CN107298936A - Vacuum coating scumbling priming paint ultraviolet-curing paint - Google Patents
Vacuum coating scumbling priming paint ultraviolet-curing paint Download PDFInfo
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- CN107298936A CN107298936A CN201710602033.7A CN201710602033A CN107298936A CN 107298936 A CN107298936 A CN 107298936A CN 201710602033 A CN201710602033 A CN 201710602033A CN 107298936 A CN107298936 A CN 107298936A
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- scumbling
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- paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/10—Esters of organic acids
- C09D101/14—Mixed esters, e.g. cellulose acetate-butyrate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a kind of vacuum coating scumbling priming paint ultraviolet-curing paint, it includes the component of following parts by weight：1 ~ 8 part of two functional aliphatic's urethane acrylate, 1 ~ 10 part of acetylbutyrylcellulose, 1 ~ 8 part of six functional aliphatic's urethane acrylate, 0.1 ~ 1.0 part of light trigger, 0.1 ~ 1.0 part of organosiloxane levelling agent, 74 ~ 97 parts of diluents.When the vacuum coating scumbling priming paint ultraviolet-curing paint that the present invention is provided is by adding acetylbutyrylcellulose so that vacuum coating scumbling priming paint forms the prime coat of 0.4 ~ 2 micron of thickness on material surface, the covering power of paint film and upper plating can be provided, strengthen the adhesive force of paint film, significantly reduce cure shrinkage, increase UV curing systems viscosity and thixotropy, cured paint film can be made to become tough and tensile, increase its impact resistance and vibration anti-wear performance.The present invention efficiently solves the adhesive force and vibration anti-wear performance of vacuum coating scumbling priming paint ultraviolet-curing paint.
Description
Technical field
The invention belongs to chemical coating field, solidify in particular to a kind of vacuum coating scumbling priming paint ultraviolet light and apply
Material.
Background technology
With the development of decorative plastic technology, a kind of plastic products metallization decoration technique is produced therewith, and it is to utilize modeling
Expect after base material coating prime lacquer, through vacuum plating, application layer of metal film layer is coated with finish paint and formed.By the plastics of application
Surface, flashes metallic luster completely, shows noble and magnificent metal quality, does not see it being plastic products at all.Modeling
The metallization decoration of material can not only save the metal material of a large amount of preciousnesses, also significantly reduce quality of item, change in recent years
Extensive accreditation is obtained in the manufacture such as cosmetic Packaging Bottle and packing box, automobile lamp, mobile phone plastic key, phone housing shell on the back
And application.
Ultraviolet light UV vacuum plating coatings are a kind of new ultra-violet photocurings grown up on the basis of UV plastic paints
Coating.Vacuum coating technology refers under vacuum conditions, certain metal or metallic compound be deposited into modeling in the form of gas phase
Materials and parts surface, belongs to physical gas-phase deposition, is widely used in PC, PP, PE, ABS, the working of plastics such as PMMA.Vacuum coating
Function is mainly to confer to the metallic luster and mirror effect of plastic part surface height, in order to increase the gloss and gold of plastic part surface
Belong to texture, spray one layer of vacuum coating priming paint during application in advance.Plastic part surface is rougher, can obtain smooth by basecoat paint
Smooth mirror effect, is conducive to obtaining uniform vacuum coating metal coating, shows higher gloss and metal-like effect.
As consumer increasingly improves to appearance requirement, plastic part surface occurs in that drawing pattern, texture line, spiral lamination, CD
The figure lines such as line, if the very thick figure lines for having covered plastic part surface of basecoat paint, then these figure lines are just not
It can clearly indicate out in product surface.But in the case of primer painting very thin thickness, it may appear that grease resistance is poor, covering power
Difference, particle is more, and yield is not high, the problems such as poor adhesive force vibration is wear-resisting, so as to influence the performance of whole film layer.
