CN107287049A - A kind of glass cleaner and preparation method thereof - Google Patents
A kind of glass cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN107287049A CN107287049A CN201710522051.4A CN201710522051A CN107287049A CN 107287049 A CN107287049 A CN 107287049A CN 201710522051 A CN201710522051 A CN 201710522051A CN 107287049 A CN107287049 A CN 107287049A
- Authority
- CN
- China
- Prior art keywords
- parts
- additive
- attapulgite clay
- surfactant
- glass cleaner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of glass cleaner, include the raw material of following parts by weight：13~22 parts of modified attapulgite clay, 10~20 parts of borage seed oil, 5~9 parts of amine oxide, 4~7 parts of polyacrylamide gel, 12~18 parts of stearic acid, 14~18 parts of APES, 2~5 parts of surfactant, 10~20 parts of ethylene glycol, 1~2 part of sodium cellulose glycolate, 5~12 parts of lauryl sodium sulfate, 0.8~1.7 part of film forming agent, 1.2~2.3 parts of chelating agent, 7~13 parts of additive, 100 parts of water.The glass cleaner clean effect is good, will not attack glass, the light transmittance to glass impacts.
Description
Technical field
The invention belongs to glass technology field, and in particular to a kind of glass cleaner and preparation method thereof.
Background technology
Cleaning agent is a kind of cleaning production for being used for washing the things such as clothing, implement or cleaning furniture of liquid condition
Product.It uses various new surfactant, and strong detergency, rinsing is easy, non-stimulated to skin, can be used for washing kitchen tools,
Furniture and fruit, melon and vegetable.As the glass cleaner of tailored version, belong to government utility hard surface cleaner scope, fall within family
Cleaning agent.Glass cleaner is a kind of cleaning agent of special glass door and window, minute surface and vehicle glass between floors etc..But pass
The glass cleaner cleaning effect of system is bad, it is necessary to repeatedly be cleaned, the duration is long.
The content of the invention
The invention provides a kind of glass cleaner and preparation method thereof, the problem of solving in above-mentioned background technology, institute
State glass cleaner clean effect good, will not attack glass, the light transmittance to glass impacts.
In order to solve the problem of prior art is present, adopt the following technical scheme that：
A kind of glass cleaner, includes the raw material of following parts by weight：13~22 parts of modified attapulgite clay, borage seed oil 10~
20 parts, 5~9 parts of amine oxide, 4~7 parts of polyacrylamide gel, 12~18 parts of stearic acid, APES 14~18
Part, 2~5 parts of surfactant, 10~20 parts of ethylene glycol, 1~2 part of sodium cellulose glycolate, lauryl sodium sulfate 5~12
Part, 0.8~1.7 part of film forming agent, 1.2~2.3 parts of chelating agent, 7~13 parts of additive, 100 parts of water.
It is preferred that, the glass cleaner includes the raw material of following parts by weight：15~20 parts of modified attapulgite clay, glass
13~18 parts of glass lettuce seed oil, 6~8 parts of amine oxide, 5~6 parts of polyacrylamide gel, 14~16 parts of stearic acid, alkyl phenol polyoxy
15~17 parts of vinethene, 3~4 parts of surfactant, 14~19 parts of ethylene glycol, 1.3~1.8 parts of sodium cellulose glycolate, 12
7~11 parts of sodium alkyl sulfate, 1.2~1.6 parts of film forming agent, 1.6~2.2 parts of chelating agent, 9~11 parts of additive, 100 parts of water.
It is preferred that, the glass cleaner includes the raw material of following parts by weight：18 parts of modified attapulgite clay, borage
15 parts of seed oil, 7 parts of amine oxide, 5.3 parts of polyacrylamide gel, 15 parts of stearic acid, 16 parts of APES, surface are lived
3.3 parts of agent of property, 18 parts of ethylene glycol, 1.4 parts of sodium cellulose glycolate, 9 parts of lauryl sodium sulfate, 1.4 parts of film forming agent, chelating agent
2.1 parts, 10 parts of additive, 100 parts of water.
