CN107267151A - A kind of soil conditioner and preparation method thereof - Google Patents
A kind of soil conditioner and preparation method thereof Download PDFInfo
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- CN107267151A CN107267151A CN201710623164.3A CN201710623164A CN107267151A CN 107267151 A CN107267151 A CN 107267151A CN 201710623164 A CN201710623164 A CN 201710623164A CN 107267151 A CN107267151 A CN 107267151A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/02—Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
- C09K17/10—Cements, e.g. Portland cement
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2109/00—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The present invention relates to a kind of soil conditioner, the soil conditioner is made up of following raw material by weight percentage：Portland clinker 10%~40%, lime stone 20%~30%, dolomite 10%~30%, sepiolite 5%~15%, zeolite 1%~10%, bentonite 1%~10%, iron ore 3%~8%, activated carbon 1%~10%.The invention further relates to the preparation method of the soil conditioner, the preparation method is：(1) kiln calcining is entered after crushing lime stone, dolomite, then discharging is cooled down；(2) heating and thermal insulation by sepiolite, zeolite, bentonite, iron ore and activated carbon be broken, after grinding, then discharging is cooled down；(3) grinding, sieving, obtain the soil conditioner after mixing step (1), step (2) resulting material with Portland clinker.Soil conditioner energy improved soil acidifying of the present invention, suppresses crops and absorbs heavy metal, increase crop yield.
Description
Technical field
The present invention relates to farmland soil modifying technical field, more particularly to a kind of soil conditioner and preparation method thereof.
Background technology
At present, excessive apply of the substantial amounts of industrial activity of China and farmland fertilizer causes soil acidification to aggravate, and adds
Total metalses and bio-available Zn concentration increase in the discharge of trade waste, soil, cause weight in the crops of part plantation
Overrun metal content.Therefore, Chinese Ministry of Environmental Protection in 2016 has put into effect " Soil Pollution Control action plan ", it is determined that to ensure agricultural product
Quality safety administers policy for the agricultural land soil of general thought.
Although there is various soil conditioners to can be used for improving soil property on the market now, their effect is mainly
Solve soil property acidifying, salinization, the problems such as hardened, fertilising is excessive, can not specific aim, efficiently reduce heavy metal pollution of soil pair
The negative effect of agricultural product, the quality safety of agricultural product is still difficult to be guaranteed.
The content of the invention
Based on this, it is an object of the present invention to provide a kind of soil conditioner, it can improved soil acidifying, suppression farming
Thing absorbs heavy metal, increases crop yield.
The technical solution adopted by the present invention is as follows：
A kind of soil conditioner, is made up of following raw material by weight percentage：Portland clinker 10%~40%,
Lime stone 20%~30%, dolomite 10%~30%, sepiolite 5%~15%, zeolite 1%~10%, bentonite 1%~
10%th, iron ore 3%~8%, activated carbon 1%~10%.
Wherein, Portland clinker is a kind of important industrial binder materials of China, and it is mainly generated after being reacted with water
Hydrated calcium silicate gel and calcium hydroxide, hydrated calcium silicate gel heavy metal ion have stronger adsorption capacity；Lime stone
Main component be to generate calcium oxide after calcium carbonate, calcining；The main component of dolomite is CaMg (CO3)2, oxygen is generated after calcining
Change calcium and magnesia；Sepiolite is a kind of hydrous magnesium silicate clay mineral, and its specific surface area is big, is that adsorption capacity is most strong glutinous
Native mineral；Zeolite is a kind of aluminosilicate mineral, and it has adsorptivity, is widely used as adsorbent；Bentonitic main component
It is montmorillonite, is also a kind of aluminosilicate mineral, it has adsorptivity and cation exchange property；Iron ore contain iron simple substance and
Iron compound；Activated carbon has huge specific surface area and complicated pore structure, is widely used as adsorbent.
Soil conditioner of the present invention is applied to after soil to react with water, the hydroxide that basic anhydride are generated with water
Thing such as calcium hydroxide, magnesium hydroxide can effective sweetening of the soil acidity, and increase the calcium in soil, magnesium ion, portland cement
The gel of calcium silicate of clinker generation can be passivated and adsorb the heavy metal ion in soil, and sepiolite, zeolite, bentonite, iron ore
There is suction-operated to the contents of many kinds of heavy metal ion in soil after stone, activated carbon compounding, heavy metal can be reduced and shifted to crops,
So as to reduce the absorption of crop heavy metal, improve soil physical chemistry character, promote crop growth.