The content of the invention
It is an object of the invention to provide a kind of vacuum coating scumbling priming paint ultraviolet-curing paint, solve prior art and drawing
Silking, texture line, spiral lamination, the figure lines plastic part surface such as CD lines is applied and loaded onto, and scumbling priming paint covering power difference poor adhesive force is shaken
Dynamic wear-resisting poor the problem of.
The purpose of the present invention can be reached by following measures：
A kind of vacuum coating scumbling priming paint ultraviolet-curing paint, it includes the component of following parts by weight：1 ~ 8 part of two function fat
Adoption urethane acrylate, 1 ~ 10 part of acetylbutyrylcellulose, 1 ~ 8 part of six functional aliphatic's urethane acrylate, 0.1 ~
1.0 parts of light triggers, 0.1 ~ 1.0 part of organosiloxane levelling agent, 74 ~ 97 parts of diluents.
In a kind of preferred scheme, this coating includes the component of following parts by weight：2 ~ 4 part of two functional aliphatic's polyurethane third
Olefin(e) acid ester, 1 ~ 6 part of acetylbutyrylcellulose, 2 ~ 4 part of six functional aliphatic's urethane acrylate, 0.1 ~ 0.4 part of light trigger,
0.1 ~ 0.3 part of organosiloxane levelling agent, 86 ~ 95 parts of diluents.
In a kind of more preferably scheme, this coating includes the component of following parts by weight：3 part of two functional aliphatic's polyurethane third
Olefin(e) acid ester, 1 ~ 6 part of acetylbutyrylcellulose, 3 part of six functional aliphatic's urethane acrylate, 0.3 part of light trigger, 0.2 part
Organosiloxane levelling agent, 88 ~ 93 parts of diluents.
Two functional aliphatic's urethane acrylates in the present invention are the UV-3000B closed including but not limited to Japanese day,
6112-100,6152-100 of TaiWan, China Changxing chemistry, the EB230, EB270, EB9260 of Qing Te companies of the U.S., the U.S. are husky more
At least one of CN9001NS of agate company.Such compound has upper plating well and heavily fortified point under the cooperation of other components
Toughness.
Acetylbutyrylcellulose in the present invention is including but not limited to Yi Shiman CAB-511-0.01, CAB-511-
0.2nd, at least one of CAB-381-0.1, CAB-381-0.5, CAB-381-2, CAB-381-20, CAB-531-1, such
Compound is a kind of cellulose esters product obtained by native cellulose through acetylation, is the double bond containing solid fiber of a class
Plain ester resin, molecular weight has a variety of different degrees of bytyries, second between 40000~60000 in its cellulosic polymer chain
Acyl group and hydroxyl, such compound have Stability Analysis of Structures, good weather resisteant, good leveling property, grease resistance under the cooperation of other components
The performance characteristics such as good, tensile strength is high, compression strength is big, heat resistance is good.
Six functional aliphatic's polyurethane acrylic resins in the present invention are the UV- closed including but not limited to Japanese day
7605B, the 6145-100,6161-100, the EB1290 of Qing Te companies of the U.S., EB5129 of TaiWan, China Changxing chemistry, the U.S. is husky
At least one of the CN9013 of Duo Ma companies, CN9010NS, such compound have richness under the cooperation of other components
The features such as high curing rate is fast.
During light trigger in the present invention is benzil class, aroyl phosphine oxide, benzophenone, alkylbenzene ketone
One or more of combinations.
Levelling agent in the present invention is polyether-modified organosiloxane levelling agent, adds lustre to good, increases sliding, levelling
Effect, it is splendid with coating resin system phase mixcibility, in coating material production and work progress, bubble can be suppressed and produce elimination bubble
Hole, does not interfere with interlayer recoatability and adhesive force, promotes ground wetting, prevents shrinkage cavity and pin hole.
Diluent in the present invention is including but not limited to ethyl acetate, methyl iso-butyl ketone (MIBK), isopropanol, ethylene glycol fourth
Ether, acetone, the one or more of combination of DIBK is mainly used for adjusting the volatilization gradient of dicyandiamide solution, increased to master
The dissolubility of body resin, consolidating for adjustment formula contains, and improves the application property of coating.