It is preferred that, the modified attapulgite clay is made by following methods：100 mesh are crossed after Concave-convex clay rod is crushed
Sieve, then adds sulfuric acid solution by the Concave-convex clay rod crushed, stirs 3~5 hours at room temperature, pH is washed to distilled water
It is worth for 5.8~7, solid is put in natural environment and air-dried by centrifugation, the modified attapulgite clay is made.
It is preferred that, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:
1。
It is preferred that, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon
Composition, wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon are 2:1:1:1:
1:2。
It is preferred that, the surfactant includes nonionic surfactant and anion surfactant, its weight ratio
For 3:1.
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 10~20 minutes, 100~200 mesh sieves are crossed,
It is standby；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 10~20 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 8~15 minutes of 2000~3000r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with 5~10 DEG C/min
Firing rate be heated to 80~90 DEG C, then ultrasonication 6~11 minutes, are cooled to normal temperature, produce the cleaning glass
Agent.
It is preferred that, the step（5）Middle mixing speed is 70~90r/min.
Compared with prior art, it has the advantages that the present invention：
（1）Glass cleaner of the present invention is using modified attapulgite clay as raw material, and modified attapulgite clay is inhaled
Attached ability is strong, and borage seed oil one works, and improves the adsorption capacity of the glass cleaner, strengthens its removal dirty
Ability, mitigates cleaning；
（2）It is micro- that glass cleaner of the present invention also added sepiolite, sodium alginate, zeolite, carbonitride, alundum (Al2O3)
Powder and activated carbon are used as additive, and modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, tristearin
Acid, APES synergy, can effectively remove magnesium in running water, the silicate of calcium ion formation and carbonate
Dirt, will not attack glass, time saving water-saving is efficient and convenient, as long as being picked with cotton on a small quantity, is evenly coated in glass surface, or uses
Sprayer is sprayed on glass, it is slightly dry after dried with clean cotton, glass is light as new, is not required to be rinsed with water.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of glass cleaner, includes the raw material of following parts by weight：13 parts of modified attapulgite clay, borage
10 parts of seed oil, 5 parts of amine oxide, 4 parts of polyacrylamide gel, 12 parts of stearic acid, 14 parts of APES, surface-active
2 parts of agent, 10 parts of ethylene glycol, 1 part of sodium cellulose glycolate, 5 parts of lauryl sodium sulfate, 0.8 part of film forming agent, 1.2 parts of chelating agent,
7 parts of additive, 100 parts of water.
Wherein, the modified attapulgite clay is made by following methods：100 mesh sieves are crossed after Concave-convex clay rod is crushed,
Then the Concave-convex clay rod crushed is added into sulfuric acid solution, stirred 3 hours at room temperature, being washed to pH value with distilled water is
5.8, solid is put in natural environment and air-dried by centrifugation, and the modified attapulgite clay is made.
Wherein, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:1.
Wherein, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon group
Into wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon is 2:1:1:1:1:
2。
Wherein, the surfactant includes nonionic surfactant and anion surfactant, and its weight ratio is
3:1。
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 10 minutes, 100~200 mesh sieves are crossed, it is standby
With；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 10 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 8 minutes of 2000r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with adding for 5 DEG C/min
Thermal velocity is heated to 80 DEG C, and then ultrasonication 6 minutes, are cooled to normal temperature, produces the glass cleaner.
Wherein, the step（5）Middle mixing speed is 70r/min.
Embodiment 2
The present embodiment is related to a kind of glass cleaner, includes the raw material of following parts by weight：22 parts of modified attapulgite clay, borage
20 parts of seed oil, 9 parts of amine oxide, 7 parts of polyacrylamide gel, 18 parts of stearic acid, 18 parts of APES, surface-active
5 parts of agent, 20 parts of ethylene glycol, 2 parts of sodium cellulose glycolate, 12 parts of lauryl sodium sulfate, 1.7 parts of film forming agent, chelating agent 2.3
Part, 13 parts of additive, 100 parts of water.
