CN107245673A - Iron-based amorphous nanometer crystalline thin strip magnet and its preparation method and application method - Google Patents
Iron-based amorphous nanometer crystalline thin strip magnet and its preparation method and application method Download PDFInfo
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- CN107245673A CN107245673A CN201710450342.7A CN201710450342A CN107245673A CN 107245673 A CN107245673 A CN 107245673A CN 201710450342 A CN201710450342 A CN 201710450342A CN 107245673 A CN107245673 A CN 107245673A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/003—Making ferrous alloys making amorphous alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/047—Alloys characterised by their composition
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F3/00—Cores, Yokes, or armatures
- H01F3/02—Cores, Yokes, or armatures made from sheets
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Abstract
Iron-based amorphous nanometer crystalline thin strip magnet of the present invention and its preparation method and application method, it is related to the amorphous alloy that iron makees main component, the iron-based amorphous nanometer crystalline thin strip magnet is Finemet type amorphous nano-crystalline thin strip magnets, its mass percent composition expression formula is AxFy, in formula, x mass percent composition limits scope and limits scope as 10≤y≤30 as 70≤x≤90, y mass percent composition；Component A is that atomic percent composition is FeaCubMcSidBeMaster alloying A, F components are the amorphous thin ribbon Fs corresponding with component A master alloying A composition, by the iron-based amorphous nanometer crystalline thin strip magnet is made by the ratio for optimizing nanocrystalline α Fe (Si) and amorphous phase, it be used to prepare iron-based amorphous and nanocrystalline soft magnetic alloy iron core product；Have that magnetic property is still relatively low instant invention overcomes existing similar products, production cost is high and is difficult the defect produced in batches in production.
Description
Technical field
Technical scheme is related to the amorphous alloy that iron makees main component, specifically iron-based amorphous nanometer crystalline
Thin strip magnet and its preparation method and application method.
Background technology
Yoshizawa of Hitachi, Ltd in 1988 et al. (Y.Yoshizawa, S.Oguma, K.Yamauchi.New Fe-
based soft magnetic alloys composed of ultrafine grain structure[J].Journal
of Applied Physics.1988,64:6044-6046.) invent the excellent amorphous ＆ nanocrystalline of soft magnet performance
Finemet.Finemet type amorphous nano-crystallines refer to carry out Fe-M-Cu-Si-B amorphous thin ribbons after Isothermal treatment, from amorphous
Nanoscale soft magnetism phase is separated out in matrix, material is obtained amorphous phase and a kind of state of nanometer crystalline phases.Due to this
Class alloy is easy to spray, and possesses good soft magnet performance, such as 1.2T saturation induction density, 104~105Initial magnetic
Small core loss value under conductance and low coercivity and wide frequency ranges, is widely used in soft magnetism industry.
At present, with the development of electrical equipment industry, the global demand to Finemet type Fe-based amorphous nanocrystalline alloys is year by year
Increase, the research and development to such magnetic material are even more like a raging fire.CN101787500B discloses a kind of FeaSibBcCdAleAmorphous is thin
The preparation method of band, but to there is coercivity larger for the amorphous thin ribbon, and there is high-melting-point Elements C in alloy, it is difficult in production
The middle defect produced in batches.CN102953020A discloses a kind of iron-based amorphous and nanocrystalline soft magnetic alloy material and its preparation
Method, but the serial strip has that initial permeability is relatively low, causes the defect that production cost increases containing expensive Co.
The content of the invention
The technical problems to be solved by the invention are：Iron-based amorphous nanometer crystalline thin strip magnet and preparation method thereof is provided and answered
With method, the iron-based amorphous nanometer crystalline thin strip magnet is Finemet type amorphous nano-crystalline thin strip magnets, by optimize nanocrystalline α-
Fe (Si) and amorphous phase ratio, the magnetic property for overcoming existing similar products presence are still relatively low, and production cost is high and is difficult
The defect produced in batches in production.
The present invention solves the technical scheme that is used of the technical problem：Iron-based amorphous nanometer crystalline thin strip magnet, be
Finemet type amorphous nano-crystalline thin strip magnets, its mass percent constitutes expression formula for AxFy, and in formula, component A is atomic percent
It is Fe than compositionaCubMcSidBeMaster alloying A, wherein M is at least one of Nb, V and Mo element element, a, b, c, d and e table
Show element composition atomic percentage, 70.0≤a≤74.5,1.0≤b≤1.5,2.5≤c≤3.5,11.5≤d≤14.5,
8.3≤e≤14.5, and meet a+b+c+d+e=100；F components are the amorphous thin ribbons corresponding with component A master alloying A composition
F, the mass percent scope of crystalline phases contained therein is 2.0%~30.0%, the composition mass percent x of component A restriction
Scope limits scope as 10≤y≤30 for the composition mass percent y's of 70≤x≤90, F components.
