CN107263972A - 无机非金属与塑料的复合体及其制备方法 - Google Patents
无机非金属与塑料的复合体及其制备方法 Download PDFInfo
- Publication number
- CN107263972A CN107263972A CN201610220541.4A CN201610220541A CN107263972A CN 107263972 A CN107263972 A CN 107263972A CN 201610220541 A CN201610220541 A CN 201610220541A CN 107263972 A CN107263972 A CN 107263972A
- Authority
- CN
- China
- Prior art keywords
- inorganic non
- plastics
- metallic
- microstructure
- metallic part
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004033 plastic Substances 0.000 title claims abstract description 121
- 229920003023 plastic Polymers 0.000 title claims abstract description 121
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229910052755 nonmetal Inorganic materials 0.000 title abstract description 11
- 239000002131 composite material Substances 0.000 title abstract 3
- 238000002347 injection Methods 0.000 claims description 26
- 239000007924 injection Substances 0.000 claims description 26
- 238000012545 processing Methods 0.000 claims description 19
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 239000011148 porous material Substances 0.000 claims description 15
- 238000004381 surface treatment Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 13
- 238000007788 roughening Methods 0.000 claims description 10
- 238000003486 chemical etching Methods 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 8
- 238000011161 development Methods 0.000 claims description 5
- 238000001259 photo etching Methods 0.000 claims description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 5
- -1 Maranyl Polymers 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 229910052594 sapphire Inorganic materials 0.000 claims description 4
- 239000010980 sapphire Substances 0.000 claims description 4
- 239000012815 thermoplastic material Substances 0.000 claims description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 3
- 239000002991 molded plastic Substances 0.000 claims description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 22
- 238000005530 etching Methods 0.000 description 22
- 239000000243 solution Substances 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 239000000052 vinegar Substances 0.000 description 7
- 235000021419 vinegar Nutrition 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000004519 grease Substances 0.000 description 6
