CN107303745A - Clad can fibrilia/polypropylene composite board - Google Patents

Clad can fibrilia/polypropylene composite board Download PDF

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Publication number
CN107303745A
CN107303745A CN201610241213.2A CN201610241213A CN107303745A CN 107303745 A CN107303745 A CN 107303745A CN 201610241213 A CN201610241213 A CN 201610241213A CN 107303745 A CN107303745 A CN 107303745A
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China
Prior art keywords
board
poplar
mould
sandwich layer
layer particle
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Granted
Application number
CN201610241213.2A
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Chinese (zh)
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CN107303745B (en
Inventor
董晶
杨庚
陈丽
于鹏飞
徐铭远
李响
沈星月
郁心悦
张鸿燕
陈胜云
张雁飞
徐国锋
隋忠海
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JILIN FOREST INDUSTRY JINQIAO FLOOR GROUP Co Ltd
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JILIN FOREST INDUSTRY JINQIAO FLOOR GROUP Co Ltd
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Priority to CN201610241213.2A priority Critical patent/CN107303745B/en
Publication of CN107303745A publication Critical patent/CN107303745A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/12Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27DWORKING VENEER OR PLYWOOD
    • B27D1/00Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
    • B27D1/04Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
    • B27D1/08Manufacture of shaped articles; Presses specially designed therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27LREMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
    • B27L11/00Manufacture of wood shavings, chips, powder, or the like; Tools therefor
    • B27L11/06Manufacture of wood shavings, chips, powder, or the like; Tools therefor of wood powder or sawdust
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/14Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Forests & Forestry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

A kind of clad can fibrilia/polypropylene composite board, it is characterised in that:Leftover pieces by the use of automotive trim wood-plastic board are used as core material, board using poplar board is pasted respectively up and down to make, mould is placed on a board using poplar board, board using poplar board as sheet material back side facing material, sandwich layer particle is uniformly mated formation in the cavity plate of mould, the sandwich layer particle in cavity plate is compacted by the punch-pin of mould, the punch-pin and cavity plate of mould are removed after compacting, a board using poplar board is put on the sandwich layer particle surface paved, then the composite board paved is put into vulcanizing press, carry out precompressed, it is then placed in another vulcanizing press and carries out hot pressing, slab is transferred in the vulcanizing press used in precompressed after release and cooled down.With antibacterial, formaldehydeless, the advantages of mechanical property is significantly larger than state-set standard;The problem of solving existing flaxen fiber/compound plastic plate poor mechanical property and cumbersome technique.