Above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, its thickness is 25~35 μm, with a width of 10~40mm.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, is comprised the following steps that：
The first step, preparation raw material：
By the composition formula Fe of atomic percentageaCubMcSidBeEach element quality is calculated, wherein M is in Nb, V and Mo element
At least one element, a, b, c, d and e represent element composition atomic percentage, 70.0≤a≤74.5,1.0≤b≤1.5,
2.5≤c≤3.5,11.5≤d≤14.5,8.3≤e≤14.5, and a+b+c+d+e=100 is met, weigh required raw material：Niobium
Iron, ferro-boron, vanadium iron, molybdenum-iron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,aCubMcSidBeMaster alloying A ingot castings；
3rd step, prepares amorphous thin ribbon F：
Master alloying A ingot castings made from above-mentioned second step are fitted into fast melt-quenching stove, with 20~45m/s's after re-melting
Linear velocity carries out fast melt-quenching on copper disk roller, and amorphous thin ribbon F is thus made；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
Master alloying A ingot castings made from above-mentioned second step are put into remelting furnace and melted, melting uniformly waits 10 before coming out of the stove~
It is the composition quality percentage in AxFy that amorphous thin ribbon F prepared by above-mentioned 3rd step is constituted expression formula by 20min by mass percentage
Than adding in the liquation of the uniform master alloying A ingot castings of remelting, in AxFy formulas, master alloying A mass percent constitutes x restriction model
Enclose for 70≤x≤90, amorphous thin ribbon F mass percent composition y's limits scope as 10≤y≤30, then to mixing
AxFy liquations carry out slag hitting, carry out spray band in an atmosphere with 20~40m/s speed, that is, iron-based amorphous nanometer crystalline strip magnetic is made
Body；
Determined through slide measure and micrometer：The thickness of obtained iron-based amorphous nanometer crystalline thin strip magnet is 25~35 μ
M, with a width of 10~40mm；Calculated according to Jade softwares：The mass fraction of crystalline phases is 2.0~30.0% in amorphous thin ribbon F.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, wherein used raw material is obtained by known approach
, equipment is known chemical industry equipment, and used process operation is known to those skilled in the art
's.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, obtained at 540~580 DEG C
Obtain equally distributed nanocrystalline on noncrystal substrate, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of obtained iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is external diameter × interior
Footpath × height=D × d × h=Φ 30mm × Φ 24.92mm × (10~40) mm；Calculated according to Jade softwares：AxFy is Fe-based amorphous
The mass fraction of crystalline phases is 78.4~86.2% in nano-crystal soft magnetic alloy iron core product；It is straight through MATS-2010SD type soft magnetisms
Flow measuring apparatus determines the product magnetic property：Saturation induction density be 1.26~1.49T, initial permeability be 125k~
148k。
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, sets wherein used equipment is known chemical industry
Standby, used process operation is known to those skilled in the art.
Beneficial effects of the present invention are as follows：
Compared with prior art, the prominent substantive distinguishing features of the present invention are：
(1) it there is the amorphous phase of shortrange order in amorphous thin ribbon F, the non crystalline structure of this shortrange order is from quality hundred
Divide than composition expression formula to be remained in AxFy molten state alloy, be uniformly distributed, by fast melt-quenching technology, alloy foundation
Structural hereditary effect, more easily forms the noncrystalline structure being evenly distributed, and be amorphous on the basis of shot-range ordered structure
Strip crystallization forming core provides forming core point, that is, reduces the activation energy of Amorphous Crystallization, so as to optimize nanocrystalline α-Fe (Si) phase and amorphous
The ratio of phase, the magnetic property for overcoming existing similar products presence is relatively low, and production cost is high and is difficult to carry out in production in batches
The defect of production.