Wherein, the modified attapulgite clay is made by following methods：100 mesh sieves are crossed after Concave-convex clay rod is crushed,
Then the Concave-convex clay rod crushed is added into sulfuric acid solution, stirred 5 hours at room temperature, it is 7 that pH value is washed to distilled water,
Solid is put in natural environment and air-dried by centrifugation, and the modified attapulgite clay is made.
Wherein, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:1.
Wherein, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon group
Into wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon is 2:1:1:1:1:
2。
Wherein, the surfactant includes nonionic surfactant and anion surfactant, and its weight ratio is
3:1。
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 20 minutes, 100~200 mesh sieves are crossed, it is standby
With；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 20 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 15 minutes of 3000r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with adding for 10 DEG C/min
Thermal velocity is heated to 90 DEG C, and then ultrasonication 11 minutes, are cooled to normal temperature, produces the glass cleaner.
Wherein, the step（5）Middle mixing speed is 90r/min.
Embodiment 3
The present embodiment is related to a kind of glass cleaner, includes the raw material of following parts by weight：15 parts of modified attapulgite clay, borage
13 parts of seed oil, 6 parts of amine oxide, 5 parts of polyacrylamide gel, 14 parts of stearic acid, 15 parts of APES, surface-active
3 parts of agent, 14 parts of ethylene glycol, 1.3 parts of sodium cellulose glycolate, 7 parts of lauryl sodium sulfate, 1.2 parts of film forming agent, chelating agent 1.6
Part, 9 parts of additive, 100 parts of water.
Wherein, the modified attapulgite clay is made by following methods：100 mesh sieves are crossed after Concave-convex clay rod is crushed,
Then the Concave-convex clay rod crushed is added into sulfuric acid solution, stirred 3.5 hours at room temperature, being washed to pH value with distilled water is
6, solid is put in natural environment and air-dried by centrifugation, and the modified attapulgite clay is made.
Wherein, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:1.
Wherein, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon group
Into wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon is 2:1:1:1:1:
2。
Wherein, the surfactant includes nonionic surfactant and anion surfactant, and its weight ratio is
3:1。
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 12 minutes, 100~200 mesh sieves are crossed, it is standby
With；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 11 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 14 minutes of 2200r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with adding for 6 DEG C/min
Thermal velocity is heated to 82 DEG C, and then ultrasonication 7 minutes, are cooled to normal temperature, produces the glass cleaner.
Wherein, the step（5）Middle mixing speed is 75r/min.
Embodiment 4
The present embodiment is related to a kind of glass cleaner, includes the raw material of following parts by weight：20 parts of modified attapulgite clay, borage
18 parts of seed oil, 8 parts of amine oxide, 6 parts of polyacrylamide gel, 16 parts of stearic acid, 17 parts of APES, surface-active
4 parts of agent, 19 parts of ethylene glycol, 1.8 parts of sodium cellulose glycolate, 11 parts of lauryl sodium sulfate, 1.6 parts of film forming agent, chelating agent 2.2
Part, 11 parts of additive, 100 parts of water.
Wherein, the modified attapulgite clay is made by following methods：100 mesh sieves are crossed after Concave-convex clay rod is crushed,
Then the Concave-convex clay rod crushed is added into sulfuric acid solution, stirred 4.5 hours at room temperature, being washed to pH value with distilled water is
6.7, solid is put in natural environment and air-dried by centrifugation, and the modified attapulgite clay is made.
Wherein, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:1.
Wherein, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon group
Into wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon is 2:1:1:1:1:
2。
Wherein, the surfactant includes nonionic surfactant and anion surfactant, and its weight ratio is
3:1。
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 18 minutes, 100~200 mesh sieves are crossed, it is standby
With；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 19 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 13 minutes of 2900r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with adding for 9 DEG C/min
Thermal velocity is heated to 87 DEG C, and then ultrasonication 10 minutes, are cooled to normal temperature, produces the glass cleaner.