Rationally, cost is low, can in advance prepare and store for future use, easy to use, energy for the formula of the soil conditioner of the present invention
Improve the heavy metal transfer in Farmland Soil Acidification, reduction soil, reduce the content of beary metal in crops, meet country to agriculture
The policy of field remediation contaminated soil, to ensureing that consumer's food security has important facilitation.
Further, the soil conditioner is made up of following raw material by weight percentage：Portland clinker
35%th, lime stone 25%, dolomite 10%, sepiolite 12%, zeolite 5%, bentonite 5%, iron ore 5%, activated carbon 3%.
Further, the soil conditioner is made up of following raw material by weight percentage：Portland clinker
25%th, lime stone 20%, dolomite 15%, sepiolite 15%, zeolite 5%, bentonite 10%, iron ore 8%, activated carbon 2%.
Further, the lime saturation factor of the Portland clinker is 0.70~0.90；Oxygen in the lime stone
The content for changing calcium is more than or equal to 45%；The content of magnesia is 15%~35% in the dolomite.
Further, the bentonite is the one or more in calcium bentonite, hydrogen matter bentonite, organobentonite；
The iron ore is the one or more in limonite, goethite, bloodstone.
The present invention also provides the preparation method of the soil conditioner described in any of the above-described, and the preparation method includes following step
Suddenly：
(1) kiln calcining is entered after crushing lime stone, dolomite, then discharging is cooled down；
(2) heating and thermal insulation by sepiolite, zeolite, bentonite, iron ore and activated carbon be broken, after grinding, then discharging is cold
But；
(3) grinding, sieving after mixing step (1), step (2) resulting material with Portland clinker, obtain described
Soil conditioner.
In step (1), generated after limestone calcination and calcium oxide and magnesia are generated after calcium oxide, dolomite calcination；Step
(2) in, heating and thermal insulation can remove the crystallization water in material, it is ensured that have enough pore structures to be used for Adsorption of Heavy Metals.
Further, step (1) is：Lime stone, dolomite are broken into after 3~5 centimetres of sizes enter kiln be fired to 600~
1000 DEG C, then discharging is cooled down.
By the block for being broken into certain size of lime stone and dolomite, be conducive to improving calcination efficiency, and limit calcining
Temperature, can ensure that lime stone is fully decomposed into calcium oxide, while ensuring that dolomite is fully decomposed into calcium oxide and magnesia.
Further, step (2) is：By sepiolite, zeolite, bentonite, iron ore and activated carbon be broken, grinding to 80~
80 DEG C~300 DEG C are heated to after 100 mesh, and is incubated 0.5~3 hour, then discharging is cooled down.
By sepiolite, zeolite, bentonite, iron ore and activated carbon be broken, grinding into the powder of certain size, be easy to uniform
Heating, while being easy to make further levigate in step (3).By limiting the scope of heating-up temperature and soaking time, on the one hand
Ensure that heating is abundant, remove the crystallization water in material, material is possessed enough pore structures, strengthen the effect of Adsorption of Heavy Metals
Really, over-heating is on the other hand avoided to destroy the crystal structure of material.
Further, step (3) is：Powder after step (1), step (2) resulting material are mixed with Portland clinker
100~200 mesh, sieving are milled to, the soil conditioner is obtained, then test, pack, be put in storage.The grinding of soil conditioner
Fineness determines that soil stickiness is lower, and soil conditioner grinding particle can be smaller with specific reference to the viscosity of soil, it is to avoid native during administration
There is hardened phenomenon in earth.
The present invention also provides the application method of the soil conditioner described in any of the above-described, and the application method includes as follows
Step：100kg~400kg soil conditioners are uniformly spread fertilizer over the fields in every mu of farmland, and after rotary tillage 1~2 time, farming is planted in interval after 2~5 days
Thing.Specifically, using measurement soil pH and content of beary metal is before needed, the consumption of soil conditioner is adjusted according to measurement result.
Embodiment
Embodiment one
Good following raw material is weighed by weight ratio：Portland clinker 35%, lime stone 25%, dolomite 10%, sea
Afrodite 12%, zeolite 5%, bentonite 5%, iron ore 5%, activated carbon 3%.