- 239000007769 metal material Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010297 mechanical methods and process Methods 0.000 description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 230000002964 excitative effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940083608 sodium hydroxide Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229960003339 sodium phosphate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14336—Coating a portion of the article, e.g. the edge of the article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14795—Porous or permeable material, e.g. foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/286—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysulphones; polysulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
- C03C23/0025—Other surface treatment of glass not in the form of fibres or filaments by irradiation by a laser beam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/12—Thermoplastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2709/00—Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
- B29K2709/02—Ceramics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2709/00—Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
- B29K2709/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0041—Crystalline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/02—2 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/101—Glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/538—Roughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/542—Shear strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- ing And Chemical Polishing (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
一种无机非金属与塑料的复合体，其包括无机非金属件及结合于该无机非金属件的塑料件，该无机非金属件具有一第一表面，该第一表面至少部分区域有沟谷状的微观结构，该沟谷状的微观结构的表面形成有凹凸不平的结构和/或多孔的结构，该塑料件结合于该无机非金属件的具有沟谷状的微观结构的第一表面。该沟谷状的微观结构及沟谷状的微观结构表面的凹凸不平的结构和/或多孔的结构可以提高塑料件与无机非金属件之间的结合面积，还可以使塑料件与无机非金属件在结合过程中产生机械咬合，从而有效的提高塑料件与无机非金属件之间的结合力。另，本发明还提供一种上述无机非金属与塑料的复合体的制备方法。
Description
技术领域
本发明涉及一种无机非金属与塑料的复合体及其制备方法。
背景技术
玻璃、陶瓷、蓝宝石等硬质无机非金属材料因具有独特的质感与特性而被广泛应用于3C电子产品等产品的外观件及结构件中。然而，无机非金属材料因韧性及延展性差而无法设计成可与其它部件结合的卡扣结构，因此，无机非金属件一般需要先与塑料件结合，借助于塑料件形成可与其它部件结合的结构件或外观件。
目前，无机非金属件与塑料件的结合方法通常为粘接法和机械法。
粘接法是指利用胶粘剂作为中间的界面材料，将无机非金属件与塑料件结合于一体的方法，然而，粘接法虽然可以实现无机非金属件与塑料件之间的连接，但其存在以下缺点：粘结强度不够高，其结合力一般小于10兆帕（MPa）；难以自动化，受操作者熟练程度影响；工作温度受胶粘剂性能影响，一般只能在-50摄氏度（℃）~100℃的温度范围内正常工作；在环境光、热、湿气等因素下，胶粘剂会产生老化断裂等现象；大部分胶粘剂有毒，操作过程中会散发有刺激性的气体，危害人体健康；无法对无机非金属件的结构复杂和/或尺寸小的部位进行粘结。
机械法是指通过结构设计将无机非金属件嵌入塑料件中的方法，机械法虽然也可以实现无机非金属件与塑料件之间的连接，但不适用于结构复杂的无机非金属件与塑料件的结合。
发明内容
有鉴于此，有必要提供一种新的无机非金属与塑料的复合体，以解决上述问题。
另，还有必要提供一种上述无机非金属与塑料的复合体的制备方法。
一种无机非金属与塑料的复合体，其包括无机非金属件及结合于该无机非金属件的塑料件，该无机非金属件具有一第一表面，该第一表面至少部分区域有沟谷状的微观结构，该沟谷状的微观结构的表面形成有凹凸不平的结构和/或多孔的结构，所述塑料件结合于该无机非金属件的具有沟谷状的微观结构的第一表面上。