(2) in preparation method of the present invention, wherein amorphous crystal structure is presented in obtained amorphous thin ribbon F on the whole, and
What actually this non crystalline structure was made up of the nanocluster of many shortrange orders, when amorphous thin ribbon F add remelting furnace in,
The interior rapid meltings in master alloying A liquid of 10~20min, the unchanged nanocluster of its each structure is evenly dispersed in master alloying A
In liquid, equivalent to the nanocluster ratio that adds additional in a short time in AxFy alloys in unit volume.Subsequent fast
Quickly cooling but in, these nanoclusters still retain in original structure, subsequent annealing process, and these clusters are exactly the shape that crystallization starts
Epipole, makes the nanometer crystalline phase after annealing more, tiny, uniform, produces the beneficial effect of " Structure Inheritance ".
(3) amorphous state belongs to the metastable state of high energy, amorphous thin ribbon F be actually subjected to when adding master alloying A liquid experience amorphous state-
The process of crystallization-fusing, and high-energy is discharged in amorphous state crystallization process, the temperature of master alloying A liquid can be made in spray
Improved before strip, the composition of liquid can be made evenly, and when improving spray liquid mobility, reduce impurity on strip
The generation of defect, so as to improve lumber recovery, may finally improve the magnetic induction intensity and magnetic conductivity of strip.
(4) in application process of the present invention, wherein rolling obtained amorphous iron core after annealing, formd on noncrystal substrate
The more uniform tiny nano-crystal soft-magnetic phase of size, adjacent nano crystalline substance is to swap coupling, nanometer by noncrystal substrate
The reduction of brilliant size increases equal to the area of interaction is increased with nanocrystalline phase amount, is made so as to improve after annealing
Iron-based amorphous and nanocrystalline soft magnetic alloy iron core product magnetic property.
(5) through retrieval, up to the present, it is not yet found that improving Finemet type alloys by adjusting foundry alloy remelting liquid
The report of amorphous nanocrystalline soft magnetic performance.
Compared with prior art, marked improvement of the invention is：
(1) iron-based amorphous nanometer crystalline thin strip magnet of the invention, by adding identical component amorphous thin ribbon in remelting liquid,
Compared with the product being not added with after amorphous thin ribbon annealing, the saturation induction density of material is improved, with higher initial magnetic
Conductance and maximum permeability, the static saturation induction density of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product at room temperature
For 1.26~1.49T, initial permeability can reach 125k~148k, higher than the magnetic property of existing similar products, not change material
The synthesis soft magnet performance and mechanical property of material are improved on the premise of material composition.
(2) in preparation method of the present invention, amorphous thin ribbon F has non-ektogenic impurity defect not when can be with early stage spray
Qualified amorphous thin ribbon is replaced, and saves the energy, improves the utilization rate of raw material, overcome prior art production cost it is high and be difficult
The defect produced in batches in production.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fe in Fig. 1 embodiment of the present invention 174.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F X ray diffracting spectrum.
Fe in Fig. 2 embodiment of the present invention 174.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F DSC test curves.
(Fe in Fig. 3 embodiment of the present invention 174.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron
The DSC test curves of based amorphous nano thin strip magnet.
(Fe in Fig. 4 embodiment of the present invention 174.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron
The X ray diffracting spectrum of based amorphous nano thin strip magnet.
(Fe in Fig. 5 embodiment of the present invention 174.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron
The hysteresis curve of based amorphous nano soft magnetic alloy core product.
Embodiment
Embodiment 1
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A, F component be group with component A master alloying A
Into corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 10.5%；The composition mass percent x of component A
It is 30 for the composition mass percent y of 70, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
By the composition formula Fe of atomic percentage74.5Cu1.5Nb2.7Si11.5B9.8Each element quality is calculated, required original is weighed
Material：Ferro-niobium, ferro-boron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings；
3rd step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 40m/s linear velocity after re-melting, Fe is thus made74.5Cu1.5Nb2.7Si11.5B9.8
Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be put into remelting furnace melt,
The Fe that 15min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F presses quality hundred
It is AxFy=(Fe to divide than composition expression formula74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) group in 30
The uniform Fe of remelting is added into mass percent74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings liquation in, then to mixed
(the Fe closed74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 liquations carry out slag hitting, in an atmosphere with
40m/s speed carries out spray band, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of obtained iron-based amorphous nanometer crystalline thin strip magnet is 25 μm, band
A width of 10mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 10.5% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 540 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 10mm；Calculated according to Jade softwares：
(Fe74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) crystalline state in 30 iron-based amorphous nanometer crystalline thin strip magnets
The mass fraction of phase is 85.5%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation magnetic
Induction is 1.49T, and initial permeability is 148k.
