CN107286593A - It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof - Google Patents
It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof Download PDFInfo
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- CN107286593A CN107286593A CN201710443485.5A CN201710443485A CN107286593A CN 107286593 A CN107286593 A CN 107286593A CN 201710443485 A CN201710443485 A CN 201710443485A CN 107286593 A CN107286593 A CN 107286593A
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- polyester fiber
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- graphene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/223—Packed additives
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The present invention discloses a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof, and the raw material of Masterbatch includes：Graphene, ethylene propylene diene rubber, diallyl phthalate, colorant, POE, ultra-violet absorber, HMDO, accelerator, propylene/alpha olefin copolymer, plasticizer, styrene and butyl acrylate；First ethylene propylene diene rubber, diallyl phthalate, POE and propylene/alpha olefin copolymer are mixed, compound is transferred in reactor again, add HMDO and plasticizer, temperature reaction, then by the mixing of reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator, extruding pelletization, the graphene heat discoloration Masterbatch for polyester fiber is obtained.The Masterbatch ensure that the integrity of temperature-sensing color-changing material during woven polyester fiber, also can guarantee that spinning the polyester fiber come inherently has temperature-sensing discoloration function.
Description
Technical field
The invention belongs to synthetic fibers technical field, and in particular to a kind of graphene heat discoloration color for polyester fiber
Master batch and preparation method thereof.
Background technology
Polyester fiber (polyester fibre) is by organic dibasic acid and the polyester of dihydric alcohol polycondensation through obtained by spinning
Synthetic fibers.Abbreviation PET, is the first big kind of current synthetic fibers.Due to dacron fibre
It is its principal item, therefore practises and claim polyester fiber to be to refer to this fiber.This kind of fiber appearance is well-pressed, and heat endurance is good, but hygroscopicity
It is slightly worse.They are mainly used in making various clothing articles, bedding, upholstery etc..
Heat discoloration fiber is to utilize the temperature-sensing color-changing material property that visible absorption spectra changes in heated or cooling
Matter and a kind of functional fibre developed.Preparing the method for heat discoloration fiber at present has microcapsule method, composite spinning method, infusion process
Deng, due to apply electronq donor class thermosensitive chromotropic material in weaving easily it is affected by environment (illumination, acid-base value, temperature,
Solvent etc.) and lose discoloration, the fiber temperature-sensing color-changing material prepared using composite spinning method and infusion process be highly vulnerable to breakage and
It is lost in, fiber performance is undesirable.
With the development of functional fabric, the demand of heat discoloration textile is increasing, due to the spinning of polyester fiber
Temperature is higher, at 285-295 DEG C, in order to avoid temperature-sensing color-changing material in spinning process not because high temperature occur degraded, it is necessary to carry
Go out the heat discoloration master batch with high-temperature stability.
The content of the invention
The technical problem of solution：It is an object of the invention to provide a kind of graphene heat discoloration color masterbatch for polyester fiber
Grain and preparation method thereof.
Technical scheme：A kind of graphene heat discoloration Masterbatch for polyester fiber, raw material includes in parts by weight：Stone
Black alkene 5-10 parts, 0.5-1 parts of ethylene propylene diene rubber, 0.2-0.8 parts of diallyl phthalate, 0.3-0.6 parts of colorant, second
Alkene -2-5 parts of octene copolymer, 0.1-0.3 parts of ultra-violet absorber, 0.6-1 parts of HMDO, accelerator 0.1-0.3
0.3-0.7 parts of part, 1-3 parts of propylene/α-olefin copolymer, 0.2-0.5 parts of plasticizer, 2-4 parts of styrene and butyl acrylate.
Further, the ultra-violet absorber is septichen phenyl ester.
Further, the accelerator is Benzenediol.
Further, the colorant is blueness or yellow colorant.
Further, the plasticizer is BBP(Butyl Benzyl Phthalate.
The preparation method of the above-mentioned graphene heat discoloration Masterbatch for polyester fiber, comprises the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins
Copolymer is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding
Under the conditions of be warming up to 100-110 DEG C, kept for 10-20 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed
Uniformly, extruding pelletization, obtains the graphene heat discoloration Masterbatch for polyester fiber.
Further, the mixing speed being well mixed in step 1 is 120-150 revs/min, and mixing time is 30-40 points
Clock.
Further, inert gas is nitrogen or argon gas in step 2.
Beneficial effect：The present invention is equipped with ethylene propylene diene rubber and ensure that using graphene as the carrier of temperature-sensing color-changing material
The flexibility of master batch, gained Masterbatch ensure that the integrity of temperature-sensing color-changing material during woven polyester fiber, also can
Ensure that spinning the polyester fiber come inherently has temperature-sensing discoloration function.
Embodiment
Embodiment 1
A kind of graphene heat discoloration Masterbatch for polyester fiber, raw material includes in parts by weight：5 parts of graphene,
0.5 part of ethylene propylene diene rubber, 0.2 part of diallyl phthalate, 0.3 part of colorant, 2 parts of ethylene-octene copolymer, ultraviolet
0.1 part of absorbent, 0.6 part of HMDO, 0.1 part of accelerator, 1 part of propylene/α-olefin copolymer, 0.2 part of plasticizer,
0.3 part of 2 parts of styrene and butyl acrylate.