The preparation method of vacuum coating scumbling priming paint ultraviolet-curing paint of the present invention is：
Step one：The solvent of 1/2 amount of acetylbutyrylcellulose（That is diluent）It is uniformly dispersed after immersion；
Step 2：Six functional groups and two functional group's aliphatic urethane acrylate resins are preheated 1 hour at 50 DEG C, with 1/2
The solvent of amount fully dissolves in a kettle.；
Step 3：Component obtained by step one and step 2 is mixed, is uniformly dispersed；
Step 4：Light trigger and organosiloxane levelling agent will be added in mixed liquor obtained by step 3；
Step 5：Mixed liquor filtering obtained by step 4 is produced.
The vacuum coating scumbling priming paint ultraviolet-curing paint that the present invention is provided by add molecular weight 40000~
Acetylbutyrylcellulose between 60000, causes vacuum coating scumbling priming paint on material surface under the synergy of each component
When forming the prime coat of 0.4 ~ 2 micron of thickness, the figure lines of plastic part surface can be clearly shown, using the teaching of the invention it is possible to provide paint film
Covering power and upper plating, significantly reduce cure shrinkage, strengthen the adhesive force of paint film, increase UV curing systems viscosity and thixotroping
Property, reduce UV coating surfaces to gas, steam, introduced contaminants sensitiveness, cured paint film can be made to become tough and tensile, increase its resist
Impact and vibration anti-wear performance.
Embodiment
Present disclosure is described further with reference to embodiments, but protection scope of the present invention is not limited to
Following embodiment.
Component in following example uses concrete model.Wherein 184 be light trigger.
The preparation method of following example comprises the following steps：
Step one：The solvent of 1/2 amount of acetylbutyrylcellulose（That is diluent）It is uniformly dispersed after immersion；
Step 2：Six functional groups and two functional group's aliphatic urethane acrylate resins are preheated 1 hour at 50 DEG C, with 1/2
The solvent of amount fully dissolves in a kettle.；
Step 3：Component obtained by step one and step 2 is mixed, is uniformly dispersed；
Step 4：Light trigger and organosiloxane levelling agent will be added in mixed liquor obtained by step 3；
Step 5：Mixed liquor filtering obtained by step 4 is produced.
Embodiment 1：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of UV-3000B
1 part of CAB-381-0.1
2 parts of UV-7605B
184 0.3 parts
0.2 part of EFKA-3883
94.5 parts of diluent.
Embodiment 2：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
2 parts of UV-3000B
2 parts of CAB-511-0.01
2 parts of CAB-381-0.1
2 parts of CAB-531-1
2 parts of UV-7605B
2 parts of 6145-100
184 0.3 parts
0.2 part of EFKA-3883
85.5 parts of diluent
Embodiment 3：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
1 part of EB230
2 parts of CAB-511-0.2
2 parts of EB1290
1 part of EB5129
2 parts of CN9010NS
184 0.3 parts
0.2 part of EFKA-3883
91.5 parts of diluent.
Embodiment 4：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
2 parts of CAB-511-0.01
2 parts of CAB-381-0.1
2 parts of CAB-531-1
2 parts of CN9010NS
184 0.3 parts
0.2 part of EFKA-3883
89.5 parts of diluent.
Embodiment 5：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
1 part of EB9260
2 parts of CAB-511-0.01
2 parts of CAB-531-1
2 parts of UV-7605B
1 part of CN9013
184 0.3 parts
0.2 part of EFKA-3883
89.5 parts of diluent.