Fig. 1 is the Fe of the present embodiment74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F X ray diffracting spectrum, sample is in 2 θ
=40 °~50 ° and 2 θ=75 °~85 ° scopes show wider diffusing scattering peak, and have the diffraction maximum of crystalline phases, show
Fe74.5Cu1.5Nb2.7Si11.5B9.8There is partiallycrystalline states phase in strip.
Fig. 2 is the Fe of the present embodiment74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F means of differential scanning calorimetry (DSC) curve,
Amorphous thin ribbon F the first starting crystallization temperature is 508 DEG C as seen from the figure, and the second starting crystallization temperature is 665 DEG C.
Fig. 3 is the (Fe of the present embodiment74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron-baseds
The DSC test curves of amorphous nano-crystalline thin strip magnet, the first starting crystallization temperature of strip is 498 DEG C, second as seen from the figure
Beginning crystallization temperature is 670 DEG C, with Fe74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon is compared, starting crystallization temperature, crystalline active energy
Reduction, the interval increase of two crystallization temperatures, is beneficial to strengthen the soft magnet performance of strip.
Fig. 4 is the (Fe of the present embodiment74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron-baseds
There are three obvious diffraction maximums in the X ray diffracting spectrum of amorphous nano-crystalline thin strip magnet, figure, calculated and understood according to Scherrer formula
Average grain size is 12nm, while also there is certain diffusing scattering peak, illustrates also there is a small amount of amorphous in strip.
Fig. 5 is the (Fe of the present embodiment74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 30 iron-baseds
Typical soft magnetism feature is presented in the hysteresis curve of amorphous and nanocrystalline soft magnetic alloy iron core product, hysteresis curve.
Embodiment 2
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A, F component be group with component A master alloying A
Into corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 15.6%；The composition mass percent x of component A
It is 20 for the composition mass percent y of 80, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
Be the same as Example 1；
Second step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings：
Be the same as Example 1；
3rd step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 35m/s linear velocity after re-melting, Fe is thus made74.5Cu1.5Nb2.7Si11.5B9.8
Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be put into remelting furnace melt,
The Fe that 15min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F presses quality hundred
It is AxFy=(Fe to divide than composition expression formula74.5Cu1.5Nb2.7Si11.5B9.8)80(Fe74.5Cu1.5Nb2.7Si11.5B9.8) group in 20
The uniform Fe of remelting is added into mass percent74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings liquation in, then to mixed
(the Fe closed74.5Cu1.5Nb2.7Si11.5B9.8)80(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 20 liquations carry out slag hitting, in an atmosphere with
40m/s speed carries out spray band, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of obtained iron-based amorphous nanometer crystalline thin strip magnet is 25 μm, band
A width of 20mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 15.6% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Be the same as Example 1；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
Be the same as Example 1；
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 20mm；Calculated according to Jade softwares：
(Fe74.5Cu1.5Nb2.7Si11.5B9.8)80(Fe74.5Cu1.5Nb2.7Si11.5B9.8) crystalline phases in 20 amorphous nano-crystalline thin strip magnets
Mass fraction is 83.6%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation induction
Intensity is 1.35T, and initial permeability is 135k.
Embodiment 3
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A, F component be group with component A master alloying A
Into corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 18.4%；The composition mass percent x of component A
It is 10 for the composition mass percent y of 90, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
Be the same as Example 1；
Second step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings：
Be the same as Example 1；
3rd step, prepares Fe74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 30m/s linear velocity after re-melting, Fe is thus made74.5Cu1.5Nb2.7Si11.5B9.8
Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings be put into remelting furnace melt,
The Fe that 15min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting74.5Cu1.5Nb2.7Si11.5B9.8Amorphous thin ribbon F presses quality hundred
It is AxFy=(Fe to divide than composition expression formula74.5Cu1.5Nb2.7Si11.5B9.8)90(Fe74.5Cu1.5Nb2.7Si11.5B9.8) group in 10
The uniform Fe of remelting is added into mass percent74.5Cu1.5Nb2.7Si11.5B9.8Master alloying A ingot castings liquation in, then to mixed
(the Fe closed74.5Cu1.5Nb2.7Si11.5B9.8)90(Fe74.5Cu1.5Nb2.7Si11.5B9.8) 10 liquations carry out slag hitting, in an atmosphere with
40m/s speed carries out spray band, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
25 μm, with a width of 30mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 18.4% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Be the same as Example 1；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
Be the same as Example 1；
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 30mm；Calculated according to Jade softwares：
(Fe74.5Cu1.5Nb2.7Si11.5B9.8)90(Fe74.5Cu1.5Nb2.7Si11.5B9.8) crystalline phases in 10 amorphous nano-crystalline thin strip magnets
Mass fraction is 78.4%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation induction
Intensity is 1.32T, and initial permeability is 127k.
