CN107267161A - A kind of environment friendly flame retardant - Google Patents
A kind of environment friendly flame retardant Download PDFInfo
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- CN107267161A CN107267161A CN201610212439.XA CN201610212439A CN107267161A CN 107267161 A CN107267161 A CN 107267161A CN 201610212439 A CN201610212439 A CN 201610212439A CN 107267161 A CN107267161 A CN 107267161A
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- flame retardant
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- environment friendly
- firebrake
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/10—Organic materials containing nitrogen
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention belongs to chemical technology field, specifically a kind of environment friendly flame retardant.The component of the present invention includes：Diethylene triamine, Firebrake ZB, ferrocene, pentaerythrite, polyol resin；Hydrotalcite, lauryl sodium sulfate and urea.The present invention is a kind of new halogen-free flame retardants, with heat endurance it is high, to base material inertia, it is nontoxic, environmentally friendly the characteristics of.Trap heat and starvation reach flame retardant effect during high-temp combustion, and smoke amount it is extremely low, nontoxic, without molten drop, be particularly suitable for use in the high fire-retardant place of oxygen index (OI) requirement.In addition, the manufacturing cost of the present invention is not high, and it is practical, it is adapted to promote the use of in Related product field.
Description
Technical field
The invention belongs to chemical technology field, specifically a kind of environment friendly flame retardant.
Background technology
With the development and the continuous expansion of application field of China's synthetic material industry, fire retardant is widely used in chemistry
In the every field such as building materials, electronic apparatus, communications and transportation, space flight and aviation, household furniture, interior decoration, clothing, food, lodging and transportion -- basic necessities of life.China hinders
Combustion agent has evolved into the second largest polymer modification additive for being only second to plasticizer, 200,000 tons or so of annual consumption.
Although the most frequently used halogenated flame retardant has the unrivaled high efficiency of other fire retardants series in fire retardant,
Its hazard ratio to environment and people is more serious.Accordingly, it would be desirable to which the improvement in technical progress, structure, mitigates fire retardant to ring
The harm in border.
The content of the invention
The invention aims to solve deficiency of the prior art, there is provided a kind of environment friendly flame retardant.
The present invention includes following components：
Diethylene triamine, Firebrake ZB, ferrocene, pentaerythrite, polyol resin；Hydrotalcite, lauryl sodium sulfate and
Urea.
It is preferred that, described component proportion includes：
10-25 parts of diethylene triamine；
20-35 parts of Firebrake ZB；
5-9 parts of ferrocene；
4-8 parts of pentaerythrite；
5 parts of polyol resin；
10-20 parts of hydrotalcite；
1-2 parts of lauryl sodium sulfate；
4-8 parts of urea.
It is preferred that, described component proportion includes：
15-20 parts of diethylene triamine；
22-30 parts of Firebrake ZB；
6-8 parts of ferrocene；
5-7 parts of pentaerythrite；
5 parts of polyol resin；
13-18 parts of hydrotalcite；
1-2 parts of lauryl sodium sulfate；
5-7 parts of urea.
It is preferred that, described component proportion includes：
17 parts of diethylene triamine；
28 parts of Firebrake ZB；
8 parts of ferrocene；
6 parts of pentaerythrite；
5 parts of polyol resin；
15 parts of hydrotalcite；
2 parts of lauryl sodium sulfate；
6 parts of urea.
The present invention is a kind of new halogen-free flame retardants, with heat endurance height, to base material inertia, nontoxic, environmentally friendly spy
Point.Trap heat and starvation reach flame retardant effect during high-temp combustion, and smoke amount it is extremely low, nontoxic, without molten drop,
It is particularly suitable for use in the high fire-retardant place of oxygen index (OI) requirement.In addition, the manufacturing cost of the present invention is not high, and it is practical, it is adapted in phase
Product scope is closed to promote the use of.
Embodiment
It present invention will be described in further detail below, which show the preferred embodiments of the present invention, it should be appreciated that
Those skilled in the art can change invention described herein and still realize advantageous effects of the invention.Therefore, it is following to retouch
State and be appreciated that for the widely known of those skilled in the art, and be not intended as limitation of the present invention.