Performance test is carried out to the vacuum coating scumbling priming paint of above-mentioned each example, it is as a result as follows：
1st, temperature cycles：25 DEG C, 95%RH, 3H is raised to 55 DEG C；95%RH, keeps 9H, and then 3H drops to 25 DEG C；95%RH, keeps
9H, the above is a circulation, is repeated 3 times, after experiment paint film without coming off, crackle, the anomaly, adhesive force >=4B such as discoloration；
2、QUV：Fluorescent tube is UVB313nm, light intensity 0.63W/m2, after temperature 60 C/4H, and 50 DEG C/4H of condensation is a circulation, altogether
12 circulations, after experiment paint film without coming off, crackle, without the substantially anomaly such as discoloration；
3rd, low temperature is stored：- 30 DEG C/6H, -40 DEG C/16H, -30 DEG C/15min, 25 DEG C/2H, after experiment paint film without coming off, crackle,
Anomaly, the adhesive force >=4B such as discoloration；
4th, high temperature storage：55 DEG C/6H, 70 DEG C/16H, 25 DEG C/2H, after experiment paint film without coming off, crackle, the anomaly such as discoloration,
Adhesive force >=4B；
5th, temperature shock：- 40 DEG C, 2H, 70 DEG C, 2H is a circulation, totally 5 circulations, after experiment paint film without coming off, crackle, change
The anomalies such as color, adhesive force >=4B；
6th, pencil hardness：No marking after Mitsubishi's pencil, 1Kg/F, experiment；
7th, resistance to cosmetics test：Vaseline, skin cream is uniformly applied to product surface, and then 25 DEG C, 95%RH, 3H is raised to 55
DEG C, 95%RH keeps 9H, and then 3H drops to 25 DEG C, 95%RH, keeps 9H, is circulating repetition 2 times, then in 25 DEG C, 75%
RH places 2H, after experiment paint film without coming off, crackle, the anomaly, adhesive force >=4B such as discoloration；
8th, resistance to hand perspiration test：Non-dust cloth is soaked with the sweat of PH=6.5 and dabs 2min in sample surfaces, is then placed again under normal temperature
Product is without significant change, adhesive force >=4B after 2H, experiment；
9th, adhesive force：0.4-2 microns of coating film thickness, can clearly show the figure lines of plastic part surface, cross-cut tester with
1.0mm draws 10 × 10, is pulled with 3M610 adhesive tapes 3 times, is 5B after experiment；
10、RCA：175g, 200 times, product is not revealed the exact details after experiment；
11st, salt spray test：In 35 DEG C of closed environments, humidity ＞ 85%, PH is connected between 6.5-7.2 with 5% sodium chloride solution
Continuous spraying 48 hours；Product is without significant change after experiment, and adhesive force test reaches more than 4B；
12nd, vibrate wear-resisting：Product is put into the vibration 2H of resistance to grinding machine, outward appearance falls paint without coming off after experiment.
Comparative example 1：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of UV-3000B
2 parts of UV-7605B
184 0.3 parts
0.2 part of EFKA-3883
95.5 parts of diluent.
Comparative example 2：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
2 parts of UV-3000B
2 parts of UV-7605B
2 parts of 6145-100
184 0.3 parts
0.2 part of EFKA-3883
91.5 parts of diluent.
Comparative example 3：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
1 part of CAB-511-0.2
2 parts of EB1290
1 part of EB5129
2 parts of CN9010NS
184 0.3 parts
0.2 part of EFKA-3883
94.5 parts of diluent
Comparative example 4：
A kind of vacuum coating scumbling priming paint ultraviolet cured paint composition includes following component and parts by weight：
2 parts of CN9001NS
2 parts of CAB-511-0.01
2 parts of CAB-381-0.1
2 parts of CAB-531-1
184 0.3 parts
0.2 part of EFKA-3883
91.5 parts of diluent.