Description

Clad can fibrilia/polypropylene composite board
Technical field
The present invention relates to a kind of clad can fibrilia/polypropylene composite environment-friendly sheet, belong to environment-friendly building materials field.
Background technology
Composite material of plant fiber, with its unique ecological dominance, highlights powerful development under current recycling economy field Potentiality, and be just developing progressively as emerging industry.Clad can flaxen fiber/poly- is prepared using the leftover pieces of automotive trim wood-plastic board Propylene composite board can not only help the problem of automotive trim enterprise solves waste disposal, realize refuse reclamation, moreover it is possible to Alleviate white pollution.In addition, this sheet material also has the value of recycling.And because this sheet material contains string and height Molecular material, the two-fold advantage with string and high polymer material, it may have and timber identical post-production performance, can Using the processing method of the similar natural timber such as sawing, planing, drilling, grinding, its manufacturing process is simple, it is not necessary to which special adds Construction equipment, wood processing enterprise it goes without doing excessive equipment adjustment and updates the processing that can be achieved to this material.Except this it Outside, surface impulse- free robustness of the veneer of its clad can after grinding is beneficial to follow-up processing.So, clad can fibrilia/polypropylene is combined Sheet material is to meet China's strategy of sustainable development, great notable environmental benefit, the novel green composite of promotional value.
For example, the invention of Application No. 201110267843.4, discloses a kind of orientation flaxen fiber/compound plastic plate Manufacture method, solves existing hot-press method and prepares flaxen fiber/compound plastic plate in mechanics direction controlling difference, flaxen fiber The technology manufacture method that bending makes the technical problem of composite board croop property difference and provided.
But, technical scheme disclosed in foregoing invention can not solve existing flaxen fiber/compound plastic plate poor mechanical property And technique it is cumbersome the problem of.
The content of the invention
Present invention aims at a kind of clad can fibrilia/polypropylene composite board is provided, with antibacterial, formaldehydeless, mechanics The advantages of performance is significantly larger than state-set standard;Solve existing flaxen fiber/compound plastic plate poor mechanical property and technique Cumbersome the problem of.
The technical proposal of the invention is realized in this way:A kind of clad can fibrilia/polypropylene composite board, its feature exists In:By the use of the leftover pieces of automotive trim wood-plastic board as core material, paste board using poplar board respectively up and down and make, its specific steps It is as follows:
(1)Calculated by 2440mm × 1220mm × 8mm specification, when made sheet material core concentration is 0.8g/cm3~1.0g/ cm3When, it is necessary to board using poplar board two, automotive trim wood-plastic board leftover pieces are 6.4kg/m2~7.7kg/m2, coupling agent(The fourth of metatitanic acid four Ester)For 0.20g ~ 0.38g, dispersant(Ethanol)For 1.20g ~ 2.28g;
(2)Suppressed using pressure sintering, select flawless board using poplar board, be placed in constant temperature oven and dry 2 h, then weigh 0.20g ~ 0.38g coupling agent, by coupling agent and dispersant according to 1:6 ratios are mixed, uniform to brush on board using poplar board surface, in 2 h are spontaneously dried under room temperature environment standby;By automotive trim leftover pieces(Abbreviation sandwich layer particle)Crushed, added without any Plus agent and to be placed in the h of natural drying at room temperature 24 standby;Mould is placed on a board using poplar board, board using poplar board is used as sheet material Back side facing material, uniformly mats formation sandwich layer particle in the cavity plate of mould, by the punch-pin of mould that the sandwich layer in cavity plate is broken Material compacting, removes the punch-pin and cavity plate of mould, a board using poplar board is put on the sandwich layer particle surface paved after compacting, then will The composite board paved is put into vulcanizing press, and 8mm finger gauge is put in composite board both sides, carries out precompressed, precompressed pressure Power is 0.1 MPa, the min of time 1;It is then placed in another vulcanizing press and carries out hot pressing, hot pressing temperature is 190 DEG C ~ 210 DEG C, hot pressing pressure is 2Mpa ~ 6Mpa, hot pressing time 5min ~ 9min, sandwich layer particle density 0.8g/cm after compacting3~1.0g/cm3; Slab is transferred in the vulcanizing press used in precompressed after release and cooled down, pressure be 0.1 MPa, the time be 6 min ~ 8min, is cut into after test specimen by national standard requirement and carries out mechanics properties testing.
The positive effect of the present invention is that its equipment is simple;In the absence of complicated technology, technique, the existing production of wood-based plate is utilized Technology can be manufactured;Required clad can board using poplar board is current domestic most common veneer species, and supply is abundant, required each Class chemical reagent has sale on the market, belongs to common chemical reagent;This sheet material contains wood fibre, with timber identical Processing characteristics, manufacturing process is simple;Clad can board using poplar board its surface after grinding is relatively smooth, is conducive to processing.This plate Material Checking of static bending intensity value is about 4 times of set quota value;Modulus of elasticity is about 3 times of setting;Band bonding strength and rule Definite value is close;Rift grain bonding strength is about 3 times of setting;Thickness swelling rate is about the half of setting.The present invention is not Only raw material sources are extensive, cost is low, simple production process, and its good effect is that properties of product are excellent.