Wherein, the step（5）Middle mixing speed is 85r/min.
Embodiment 5
The present embodiment is related to a kind of glass cleaner, includes the raw material of following parts by weight：18 parts of modified attapulgite clay, borage
15 parts of seed oil, 7 parts of amine oxide, 5.3 parts of polyacrylamide gel, 15 parts of stearic acid, 16 parts of APES, surface are lived
3.3 parts of agent of property, 18 parts of ethylene glycol, 1.4 parts of sodium cellulose glycolate, 9 parts of lauryl sodium sulfate, 1.4 parts of film forming agent, chelating agent
2.1 parts, 10 parts of additive, 100 parts of water.
Wherein, the modified attapulgite clay is made by following methods：100 mesh sieves are crossed after Concave-convex clay rod is crushed,
Then the Concave-convex clay rod crushed is added into sulfuric acid solution, stirred 4 hours at room temperature, being washed to pH value with distilled water is
6.5, solid is put in natural environment and air-dried by centrifugation, and the modified attapulgite clay is made.
Wherein, the sulfuric acid solution concentration is 2mol/L, and the volume ratio of the sulfuric acid solution and attapulgite clay is 10:1.
Wherein, the additive is by sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon group
Into wherein the weight ratio of sepiolite, sodium alginate, zeolite, carbonitride, aluminium oxide powder and activated carbon is 2:1:1:1:1:
2。
Wherein, the surfactant includes nonionic surfactant and anion surfactant, and its weight ratio is
3:1。
A kind of method for preparing the glass cleaner, comprises the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 15 minutes, 100~200 mesh sieves are crossed, it is standby
With；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 15 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 12 minutes of 2500r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with adding for 7 DEG C/min
Thermal velocity is heated to 85 DEG C, and then ultrasonication 8 minutes, are cooled to normal temperature, produces the glass cleaner.
Wherein, the step（5）Middle mixing speed is 80r/min.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (9)
1. a kind of glass cleaner, it is characterised in that include the raw material of following parts by weight：13~22 parts of modified attapulgite clay,
10~20 parts of borage seed oil, 5~9 parts of amine oxide, 4~7 parts of polyacrylamide gel, 12~18 parts of stearic acid, alkyl phenol gather
14~18 parts of oxygen vinethene, 2~5 parts of surfactant, 10~20 parts of ethylene glycol, 1~2 part of sodium cellulose glycolate, dodecane
5~12 parts of base sodium sulphate, 0.8~1.7 part of film forming agent, 1.2~2.3 parts of chelating agent, 7~13 parts of additive, 100 parts of water.
2. glass cleaner according to claim 1, it is characterised in that include the raw material of following parts by weight：It is modified concavo-convex
15~20 parts of rod clay, 13~18 parts of borage seed oil, 6~8 parts of amine oxide, 5~6 parts of polyacrylamide gel, stearic acid 14
~16 parts, 15~17 parts of APES, 3~4 parts of surfactant, 14~19 parts of ethylene glycol, hydroxymethyl cellulose
1.3~1.8 parts of sodium, 7~11 parts of lauryl sodium sulfate, 1.2~1.6 parts of film forming agent, 1.6~2.2 parts of chelating agent, additive 9
~11 parts, 100 parts of water.
3. glass cleaner according to claim 1, it is characterised in that include the raw material of following parts by weight：It is modified concavo-convex
18 parts of rod clay, 15 parts of borage seed oil, 7 parts of amine oxide, 5.3 parts of polyacrylamide gel, 15 parts of stearic acid, alkyl phenol polyoxy
16 parts of vinethene, 3.3 parts of surfactant, 18 parts of ethylene glycol, 1.4 parts of sodium cellulose glycolate, 9 parts of lauryl sodium sulfate,
1.4 parts of film forming agent, 2.1 parts of chelating agent, 10 parts of additive, 100 parts of water.