Embodiment 4
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe74.5Cu1.5V2.7Si11.5B9.8Master alloying A, F component be group with component A master alloying A
Into corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 12.5%；The composition mass percent x of component A
It is 30 for the composition mass percent y of 70, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
By the composition formula Fe of atomic percentage74.5Cu1.5V2.7Si11.5B9.8Each element quality is calculated, required raw material is weighed：
Vanadium iron, ferro-boron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe74.5Cu1.5V2.7Si11.5B9.8Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,74.5Cu1.5V2.7Si11.5B9.8Master alloying A ingot castings；
3rd step, prepares Fe74.5Cu1.5V2.7Si11.5B9.8Amorphous thin ribbon F：
By Fe made from above-mentioned second step74.5Cu1.5V2.7Si11.5B9.8Master alloying A ingot castings be fitted into fast melt-quenching stove, weight
Fast melt-quenching is carried out on copper disk roller with 40m/s linear velocity after new melting, Fe is thus made74.5Cu1.5V2.7Si11.5B9.8Amorphous
Strip F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step74.5Cu1.5V2.7Si11.5B9.8Master alloying A ingot castings be put into remelting furnace melt, melt
The uniform Fe for waiting that 15min prepares above-mentioned 3rd step before coming out of the stove of refining74.5Cu1.5V2.7Si11.5B9.8Amorphous thin ribbon F is by mass percentage
Composition expression formula is AxFy=(Fe74.5Cu1.5V2.7Si11.5B9.8)70(Fe74.5Cu1.5V2.7Si11.5B9.8) composition quality in 30
Percentage adds the uniform Fe of remelting74.5Cu1.5V2.7Si11.5B9.8Master alloying A ingot castings liquation in, then to mixing
(Fe74.5Cu1.5Nb2.7Si11.5B9.8)70(Fe74.5Cu1.5Nb2.7Si11.5B9.8) the progress slag hitting of 30 liquations, in an atmosphere with 40m/s
Speed carries out spray band, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
25 μm, with a width of 10mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 12.5% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 540 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 10mm；Calculated according to Jade softwares：
(Fe74.5Cu1.5V2.7Si11.5B9.8)70(Fe74.5Cu1.5V2.7Si11.5B9.8) matter of crystalline phases in 30 amorphous nano-crystalline thin strip magnets
It is 84.5% to measure fraction；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation induction is strong
Spend for 1.32T, initial permeability is 138k.
Embodiment 5
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A, F component be group with component A master alloying A
Into corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 11.6%；The composition mass percent x of component A
It is 30 for the composition mass percent y of 70, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
By the composition formula Fe of atomic percentage74.5Cu1.5Mo2.7Si11.5B9.8Each element quality is calculated, required original is weighed
Material：Vanadium iron, ferro-boron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A ingot castings；
3rd step, prepares Fe74.5Cu1.5Mo2.7Si11.5B9.8Amorphous thin ribbon F：
By Fe made from above-mentioned second step74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A ingot castings be fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 40m/s linear velocity after re-melting, Fe is thus made74.5Cu1.5Mo2.7Si11.5B9.8
Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A ingot castings be put into remelting furnace melt,
The Fe that 15min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting74.5Cu1.5Mo2.7Si11.5B9.8Amorphous thin ribbon F presses quality hundred
It is AxFy=(Fe to divide than composition expression formula74.5Cu1.5Mo2.7Si11.5B9.8)70(Fe74.5Cu1.5Mo2.7Si11.5B9.8) group in 30
The uniform Fe of remelting is added into mass percent74.5Cu1.5Mo2.7Si11.5B9.8Master alloying A ingot castings liquation in, then to mixed
(the Fe closed74.5Cu1.5Mo2.7Si11.5B9.8)70(Fe74.5Cu1.5Mo2.7Si11.5B9.8) 30 liquations carry out slag hitting, in an atmosphere with
40m/s speed carries out spray band, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
25 μm, with a width of 40mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 11.6% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 540 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 40mm；Calculated according to Jade softwares：
(Fe74.5Cu1.5Mo2.7Si11.5B9.8)70(Fe74.5Cu1.5Mo2.7Si11.5B9.8) crystalline phases in 30 amorphous nano-crystalline thin strip magnets
Mass fraction is 82.3%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation induction
Intensity is 1.28T, and initial permeability is 132k.
