CN107286263A - 一种油/水两亲性淀粉衍生物及其制备方法和用途 - Google Patents
一种油/水两亲性淀粉衍生物及其制备方法和用途 Download PDFInfo
- Publication number
- CN107286263A CN107286263A CN201710605247.XA CN201710605247A CN107286263A CN 107286263 A CN107286263 A CN 107286263A CN 201710605247 A CN201710605247 A CN 201710605247A CN 107286263 A CN107286263 A CN 107286263A
- Authority
- CN
- China
- Prior art keywords
- starch
- weight
- parts
- oil
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 229920000881 Modified starch Polymers 0.000 title claims abstract description 66
- 235000019426 modified starch Nutrition 0.000 title claims abstract description 66
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- 229920002472 Starch Polymers 0.000 claims abstract description 165
- 235000019698 starch Nutrition 0.000 claims abstract description 165
- 239000008107 starch Substances 0.000 claims abstract description 163
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical group CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 84
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 43
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 42
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 29
- 239000007864 aqueous solution Substances 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 238000006467 substitution reaction Methods 0.000 claims description 27
- 229920002261 Corn starch Polymers 0.000 claims description 23
- 239000008120 corn starch Substances 0.000 claims description 23
- 229940099112 cornstarch Drugs 0.000 claims description 23
- 238000006266 etherification reaction Methods 0.000 claims description 23
- 238000010792 warming Methods 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 235000019260 propionic acid Nutrition 0.000 claims description 20
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 20
- 230000032050 esterification Effects 0.000 claims description 19
- 238000005886 esterification reaction Methods 0.000 claims description 19
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 15
- -1 Chloroacetic acid sodium ethoxide Chemical compound 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 5
- 229940106681 chloroacetic acid Drugs 0.000 claims description 5
- 239000012362 glacial acetic acid Substances 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- 239000013049 sediment Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000007039 two-step reaction Methods 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims 1
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 claims 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 74
- 229920000728 polyester Polymers 0.000 abstract description 61
- 239000002002 slurry Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 description 43
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 28
- 230000000694 effects Effects 0.000 description 20
- 239000004753 textile Substances 0.000 description 18
- 238000004513 sizing Methods 0.000 description 17
- 235000011187 glycerol Nutrition 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 240000003183 Manihot esculenta Species 0.000 description 14
- 239000004014 plasticizer Substances 0.000 description 13
- 239000005020 polyethylene terephthalate Substances 0.000 description 13
- 229920004933 Terylene® Polymers 0.000 description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 10
- 239000004202 carbamide Substances 0.000 description 10
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 150000002314 glycerols Chemical class 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000009990 desizing Methods 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical class NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000001254 oxidized starch Substances 0.000 description 6
- 235000013808 oxidized starch Nutrition 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 238000009955 starching Methods 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 238000004925 denaturation Methods 0.000 description 5
- 230000036425 denaturation Effects 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical class NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical group CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 150000002895 organic esters Chemical class 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical group OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- GUOCOOQWZHQBJI-UHFFFAOYSA-N 4-oct-7-enoxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCCCCCCC=C GUOCOOQWZHQBJI-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 241000256135 Chironomus thummi Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 244000151018 Maranta arundinacea Species 0.000 description 1
- 235000010804 Maranta arundinacea Nutrition 0.000 description 1