Composite board is L using sandwich layer particle density after hot pressing temperature, hot pressing pressure, hot pressing time, compacting as four factors (34) after orthogonal test, and drawn with range method analysis:When hot pressing temperature is 210 DEG C, hot pressing time is 9min, and hot pressing pressure is Sandwich layer particle density is 0.9g/cm after 3MPa, compacting3When, clad can fibrilia/polypropylene composite board good mechanical properties, property The Some Mechanical Properties testing result of energy preferably sheet material is as shown in table 1.
Brief description of the drawings
Fig. 1 is clad can fibrilia/polypropylene composite board of the present invention, and 1,3 be board using poplar board, and 2 be sandwich layer particle.
Fig. 2 is clad can fibrilia/polypropylene composite board process chart of the present invention.
Embodiment
The present invention will be further described with reference to the accompanying drawings and examples:
Embodiment 1
(1)It is that 2440mm × 1220mm × 8mm is calculated by specification, when made sheet material core concentration is 0.8g/cm3~1.0g/ cm3When, it is necessary to board using poplar board two, automotive trim wood-plastic board leftover pieces are 6.4kg/m2~7.7kg/m2, coupling agent(The fourth of metatitanic acid four Ester)For 0.20g ~ 0.38g, dispersant(Ethanol)For 1.20g ~ 2.28g.
(2)Clad can fibrilia/polypropylene composite board is suppressed using pressure sintering, its preparation technology flow is as shown in Figure 2.Choose Flawless board using poplar board is selected, is placed in constant temperature oven and dries 2 h, then weigh 0.38g coupling agent, by coupling agent with disperseing Agent is according to 1:6 ratios are mixed, uniform to brush on board using poplar board surface, standby in spontaneously drying 2 h under room temperature environment;By in automobile Edging corner material(Abbreviation sandwich layer particle)Crushed, without any additive and to be placed in the h of natural drying at room temperature 24 standby;Will Mould is placed on a board using poplar board, and board using poplar board uniformly mats formation sandwich layer particle as the back side facing material of sheet material In the cavity plate of mould, the sandwich layer particle in cavity plate is compacted by the punch-pin of mould, the punch-pin and cavity plate of mould are removed after compacting, A board using poplar board is put on the sandwich layer particle surface paved, then the composite board paved is put into vulcanizing press, 8mm finger gauge is put in composite board both sides, carries out precompressed, and preload pressure is 0.1 MPa, the min of time 1;It is then placed in another Hot pressing is carried out in platform vulcanizing press, hot pressing temperature is 210 DEG C, and hot pressing pressure is 6Mpa, and hot pressing time 9min, sandwich layer particle is close Spend 1.0g/cm3;Slab is transferred in the vulcanizing press used in precompressed after release and cooled down, pressure is 0.1 MPa, when Between be 6 min ~ 8min, be cut into by national standard requirement after test specimen and carry out mechanics properties testing.
Embodiment 2
Flawless board using poplar board is selected as shown in Figure 1, is placed in constant temperature oven and dries 2 h, then adds 0.20g metatitanic acid four Butyl ester, by butyl titanate and ethanol according to 1:6 ratios are mixed, uniform to brush on board using poplar board surface, under room temperature environment from So dry 2 h standby;By automotive trim leftover pieces(Abbreviation sandwich layer particle)Crushed, room temperature is placed in certainly without any filling So dry 24 h standby;Mould is placed on a board using poplar board, board using poplar board as sheet material back side facing material, core Layer particle is uniformly mated formation in the cavity plate of mould, is compacted the sandwich layer particle in cavity plate by the punch-pin of mould, is removed after compacting The punch-pin and cavity plate of mould, put a board using poplar board, then by the composite board paved on the sandwich layer particle surface paved It is put into vulcanizing press, 8mm finger gauge is put in composite board both sides, carries out precompressed, preload pressure is 0.1 MPa, time 1 min;It is then placed in another vulcanizing press and carries out hot pressing, hot pressing temperature is 190 DEG C, and hot pressing pressure is 2Mpa, during hot pressing Between 5min, sandwich layer particle density 0.8g/cm3;Slab is transferred in the vulcanizing press used in precompressed after release and cooled down, Pressure is 0.1 MPa, and the time is 6 min, is cut into by national standard requirement after test specimen and carries out mechanics properties testing.
Embodiment 3
As shown in Figure 1, 2, flawless board using poplar board is selected, is placed in constant temperature oven and dries 2 h, then weigh 0.28g titanium Sour four butyl esters, by butyl titanate and ethanol according to 1:6 ratios are mixed, and are uniformly brushed on board using poplar board surface, in room temperature environment 2 h of lower natural drying are standby;By automotive trim leftover pieces(Abbreviation sandwich layer particle)Crushed, without any additive and put It is standby in the h of natural drying at room temperature 24;Mould is placed on a board using poplar board, board using poplar board as sheet material back side clad can Material, uniformly mats formation sandwich layer particle in the cavity plate of mould, is compacted the sandwich layer particle in cavity plate by the punch-pin of mould, pressure The punch-pin and cavity plate of mould are removed after reality, on the sandwich layer particle surface paved a board using poplar board is put, then will be paved Composite board is put into vulcanizing press, and 8mm finger gauge is put in composite board both sides, carries out precompressed, preload pressure is 0.1 MPa, the min of time 1;It is then placed in another vulcanizing press and carries out hot pressing, hot pressing temperature is 200 DEG C, hot pressing pressure is 4Mpa, hot pressing time 7min, sandwich layer particle density 0.9g/cm3;Slab is transferred to the vulcanizing press used in precompressed after release Middle to be cooled down, pressure is 0.1 MPa, and the time is 7min, is cut into by national standard requirement after test specimen and carries out mechanics properties testing.

