preferably, the process of the mixing is to be sufficiently mixed in ultrasonic oscillation instrument 10 minutes.
Filtrate aftertreatment fluid provided by the present invention is used to handle filtrate, makes filtrate while having dedusting and denitration function. Specifically, it is achieved by the steps of:
Filtrate is sufficiently impregnated in the filtrate aftertreatment fluid, then thermal finalization is carried out to filtrate, then rapid cooling, system There must be the filtrate of dedusting denitrification integral function.
Preferably, the time of the dipping is 3-10 minutes, and the process of the thermal finalization is to insert filtrate in forming machine Shaped 5-15 minutes with 210-240 DEG C.
The present invention has advantages below compared with prior art:Cause after the filtrate aftertreatment fluid processing filtrate that the present invention is provided Filtrate has the denitration efficiency that low temperature catalyst has concurrently while with dedusting function itself, so as to realize filtrate dedusting The effect of denitrification integral, improves filter efficiency and the service life of filtrate, and can simplify flue gas purification system, saves a large amount of Human and material resources resource.
Embodiment
Embodiments of the invention are elaborated below, the present embodiment is carried out lower premised on technical solution of the present invention Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following implementations Example.
Embodiment 1
A) the preparation of filtrate aftertreatment fluid:
At 20 DEG C, by manganese nitrate solution 100g, cerous nitrate 45g, ammonium metavanadate 9g, ammonium paratungstate 20g, stearic acid 10g, Polyethylene glycol oxide 1g is sequentially added in beaker, is put into ultrasonic oscillation instrument and is sufficiently mixed 10 minutes to uniform, is made after filtrate Treatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
P84 composite filtering materials is sufficiently impregnated in above-mentioned filtrate aftertreatment fluid 5 minutes, then insert in forming machine with 210 DEG C High-temperature shaping 10 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
The test that filter efficiency is carried out to filtrate using the dynamic test platform of AFC-133 filtrates uses activity rating device pair Filtrate carries out the test of denitration efficiency.After tested, the denitration efficiency of aftertreatment fluid processing filtrate is 85%, and filter efficiency is 99.997%, it is fully able to reach the effect of dedusting denitration, realizes dedusting denitrification integral;And without the processing of above-mentioned aftertreatment fluid Filtrate denitration efficiency be 0%, filter efficiency is 99.995%, and the filtrate does not have the performance of denitration, is unsatisfactory for filtrate Dedusting and the requirement of denitration.
Embodiment 2
A) the preparation of filtrate aftertreatment fluid:
At 25 DEG C, by manganese nitrate solution 65g, cerous nitrate 30g, ammonium metavanadate 12g, ammonium paratungstate 20g, stearic acid 10g, Polyethylene glycol oxide 3g is sequentially added in beaker, is put into ultrasonic oscillation instrument and is sufficiently mixed 10 minutes to uniform, is made after filtrate Treatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
P84 composite filtering materials is sufficiently impregnated in above-mentioned filtrate aftertreatment fluid 5 minutes, then insert in forming machine with 220 DEG C High-temperature shaping 10 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after tested, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 86.5%, and filter efficiency is 99.993%, is fully able to reach the effect of dedusting denitration, realizes dedusting denitration one Change.
Embodiment 3
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, by manganese nitrate solution 30g, cerous nitrate 10g, ammonium metavanadate 5g, ammonium paratungstate 10g, stearic acid 5g, poly- Ethylene oxide 0.5g is sequentially added in beaker, is put into ultrasonic oscillation instrument and is sufficiently mixed 10 minutes to uniform, is made after filtrate Treatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
P84 composite filtering materials is sufficiently impregnated in above-mentioned filtrate aftertreatment fluid 10 minutes, then insert in forming machine with 240 DEG C high-temperature shaping 15 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after tested, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 82%, and filter efficiency is 99.994%, is fully able to reach the effect of dedusting denitration, realizes dedusting denitration one Change.
Embodiment 4
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, by manganese nitrate solution 100g, cerous nitrate 50g, ammonium metavanadate 20g, ammonium paratungstate 30g, stearic acid 15g, polyethylene glycol oxide 5g are sequentially added in beaker, are put into ultrasonic oscillation instrument and are sufficiently mixed mixing 10 minutes to uniform, make Obtain filtrate aftertreatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
PTFE is sufficiently impregnated with PPS composite filtering materials in above-mentioned filtrate aftertreatment fluid 10 minutes, then insert in forming machine With 210 DEG C of high-temperature shaping 5 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after testing, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 84%, and filter efficiency is 99.993%, is fully able to reach the effect of dedusting denitration, realizes dedusting denitration one Change.
Embodiment 5
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, by manganese nitrate solution 60g, cerous nitrate 30g, ammonium metavanadate 15g, ammonium paratungstate 20g, stearic acid 10g, Polyethylene glycol oxide 3g is sequentially added in beaker, is put into ultrasonic oscillation instrument and is sufficiently mixed 10 minutes to uniform, is made after filtrate Treatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
PTFE is sufficiently impregnated with PPS composite filtering materials in above-mentioned filtrate aftertreatment fluid 10 minutes, then insert in forming machine With 220 DEG C of high-temperature shapings 10 minutes, aftertreatment fluid processing filtrate was made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after testing, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 83%, and filter efficiency is 99.998%, is fully able to reach the effect of dedusting denitration, realizes dedusting denitration one Change.
Comparative example 1
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, by manganese nitrate solution 15g, cerous nitrate 5g, ammonium metavanadate 15g, ammonium paratungstate 2.5g, stearic acid 9g, Polyethylene glycol oxide 0.15g is sequentially added in beaker, is put into ultrasonic oscillation instrument and is sufficiently mixed uniform, obtained filtrate post processing Liquid.
B) aftertreatment fluid handles the preparation of filtrate:
P84 composite filtering materials is sufficiently impregnated in above-mentioned filtrate aftertreatment fluid 10 minutes, then insert in forming machine with 210 DEG C High-temperature shaping 7 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after tested, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 69%, and filter efficiency is 99.995%.Denitration efficiency is relatively low, it is impossible to guarantee to ensure the effect of denitration.Rely on In the dustproof function of filtrate in itself, its filter efficiency is ideal.
Comparative example 2
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, by manganese nitrate solution 60g, ammonium metavanadate 15g, ammonium paratungstate 3g, stearic acid 5g, polyethylene glycol oxide 3g Sequentially add in beaker, be put into ultrasonic oscillation instrument and be sufficiently mixed uniform, obtained filtrate aftertreatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
PTFE is sufficiently impregnated with PPS composite filtering materials in above-mentioned filtrate aftertreatment fluid 15 minutes, then insert in forming machine With 200 DEG C of high-temperature shaping 10 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after tested, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 65%, and filter efficiency is 99.993%.Denitration efficiency is relatively low, it is impossible to guarantee to ensure the effect of denitration.Rely on In the dustproof function of filtrate in itself, its filter efficiency is ideal.
Comparative example 3
A) the preparation of filtrate aftertreatment fluid:
At 30 DEG C, ammonium metavanadate 10g, ammonium paratungstate 20g, stearic acid 10g, polyethylene glycol oxide 5g sequentially add beaker In, it is put into ultrasonic oscillation instrument and is sufficiently mixed uniform, obtained filtrate aftertreatment fluid.
B) aftertreatment fluid handles the preparation of filtrate:
PTFE is sufficiently impregnated with PPS composite filtering materials in above-mentioned filtrate aftertreatment fluid 15 minutes, then insert in forming machine With 210 DEG C of high-temperature shaping 7 minutes, aftertreatment fluid processing filtrate is made in then rapid cooling.
C) dedusting of filtrate and denitration efficiency test:
Dedusting and the denitration efficiency of filtrate are tested according to the method for embodiment 1, after tested, aftertreatment fluid handles the de- of filtrate Nitre efficiency is 45%, and filter efficiency is 99.991%.Denitration efficiency is relatively low, it is impossible to guarantee to ensure the effect of denitration.Rely on In the dustproof function of filtrate in itself, its filter efficiency is ideal.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.