- 235000012419 Thalia geniculata Nutrition 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-DVKNGEFBSA-N alpha-D-glucose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-DVKNGEFBSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- JBJWASZNUJCEKT-UHFFFAOYSA-M sodium;hydroxide;hydrate Chemical compound O.[OH-].[Na+] JBJWASZNUJCEKT-UHFFFAOYSA-M 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/16—Ether-esters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710605247.XA CN107286263B (zh) | 2017-07-24 | 2017-07-24 | 一种油/水两亲性淀粉衍生物及其制备方法和用途 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710605247.XA CN107286263B (zh) | 2017-07-24 | 2017-07-24 | 一种油/水两亲性淀粉衍生物及其制备方法和用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107286263A true CN107286263A (zh) | 2017-10-24 |
CN107286263B CN107286263B (zh) | 2020-10-23 |
Family
ID=60102995
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710605247.XA Active CN107286263B (zh) | 2017-07-24 | 2017-07-24 | 一种油/水两亲性淀粉衍生物及其制备方法和用途 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107286263B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108164609A (zh) * | 2017-12-19 | 2018-06-15 | 广州市高士实业有限公司 | 一种羧甲基乙酰基醚酯化协同复合改性淀粉及其制备方法 |
CN110343184A (zh) * | 2019-08-08 | 2019-10-18 | 广西民族大学 | 一种醚化-酯化淀粉基表面活性剂及其制备方法 |
CN110511289A (zh) * | 2019-08-23 | 2019-11-29 | 安徽工程大学 | 一种具有低表面张力的双重酯化淀粉浆料及其制备方法 |
CN112961293A (zh) * | 2021-04-21 | 2021-06-15 | 安徽工程大学 | 一种两步制备高表面活性两亲性接枝淀粉浆料的制备方法及其产品和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000072801A (ja) * | 1998-08-31 | 2000-03-07 | Oji Cornstarch Kk | カルボキシアルキルエーテル化澱粉のエステル架橋化誘導体を含む組成物及びその製造方法 |
CN1844152A (zh) * | 2006-04-25 | 2006-10-11 | 李国桐 | 有机酯化淀粉的生产方法 |
CN102199639A (zh) * | 2011-04-11 | 2011-09-28 | 江南大学 | 一种羧甲基淀粉硬脂酸酯及其制备方法 |
CN102477100A (zh) * | 2010-11-23 | 2012-05-30 | 兰州瑞特变性淀粉科技有限公司 | 酯化-醚化双变性淀粉及其固相制备方法 |
-
2017
- 2017-07-24 CN CN201710605247.XA patent/CN107286263B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000072801A (ja) * | 1998-08-31 | 2000-03-07 | Oji Cornstarch Kk | カルボキシアルキルエーテル化澱粉のエステル架橋化誘導体を含む組成物及びその製造方法 |
CN1844152A (zh) * | 2006-04-25 | 2006-10-11 | 李国桐 | 有机酯化淀粉的生产方法 |
CN102477100A (zh) * | 2010-11-23 | 2012-05-30 | 兰州瑞特变性淀粉科技有限公司 | 酯化-醚化双变性淀粉及其固相制备方法 |
CN102199639A (zh) * | 2011-04-11 | 2011-09-28 | 江南大学 | 一种羧甲基淀粉硬脂酸酯及其制备方法 |
Non-Patent Citations (3)
Title |
---|
张惠 等: "丙酸酯变性淀粉浆料的研究", 《东华大学学报(自然科学版)》 * |
祝志峰 等: "低取代度羧甲基淀粉对纤维粘附性能", 《高分子材料科学与工程》 * |
祝志峰 等: "涤/棉混纺经纱接枝变性淀粉浆料的单体选择", 《纺织学报》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108164609A (zh) * | 2017-12-19 | 2018-06-15 | 广州市高士实业有限公司 | 一种羧甲基乙酰基醚酯化协同复合改性淀粉及其制备方法 |
CN108164609B (zh) * | 2017-12-19 | 2020-05-12 | 广州市高士实业有限公司 | 一种羧甲基乙酰基醚酯化协同复合改性淀粉及其制备方法 |
CN110343184A (zh) * | 2019-08-08 | 2019-10-18 | 广西民族大学 | 一种醚化-酯化淀粉基表面活性剂及其制备方法 |
CN110511289A (zh) * | 2019-08-23 | 2019-11-29 | 安徽工程大学 | 一种具有低表面张力的双重酯化淀粉浆料及其制备方法 |
CN112961293A (zh) * | 2021-04-21 | 2021-06-15 | 安徽工程大学 | 一种两步制备高表面活性两亲性接枝淀粉浆料的制备方法及其产品和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN107286263B (zh) | 2020-10-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107286263A (zh) | 一种油/水两亲性淀粉衍生物及其制备方法和用途 | |
CN102978984B (zh) | 一种表面改性的球磨细化植物纤维的制备方法 | |
CN101173107B (zh) | 木质素-无机纳米复合材料及制备方法 | |
CN1102944C (zh) | 复合树脂组合物 | |
CN102604349B (zh) | 一种聚乳酸/淀粉全生物基可降解复合材料及其制备方法 | |
CN109487545B (zh) | 一种改善麻/树脂复合材料界面黏结性的方法 | |
CN107254777A (zh) | 一种改善淀粉浆料对涤纶短纤维粘合强度的方法 | |
CN105885111A (zh) | 一种易降解塑料袋 | |
CN112709092A (zh) | 一种以纺织、工业、农业废渣制造的纸张和造纸方法 | |
Pitaloka et al. | Water hyacinth for superabsorbent polymer material | |
CN105218868A (zh) | 一步改性疏水型热塑性淀粉基可生物降解材料及制备方法 | |
CN1021351C (zh) | 纺织品经纱浆料 | |
CN101353393B (zh) | 一种具有改进侧枝构成的接枝淀粉及其清洁制备方法和应用 | |
CN105885112A (zh) | 一种环保塑料袋 | |
CN102898594B (zh) | 脂肪族水性聚酯接枝共聚物、改善淀粉浆料对涤纶纤维粘合强度的粘合促进剂及制备方法 | |
CN107955987A (zh) | 一种稀土夜光纤维的制备方法 | |
CN102277655A (zh) | 一种可生物降解淀粉基纤维的制造方法 | |
CN101274975A (zh) | 一种对接枝淀粉浆料提高接枝效率的方法 | |
CN108485299A (zh) | 一种植物纤维餐具的制备方法 | |
CN107385911A (zh) | 一种粘合促进剂及其制备方法和用途 | |
Satyamurthy et al. | Nanocellulose induces cellulase production in Trichoderma reesei | |
TWI577725B (zh) | One - step modified hydrophobic thermoplastic starch - based biodegradable material and its preparation method | |
CN101368335B (zh) | 一种用于热敏感型经纱低温上浆的变性淀粉浆料及其制备方法 | |
CN109811585B (zh) | 一种提高箱板纸强度性能的方法 | |
Xiao et al. | Current situation of environment protection sizing agent and paste |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to an oil / water amphiphilic starch derivative and a preparation method and application thereof Effective date of registration: 20220427 Granted publication date: 20201023 Pledgee: Agricultural Bank of China Limited by Share Ltd. Wuxi Xishan branch Pledgor: XIDA (WUXI) BIOTECHNOLOGY CO.,LTD. Registration number: Y2022980004801 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230830 Granted publication date: 20201023 Pledgee: Agricultural Bank of China Limited by Share Ltd. Wuxi Xishan branch Pledgor: XIDA (WUXI) BIOTECHNOLOGY CO.,LTD. Registration number: Y2022980004801 |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231010 Address after: Floor 2, No. 10, Lane 658, Jinzhong Road, Changning District, Shanghai, 200000 Patentee after: Xinxida (Shanghai) Biotechnology Co.,Ltd. Address before: 214000 south of Jiaoyang Road, west of Dongsheng 2nd Road, high tech Industrial Park, Xishan Economic Development Zone, Wuxi City, Jiangsu Province Patentee before: XIDA (WUXI) BIOTECHNOLOGY CO.,LTD. |