Embodiment 6
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A, F component be and component A master alloying A
The corresponding amorphous thin ribbon F of composition, the mass percent of crystalline phases contained therein is 5.5%；The composition mass percent of component A
X is that the composition mass percent y of 70, F components is 30.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
By the composition formula Fe of atomic percentage72.5Cu1.2Nb2V1.5Si14.5B8.3Each element quality is calculated, required original is weighed
Material：Ferro-niobium, ferro-boron, vanadium iron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A casting
Ingot；
3rd step, prepares Fe72.5Cu1.2Nb2V1.5Si14.5B8.3Amorphous thin ribbon F：
By Fe made from above-mentioned second step72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A ingot castings are fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 45m/s linear velocity after re-melting, is thus made
Fe72.5Cu1.2Nb2V1.5Si14.5B8.3Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A ingot castings, which are put into remelting furnace, to be melted,
The Fe that 10min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting72.5Cu1.2Nb2V1.5Si14.5B8.3Amorphous thin ribbon F presses quality
Percentage composition expression formula is AxFy=(Fe72.5Cu1.2Nb2V1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2V1.5Si14.5B8.3)30
In composition mass percent add remelting uniform Fe72.5Cu1.2Nb2V1.5Si14.5B8.3Master alloying A ingot castings liquation in,
Then to the (Fe of mixing72.5Cu1.2Nb2V1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2V1.5Si14.5B8.3) the progress slag hitting of 30 liquations,
Spray band is carried out with 20m/s speed in an atmosphere, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
35 μm, with a width of 40mm；Calculated according to Jade softwares：The mass fraction of crystalline phases is 5.5% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 560 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 40mm；Calculated according to Jade softwares：
(Fe72.5Cu1.2Nb2V1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2V1.5Si14.5B8.3) in 30 iron-based amorphous nanometer crystalline thin strip magnets
The mass fraction of crystalline phases is 83.3%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：It is full
It is 1.41T with magnetic induction intensity, initial permeability is 146k.
Embodiment 7
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A, F component be and component A master alloying A
The corresponding amorphous thin ribbon F of composition, the mass percent of crystalline phases contained therein is 2.0%；The composition quality percentage of component A
It is 30 than the composition mass percent y for 70, F components.
The preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, step is as follows：
The first step, preparation raw material：
By the composition formula Fe of atomic percentage72.5Cu1.2Nb2Mo1.5Si14.5B8.3Each element quality is calculated, needed for weighing
Raw material：Ferro-niobium, ferro-boron, molybdenum-iron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A casting
Ingot；
3rd step, prepares Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3Amorphous thin ribbon F：
By Fe made from above-mentioned second step72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A ingot castings are fitted into fast melt-quenching stove,
Fast melt-quenching is carried out on copper disk roller with 45m/s linear velocity after re-melting, is thus made
Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A ingot castings, which are put into remelting furnace, to be melted,
The Fe that 10min prepares above-mentioned 3rd step before coming out of the stove uniformly is waited in melting72.5Cu1.2Nb2Mo1.5Si14.5B8.3Amorphous thin ribbon F presses quality
Percentage composition expression formula is AxFy=(Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3)
Composition mass percent in 30 adds the uniform Fe of remelting72.5Cu1.2Nb2Mo1.5Si14.5B8.3Master alloying A ingot castings liquation
In, then to the (Fe of mixing72.5Cu1.2Nb2Mo1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3) progress of 30 liquations
Slag hitting, carries out spray band with 20m/s speed in an atmosphere, that is, iron-based amorphous nanometer crystalline thin strip magnet is made.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
35 μm, with a width of 40mm；Calculated according to Jade softwares, the mass fraction of crystalline phases is 2.0% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 560 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 40mm；Calculated according to Jade softwares：
(Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3)70(Fe72.5Cu1.2Nb2Mo1.5Si14.5B8.3) brilliant in 30 amorphous nano-crystalline thin strip magnets
The mass fraction of state phase is 81.6%；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation
Magnetic induction intensity is 1.38T, and initial permeability is 137k.
