CN107245241A - It is a kind of for cable material of power system and preparation method thereof - Google Patents

It is a kind of for cable material of power system and preparation method thereof Download PDF

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Publication number
CN107245241A
CN107245241A CN201710479810.3A CN201710479810A CN107245241A CN 107245241 A CN107245241 A CN 107245241A CN 201710479810 A CN201710479810 A CN 201710479810A CN 107245241 A CN107245241 A CN 107245241A
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Prior art keywords
parts
plasticizer
cable material
power system
rubber
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CN201710479810.3A
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Chinese (zh)
Inventor
伍文慧
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Hefei Li Xing Power Engineering Co Ltd
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Hefei Li Xing Power Engineering Co Ltd
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Priority to CN201710479810.3A priority Critical patent/CN107245241A/en
Publication of CN107245241A publication Critical patent/CN107245241A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to electric power electrical materials and appliances production technical field there is provided a kind of for cable material of power system and preparation method thereof, the cable material includes the raw material of following parts by weight:30 50 parts of compounded rubber, 20 40 parts of plasticizer, 20 40 parts of toughener, 3 10 parts of fire retardant, 13 parts of lubricant, 13 parts of filler, 20 40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:20 40 parts of silicon rubber, 20 30 parts of nitrile rubber, 10 14 parts of neoprene, 8 21 parts of neoprene, 29 parts of polyisoprene rubber.Cable material prepared by the present invention is ageing-resistant, intensity is big, pliability, draftability are good.