Claims (1)

1. a kind of clad can fibrilia/polypropylene composite board, it is characterised in that:By the use of automotive trim wood-plastic board leftover pieces as Core material, pastes board using poplar board and makes, it is comprised the following steps that respectively up and down:
(1)Calculated by 2440mm × 1220mm × 8mm specification, when made sheet material core concentration is 0.8g/cm3~1.0g/cm3 When, it is necessary to board using poplar board two, automotive trim wood-plastic board leftover pieces are 6.4kg/m2~7.7kg/m2, coupling agent(Butyl titanate) For 0.20g ~ 0.38g, dispersant(Ethanol)For 1.20g ~ 2.28g;
(2)Suppressed using pressure sintering, select flawless board using poplar board, be placed in constant temperature oven and dry 2 h, then weigh 0.20g ~ 0.38g coupling agent, by coupling agent and dispersant according to 1:6 ratios are mixed, uniform to brush on board using poplar board surface, in 2 h are spontaneously dried under room temperature environment standby;By automotive trim leftover pieces(Abbreviation sandwich layer particle)Crushed, added without any Plus agent and to be placed in the h of natural drying at room temperature 24 standby;Mould is placed on a board using poplar board, board using poplar board is used as sheet material Back side facing material, uniformly mats formation sandwich layer particle in the cavity plate of mould, by the punch-pin of mould that the sandwich layer in cavity plate is broken Material compacting, removes the punch-pin and cavity plate of mould, a board using poplar board is put on the sandwich layer particle surface paved after compacting, then will The composite board paved is put into vulcanizing press, and 8mm finger gauge is put in composite board both sides, carries out precompressed, precompressed pressure Power is 0.1 MPa, the min of time 1;It is then placed in another vulcanizing press and carries out hot pressing, hot pressing temperature is 190 DEG C ~ 210 DEG C, hot pressing pressure is 2Mpa ~ 6Mpa, hot pressing time 5min ~ 9min, sandwich layer particle density 0.8g/cm3~1.0g/cm3;After release Slab is transferred in the vulcanizing press used in precompressed and cooled down, pressure is 0.1 MPa, the time is 6 min ~ 8min, is pressed National standard requirement, which is cut into after test specimen, carries out mechanics properties testing.
CN201610241213.2A 2016-04-19 2016-04-19 Clad can fibrilia/polypropylene composite board Active CN107303745B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111015842A (en) * 2019-12-18 2020-04-17 南宁科天水性科技有限责任公司 Composite new material veneer ecological board and manufacturing method thereof
CN112497693A (en) * 2020-09-14 2021-03-16 广东中晨电子科技有限公司 Preparation method and system of film-coated base plate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5439749A (en) * 1994-08-18 1995-08-08 Andersen Corporation Composite wood structure
CN101537652A (en) * 2009-04-29 2009-09-23 西北农林科技大学 Wood-plastic reconstituted wood and fabricating method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5439749A (en) * 1994-08-18 1995-08-08 Andersen Corporation Composite wood structure
CN101537652A (en) * 2009-04-29 2009-09-23 西北农林科技大学 Wood-plastic reconstituted wood and fabricating method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111015842A (en) * 2019-12-18 2020-04-17 南宁科天水性科技有限责任公司 Composite new material veneer ecological board and manufacturing method thereof
CN112497693A (en) * 2020-09-14 2021-03-16 广东中晨电子科技有限公司 Preparation method and system of film-coated base plate

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