4. glass cleaner according to claim 1, it is characterised in that the modified attapulgite clay is by following methods system
：100 mesh sieves are crossed after Concave-convex clay rod is crushed, the Concave-convex clay rod crushed is then added into sulfuric acid solution, room temperature
Lower stirring 3~5 hours, it is 5.8~7 that pH value is washed to distilled water, and solid is put in natural environment and air-dried by centrifugation, and institute is made
State modified attapulgite clay.
5. glass cleaner according to claim 4, it is characterised in that the sulfuric acid solution concentration is 2mol/L, described
The volume ratio of sulfuric acid solution and attapulgite clay is 10:1.
6. glass cleaner according to claim 1, it is characterised in that the additive is by sepiolite, sodium alginate, boiling
Stone, carbonitride, aluminium oxide powder and activated carbon composition, wherein sepiolite, sodium alginate, zeolite, carbonitride, three oxidations two
The weight ratio of aluminium micro mist and activated carbon is 2:1:1:1:1:2.
7. glass cleaner according to claim 1, it is characterised in that the surfactant is lived including non-ionic surface
Property agent and anion surfactant, its weight ratio is 3:1.
8. a kind of method for preparing any one of claim 1~7 glass cleaner, it is characterised in that the preparation method
Comprise the following steps：
（1）By above-mentioned formula weigh modified attapulgite clay, borage seed oil, amine oxide, polyacrylamide gel, stearic acid,
APES, surfactant, ethylene glycol, sodium cellulose glycolate, lauryl sodium sulfate, film forming agent, chelating
Agent, additive, water；
（2）Modified attapulgite clay and additive are respectively placed in grinder and ground 10~20 minutes, 100~200 mesh sieves are crossed,
It is standby；
（3）Surfactant, film forming agent and chelating agent are placed in resistance to acid solution and mixed, is added water and ethylene glycol dissolving, stirring is equal
Even, frequency low-amplitude shakes 10~20 minutes；
（4）To step（3）Modified attapulgite clay and additive after being ground in obtained mixed solution, are placed in high speed dispersor
In with scattered 8~15 minutes of 2000~3000r/min rate of dispersion；
（5）To step（4）Borage seed oil, amine oxide, polyacrylamide gel, tristearin are sequentially added in obtained mixed liquor
Acid, APES, sodium cellulose glycolate, lauryl sodium sulfate, heat while stirring, with 5~10 DEG C/min
Firing rate be heated to 80~90 DEG C, then ultrasonication 6~11 minutes, are cooled to normal temperature, produce the cleaning glass
Agent.