一种上述无机非金属与塑料的复合体的制备方法，其包括如下步骤：
提供无机非金属件，该无机非金属件具有至少一第一表面；
对所述无机非金属件的第一表面进行第一次表面处理，以在该第一表面上形成沟谷状的微观结构，得到第一中间体；
对所述第一中间体进行第二次表面处理，以在该第一中间体的沟谷状的微观结构的表面形成凹凸不平的结构和/或多孔的结构，得到第二中间体；
提供一注塑成型模具，将所述第二中间体置于该注塑成型模具内，注塑塑料于该第二中间体上以形成塑料件，该塑料件结合于所述无机非金属件的具有沟谷状的微观结构的第一表面上。
所述无机非金属与塑料的复合体通过在无机非金属件的第一表面上形成沟谷状的微观结构，并在沟谷状的微观结构的表面形成凹凸不平的结构和/或多孔的结构，然后通过模内注塑成型的方法在该第一表面上形成塑料件，使该塑料件部分填充于沟谷状的微观结构内及沟谷状的微观结构的表面的凹凸不平的结构和/或多孔的结构内。该第一表面上的沟谷状的微观结构及该沟谷状的微观结构表面的凹凸不平的结构和/或多孔的结构不仅可以提高塑料件与无机非金属件之间的结合面积，还可以使塑料件与无机非金属件在结合过程中产生机械咬合，从而有效的提高塑料件与无机非金属件之间的结合力，使无机非金属与塑料的复合体中的无机非金属件与塑料件之间具有较高的结合强度。
附图说明
图1是本发明较佳实施方式的无机非金属与塑料的复合体的剖视示意图。
图2是本发明较佳实施方式的第一中间体的剖视示意图。
图3是图2所示的第一中间体的具有沟谷状的微观结构的表面的扫描电镜图。
图4是本发明较佳实施方式的第二中间体的具有具有沟谷状的微观结构的剖视示意图。
图5是图4所示的第二中间体的具有沟谷状的微观结构的表面的扫面电镜图。
图6是本发明较佳实施方式的注塑成型模具内注塑形成结合于第二中间体的塑料件的示意图。
主要元件符号说明
| 无机非金属与塑料的复合体 | 100 |
| 无机非金属件 | 10 |
| 第一表面 | 11 |
| 沟谷状的微观结构 | 111 |
| 谷状突起 | 1111 |
| 沟槽 | 1112 |
| 塑料件 | 20 |
| 第一中间体 | 200 |
| 第二中间体 | 300 |
| 注塑成型模具 | 400 |
| 上模 | 401 |
| 浇口 | 4011 |
| 第一模穴 | 4012 |
| 下模 | 402 |
| 第二模穴 | 4021 |
如下具体实施方式将结合上述附图进一步说明本发明。
具体实施方式
请参阅图1，本发明一较佳实施方式的无机非金属与塑料的复合体100，其可以为电子产品的外壳，也可为建筑用件、医疗器件及汽车等交通工具的零部件等。该无机非金属与塑料的复合体100包括无机非金属件10及结合于该非金属件10的塑料件20。
该无机非金属件10具有至少一第一表面11。该第一表面11至少部分区域形成有沟谷状的微观结构111。该沟谷状的微观结构111为纳米尺寸或微米尺寸。该沟谷状的微观结构111包括谷状突起1111及与该谷状突起1111交替设置的沟槽1112。该沟谷状的微观结构111不仅可以提高塑料件20与无机非金属件10之间的结合面积，还可以使塑料件20与无机非金属件10在结合过程中产生机械咬合，从而有效的提高无机非金属与塑料的复合体100中的塑料件20与无机非金属件10之间的结合力。
在至少一实施例中，该谷状突起1111在该第一表面11所在平面的投影宽度范围为10nm~50µm，该沟槽1112的宽度范围为10nm~50µm，该沟槽1112的深度范围为10nm~100µm。可以理解的，在其它实施例中，该沟谷状的微观结构111的谷状突起1111在该第一表面11所在平面的投影宽度范围、该沟槽1112的宽度范围及该沟槽1112的深度范围可以为其它任意的数值，只要有利于无机非金属件10与塑料件20结合在一起即可。
所述沟谷状的微观结构111是通过对无机非金属件10的第一表面11表面粗化处理或表面成孔处理后形成。该表面粗糙化处理或表面成孔处理可以为化学蚀刻、电化学蚀刻、镭射、光刻显影等本领域习知的表面粗糙化或表面成孔的方法。
所述沟谷状的微观结构111的表面形成有凹凸不平的结构和/或多孔的结构。所述塑料件20部分填充于该沟谷状的微观结构111表面的凹凸不平的结构和/或多孔的结构内。该沟谷状的微观结构111表面的凹凸不平的结构和/或多孔的结构不仅可以进一步提高塑料件20与无机非金属件10之间的结合面积，还可以进一步使塑料件20与无机非金属件10在结合过程中产生机械咬合，从而进一步有效的提高塑料件20与无机非金属件10之间的结合力，得到无机非金属件10与塑料件20之间结合强度较高的无机非金属与塑料的复合体100。
当所述沟谷状的微观结构111的表面具有凹凸不平的结构时，该沟谷状的微观结构111的表面的粗糙度的范围优选为3~500纳米（nm）。当所述沟谷状的微观结构111的表面具有多孔的结构时，该孔的孔径范围优选为2~100nm。可以理解的，该粗糙度范围及孔径范围可以为其它任意的数值，只要有利于无机非金属件10与塑料件20结合在一起即可。
可以理解的，所述沟谷状的微观结构111表面的凹凸不平的结构和/或多孔的结构可以为沟谷状的微观结构111形成的过程中形成的，或者该凹凸不平的结构和多孔的结构是沟谷状的微观结构111形成后对沟谷状的微观结构111进行表面粗化处理或表面成孔处理后形成。
所述无机非金属件10的材质为玻璃、陶瓷、蓝宝石等硬质无机非金属材料。
所述塑料件20以模内注塑的方式结合于所述无机非金属件10的第一表面11上。该塑料件20的主要材质为塑料，该塑料可以为具有高流动的结晶型热塑性塑料，如聚苯硫醚（PPS）塑料、聚酰胺（PA）塑料、聚对苯二甲酸丁二醇酯（PBT）塑料、聚碳酸酯（PC）、对苯二甲酸乙二醇酯（PET）塑料等。