Wherein, the ultra-violet absorber is septichen phenyl ester；The accelerator is Benzenediol；The colorant is
Blue colorant；The plasticizer is BBP(Butyl Benzyl Phthalate.
The preparation method of the above-mentioned graphene heat discoloration Masterbatch for polyester fiber, comprises the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins
Copolymer is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding
Under the conditions of be warming up to 100 DEG C, kept for 20 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed
Uniformly, extruding pelletization, obtains the graphene heat discoloration Masterbatch for polyester fiber.
Wherein, the mixing speed being well mixed in step 1 is 120 revs/min, and mixing time is 40 minutes；It is lazy in step 2
Property gas be nitrogen.
By gained Masterbatch and polyester master particle by weight 1：Spinning is weaved cotton cloth after 10 mixing, and gained cloth master batch is in 30-40
DEG C become blueness.
Embodiment 2
A kind of graphene heat discoloration Masterbatch for polyester fiber, raw material includes in parts by weight：7 parts of graphene,
0.6 part of ethylene propylene diene rubber, 0.4 part of diallyl phthalate, 0.5 part of colorant, 3 parts of ethylene-octene copolymer, ultraviolet
0.2 part of absorbent, 0.8 part of HMDO, 0.2 part of accelerator, 2 parts of propylene/α-olefin copolymer, 0.4 part of plasticizer,
0.5 part of 3 parts of styrene and butyl acrylate.
Wherein, the ultra-violet absorber is septichen phenyl ester；The accelerator is Benzenediol；The colorant is
Blue colorant；The plasticizer is BBP(Butyl Benzyl Phthalate.
The preparation method of the above-mentioned graphene heat discoloration Masterbatch for polyester fiber, comprises the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins
Copolymer is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding
Under the conditions of be warming up to 105 DEG C, kept for 15 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed
Uniformly, extruding pelletization, obtains the graphene heat discoloration Masterbatch for polyester fiber.
Wherein, the mixing speed being well mixed in step 1 is 140 revs/min, and mixing time is 35 minutes；It is lazy in step 2
Property gas be argon gas.
By gained Masterbatch and polyester master particle by weight 1：Spinning is weaved cotton cloth after 10 mixing, and gained cloth master batch is in 40-50
DEG C become yellow.
Embodiment 3
A kind of graphene heat discoloration Masterbatch for polyester fiber, raw material includes in parts by weight：8 parts of graphene,
0.7 part of ethylene propylene diene rubber, 0.5 part of diallyl phthalate, 0.4 part of colorant, 4 parts of ethylene-octene copolymer, ultraviolet
0.1 part of absorbent, 0.9 part of HMDO, 0.1 part of accelerator, 2 parts of propylene/α-olefin copolymer, 0.4 part of plasticizer,
0.5 part of 3 parts of styrene and butyl acrylate.
Wherein, the ultra-violet absorber is septichen phenyl ester；The accelerator is Benzenediol；The colorant is
Blue colorant；The plasticizer is BBP(Butyl Benzyl Phthalate.
The preparation method of the above-mentioned graphene heat discoloration Masterbatch for polyester fiber, comprises the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins
Copolymer is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding
Under the conditions of be warming up to 100 DEG C, kept for 20 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed
Uniformly, extruding pelletization, obtains the graphene heat discoloration Masterbatch for polyester fiber.
Wherein, the mixing speed being well mixed in step 1 is 120 revs/min, and mixing time is 40 minutes；It is lazy in step 2
Property gas be nitrogen.
By gained Masterbatch and polyester master particle by weight 1：Spinning is weaved cotton cloth after 10 mixing, and gained cloth master batch is in 30-40
DEG C become blueness.
Embodiment 4
A kind of graphene heat discoloration Masterbatch for polyester fiber, raw material includes in parts by weight：10 parts of graphene,
1 part of ethylene propylene diene rubber, 0.8 part of diallyl phthalate, 0.6 part of colorant, 5 parts of ethylene-octene copolymer, ultraviolet is inhaled
Receive 0.3 part of agent, 1 part of HMDO, 0.3 part of accelerator, 3 parts of propylene/α-olefin copolymer, 0.5 part of plasticizer, benzene second
0.7 part of 4 parts of alkene and butyl acrylate.
Wherein, the ultra-violet absorber is septichen phenyl ester；The accelerator is Benzenediol；The colorant is
Yellow colorant；The plasticizer is BBP(Butyl Benzyl Phthalate.
The preparation method of the above-mentioned graphene heat discoloration Masterbatch for polyester fiber, comprises the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins
Copolymer is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding
Under the conditions of be warming up to 110 DEG C, kept for 10 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed
Uniformly, extruding pelletization, obtains the graphene heat discoloration Masterbatch for polyester fiber.
Wherein, the mixing speed being well mixed in step 1 is 150 revs/min, and mixing time is 30 minutes；It is lazy in step 2
Property gas be nitrogen.