Lime stone, dolomite are broken into and enters kiln after 3~5 centimetres of sizes and is fired to 800 DEG C, then discharging is cooled down.By sea
Afrodite, zeolite, bentonite, iron ore and activated carbon are broken, be heated to 100 DEG C after grinding to 80~100 mesh, and are incubated 2 hours,
Then discharging is cooled down.Grinding is obtained to 100~200 mesh, sieving after above step resulting material is mixed with Portland clinker
To soil conditioner, then test, pack, be put in storage.
Using preceding measurement soil pH and content of beary metal, it is made according to measurement result per the even 100kg~400kg that spreads fertilizer over the fields per mu
Soil conditioner, after rotary tillage 1~2 time, be spaced 2~5 days or so rear Planting Crops.
Embodiment two
Good following raw material is weighed by weight ratio：Portland clinker 25%, lime stone 20%, dolomite 15%, sea
Afrodite 15%, zeolite 5%, bentonite 10%, iron ore 8%, activated carbon 2%.
Lime stone, dolomite are broken into and enters kiln after 3~5 centimetres of sizes and is fired to 1000 DEG C, then discharging is cooled down.By sea
Afrodite, zeolite, bentonite, iron ore and activated carbon are broken, be heated to 200 DEG C after grinding to 80~100 mesh, and are incubated 1 hour,
Then discharging is cooled down.Grinding is obtained to 100~200 mesh, sieving after above step resulting material is mixed with Portland clinker
To soil conditioner, then test, pack, be put in storage.
Using preceding measurement soil pH and content of beary metal, it is made according to measurement result per the even 100kg~400kg that spreads fertilizer over the fields per mu
Soil conditioner, after rotary tillage 1~2 time, be spaced 2~5 days or so rear Planting Crops.
Embodiment three
Good following raw material is weighed by weight ratio：Portland clinker 10%, lime stone 30%, dolomite 30%, sea
Afrodite 6%, zeolite 10%, bentonite 1%, iron ore 3%, activated carbon 10%.
Lime stone, dolomite are broken into after 3~5cm sizes and enters kiln and is fired to 600 DEG C, then discharging is cooled down.By Hai Pao
Stone, zeolite, bentonite, iron ore and activated carbon are broken, be heated to 300 DEG C after grinding to 80~100 mesh, and are incubated 0.5 hour,
Then discharging is cooled down.Grinding is obtained to 100~200 mesh, sieving after above step resulting material is mixed with Portland clinker
To soil conditioner, then test, pack, be put in storage.
Using preceding measurement soil pH and content of beary metal, it is made according to measurement result per the even 100kg~400kg that spreads fertilizer over the fields per mu
Soil conditioner, after rotary tillage 1~2 time, be spaced 2~5 days or so rear Planting Crops.
Example IV
Good following raw material is weighed by weight ratio：Portland clinker 40%, lime stone 20%, dolomite 20%, sea
Afrodite 5%, zeolite 3%, bentonite 5%, iron ore 4%, activated carbon 3%.
Lime stone, dolomite are broken into and enters kiln after 3~5 centimetres of sizes and is fired to 900 DEG C, then discharging is cooled down.By sea
Afrodite, zeolite, bentonite, iron ore and activated carbon are broken, be heated to 80 DEG C after grinding to 80~100 mesh, and are incubated 3 hours,
Then discharging is cooled down.Grinding is obtained to 100~200 mesh, sieving after above step resulting material is mixed with Portland clinker
To soil conditioner, then test, pack, be put in storage.
Using preceding measurement soil pH and content of beary metal, it is made according to measurement result per the even 100kg~400kg that spreads fertilizer over the fields per mu
Soil conditioner, after rotary tillage 1~2 time, be spaced 2~5 days or so rear Planting Crops.
Effect test
Soil conditioner made from embodiment one to four is applied to paddy rice cell respectively as experiment, each plot area
For 30m2, according to every 667m2Using the consumption of 300kg soil conditioners, in triplicate, to verify soil conditioning of the present invention
Agent improved soil is acidified, and suppresses rice absorbing heavy metal, increases the effect of rice yield.
(1) soil conditioner is applied to experimental field one
Before soil conditioner, experimental field the basic physicochemical character of one soil see the table below 1.
Table 1
Using soil conditioner, plant and gather in paddy rice after, detection experimental field one soil pH value, cell rice yield
And the content of beary metal in output brown rice, specific testing result such as table 2 below.