可以理解的，为了提高所述塑料件20的耐冲击性、耐热性及其它的机械性能，还可于该塑料中添加玻璃纤维或碳纤维等增强材料。优选的，该增强材料为玻璃纤维。该玻璃纤维的添加还可以缩小无机非金属件10与塑料件20之间的膨胀系数，可有效的防止塑料件20发生收缩、翘起或脱落，进而提高塑料件20与无机非金属件10之间的结合力。
请结合参阅1~6，一种上述无机非金属与塑料的复合体100的制备方法，其包括如下步骤：
步骤S1：提供无机非金属件10。
该无机非金属件10的材质为玻璃、陶瓷、蓝宝石等硬质无机非金属材料。
步骤S2：对所述无机非金属件10进行表面预处理。
该表面预处理可以为常规的脱脂除油处理，以去除该无机非金属件10表面的油脂等污垢，使该无机非金属件10的表面清洁。
该脱脂除油处理的工艺为：使用清洗剂对该无机非金属件10进行超声波清洗。该清洗剂为酒精、丙酮等常规用于去除油脂的清洗剂。该超声波清洗的时间优选为2~10min。
步骤S3：请结合参阅图2~3，对所述经表面预处理后的无机非金属件10的第一表面11进行第一次表面处理，以在该第一表面11上形成沟谷状的微观结构111，得到第一中间体200。
所述沟谷状的微观结构111包括谷状突起1111及与该谷状突起1111交替设置的沟槽1112。该谷状突起1111在该第一表面11所在平面的投影宽度范围优选为10nm~50µm，该沟槽1112的宽度范围优选为10nm~50µm，该沟槽1112的深度范围优选为10nm~100µm。
所述第一次表面处理为表面粗糙化处理和/或表面成孔处理。在一实施方式中，采用光刻显影的方法对所述无机非金属件10的第一表面11进行第一次表面处理。
该光刻显影的具体工艺为：采用感光油墨或光刻胶对该无机非金属件10的不需要进行第一次表面处理的区域进行遮蔽，接着采用腐蚀液对无机非金属件10的未被遮蔽的区域腐蚀5~15min，接着在100~180℃的温度下热处理10~20min，重复该腐蚀-热处理的步骤若干次，然后去除油墨或光刻胶，即在第一表面11上形成沟谷状的微观结构111，得到第一中间体200。其中，腐蚀液的主要成分包括但不限于氢氟酸、氢氟酸铵、硝酸、磷酸、盐酸、草酸、硫酸铵、甘油、硫酸钡、醋氟化氨、硫酸钠、甘油、氟化氢铵、氟化铵、氟化钙、氟硼酸钠、氟硼酸钾、氟硼酸镁、淀粉及氟硅酸钠中的一种或几种。
可以理解的，在其它实施方式中，还可以采用化学蚀刻、电化学蚀刻、镭射等本领域习知的表面粗糙化处理或表面成孔处理的方法对所述第一表面11进行表面粗糙化处理和/或表面成孔处理，以在该第一表面11上形成沟谷状的微观结构111。
步骤S4：请结合参阅图4~5对所述第一中间体200进行第二次表面处理，以在该第一中间体200的沟谷状的微观结构111的表面形成凹凸不平的结构和/或多孔的结构，得到第二中间体300。
当所述沟谷状的微观结构111的表面具有凹凸不平的结构时，该沟谷状的微观结构111的表面的粗糙度的范围优选为3~500nm。当所述沟谷状的微观结构111的表面具有多孔的结构的时候，该孔的孔径范围优选为2~100nm。
所述第二次表面处理为表面粗糙化处理和/或表面成孔处理。在一实施方式中，采用化学蚀刻的方法对所述沟谷状的微观结构111的表面进行第二次表面处理。
该化学蚀刻的具体工艺为：采用感光油墨或光刻胶对该第一中间体200的不需要进行第二次表面处理的区域进行遮蔽，然后将遮蔽后的第一中间体200置于蚀刻液中，在60~70℃的温度下超声波处理30min，即在第一表面11的沟谷状的微观结构111的表面蚀刻形成凹凸不平的结构和/或多孔的结构，得到第二中间体300。其中，该蚀刻液的主要成分包括但不限于氢氧化钠、磷酸钠、焦磷酸钠、EDTA二钠的一种或几种。
可以理解的，在其它实施方式中，还可以采用光刻显影、电化学蚀刻、镭射等本领域***的结构和/或多孔的结构。
步骤S5：请进一步参阅图6，对所述第二中间体300进行模内注塑成型，以在该第二中间体300的第一表面11上形成塑料件20。
提供一注塑成型模具400，将所述第二中间体300置于该注塑成型模具400中。该注塑成型模具400包括上模401及下模402。上模401设置有若干浇口4011及一第一模穴4012，该第一模穴4012用于形成所述塑料件20。下模402形成有可容置所述第二中间体300的第二模穴4021。将所述第二中间体300置于该第二模穴4021中，经由若干浇口4011注塑塑料于第一模穴4012中，冷却后即形成塑料件20，制得所述无机非金属材料与塑料的复合体100。其中，该塑料件20部分填充于所述沟谷状的微观结构111内及沟谷状的微观结构111的表面的凹凸不平的结构和/或多孔的结构内。
下面通过具体实施例对本发明进行进一步说明。
实施例1
提供无机非金属件10，该无机非金属件10的材质为玻璃，该无机非金属件10具有一需要与塑料件20结合的第一表面11。
采用酒精对所述无机非金属件10进行表面预处理，以去除该无机非金属件10表面的油脂等污垢。
采用镭射的方法对所述经表面预处理后的无机非金属件10进行第一次表面处理，以在所述第一表面11上镭射形成沟谷状的微观结构111，得到一第一中间体200。该沟谷状的微观结构111的沟槽1112的宽度范围为10nm~2µm，该沟槽1112的深度范围为1µm~100µm。
将所述第一中间体200不需要进行第二次表面处理的区域使用油墨进行遮蔽，然后采用质量浓度为20%的NaOH溶液作为蚀刻液，将所述第一中间200体置于该蚀刻液中，在70℃的温度下超声处理30min，在第一中间体200的沟谷状的微观结构111的表面蚀刻形成凹凸不平的结构和/或多孔的结构，去除油墨，得到第二中间体300。
提供一注塑成型模具400，将所述第二中间体300置于该注塑成型模具400中。对所述第二中间体300进行模内注塑成型，在该第二中间体300的第一表面11上形成塑料件20，制得无机非金属材料与塑料的复合体100。
实施例2
提供无机非金属件10，该无机非金属件10的材质为玻璃，该无机非金属件10具有一需要与塑料件20结合的第一表面11。
