CN107286744A - A kind of quick-drying thermosetting ink - Google Patents

A kind of quick-drying thermosetting ink Download PDF

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Publication number
CN107286744A
CN107286744A CN201710652868.3A CN201710652868A CN107286744A CN 107286744 A CN107286744 A CN 107286744A CN 201710652868 A CN201710652868 A CN 201710652868A CN 107286744 A CN107286744 A CN 107286744A
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China
Prior art keywords
parts
drier
quick
degree
thermosetting ink
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Pending
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CN201710652868.3A
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Chinese (zh)
Inventor
邵素丽
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Jieshou City Xinwang Printing Research Center
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Jieshou City Xinwang Printing Research Center
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Priority to CN201710652868.3A priority Critical patent/CN107286744A/en
Publication of CN107286744A publication Critical patent/CN107286744A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/08Printing inks based on natural resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/12Printing inks based on waxes or bitumen

Abstract

A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:10 15 parts of silicone oil, 5 10 parts of acrylate, 36 parts of lubricating grease, 48 parts of polyethylene glycol, 24 parts of methylcellulose, 23 parts of graphite, 25 parts of vinylacetate, 13 parts of polyacrylate emulsion, 13 parts of phenolic resin, 13 parts of epoxy resin modified acrylic resin, 0.8 1.5 parts of paraffin, 24 parts of ethylene glycol, 24 parts of aqueous magnesium drier, 13 parts of aqueous zinc drier, 13 parts of antioxidant.The present invention has set speed fast, and film forming is fast, and rate of drying is fast, and degree of adhesion is high, not oxidizable advantage.