Table 2
(2) soil conditioner is applied to experimental field two
The experimental field basic physicochemical character of two soil such as table 3 below.
Table 3
Using soil conditioner, plant and gather in paddy rice after, detection experimental field two soil pH value, cell rice yield
And the content of beary metal in output brown rice, specific testing result such as table 4 below.
Table 4
(3) test result analysis
Contrast Tables 1 and 2, contrast table 3 and table 4 are understood respectively, compared with applying the soil pH before soil conditioner, are applied
Soil pH value is significantly improved after soil conditioner made from embodiment one to four.
It can be seen that, compared with not applying the processing mode of soil conditioner, made using embodiment one to four by table 2 and table 4
Soil conditioner after soil acidification situation be improved significantly, per 30m2The rice yield of plot area is dramatically increased, and
And cadmium, lead, chromium, mercury, the content of the heavy metal species of arsenic five are also substantially reduced in output brown rice, especially cadmium, lead and chromium are turned to crop
The inhibition of shifting is more preferable.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.
Claims (10)
1. a kind of soil conditioner, it is characterised in that：It is made up by weight percentage of following raw material：Portland clinker
10%~40%, lime stone 20%~30%, dolomite 10%~30%, sepiolite 5%~15%, zeolite 1%~10%, swollen
Profit soil 1%~10%, iron ore 3%~8%, activated carbon 1%~10%.
2. soil conditioner according to claim 1, it is characterised in that：It is made up by weight percentage of following raw material：
Portland clinker 35%, lime stone 25%, dolomite 10%, sepiolite 12%, zeolite 5%, bentonite 5%, iron ore
5%th, activated carbon 3%.
3. soil conditioner according to claim 1, it is characterised in that：It is made up by weight percentage of following raw material：
Portland clinker 25%, lime stone 20%, dolomite 15%, sepiolite 15%, zeolite 5%, bentonite 10%, iron ore
8%th, activated carbon 2%.
4. the soil conditioner according to claim any one of 1-3, it is characterised in that：The stone of the Portland clinker
Grey saturation coefficient is 0.70~0.90；The content of calcium oxide is more than or equal to 45% in the lime stone；Oxygen in the dolomite
The content for changing magnesium is 15%~35%.
5. the soil conditioner according to claim any one of 1-3, it is characterised in that：The bentonite is calcic bentonite
One or more in soil, hydrogen matter bentonite, organobentonite；The iron ore is one in limonite, goethite, bloodstone
Plant or a variety of.
6. the preparation method of the soil conditioner described in claim any one of 1-5, it is characterised in that comprise the following steps：
(1) kiln calcining is entered after crushing lime stone, dolomite, then discharging is cooled down；
(2) heating and thermal insulation by sepiolite, zeolite, bentonite, iron ore and activated carbon be broken, after grinding, then discharging is cooled down；
(3) grinding, sieving, obtain the soil after mixing step (1), step (2) resulting material with Portland clinker
Conditioner.
7. the preparation method of soil conditioner according to claim 6, it is characterised in that：Step (1) is：By lime stone,
Dolomite, which is broken into, to be entered kiln after 3~5 centimetres of sizes and is fired to 600~1000 DEG C, and then discharging is cooled down.
8. the preparation method of soil conditioner according to claim 6, it is characterised in that：Step (2) is：By sepiolite,
Zeolite, bentonite, iron ore and activated carbon are broken, 80 DEG C~300 DEG C are heated to after grinding to 80~100 mesh, and it is incubated 0.5~
3 hours, then discharging was cooled down.
9. the preparation method of soil conditioner according to claim 6, it is characterised in that：Step (3) is：By step (1),
Grinding obtains the soil conditioning to 100~200 mesh, sieving after step (2) resulting material is mixed with Portland clinker
Agent, then test, pack, be put in storage.
10. the application method of the soil conditioner described in claim any one of 1-5, it is characterised in that comprise the following steps：Often
100kg~400kg soil conditioners are uniformly spread fertilizer over the fields in mu farmland, after rotary tillage 1~2 time, interval Planting Crops after 2~5 days.