Claims (8)

1. a kind of dedusting denitrification integral filtrate aftertreatment fluid, it is characterised in that the aftertreatment fluid includes following component:Nitric acid Manganese solution, cerous nitrate, ammonium metavanadate, ammonium paratungstate, stearic acid and polyethylene glycol oxide.
2. filtrate aftertreatment fluid according to claim 1, it is characterised in that according to mass fraction meter, the aftertreatment fluid Include following component:30-100 parts of manganese nitrate solution, 10-50 parts of cerous nitrate, 5-20 parts of ammonium metavanadate, 10-30 parts of ammonium paratungstate, 5-15 parts of stearic acid, 0.5-5 parts of polyethylene glycol oxide.
3. filtrate aftertreatment fluid according to claim 2, it is characterised in that according to mass fraction meter, the aftertreatment fluid Include following component:65 parts of manganese nitrate solution, 30 parts of cerous nitrate, 12 parts of ammonium metavanadate, 20 parts of ammonium paratungstate, 10 parts of stearic acid, 3 parts of polyethylene glycol oxide.
4. the preparation method of the filtrate aftertreatment fluid any one of claims 1 to 3, it is characterised in that the preparation side Method includes:
At 20-30 DEG C, cerous nitrate, ammonium metavanadate, ammonium paratungstate, stearic acid and polyoxygenated are sequentially added into manganese nitrate solution Ethene, is then well mixed, and filtrate aftertreatment fluid is made.
5. preparation method according to claim 4, it is characterised in that the process of the mixing is in ultrasonic oscillation instrument It is sufficiently mixed 10 minutes.
6. application of the filtrate aftertreatment fluid in processing filtrate any one of claims 1 to 3.
7. application according to claim 6, it is characterised in that the application is achieved by the steps of:
Filtrate is sufficiently impregnated in the filtrate aftertreatment fluid, then thermal finalization is carried out to filtrate, then rapid cooling, is made tool There is the filtrate of dedusting denitrification integral function.
8. application according to claim 7, it is characterised in that the time of the dipping is 3-10 minutes, the thermal finalization Process be by filtrate insert in forming machine with 210-240 DEG C shape 5-15 minutes.
CN201710763336.7A 2017-08-30 2017-08-30 A kind of dedusting denitrification integral filtrate aftertreatment fluid and its preparation method and application Pending CN107308724A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108404520A (en) * 2018-03-12 2018-08-17 江苏新亿源环保科技有限公司 A kind of preparation method of high intensity flue filtering material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104307553A (en) * 2014-09-16 2015-01-28 东营信拓汽车***有限公司 Preparation method of wide-temperature range rare earth-based composite oxide denitration catalyst
CN104941319A (en) * 2015-06-19 2015-09-30 合肥工业大学 Method for preparing manganese-base dedusting and denitration integration function filter material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104307553A (en) * 2014-09-16 2015-01-28 东营信拓汽车***有限公司 Preparation method of wide-temperature range rare earth-based composite oxide denitration catalyst
CN104941319A (en) * 2015-06-19 2015-09-30 合肥工业大学 Method for preparing manganese-base dedusting and denitration integration function filter material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108404520A (en) * 2018-03-12 2018-08-17 江苏新亿源环保科技有限公司 A kind of preparation method of high intensity flue filtering material

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Application publication date: 20171103