Description

A kind of quick-drying thermosetting ink
Technical field
The present invention relates to printing technology, and in particular to a kind of quick-drying thermosetting ink.
Background technology
Ink is the important materials for printing, and it is shown pattern, word on stock by printing or air brushing.Oil Ink includes main component and auxiliary element, and they equably mix and form a kind of stickiness colloidal fluid through repeat-rolling.By Link stuff, pigment, filler, auxiliary agent and solvent etc. are constituted.For books and periodicals, packing and decorating, building decoration and electronic circuit sheet material etc. Various printings.As social demand increases, ink kind and yield also respective extension and growth.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of quick-drying thermosetting ink.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
10-15 parts of silicone oil, 5-10 parts of acrylate, 3-6 parts of lubricating grease, 4-8 parts of polyethylene glycol, methylcellulose 2-4 Part, 2-3 parts of graphite, 2-5 parts of vinylacetate, 1-3 parts of polyacrylate emulsion, 1-3 parts of phenolic resin, epoxy resin modification propylene 1-3 parts of acid resin, 0.8-1.5 parts of paraffin, 2-4 parts of ethylene glycol, 2-4 parts of aqueous magnesium drier, aqueous zinc drier 1-3 parts, resist 1-3 parts of oxidant.
The preferable weight of above-mentioned each component is:12 parts of silicone oil, 8 parts of acrylate, 5 parts of lubricating grease, 6 parts of polyethylene glycol, 3 parts of methylcellulose, 2 parts of graphite, 4 parts of vinylacetate, 2 parts of polyacrylate emulsion, 2 parts of phenolic resin, epoxy resin modification 2 parts of acrylic resin, 1.2 parts of paraffin, 3 parts of ethylene glycol, 3 parts of aqueous magnesium drier, 2 parts of aqueous zinc drier, antioxidant 2 Part.
The antioxidant composition is made up of the component of following parts by weight:10-20 parts of sodium tripolyphosphate, sodium sulfite 5-10 Part, 3-6 parts of dicyclopentadiene, 2-4 parts of paracresol, 5-8 parts of malic acid.
The component of the antioxidant composition preferably following parts by weight is made:15 parts of sodium tripolyphosphate, 8 parts of sodium sulfite, 5 parts of dicyclopentadiene, 3 parts of paracresol, 6 parts of malic acid.
The preparation method of above-mentioned quick-drying thermosetting ink is to comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 110-120 degree, stirring reaction 0.5-1 hours;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, second two Alcohol, aqueous magnesium drier, aqueous zinc drier are sequentially added in reactor, are heated to 180 degree, are melted resin, start stirring, Temperature rises to 220 degree, is incubated 1.5-2 hours;
D, the step c mixtures handled well are down to 80-90 degree, add step a and step b mixture, add antioxygen Agent, is put into mixer stirring, mixer rotating speed 1200-1400r/min;
E, the mixture pH regulations most 7 that step d is stirred, that is, obtain product.
Beneficial effect of the present invention:
Inventive formulation rationally, on the basis of traditional ink lubricity height, wettability are strong, add cosolvent, urges dry Agent, drier, antioxidant, are that the density of ink of the present invention is high, fast with set speed, film forming is fast, and rate of drying is fast, bonding Degree is high, not oxidizable advantage.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
10 parts of silicone oil, 5 parts of acrylate, 3 parts of lubricating grease, 4 parts of polyethylene glycol, 2 parts of methylcellulose, 2 parts of graphite, vinegar 2 parts of vinyl acetate, 1 part of polyacrylate emulsion, 1 part of phenolic resin, 1 part of epoxy resin modified acrylic resin, 0.8 part of paraffin, 2 parts of ethylene glycol, 2 parts of aqueous magnesium drier, 1 part of aqueous zinc drier.
The preparation method of above-mentioned quick-drying thermosetting ink is to comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 110 degree, stirring reaction 0.5 is small When;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, second two Alcohol, aqueous magnesium drier, aqueous zinc drier are sequentially added in reactor, are heated to 180 degree, are melted resin, start stirring, Temperature rises to 220 degree, is incubated 1.5 hours;
D, the step c mixtures handled well are down to 80 degree, add step a and step b mixture, add anti-oxidant Agent, is put into mixer stirring, mixer rotating speed 1200r/min;
E, the mixture pH regulations most 7 that step d is stirred, that is, obtain product.
Embodiment 2
A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
15 parts of silicone oil, 10 parts of acrylate, 6 parts of lubricating grease, 8 parts of polyethylene glycol, 4 parts of methylcellulose, 3 parts of graphite, 5 parts of vinylacetate, 3 parts of polyacrylate emulsion, 3 parts of phenolic resin, 3 parts of epoxy resin modified acrylic resin, paraffin 1.5 Part, 4 parts of ethylene glycol, 4 parts of aqueous magnesium drier, 3 parts of aqueous zinc drier.
The preparation method of above-mentioned quick-drying thermosetting ink is to comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 120 degree, stirring reaction 1 hour;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, second two Alcohol, aqueous magnesium drier, aqueous zinc drier are sequentially added in reactor, are heated to 180 degree, are melted resin, start stirring, Temperature rises to 220 degree, is incubated 2 hours;
D, the step c mixtures handled well are down to 90 degree, add step a and step b mixture, add anti-oxidant Agent, is put into mixer stirring, mixer rotating speed 1400r/min;
E, the mixture pH regulations most 7 that step d is stirred, that is, obtain product.
Control group 1
A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
10 parts of silicone oil, 5 parts of acrylate, 3 parts of lubricating grease, 4 parts of polyethylene glycol, 2 parts of methylcellulose, 2 parts of graphite, vinegar 2 parts of vinyl acetate, 1 part of polyacrylate emulsion, 1 part of phenolic resin, 1 part of epoxy resin modified acrylic resin, 0.8 part of paraffin, 2 parts of ethylene glycol, 2 parts of drier.
The preparation method of above-mentioned quick-drying thermosetting ink is to comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 110 degree, stirring reaction 0.5 is small When;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, second two Alcohol, drier are sequentially added in reactor, are heated to 180 degree, melt resin, start stirring, and temperature rises to 220 degree, insulation 1.5 hour;
D, the step c mixtures handled well are down to 80 degree, add step a and step b mixture, add anti-oxidant Agent, is put into mixer stirring, mixer rotating speed 1200r/min;
E, the mixture pH regulations most 7 that step d is stirred, that is, obtain product.
Control group 2
A kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
15 parts of silicone oil, 10 parts of acrylate, 6 parts of lubricating grease, 8 parts of polyethylene glycol, 4 parts of methylcellulose, 3 parts of graphite, 5 parts of vinylacetate, 3 parts of polyacrylate emulsion, 3 parts of phenolic resin, 3 parts of epoxy resin modified acrylic resin, paraffin 0.5 Part, 0.4 part of ethylene glycol, 0.4 part of aqueous magnesium drier, 0.3 part of aqueous zinc drier.
The preparation method of above-mentioned quick-drying thermosetting ink is to comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 120 degree, stirring reaction 1 hour;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, second two Alcohol, aqueous magnesium drier, aqueous zinc drier are sequentially added in reactor, are heated to 180 degree, are melted resin, start stirring, Temperature rises to 220 degree, is incubated 2 hours;
D, the step c mixtures handled well are down to 90 degree, add step a and step b mixture, add anti-oxidant Agent, is put into mixer stirring, that is, obtains product.
It is the density height of ink of the present invention, fast with set speed, film forming is fast, and rate of drying is fast, and degree of adhesion is high, is difficult oxygen The advantage of change.
Table 1 is the present invention and control group performance test
Experiment proves that set speed of the present invention is fast, and film forming is fast, and rate of drying is fast, and degree of adhesion is high, not oxidizable advantage.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