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| CN108795430A (en) * | 2018-05-22 | 2018-11-13 | 北京市农林科学院 | A kind of renovation agent and soil remediation method of cadmium pollution soil |
| CN108841394A (en) * | 2018-06-19 | 2018-11-20 | 合肥职业技术学院 | A kind of soil-repairing agent and preparation method thereof based on garden waste and gangue |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0756904A2 (en) * | 1995-07-24 | 1997-02-05 | HARBOUR REMEDIATION & TRANSFER, INC. (HR&T) | Method of soil remediation |
| US20050016421A1 (en) * | 2001-02-14 | 2005-01-27 | Shinsaku Fujimori | Cement composition |
| CN1587157A (en) * | 2004-09-14 | 2005-03-02 | 中国建筑材料科学研究院 | High strength silicate clinker and its preparing method |
| EP1741766A1 (en) * | 2004-01-27 | 2007-01-10 | Incorporated Administrative Agency National Agriculture and Food Research Organisation | Soil solidifying agent |
| JP2008231389A (en) * | 2007-03-20 | 2008-10-02 | Nagara Bionics Kk | Soil depurating and stabilizing agent |
| CN102295933A (en) * | 2011-07-01 | 2011-12-28 | 浙江大学 | Special stabilizing agent for chromium polluted soil |
| CN103922866A (en) * | 2013-01-11 | 2014-07-16 | 海拓(北京)矿物肥料有限公司 | Soil conditioner and preparation method thereof |
| CN105199737A (en) * | 2015-10-28 | 2015-12-30 | 雷志刚 | Soil conditioner used for treating heavy metal pollution |
| CN105316000A (en) * | 2014-07-07 | 2016-02-10 | 山东乾坤环境工程科技有限公司 | Preparation method of medicine for remediation of heavy metal-polluted soil |
-
2017
- 2017-07-27 CN CN201710623164.3A patent/CN107267151B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0756904A2 (en) * | 1995-07-24 | 1997-02-05 | HARBOUR REMEDIATION & TRANSFER, INC. (HR&T) | Method of soil remediation |
| US20050016421A1 (en) * | 2001-02-14 | 2005-01-27 | Shinsaku Fujimori | Cement composition |
| EP1741766A1 (en) * | 2004-01-27 | 2007-01-10 | Incorporated Administrative Agency National Agriculture and Food Research Organisation | Soil solidifying agent |
| CN1587157A (en) * | 2004-09-14 | 2005-03-02 | 中国建筑材料科学研究院 | High strength silicate clinker and its preparing method |
| JP2008231389A (en) * | 2007-03-20 | 2008-10-02 | Nagara Bionics Kk | Soil depurating and stabilizing agent |
| CN102295933A (en) * | 2011-07-01 | 2011-12-28 | 浙江大学 | Special stabilizing agent for chromium polluted soil |
| CN103922866A (en) * | 2013-01-11 | 2014-07-16 | 海拓(北京)矿物肥料有限公司 | Soil conditioner and preparation method thereof |
| CN105316000A (en) * | 2014-07-07 | 2016-02-10 | 山东乾坤环境工程科技有限公司 | Preparation method of medicine for remediation of heavy metal-polluted soil |
| CN105199737A (en) * | 2015-10-28 | 2015-12-30 | 雷志刚 | Soil conditioner used for treating heavy metal pollution |
Non-Patent Citations (3)
| Title |
|---|
| LAURA CUTILLAS ETAL: "Lithological and land-use based assessment of heavy metal pollution in soils surrounding a cement plant in SW Europe", 《SCIENCE OF THE TOTAL ENVIRONMENT》 * |
| 张杨珠等: "《肥料高效施用技术手册》", 31 August 2013, 湖南科学技术出版社 * |
| 王金恒等: "固化剂对Cd污染土壤的固化效果研究", 《常州大学学报（自然科学版）》 * |
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| CN111876161A (en) * | 2020-08-25 | 2020-11-03 | 广西桂林新大桂工环境科技中心(有限合伙) | Heavy metal curing additive for treating polluted soil and preparation method thereof |
| CN112552919A (en) * | 2020-12-15 | 2021-03-26 | 云南省生态环境科学研究院 | Repairing agent and preparation method and application thereof |
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| CN113817474A (en) * | 2021-11-02 | 2021-12-21 | 创想未来生物工程(北京)有限公司 | Acidic soil conditioner and preparation method thereof |
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| CN114317004A (en) * | 2022-01-28 | 2022-04-12 | 徐光� | Medium-element water-soluble fertilizer and soil conditioner and preparation method thereof |
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