Performance test is carried out to the vacuum coating scumbling priming paint of above-mentioned each comparative example, it is as a result as follows：
The difference of comparative example 1 and embodiment 1 is to lack acetylbutyrylcellulose, and the difference of comparative example 2 and embodiment 2 is lain also in
Lack acetylbutyrylcellulose, this two groups of difference is the composition quantities of acetylbutyrylcellulose, comparative example 1 and comparative example 2
When forming the prime coat of 0.4 ~ 2 micron of thickness on material surface, it is impossible to show the figure lines of plastic part surface, modeling
The figure lines on materials and parts surface is all covered, and loses the decorative effect of coating in itself, in addition without big in coating system
The resin of molecular weight, covering power and grease resistance are bad during spraying, there is little particle and small shrinkage cavity during coating film forming, and vinegar is not added in addition
In the comparative example 1 and comparative example 2 of sour cellulose butyrate, coating system cure shrinkage is high, and the upper plating after coating film forming is bad,
Test adhesive force NG.The difference of comparative example 3 and embodiment 3 is to lack two functional group's aliphatic urethane acrylates, adhered to
Power NG, vibrates wear-resisting NG, and the difference of comparative example 4 and embodiment 4 is to lack six functional groups aliphatic urethane acrylate, applies
Not enough, curing rate is slow, does not react completely, resistance to hand perspiration, salt spray test NG for material solidification crosslink density.
The vacuum coating scumbling primer base application method of the present invention is as follows：
1. spraying：Treated material is sprayed into last layer priming paint, thickness 0.4-2um；
2. infrared levelling：Above-mentioned treated material is toasted into 4-6min under 60 DEG C of environment；
3. ultra-violet curing：By above-mentioned treated material by UV illumination, intensity of illumination is 800-1000mj/cm2, according to technique
Energy needed for condition adjustment.
The coating manufacture craft of the present invention is fairly simple, and each component is added into reactor, is well mixed, by ultraviolet lighting
After penetrating, light trigger is activated, is acted on unsaturated group, triggers a series of polymerisation crosslinking film forming, then by vacuum coating,
The middle painting of appropriate mix and finish paint.
It is emphasized that：Embodiment described above only expresses presently preferred embodiments of the present invention, and it is described more
It is specific and detailed, but the limitation to the scope of the claims of the present invention therefore can not be interpreted as, every technology according to the present invention is real
The technical scheme that confrontation above example is obtained using the form of equivalent substitution or equivalent transformation, still falls within the technology of the present invention
Within the protection domain of scheme.
Claims (8)
1. a kind of vacuum coating scumbling priming paint ultraviolet-curing paint, it is characterised in that it includes the component of following parts by weight：1~
8 part of two functional aliphatic's urethane acrylate, 1 ~ 10 part of acetylbutyrylcellulose, 1 ~ 8 part of six functional aliphatic's polyurethane third
Olefin(e) acid ester, 0.1 ~ 1.0 part of light trigger, 0.1 ~ 1.0 part of organosiloxane levelling agent, 74 ~ 97 parts of diluents.
2. vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1, it is characterised in that it includes as follows
The component of parts by weight：2 ~ 4 part of two functional aliphatic's urethane acrylate, 1 ~ 6 part of acetylbutyrylcellulose, 2 ~ 4 part of six function
Aliphatic urethane acrylate, 0.1 ~ 0.4 part of light trigger, 0.1 ~ 0.3 part of organosiloxane levelling agent, 86 ~ 95 parts are dilute
Release agent.
3. vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 2, it is characterised in that it includes as follows
The component of parts by weight：3 part of two functional aliphatic's urethane acrylate, 1 ~ 6 part of acetylbutyrylcellulose, 3 part of six function fat
Adoption urethane acrylate, 0.3 part of light trigger, 0.2 part of organosiloxane levelling agent, 88 ~ 93 parts of diluents.
4. the vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1,2 or 3, it is characterised in that described two
Functional aliphatic's urethane acrylate, which is selected from, closes UV-3000B, Changxing chemistry 6112-100, Changxing chemistry 6152-100, cyanogen day
At least one of special company EB230, Qing Te company EB270, Qing Te company EB9260, Sartomer CN9001NS.
5. the vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1,2 or 3, it is characterised in that the vinegar
Sour cellulose butyrate is selected from Yi Shiman CAB-511-0.01, CAB-511-0.2, CAB-381-0.1, CAB-381-0.5, CAB-
At least one of 381-2, CAB-381-20, CAB-531-1, are the cellulose esters obtained by native cellulose through acetylation
Class product, its molecular weight is between 40000~60000.