1. a kind of quick-drying thermosetting ink, is made up of the component of following parts by weight:
10-15 parts of silicone oil, 5-10 parts of acrylate, 3-6 parts of lubricating grease, 4-8 parts of polyethylene glycol, 2-4 parts of methylcellulose, stone Black 2-3 parts, 2-5 parts of vinylacetate, 1-3 parts of polyacrylate emulsion, 1-3 parts of phenolic resin, epoxy resin modification acrylic acid tree 1-3 parts of fat, 0.8-1.5 parts of paraffin, 2-4 parts of ethylene glycol, 2-4 parts of aqueous magnesium drier, aqueous zinc drier 1-3 parts.
2. quick-drying thermosetting ink according to claim 1, it is characterised in that the component of preferred following parts by weight is made: 12 parts of silicone oil, 8 parts of acrylate, 5 parts of lubricating grease, 6 parts of polyethylene glycol, 3 parts of methylcellulose, 2 parts of graphite, vinylacetate 4 parts, 2 parts of polyacrylate emulsion, 2 parts of phenolic resin, 2 parts of epoxy resin modified acrylic resin, 1.2 parts of paraffin, ethylene glycol 3 Part, 3 parts of aqueous magnesium drier, 2 parts of aqueous zinc drier.
3. quick-drying thermosetting ink according to claim 1 or 2, it is characterised in that the antioxidant composition is by following weight The component of number is made:10-20 parts of sodium tripolyphosphate, 5-10 parts of sodium sulfite, 3-6 parts of dicyclopentadiene, 2-4 parts of paracresol, 5-8 parts of malic acid.
4. quick-drying thermosetting ink according to claim 3, it is characterised in that the antioxidant composition preferably following parts by weight Several components are made:15 parts of sodium tripolyphosphate, 8 parts of sodium sulfite, 5 parts of dicyclopentadiene, 3 parts of paracresol, 6 parts of malic acid.
5. a kind of preparation method for preparing quick-drying thermosetting ink described in claim 1 or 2, it is characterised in that comprise the following steps:
A, by silicone oil, acrylate, lubricating grease mix, stirring, be heated to lubricating grease dissolving;
B, by polyethylene glycol, methylcellulose, graphite mix, stir, be warming up to 110-120 degree, stirring reaction 0.5-1 is small When;
C, by vinylacetate, polyacrylate emulsion, phenolic resin, epoxy resin modified acrylic resin, paraffin, ethylene glycol, Aqueous magnesium drier, aqueous zinc drier are sequentially added in reactor, are heated to 180 degree, are melted resin, start stirring, temperature Degree rises to 220 degree, is incubated 1.5-2 hours;
D, the step c mixtures handled well are down to 80-90 degree, add step a and step b mixture, add antioxidant, It is put into mixer stirring, mixer rotating speed 1200-1400r/min;
E, the mixture pH regulations most 7 that step d is stirred, that is, obtain product.
CN201710652868.3A 2017-08-02 2017-08-02 A kind of quick-drying thermosetting ink Pending CN107286744A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108504170A (en) * 2018-05-27 2018-09-07 贵州西牛王印务有限公司 A kind of ink and preparation method thereof
CN110903698A (en) * 2019-12-06 2020-03-24 广州亦盛环保科技有限公司 Water-based thermosetting ink and preparation method thereof
CN114196258A (en) * 2022-01-20 2022-03-18 湖南互力达涂料科技有限公司 Water-based ink composition for PVC (polyvinyl chloride), and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1083502A (en) * 1992-09-02 1994-03-09 四川广播电视大学 Anti-forgery colour printing ink
CN101831215A (en) * 2010-04-28 2010-09-15 王学珍 High-performance jet ink

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1083502A (en) * 1992-09-02 1994-03-09 四川广播电视大学 Anti-forgery colour printing ink
CN101831215A (en) * 2010-04-28 2010-09-15 王学珍 High-performance jet ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108504170A (en) * 2018-05-27 2018-09-07 贵州西牛王印务有限公司 A kind of ink and preparation method thereof
CN110903698A (en) * 2019-12-06 2020-03-24 广州亦盛环保科技有限公司 Water-based thermosetting ink and preparation method thereof
CN114196258A (en) * 2022-01-20 2022-03-18 湖南互力达涂料科技有限公司 Water-based ink composition for PVC (polyvinyl chloride), and preparation method and application thereof
CN114196258B (en) * 2022-01-20 2023-07-04 湖南互力达涂料科技有限公司 Water-based ink composition for PVC, and preparation method and application thereof

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