By gained Masterbatch and polyester master particle by weight 1：Spinning is weaved cotton cloth after 10 mixing, and gained cloth master batch is in 40-50
DEG C become yellow.
Claims (8)
1. a kind of graphene heat discoloration Masterbatch for polyester fiber, it is characterised in that raw material includes in parts by weight：Stone
Black alkene 5-10 parts, 0.5-1 parts of ethylene propylene diene rubber, 0.2-0.8 parts of diallyl phthalate, 0.3-0.6 parts of colorant, second
Alkene -2-5 parts of octene copolymer, 0.1-0.3 parts of ultra-violet absorber, 0.6-1 parts of HMDO, accelerator 0.1-0.3
0.3-0.7 parts of part, 1-3 parts of propylene/α-olefin copolymer, 0.2-0.5 parts of plasticizer, 2-4 parts of styrene and butyl acrylate.
2. the graphene heat discoloration Masterbatch according to claim 1 for polyester fiber, it is characterised in that ultraviolet
Absorbent is septichen phenyl ester.
3. the graphene heat discoloration Masterbatch according to claim 1 for polyester fiber, it is characterised in that accelerator
For Benzenediol.
4. the graphene heat discoloration Masterbatch according to claim 1 for polyester fiber, it is characterised in that colorant is
Blueness or yellow colorant.
5. the graphene heat discoloration Masterbatch according to claim 1 for polyester fiber, it is characterised in that plasticizer
For BBP(Butyl Benzyl Phthalate.
6. the preparation method of the graphene heat discoloration Masterbatch for polyester fiber described in claim 1, it is characterised in that
Comprise the following steps：
Step 1, by ethylene propylene diene rubber, diallyl phthalate, ethylene-octene copolymer and propylene/alpha-olefins copolymerization
Thing is well mixed in mixing and blending machine, obtains compound；
Step 2, compound is transferred in reactor, HMDO and plasticizer is added, in inert gas shielding condition
Under be warming up to 100-110 DEG C, kept for 10-20 minutes, obtain reactant；
Step 3, reactant, styrene, butyl acrylate, graphene, colorant, ultra-violet absorber and accelerator are mixed equal
Even, extruding pelletization obtains the graphene heat discoloration Masterbatch for polyester fiber.
7. the preparation method of the graphene heat discoloration Masterbatch according to claim 6 for polyester fiber, its feature
It is, the mixing speed being well mixed in step 1 is 120-150 revs/min, mixing time is 30-40 minutes.
8. the preparation method of the graphene heat discoloration Masterbatch according to claim 6 for polyester fiber, its feature
It is, inert gas is nitrogen or argon gas in step 2.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710443485.5A CN107286593A (en) | 2017-06-13 | 2017-06-13 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
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| CN201710443485.5A CN107286593A (en) | 2017-06-13 | 2017-06-13 | It is a kind of for graphene heat discoloration Masterbatch of polyester fiber and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2548657A1 (en) * | 2011-07-22 | 2013-01-23 | International Automotive Components Group GmbH | Coated plastic part and method of producing a coated plastic part |
| CN103709489A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | General white master batch and preparation method thereof |
| CN104861470A (en) * | 2014-10-11 | 2015-08-26 | 青岛欣展塑胶有限公司 | PBT filling color master batch |
| CN105017742A (en) * | 2014-04-15 | 2015-11-04 | 安炬科技股份有限公司 | Graphene color master batch |
| CN105802140A (en) * | 2016-03-14 | 2016-07-27 | 浙江金彩新材料有限公司 | Heat discoloration color master batches for polyester fiber and preparing method thereof |
| CN106800752A (en) * | 2016-12-23 | 2017-06-06 | 苏州曙帆信电子科技有限公司 | A kind of fast light blast PET color master batch |
-
2017
- 2017-06-13 CN CN201710443485.5A patent/CN107286593A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2548657A1 (en) * | 2011-07-22 | 2013-01-23 | International Automotive Components Group GmbH | Coated plastic part and method of producing a coated plastic part |
| CN103709489A (en) * | 2012-09-29 | 2014-04-09 | 青岛欣展塑胶有限公司 | General white master batch and preparation method thereof |
| CN105017742A (en) * | 2014-04-15 | 2015-11-04 | 安炬科技股份有限公司 | Graphene color master batch |
| CN104861470A (en) * | 2014-10-11 | 2015-08-26 | 青岛欣展塑胶有限公司 | PBT filling color master batch |
| CN105802140A (en) * | 2016-03-14 | 2016-07-27 | 浙江金彩新材料有限公司 | Heat discoloration color master batches for polyester fiber and preparing method thereof |
| CN106800752A (en) * | 2016-12-23 | 2017-06-06 | 苏州曙帆信电子科技有限公司 | A kind of fast light blast PET color master batch |
Non-Patent Citations (1)
| Title |
|---|
| 姚连珍，等: "智能纤维及其纺织品的研究进展", 《智能纤维及其纺织品的研究进展》 * |
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Application publication date: 20171024 |