6. the vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1,2 or 3, it is characterised in that described six
Functional aliphatic's urethane acrylate, which is selected from, closes UV-7605B, Changxing chemistry 6145-100, Changxing chemistry 6161-100, cyanogen day
At least one of special company EB1290, Qing Te company EB5129, Sartomer CN9013, Sartomer CN9010NS.
7. the vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1,2 or 3, it is characterised in that the light
Initiator is one or more of combinations in benzil class, aroyl phosphine oxide, benzophenone, alkylbenzene ketone.
8. the vacuum coating scumbling priming paint ultraviolet-curing paint according to claim 1,2 or 3, it is characterised in that described dilute
It is the one or more of group of ethyl acetate, methyl iso-butyl ketone (MIBK), isopropanol, butyl glycol ether, acetone, DIBK to release agent
Close.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710602033.7A CN107298936A (en) | 2017-07-21 | 2017-07-21 | Vacuum coating scumbling priming paint ultraviolet-curing paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710602033.7A CN107298936A (en) | 2017-07-21 | 2017-07-21 | Vacuum coating scumbling priming paint ultraviolet-curing paint |
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| CN107298936A true CN107298936A (en) | 2017-10-27 |
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| CN201710602033.7A Pending CN107298936A (en) | 2017-07-21 | 2017-07-21 | Vacuum coating scumbling priming paint ultraviolet-curing paint |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111019512A (en) * | 2019-12-25 | 2020-04-17 | 无锡中星新材料科技股份有限公司 | UV release agent |
| CN111087920A (en) * | 2019-12-24 | 2020-05-01 | 珠海华彩新材料科技有限公司 | Gloss oil and preparation method and application thereof |
| CN111471964A (en) * | 2020-04-28 | 2020-07-31 | 深圳天成真空技术有限公司 | Coating of vacuum coating equipment and coating method |
| CN112063292A (en) * | 2020-09-25 | 2020-12-11 | 惠州市韵点新材料科技股份有限公司 | High-adhesion mobile phone vacuum electroplating UV (ultraviolet) curing coating |
| CN112538293A (en) * | 2020-12-04 | 2021-03-23 | 东莞市贝特利新材料有限公司 | Vibration wear-resistant coating and preparation method and spraying process thereof |
| CN113698862A (en) * | 2021-09-16 | 2021-11-26 | 湖南松井新材料股份有限公司 | Water-based paint and preparation method and application thereof |
| CN115074018A (en) * | 2021-12-31 | 2022-09-20 | 荣耀终端有限公司 | Finishing coat composition, composite material, electronic equipment middle frame, electronic equipment shell and electronic equipment |
| CN115558403A (en) * | 2022-09-19 | 2023-01-03 | 广东希贵光固化材料有限公司 | Ultraviolet photocureable coating for stainless steel condenser tube |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464938A (en) * | 2010-11-16 | 2012-05-23 | 深圳市嘉卓成科技发展有限公司 | Plastic single-coating coloring UV (Ultraviolet) radiation cured paint and production and use methods thereof |
-
2017
- 2017-07-21 CN CN201710602033.7A patent/CN107298936A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102464938A (en) * | 2010-11-16 | 2012-05-23 | 深圳市嘉卓成科技发展有限公司 | Plastic single-coating coloring UV (Ultraviolet) radiation cured paint and production and use methods thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111087920A (en) * | 2019-12-24 | 2020-05-01 | 珠海华彩新材料科技有限公司 | Gloss oil and preparation method and application thereof |
| CN111087920B (en) * | 2019-12-24 | 2021-10-22 | 珠海华彩新材料科技有限公司 | Gloss oil and preparation method and application thereof |
| CN111019512A (en) * | 2019-12-25 | 2020-04-17 | 无锡中星新材料科技股份有限公司 | UV release agent |
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Application publication date: 20171027 |