Embodiment 8
The iron-based amorphous nanometer crystalline thin strip magnet of the present embodiment, its mass percent constitutes expression formula for AxFy, in formula, A
Component is that atomic percent composition is Fe70Cu1Nb2.5Si12B14.5Master alloying A, F component be composition with component A master alloying A
Corresponding amorphous thin ribbon F, the mass percent of crystalline phases contained therein is 30.0%；The composition mass percent x of component A is
The composition mass percent y of 70, F components is 30.
The first step, preparation raw material：
By the composition formula Fe of atomic percentage70Cu1Nb2.5Si12B14.5Each element quality is calculated, required raw material is weighed：Niobium
Iron, ferro-boron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares Fe70Cu1Nb2.5Si12B14.5Master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating
Melting, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting to fused solution afterwards and remove
Slag, finally pours into mould and cools down, and it is Fe that atomic percent composition, which is made,70Cu1Nb2.5Si12B14.5Master alloying A ingot castings；
3rd step, prepares Fe70Cu1Nb2.5Si12B14.5Amorphous thin ribbon F：
By Fe made from above-mentioned second step70Cu1Nb2.5Si12B14.5Master alloying A ingot castings are fitted into fast melt-quenching stove, melt again
Fast melt-quenching is carried out on copper disk roller with 20m/s linear velocity after melting, Fe is thus made70Cu1Nb2.5Si12B14.5Amorphous thin ribbon F；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
By Fe made from above-mentioned second step70Cu1Nb2.5Si12B14.5Master alloying A ingot castings, which are put into remelting furnace, to be melted, and melting is equal
The even Fe for waiting that 20min prepares above-mentioned 3rd step before coming out of the stove70Cu1Nb2.5Si12B14.5Amorphous thin ribbon F constitutes table by mass percentage
It is AxFy=(Fe up to formula70Cu1Nb2.5Si12B14.5)70(Fe70Cu1Nb2.5Si12B14.5) the composition mass percent in 30 adds
The uniform Fe of remelting70Cu1Nb2.5Si12B14.5Master alloying A ingot casting liquations in, then to mixing
(Fe70Cu1Nb2.5Si12B14.5)70(Fe70Cu1Nb2.5Si12B14.5) the progress slag hitting of 30 liquations, entered in an atmosphere with 30m/s speed
Row spray band, that is, be made iron-based amorphous nanometer crystalline thin strip magnet.
Determined through slide measure and micrometer：The thickness of iron-based amorphous nanometer crystalline thin strip magnet obtained by the present embodiment is
30 μm, with a width of 20mm；Calculated according to Jade softwares：The mass fraction of crystalline phases is 30.0% in amorphous thin ribbon F.
The application process of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, for preparing iron-based amorphous and nanocrystalline soft magnetic alloy iron
Core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
Iron-based amorphous nanometer crystalline thin strip magnet made from the preparation method of above-mentioned iron-based amorphous nanometer crystalline thin strip magnet is led to
The Fe-based amorphous iron core for the dimension crossed needed for tape handler is rolled into；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, is obtained non-at 580 DEG C
It is equally distributed nanocrystalline on brilliant matrix, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of iron-based amorphous and nanocrystalline soft magnetic alloy iron core product obtained by the present embodiment is
External diameter × internal diameter × height=D × d × h=Φ 30mm × Φ 24.92mm × 20mm；Calculated according to Jade softwares：
(Fe70Cu1Nb2.5Si12B14.5)70(Fe70Cu1Nb2.5Si12B14.5) matter of crystalline phases in 30 iron-based amorphous nanometer crystalline thin strip magnets
It is 86.2% to measure fraction；Determining the product magnetic property through MATS-2010SD type soft magnetism direct-current measuring devices is：Saturation induction is strong
Spend for 1.26T, initial permeability is 125k.
Claims (4)
1. iron-based amorphous nanometer crystalline thin strip magnet, it is characterised in that：It is Finemet type amorphous nano-crystalline thin strip magnets, its quality
Percentage constitutes expression formula for AxFy, in formula, and component A is that atomic percent composition is FeaCubMcSidBeMaster alloying A, wherein M
For at least one of Nb, V and Mo element element, a, b, c, d and e represent the atomic percentage of element composition, 70.0≤a≤
74.5,1.0≤b≤1.5,2.5≤c≤3.5,11.5≤d≤14.5,8.3≤e≤14.5, and meet a+b+c+d+e=100；
F components are the amorphous thin ribbon Fs corresponding with component A master alloying A composition, and the mass percent scope of crystalline phases contained therein is
2.0%~30.0%, the composition mass percent x's of component A limits composition quality percentage of the scope as 70≤x≤90, F components
Scope is limited as 10≤y≤30 than y.