For clarity, not describing whole features of practical embodiments.In the following description, it is not described in detail known function
And structure, because they can make the present invention chaotic due to unnecessary details.It will be understood that opening in any practical embodiments
In hair, it is necessary to make a large amount of implementation details to realize the specific objective of developer, such as according to relevant system or relevant business
Limitation, another embodiment is changed into by one embodiment.Additionally, it should think that this development is probably complicated and expended
Time, but it is only to those skilled in the art routine work.
To become apparent the purpose of the present invention, feature, the embodiment to the present invention makees further below
Explanation.
Embodiment one：
The component proportion of environment friendly flame retardant of the present invention includes：
10-25 parts of diethylene triamine；20-35 parts of Firebrake ZB；5-9 parts of ferrocene；
4-8 parts of pentaerythrite；5 parts of polyol resin；10-20 parts of hydrotalcite；1-2 parts of lauryl sodium sulfate；Urea 4-8
Part.
Embodiment two：
The component proportion of environment friendly flame retardant of the present invention includes：
15-20 parts of diethylene triamine；22-30 parts of Firebrake ZB；
6-8 parts of ferrocene；5-7 parts of pentaerythrite；5 parts of polyol resin；13-18 parts of hydrotalcite；
1-2 parts of lauryl sodium sulfate；5-7 parts of urea.
Embodiment three：
The component optimum proportioning of environment friendly flame retardant of the present invention includes：
17 parts of diethylene triamine；28 parts of Firebrake ZB；
8 parts of ferrocene；6 parts of pentaerythrite；5 parts of polyol resin；15 parts of hydrotalcite；
2 parts of lauryl sodium sulfate；6 parts of urea.
The present invention is a kind of new halogen-free flame retardants, generates one layer of uniform carbonaceous coatings in compound surface, can rise
To heat-insulated, the effect such as oxygen barrier and suppression cigarette, the phenomenons such as dissolved drip are effectively prevented.In Fourier turn infrared
(FTR) during, thermogravimetric (TG), differential scanning calorimetry (DSC) analysis are determined, the fire retardant has cyclic structure, in (TG) analysis
It is middle to find, with excellent heat endurance and higher into carbon, to reach more than 46% into carbon, raw smoke reduce 30%-
80%, with good flame retardant effect.
The environment friendly flame retardant of the present invention is widely used in various fireproof coatings, fire-retarding of wood, fabrics flame resistance field, simultaneously
The characteristics of with high-effect fire-extinguishing is played to chemicals, combustion gas, oil product, heavy chemicals, forest extinguishing etc., with higher society
Benefit.
A variety of modifications to these embodiments will be apparent for those skilled in the art, herein
Defined General Principle can be real in other embodiments in the case where not departing from the spirit or scope of the embodiment of the present invention
It is existing.Therefore, the embodiment of the present invention is not intended to be limited to the embodiments shown herein, and be to fit to it is disclosed herein
The principle most wide scope consistent with features of novelty.
The preferred embodiment of the embodiment of the present invention is these are only, embodiment is not intended to limit the invention, it is all at this
Within the spirit and principle of inventive embodiments, any modification, equivalent substitution and improvements made etc. should be included in of the invention real
Apply within the protection domain of example.
Claims (4)
1. a kind of environment friendly flame retardant, it is characterised in that including following components：
Diethylene triamine, Firebrake ZB, ferrocene, pentaerythrite, polyol resin, hydrotalcite, lauryl sodium sulfate and urea.
2. a kind of environment friendly flame retardant according to claim 1, it is characterised in that described component proportion includes：
10-25 parts of diethylene triamine；
20-35 parts of Firebrake ZB；
5-9 parts of ferrocene；
4-8 parts of pentaerythrite；
5 parts of polyol resin；
10 1 20 parts of hydrotalcite；
1-2 parts of lauryl sodium sulfate；
4-8 parts of urea.
3. a kind of environment friendly flame retardant according to claim 2, it is characterised in that described component proportion includes：
15-20 parts of diethylene triamine；
22-30 parts of Firebrake ZB；
6-8 parts of ferrocene；
5-7 parts of pentaerythrite；
5 parts of polyol resin；
13-18 parts of hydrotalcite；
1-2 parts of lauryl sodium sulfate；
5-7 parts of urea.