采用酒精对所述无机非金属件10进行表面预处理，以去除该无机非金属件10表面的油脂等污垢。
将所述经表面预处理后的无机非金属件10的不需要形成沟谷状的微观结构111的表面进行遮蔽。采用HF: HNO3: H2O体积比为20:14:66的溶液作为蚀刻液，对无机非金属件10未被遮蔽的区域蚀刻10min，重复该蚀刻步骤3次，在无机非金属件10的第一表面11上蚀刻形成沟谷状的微观结构111，得到一第一中间体200。
采用质量浓度为20%的NaOH溶液作为蚀刻液，将所述第一中间体200置于该蚀刻液中，在70℃的温度下超声处理30min，在第一中间体200的沟谷状的微观结构111的表面蚀刻形成凹凸不平的结构和/或多孔的结构。
提供一注塑成型模具400，将所述第二中间体300置于该注塑成型模具400中。对所述第二中间体300进行模内注塑成型，在该第二中间体300的第一表面11上形成塑料件20，制得无机非金属材料与塑料的复合体100。
实施例3
提供无机非金属件10，该无机非金属件10的材质为玻璃，该无机非金属件10具有一需要与塑料件20结合的第一表面11。
采用酒精对所述无机非金属件10进行表面预处理，以去除该无机非金属件10表面的油脂等污垢。
将所述经表面预处理后的无机非金属件10的不需要形成沟谷状的微观结构111的表面进行遮蔽。采用醋氟化氨与硫酸的混合溶液作为蚀刻液，对无机非金属件10未被遮蔽的区域蚀刻10min，重复该蚀刻步骤3次，在无机非金属件10的第一表面11上蚀刻形成沟谷状的微观结构111，得到一第一中间体200。其中，该醋氟化氨与硫酸的混合溶液由180g醋氟化氨、30g硫酸及90g水配置而成。
采用质量浓度为20%的NaOH溶液作为蚀刻液，将所述第一中间体200置于该蚀刻液中，在70℃的温度下超声处理30min，在第一中间体200的沟谷状的微观结构111的表面蚀刻形成凹凸不平的结构和/或多孔的结构。
提供一注塑成型模具400，将所述第二中间体300置于该注塑成型模具400中。对所述第二中间体300进行模内注塑成型，在该第二中间体300的第一表面11上形成塑料件20，制得无机非金属材料与塑料的复合体100。
实施例4
提供无机非金属件10，该无机非金属件10的材质为玻璃，该无机非金属件10具有一需要与塑料件20结合的第一表面11。
采用酒精对所述无机非金属件10进行表面预处理，以去除该无机非金属件10表面的油脂等污垢。
将所述经表面预处理后的无机非金属件10的不需要形成沟谷状的微观结构111的表面进行遮蔽。采用醋氟化氨、草酸、硫酸铵、硫酸钠、甘油及水的混合溶液作为蚀刻液，对无机非金属件10未被遮蔽的区域蚀刻10min，重复该蚀刻步骤3次，在无机非金属件10的第一表面11上蚀刻形成沟谷状的微观结构111，得到一第一中间体200。其中该醋氟化氨、草酸、硫酸铵、硫酸钠、甘油及水的混合溶液由15g醋氟化氨、7g草酸、8g硫酸铵、14g硫酸钠、35g甘油及10水配置而成。
采用质量浓度为20%的NaOH溶液作为蚀刻液，将所述第一中间体200置于该蚀刻液中，在70℃的温度下超声处理30min，在第一中间体200的沟谷状的微观结构111的表面蚀刻形成凹凸不平的结构和/或多孔的结构。
提供一注塑成型模具400，将所述第二中间体300置于该注塑成型模具400中。对所述第二中间体300进行模内注塑成型，在该第二中间体300的第一表面11上形成塑料件20，制得无机非金属材料与塑料的复合体100。
对上述实施例1~4中制得的无机非金属与塑料的复合体100分别进行结合剪切强度测试，测试结果表明实施例1~4中的无机非金属与塑料的复合体100中无机非金属件10与塑料件20之间的结合强度为分别为19.8MPa 、18.6MPa
、18.9MPa 、19.2MPa。而习知的通过胶粘法得到的无机非金属与塑料的复合体中无机非金属件与塑料件的结合强度为5~10MPa。可见，通过本发明的无机非金属与塑料的复合体100的制备方法制得的无机非金属与塑料的复合体100中的无机非金属件10与塑料件20具有较高的结合强度。
本发明的无机非金属与塑料的复合体100通过在无机非金属件10的第一表面11上形成沟谷状的微观结构111，并在沟谷状的微观结构111的表面形成凹凸不平的结构和/或多孔的结构，然后通过模内注塑成型的方法在该第一表面11上形成塑料件20，使该塑料件20部分填充于沟谷状的微观结构111内及沟谷状的微观结构111的表面的凹凸不平的结构和/或多孔的结构内。该第一表面11上的沟谷状的微观结构111及该沟谷状的微观结构111表面的凹凸不平的结构和/或多孔的结构不仅可以提高塑料件20与无机非金属件10之间的结合面积，还可以使塑料件20与无机非金属件10在结合过程中产生机械咬合，从而有效的提高塑料件20与无机非金属件10之间的结合力，使无机非金属与塑料的复合体100中的无机非金属件10与塑料件20之间具有较高的结合强度。
另外，对于本领域的普通技术人员来说，可以根据本发明的技术构思做出其它各种相应的改变与变形，而所有这些改变与变形都应属于本发明权利要求的保护范围。
Claims (10)
1.一种无机非金属与塑料的复合体，其特征在于：该无机非金属与塑料的复合体包括无机非金属件及结合于该无机非金属件的塑料件，该无机非金属件具有至少一第一表面，该第一表面的至少部分区域具有沟谷状的微观结构，该沟谷状的微观结构的表面具有凹凸不平的结构及多孔的结构中的一种或两种，所述塑料件结合于该无机非金属件的具有沟谷状的微观结构的第一表面上。
2.如权利要求1所述的无机非金属与塑料的复合体，其特征在于：所述塑料件部分填充于该沟谷状的微观结构内。
3.如权利要求1所述的无机非金属与塑料的复合体，其特征在于：所述塑料件部分填充于该沟谷状的微观结构表面的凹凸不平的结构及多孔的结构内。
4.如权利要求1所述的无机非金属与塑料的复合体，其特征在于：所述无机非金属件的材质为玻璃、陶瓷或蓝宝石。