Above-mentioned iron-based amorphous nanometer crystalline thin strip magnet, its thickness is 25~35 μm, with a width of 10~40mm.
2. iron-based amorphous nanometer crystalline thin strip magnet according to claim 1, it is characterised in that：Its thickness is 25~35 μm, band
A width of 10~40mm.
3. the preparation method of iron-based amorphous nanometer crystalline thin strip magnet described in a kind of claim 1, it is characterised in that specific steps are such as
Under：
The first step, preparation raw material：
By the composition formula Fe of atomic percentageaCubMcSidBeCalculate each element quality, wherein M be Nb, V and Mo element in extremely
A kind of few element, a, b, c, d and e represent the atomic percentage of element composition, 70.0≤a≤74.5,1.0≤b≤1.5,2.5≤
C≤3.5,11.5≤d≤14.5,8.3≤e≤14.5, and a+b+c+d+e=100 is met, weigh required raw material：Ferro-niobium, boron
Iron, vanadium iron, molybdenum-iron, pure silicon, fine copper and pure iron, complete the preparation of raw material；
Second step, prepares master alloying A ingot castings：
The raw material that the above-mentioned first step is prepared is added in smelting furnace, and vacuum is evacuated to body of heater<5×10-1Pa, heating is molten
Refining, until the whole melting sources added, and makes untill composition is uniformly distributed, to carry out slag hitting and slagging-off to fused solution afterwards,
Finally pour into mould and cool down, it is Fe that atomic percent composition, which is made,aCubMcSidBeMaster alloying A ingot castings；
3rd step, prepares amorphous thin ribbon F：
Master alloying A ingot castings made from above-mentioned second step are fitted into fast melt-quenching stove, with 20~45m/s linear speed after re-melting
Degree carries out fast melt-quenching on copper disk roller, and amorphous thin ribbon F is thus made；
4th step, prepares iron-based amorphous nanometer crystalline thin strip magnet：
Master alloying A ingot castings made from above-mentioned second step are put into remelting furnace and melted, melting uniformly waits that 10~20min will before coming out of the stove
Amorphous thin ribbon F prepared by above-mentioned 3rd step constitutes expression formula and adds weight for the composition mass percent in AxFy by mass percentage
In the liquation for melting uniform master alloying A ingot castings, in AxFy formulas, master alloying A mass percent composition x limit scope as 70≤
X≤90, amorphous thin ribbon F mass percent composition y's limits scope as 10≤y≤30, and then the AxFy liquations of mixing are entered
Row slag hitting, carries out spray band with 20~40m/s speed in an atmosphere, that is, iron-based amorphous nanometer crystalline thin strip magnet is made；
Determined through slide measure and micrometer：The thickness of obtained iron-based amorphous nanometer crystalline thin strip magnet is 25~35 μm, band
A width of 10~40mm；Calculated according to Jade softwares：The mass fraction of crystalline phases is 2.0~30.0% in amorphous thin ribbon F.
4. the application process of iron-based amorphous nanometer crystalline thin strip magnet described in a kind of claim 1, it is characterised in that for preparing iron
Based amorphous nano soft magnetic alloy core product, step is as follows：
The first step, prepares Fe-based amorphous iron core：
The iron-based of dimension needed for iron-based amorphous nanometer crystalline thin strip magnet described in claim 1 is rolled into by tape handler
Amorphous iron core；
Second step, prepares iron-based amorphous and nanocrystalline soft magnetic alloy iron core product：
The obtained Fe-based amorphous iron core of above-mentioned first step volume is put into annealing furnace, is annealed, obtained at 540~580 DEG C
It is equally distributed nanocrystalline on noncrystal substrate, that is, iron-based amorphous and nanocrystalline soft magnetic alloy iron core product is made.
Determined through slide measure：The size of obtained iron-based amorphous and nanocrystalline soft magnetic alloy iron core product be external diameter × internal diameter ×
Height=D × d × h=Φ 30mm × Φ 24.92mm × (10~40) mm；Calculated according to Jade softwares：The Fe-based amorphous nanometers of AxFy
The mass fraction of crystalline phases is 78.4~86.2% in brilliant soft magnetic alloy core product；Surveyed through MATS-2010SD type soft magnetisms direct current
Amount device determines the product magnetic property and is：Saturation induction density is 1.26~1.49T, and initial permeability is 125k~148k.
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