9. preparation method according to claim 8, it is characterised in that the step（5）Middle mixing speed is 70~90r/
min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522051.4A CN107287049A (en) | 2017-06-30 | 2017-06-30 | A kind of glass cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522051.4A CN107287049A (en) | 2017-06-30 | 2017-06-30 | A kind of glass cleaner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107287049A true CN107287049A (en) | 2017-10-24 |
Family
ID=60098804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710522051.4A Withdrawn CN107287049A (en) | 2017-06-30 | 2017-06-30 | A kind of glass cleaner and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107287049A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108441034A (en) * | 2018-04-23 | 2018-08-24 | 合肥浦尔菲电线科技有限公司 | One kind having antibacterial taste removal effect environment protection type wall covering paint |
| CN108559676A (en) * | 2018-05-14 | 2018-09-21 | 合肥钢骨玻璃制品有限公司 | A kind of general glass cleaner and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050559A (en) * | 1989-09-30 | 1991-04-10 | 中国科学院地质研究所 | Household utensil detergent and method for making thereof |
| CN1067266A (en) * | 1991-05-24 | 1992-12-23 | 覃建华 | Bad smell removal detergent paste |
| CN104371855A (en) * | 2014-10-31 | 2015-02-25 | 田琳琳 | Low-foam glass cleaner |
| CN105296171A (en) * | 2015-12-02 | 2016-02-03 | 苏州龙腾万里化工科技有限公司 | Low-foam glass cleaner |
-
2017
- 2017-06-30 CN CN201710522051.4A patent/CN107287049A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050559A (en) * | 1989-09-30 | 1991-04-10 | 中国科学院地质研究所 | Household utensil detergent and method for making thereof |
| CN1067266A (en) * | 1991-05-24 | 1992-12-23 | 覃建华 | Bad smell removal detergent paste |
| CN104371855A (en) * | 2014-10-31 | 2015-02-25 | 田琳琳 | Low-foam glass cleaner |
| CN105296171A (en) * | 2015-12-02 | 2016-02-03 | 苏州龙腾万里化工科技有限公司 | Low-foam glass cleaner |
Non-Patent Citations (1)
| Title |
|---|
| 商平等: "《环境矿物材料》", 31 January 2008, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108441034A (en) * | 2018-04-23 | 2018-08-24 | 合肥浦尔菲电线科技有限公司 | One kind having antibacterial taste removal effect environment protection type wall covering paint |
| CN108559676A (en) * | 2018-05-14 | 2018-09-21 | 合肥钢骨玻璃制品有限公司 | A kind of general glass cleaner and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106467390B (en) | A kind of graphene boccaro composite material and its manufactured boccaro ware, preparation method | |
| CN102584343B (en) | Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic | |
| CN105819752B (en) | A kind of nanometer oyster shell whiting ecological functions are flat to apply coating | |
| CN101831364A (en) | Sterilized mildew-proof cleaning powder of natural shell powder and preparation method thereof | |
| CN106904625B (en) | A kind of charing method of the compound intercalated montmorillonite of cellulose | |
| CN105132208A (en) | Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof | |
| CN107287049A (en) | A kind of glass cleaner and preparation method thereof | |
| CN105130495B (en) | A kind of high strength lightweight silica brick and preparation method thereof | |
| CN102614829A (en) | Method for preparing mycotoxin adsorbent for efficient carbon silicon feed by taking rice hulls as raw materials | |
| CN103789095A (en) | Glass cleaner composition | |
| CN103710182A (en) | Marine biological resource based micro-nano healthy and environment-friendly washing product and preparation method thereof | |
| CN106221957A (en) | A kind of scrubbing cleaning agent of wicker products | |
| CN104759257B (en) | A kind of environment protection modification natural zeolite sorbent preparation method for being used to adsorb LAS in waste water | |
| CN107570109A (en) | A kind of method that carbide slag treated coal ash realizes its recycling | |
| CN105131662A (en) | Conductive coating easy to clean, preparation method of conductive coating easy to clean, dust collector dust collection barrel and dust collector | |
| CN103484266A (en) | Formula of horsehair cleaning liquor | |
| DE3007320A1 (en) | MACHINE APPLICABLE CLEANING AGENTS | |
| CN106479735A (en) | A kind of textile cleaning agent and preparation method thereof | |
| CN107523448A (en) | A kind of cleaning agent of cleaning fan of sucking oil fume heavy oil stain and preparation method thereof | |
| CN108947258A (en) | It is a kind of to mention devitrified glass of the titanium slag as raw material containing chlorine | |
| CN103387887A (en) | Carpet cleaning agent and preparation method thereof | |
| CN103173299A (en) | Novel water-saving and environment-friendly bio-cleaning material and preparation method thereof | |
| CN103710173B (en) | Alkaline decontamination cleaning agent used for filter element | |
| CN110394151A (en) | A kind of high-grade diatomite and preparation method thereof with molecular sieve structure | |
| CN111423121A (en) | Antibacterial ceramic glaze and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171024 |
|
| WW01 | Invention patent application withdrawn after publication |