5.如权利要求1所述的无机非金属与塑料的复合体，其特征在于：所述塑料件的材质为结晶型热塑性塑料，该结晶型热塑性塑料为聚苯硫醚塑料、聚酰胺塑料、聚对苯二甲酸丁二醇酯塑料或聚对苯二甲酸乙二醇酯塑料。
6.如权利要求5所述的无机非金属与塑料的复合体，其特征在于：所述结晶型热塑性塑料中添加有玻璃纤维或碳纤维。
7.如权利要求1所述的无机非金属与塑料的复合体，其特征在于：所述沟谷状的微观结构包括谷状突起及与该谷状突起交替设置的沟槽，该谷状突起在该第一表面所在平面的投影宽度范围为10nm~50µm，该沟槽的宽度范围为10nm~50µm，该沟槽的深度范围为10nm~100µm。
8.一种如权利要求1~7中任一项所述的无机非金属与塑料的复合体的制备方法，其包括如下步骤：
提供无机非金属件，该无机非金属件具有至少一第一表面；
对所述无机非金属件的第一表面进行第一次表面处理，以在该第一表面上形成沟谷状的微观结构，得到第一中间体；
对所述第一中间体进行第二次表面处理，以在该第一中间体的沟谷状的微观结构的表面形成凹凸不平的结构及多孔的结构中的一种或两种，得到第二中间体；
提供一注塑成型模具，将所述第二中间体置于该注塑成型模具内，注塑塑料于该第二中间体上以形成塑料件，该塑料件结合于所述无机非金属件的具有沟谷状的微观结构的第一表面上。
9.如权利要求8所述的无机非金属与塑料的复合体的制备方法，其特征在于：在对所述无机非金属件进行第一次表面处理之前还包括对该无机非金属件进行表面预处理的步骤，该表面预处理用于去除该无机非金属件表面的污垢。
10.如权利要求8所述的无机非金属与塑料的复合体的制备方法，其特征在于：所述第一第表面处理及第二次表面处理均为表面粗糙化处理及表面成孔处理中的一种或两种，该表面粗糙化处理及表面成孔处理为光刻显影、化学蚀刻、电化学蚀刻或镭射。
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610220541.4A CN107263972A (zh) | 2016-04-08 | 2016-04-08 | 无机非金属与塑料的复合体及其制备方法 |
| TW105112736A TWI653146B (zh) | 2016-04-08 | 2016-04-22 | 無機非金屬與塑膠的複合體及其製備方法 |
| US15/391,797 US20170291394A1 (en) | 2016-04-08 | 2016-12-27 | Composite article of inorganic non-metal and resin and method for making the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610220541.4A CN107263972A (zh) | 2016-04-08 | 2016-04-08 | 无机非金属与塑料的复合体及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107263972A true CN107263972A (zh) | 2017-10-20 |
Family
ID=59999982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610220541.4A Pending CN107263972A (zh) | 2016-04-08 | 2016-04-08 | 无机非金属与塑料的复合体及其制备方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20170291394A1 (zh) |
| CN (1) | CN107263972A (zh) |
| TW (1) | TWI653146B (zh) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108215058A (zh) * | 2018-03-09 | 2018-06-29 | 瑞声精密制造科技(常州)有限公司 | 金属玻璃产品的成型方法 |
| CN108901166A (zh) * | 2018-08-01 | 2018-11-27 | Oppo广东移动通信有限公司 | 金属复合半成品及其制造方法、外壳及电子装置 |
| CN109016332A (zh) * | 2018-07-12 | 2018-12-18 | 歌尔股份有限公司 | 无机非金属与塑料的结合体及其制备方法 |
| WO2020010812A1 (zh) * | 2018-07-12 | 2020-01-16 | 歌尔股份有限公司 | 一种陶瓷与塑胶的复合件的制备方法 |
| CN112428629A (zh) * | 2020-11-13 | 2021-03-02 | Oppo广东移动通信有限公司 | 壳体组件、制备方法和电子设备 |
| CN114425835A (zh) * | 2020-10-29 | 2022-05-03 | 比亚迪股份有限公司 | 一种陶瓷基体、陶瓷塑胶复合体及其制备方法 |
| CN114679874A (zh) * | 2020-12-24 | 2022-06-28 | 富联裕展科技(深圳)有限公司 | 金属复合件、金属复合件的制备方法及电子装置的壳体 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3453510B1 (en) * | 2017-09-08 | 2022-03-02 | Apple Inc. | Bonding polymer material to anodized metal using cavities |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101516598A (zh) * | 2006-09-19 | 2009-08-26 | 诺基亚公司 | 塑料-接受体混合构件 |