4. a kind of environment friendly flame retardant according to claim 2, it is characterised in that described component proportion includes：
17 parts of diethylene triamine；
28 parts of Firebrake ZB；
8 parts of ferrocene；
6 parts of pentaerythrite；
5 parts of polyol resin；
15 parts of hydrotalcite；
2 parts of lauryl sodium sulfate；
6 parts of urea.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610212439.XA CN107267161A (en) | 2016-04-07 | 2016-04-07 | A kind of environment friendly flame retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610212439.XA CN107267161A (en) | 2016-04-07 | 2016-04-07 | A kind of environment friendly flame retardant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107267161A true CN107267161A (en) | 2017-10-20 |
Family
ID=60052294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610212439.XA Pending CN107267161A (en) | 2016-04-07 | 2016-04-07 | A kind of environment friendly flame retardant |
Country Status (1)
| Country | Link |
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| CN (1) | CN107267161A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746734A (en) * | 2019-11-07 | 2020-02-04 | 厦门港沅塑胶工业有限公司 | High-toughness styrene thermoplastic elastomer and preparation method thereof |
Citations (8)
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|---|---|---|---|---|
| CN1170029A (en) * | 1996-05-23 | 1998-01-14 | 沃尔曼股份公司 | Fire-resistant rear-ventilated cladding |
| US20070129452A1 (en) * | 2005-12-01 | 2007-06-07 | Bayer Materialscience Llc | Water-blown, flame retardant rigid polyurethane foam |
| CN101875745A (en) * | 2010-03-30 | 2010-11-03 | 金发科技股份有限公司 | Flame-retardant styrene polymer compound containing smoke inhibitor and preparation method thereof |
| CN102031124A (en) * | 2009-09-29 | 2011-04-27 | 朱盈豹 | Environment-friendly flame-retardant agent |
| CN102585845A (en) * | 2010-12-31 | 2012-07-18 | 梁清源 | Inorganic mineral composite flame retardant and preparation method thereof |
| WO2013032447A1 (en) * | 2011-08-30 | 2013-03-07 | Empire Technology Development Llc | Ferrocene /carbon dioxide releasing system |
| CN103724666A (en) * | 2013-12-26 | 2014-04-16 | 辽宁工程技术大学 | Composite flame retardant containing microcapsule-coated intumescent flame retardant and preparation method |
| CN104647518A (en) * | 2013-11-22 | 2015-05-27 | 高天红 | Composite efficient fire retardant used for wood fire retardation and containing phosphorus, nitrogen and boron |
-
2016
- 2016-04-07 CN CN201610212439.XA patent/CN107267161A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170029A (en) * | 1996-05-23 | 1998-01-14 | 沃尔曼股份公司 | Fire-resistant rear-ventilated cladding |
| US20070129452A1 (en) * | 2005-12-01 | 2007-06-07 | Bayer Materialscience Llc | Water-blown, flame retardant rigid polyurethane foam |
| CN102031124A (en) * | 2009-09-29 | 2011-04-27 | 朱盈豹 | Environment-friendly flame-retardant agent |
| CN101875745A (en) * | 2010-03-30 | 2010-11-03 | 金发科技股份有限公司 | Flame-retardant styrene polymer compound containing smoke inhibitor and preparation method thereof |
| CN102585845A (en) * | 2010-12-31 | 2012-07-18 | 梁清源 | Inorganic mineral composite flame retardant and preparation method thereof |
| WO2013032447A1 (en) * | 2011-08-30 | 2013-03-07 | Empire Technology Development Llc | Ferrocene /carbon dioxide releasing system |
| CN104647518A (en) * | 2013-11-22 | 2015-05-27 | 高天红 | Composite efficient fire retardant used for wood fire retardation and containing phosphorus, nitrogen and boron |
| CN103724666A (en) * | 2013-12-26 | 2014-04-16 | 辽宁工程技术大学 | Composite flame retardant containing microcapsule-coated intumescent flame retardant and preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746734A (en) * | 2019-11-07 | 2020-02-04 | 厦门港沅塑胶工业有限公司 | High-toughness styrene thermoplastic elastomer and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171020 |
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| RJ01 | Rejection of invention patent application after publication |