| WO2011125903A1 (ja) * | 2010-03-31 | 2011-10-13 | 三菱化学株式会社 | ポリカーボネート樹脂組成物、その製造方法及び同樹脂組成物の成形体 |
| CN103507203A (zh) * | 2012-06-25 | 2014-01-15 | 比亚迪股份有限公司 | 一种金属树脂复合体及其制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4683168A (en) | 1985-01-10 | 1987-07-28 | Corning Glass Works | Method of producing a composite body |
| GB9200181D0 (en) | 1992-01-07 | 1992-02-26 | Whitford Plastics | Non-stick coatings |
| JPH11214450A (ja) | 1997-11-18 | 1999-08-06 | Matsushita Electric Ind Co Ltd | 電子部品実装体とそれを用いた電子機器と電子部品実装体の製造方法 |
-
2016
- 2016-04-08 CN CN201610220541.4A patent/CN107263972A/zh active Pending
- 2016-04-22 TW TW105112736A patent/TWI653146B/zh not_active IP Right Cessation
- 2016-12-27 US US15/391,797 patent/US20170291394A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101516598A (zh) * | 2006-09-19 | 2009-08-26 | 诺基亚公司 | 塑料-接受体混合构件 |
| WO2011125903A1 (ja) * | 2010-03-31 | 2011-10-13 | 三菱化学株式会社 | ポリカーボネート樹脂組成物、その製造方法及び同樹脂組成物の成形体 |
| CN103507203A (zh) * | 2012-06-25 | 2014-01-15 | 比亚迪股份有限公司 | 一种金属树脂复合体及其制备方法 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108215058A (zh) * | 2018-03-09 | 2018-06-29 | 瑞声精密制造科技(常州)有限公司 | 金属玻璃产品的成型方法 |
| CN109016332A (zh) * | 2018-07-12 | 2018-12-18 | 歌尔股份有限公司 | 无机非金属与塑料的结合体及其制备方法 |
| WO2020010812A1 (zh) * | 2018-07-12 | 2020-01-16 | 歌尔股份有限公司 | 一种陶瓷与塑胶的复合件的制备方法 |
| CN108901166A (zh) * | 2018-08-01 | 2018-11-27 | Oppo广东移动通信有限公司 | 金属复合半成品及其制造方法、外壳及电子装置 |
| CN114425835A (zh) * | 2020-10-29 | 2022-05-03 | 比亚迪股份有限公司 | 一种陶瓷基体、陶瓷塑胶复合体及其制备方法 |
| CN114425835B (zh) * | 2020-10-29 | 2023-08-08 | 比亚迪股份有限公司 | 一种陶瓷基体、陶瓷塑胶复合体及其制备方法 |
| CN112428629A (zh) * | 2020-11-13 | 2021-03-02 | Oppo广东移动通信有限公司 | 壳体组件、制备方法和电子设备 |
| CN114679874A (zh) * | 2020-12-24 | 2022-06-28 | 富联裕展科技(深圳)有限公司 | 金属复合件、金属复合件的制备方法及电子装置的壳体 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201736102A (zh) | 2017-10-16 |
| TWI653146B (zh) | 2019-03-11 |
| US20170291394A1 (en) | 2017-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107263972A (zh) | 无机非金属与塑料的复合体及其制备方法 | |
| US20140028163A1 (en) | Housing and method for manufacturing the same | |
| TWI510367B (zh) | 金屬與樹脂的複合體及其製造方法 | |
| KR101630415B1 (ko) | 플라스틱과 금속 복합재료 및 그 제조방법 | |
| CN107709002B (zh) | 金属树脂复合成型体及其制造方法 | |
| CN107263939A (zh) | 复合体及其制备方法 | |
| US20130157038A1 (en) | Composite and method for making the same | |
| US20130157006A1 (en) | Method for making magnesium/magnesium alloy-and-resin composite and magnesium/magnesium alloy-and-resin composite thereof | |
| CN101623933A (zh) | 热塑性物质嵌入金属材的方法 | |
| CN107010998A (zh) | 陶瓷的表面处理方法、陶瓷制品及陶瓷塑料复合体 | |
| JP2016525032A (ja) | 金属合金とセラミック樹脂の複合体及びその製造方法 | |
| US9610717B2 (en) | Composite of resin and other materials and method for manufacturing the same | |
| CN107415136A (zh) | 陶瓷和塑料的复合制品及其制备方法 | |
| JP6547033B2 (ja) | セラミックプラスチック複合体及びその製造方法 | |
| US20120295094A1 (en) | Composite article of glass part and plastic part and method for manufacturing same | |
| TW201302423A (zh) | 鋁－樹脂射出一體成形品製造用之鋁形狀體、使用其之鋁－樹脂射出一體成形品、以及其等之製造方法 | |
| US7122074B2 (en) | Device and method of removing bubbles generated in molding glass fiber-reinforced plastic parts | |
| CN111319323A (zh) | 一种复合材料及其制备方法、电子设备 | |
| KR101568991B1 (ko) | 알루미늄-수지 금속 복합체 및 이의 제조방법 | |
| JP2019025868A (ja) | 金属／樹脂複合構造体、金属／樹脂複合構造体の製造方法および耐リーク性部品 | |
| CN105479659B (zh) | 金属与塑胶的复合体及其制造方法 | |
| CN104816429A (zh) | 金属表面与塑胶一体注塑并相互牢固粘结的生产工艺 | |
| CN108790013B (zh) | 不锈钢件与塑料件的复合体及其制备方法 | |
| CN108724598A (zh) | 氧化锆陶瓷与塑料件的复合体及其制备方法 | |
| CN106148962A (zh) | 一种不锈钢表面纳米孔洞的处理液及其应用方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190704 Address after: 065000 Foxconn C01, No. 369 South Construction Road, Anci District, Langfang City, Hebei Province Applicant after: YOUER INDUSTRIAL MATERIAL (LANGFANG) CO.,LTD. Applicant after: FuTaiHua Industry (Shenzhen) Co.,Ltd. Applicant after: Youer Hongxin Detection Technology (Shenzhen) Co.,Ltd. Address before: 518109 Area F, Building B, 1st floor, Foxconn Science Park Area C, No. 2 East Ring Road, Longhua Office, Longhua New District, Shenzhen City, Guangdong Province Applicant before: YOUER MATERIAL INDUSTRY (SHENZHEN) CO.,LTD. Applicant before: HON HAI PRECISION INDUSTRY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20201111 Address after: 518109 Four, Six, Seven and Thirteen Workshops in Area B of Foxconn Guanlan Science Park, Dasan Community, Guanlan Street, Longhua New District, Shenzhen City, Guangdong Province (Section I) Applicant after: FuTaiHua Industry (Shenzhen) Co.,Ltd. Applicant after: Youer Hongxin Detection Technology (Shenzhen) Co.,Ltd. Address before: 065000 Foxconn C01, Jianshe South Road, Anci District, Hebei, Langfang 369, China Applicant before: YOUER INDUSTRIAL MATERIAL (LANGFANG) Co.,Ltd. Applicant before: FuTaiHua Industry (Shenzhen) Co.,Ltd. Applicant before: Youer Hongxin Detection Technology (Shenzhen) Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171020 |
|
| RJ01 | Rejection of invention patent application after publication |