Description

It is a kind of for cable material of power system and preparation method thereof
Technical field
The invention belongs to electric power electrical materials and appliances production technical field, specifically, a kind of cable material for power system and its Preparation method.
Background technology
With developing rapidly that national grid is built, the application of high voltage power cable is more and more, and people are reliable to powering The requirement of rate also more and more higher.To ensure cable safe and stable operation, prevent it is new go into operation and working line there is ground wire, it is coaxial There are various safety problems in cable.But the application scenario frequently moved at some, cable is often frequently bended or stretched, and is led The service life for sending a telegraph cable is short, and cable is easily broken or fractureed, and traditional polyvinyl chloride cable usually can not meet electric wire electricity Anti-aging demand of the cable in practice.
In addition, countries in the world are attached great importance to the public hazards present situation of electric wire in recent years, laws and regulations electric wire has been formulated Overall monitor is implemented in manufacturing process and the processing scrapped, it is desirable to which electric wire manufacturing enterprise is passed using the material substitution for meeting environmental protection Commons material, the security, non-toxic index especially to product is especially strict, to reach the requirement of environmental protection.
The content of the invention
For defect of the prior art, the purpose of the present invention is on the one hand to provide a kind of cable material for power system Material and preparation method so that the cable material of preparation is ageing-resistant, intensity is big, pliability, draftability are good.
A kind of cable material for power system provided according to an aspect of the present invention, the cable material includes as follows The raw material of parts by weight:30-50 parts of compounded rubber, 20-40 parts of plasticizer, 20-40 parts of toughener, 3-10 parts of fire retardant, lubrication 1-3 parts of agent, 1-3 parts of filler, 20-40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:Silicon rubber 20-40 parts, 20-30 parts of nitrile rubber, 10-14 parts of neoprene, 8-21 parts of neoprene, 2-9 parts of polyisoprene rubber.
Preferably, the fire retardant is magnalium flame retardant.
Preferably, the toughener is polyvinyl butyral resin or polyether sulfone.
Preferably, the filler is mineral filler.
Preferably, the mineral filler be nano-calcium carbonate, calcined kaolin, talcum powder, magnesia in one kind or It is several.
Preferably, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation Fatty acid alkyl esters, second plasticizer includes epoxidation natural oil.
Preferably, the preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubrication by any described formulas of claim 1-7 Agent, filler, antioxidant, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165-185 DEG C, Pelletizing, cooling obtains the cable material for power system.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of cable material for power system that the present invention is provided, using compounded rubber, while using plasticizer, increasing Tough dose, fire retardant, lubricant, filler, antioxidant is modified to the compounded rubber so that the cable material of preparation is resistance to old Change, intensity is big, pliability, draftability are good.The preparation technology of cable material provided in an embodiment of the present invention for power system Simply, material be easy to get, effect it is notable;
(2)Major ingredient is compounded rubber, the compound rubber in a kind of cable material formula for power system that the present invention is provided Glue is made up of silicon rubber, nitrile rubber, neoprene, neoprene, polyisoprene rubber, flexible soft and wear-resistant Etc. characteristic, -50-65 DEG C of extreme environment is can adapt to, with the continuous reduction of environment temperature, will not substantially harden and lose Flexibility and elasticity;
(3)Contain plasticizer in a kind of cable material formula for power system that the present invention is provided, can using this plasticizer Enable the cable material prepared that there is good weatherability properties, pliability and elasticity, weather resistance, pliability and elasticity are not at any time Between and change, this plasticizer reduce cable material discoloration and smell.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention.
Embodiment 1
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight Material:50 parts of compounded rubber, 20 parts of plasticizer, 40 parts of toughener, 3 parts of fire retardant, 3 parts of lubricant, 1 part of filler, antioxidant 40 Part, the compounded rubber includes the raw material of following parts by weight:40 parts of silicon rubber, 20 parts of nitrile rubber, 14 parts of neoprene, chlorine 8 parts of buna, 9 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone
Wherein, the filler is mineral filler.Preferably, the mineral filler uses nano-calcium carbonate, cunning The mixture of stone flour, magnesia.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 175 DEG C, pelletizing, Cooling, obtains the cable material for power system.
Embodiment 2
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight Material:30 parts of compounded rubber, 40 parts of plasticizer, 20 parts of toughener, 10 parts of fire retardant, 1 part of lubricant, 3 parts of filler, antioxidant 20 Part, the compounded rubber includes the raw material of following parts by weight:20 parts of silicon rubber, 30 parts of nitrile rubber, 10 parts of neoprene, chlorine 21 parts of buna, 2 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone
Wherein, the filler is mineral filler.Preferably, the mineral filler uses nano-calcium carbonate, forged Burn kaolin mixture.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165 DEG C, pelletizing, Cooling, obtains the cable material for power system.
Embodiment 3
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight Material:35 parts of compounded rubber, 30 parts of plasticizer, 23 parts of toughener, 7 parts of fire retardant, 2 parts of lubricant, 2 parts of filler, antioxidant 28 Part, the compounded rubber includes the raw material of following parts by weight:22 parts of silicon rubber, 24 parts of nitrile rubber, 12 parts of neoprene, chlorine 11 parts of buna, 4 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone.
Wherein, the filler is mineral filler.Preferably, the mineral filler uses talcum powder, hardship The mixture of native powder.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 185 DEG C, pelletizing, Cooling, obtains the cable material for power system.
Embodiment 4
Performance test:
According to the raw material and proportioning described in embodiment 1-3, the cable material for power system is prepared, while choosing commercially available general Logical cable material, labeled as 1 group of experiment, 2 groups of experiment, experiment 3 groups, control group, using specified specified in UL758 and UL1581 105 DEG C of polyvinyl chloride cable testing standards of temperature, to forced ventilation as defined in embodiment and the cable material UL standards of control group Formula constant temperature(136+/-1℃)Accelerated ageing test 168h is carried out in ageing oven, test result is shown in Table 1.
The performance test situation list of table 1
Data from table 1, the cable material of the present embodiment is ageing-resistant, intensity is big, pliability, draftability are good, more typically Cable material it is good.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of cable material for power system, it is characterised in that:The cable material includes the original of following parts by weight Material:30-50 parts of compounded rubber, 20-40 parts of plasticizer, 20-40 parts of toughener, 3-10 parts of fire retardant, 1-3 parts of lubricant, filling 1-3 parts of agent, 20-40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:20-40 parts of silicon rubber, butyronitrile rubber 20-30 parts of glue, 10-14 parts of neoprene, 8-21 parts of neoprene, 2-9 parts of polyisoprene rubber.
2. a kind of cable material for power system according to claim 1, it is characterised in that:The fire retardant is aluminium Magnesium flame retardant.
3. a kind of cable material for power system according to claim 1, it is characterised in that:The toughener is poly- Vinyl butyral or polyether sulfone.
4. a kind of cable material for power system according to claim 1, it is characterised in that:The filler is ore deposit Thing filler.
5. a kind of cable material for power system according to claim 4, it is characterised in that:The mineral filler For the one or more in nano-calcium carbonate, calcined kaolin, talcum powder, magnesia.
6. a kind of cable material for power system according to claim 1, it is characterised in that:The plasticizer includes First plasticizer and the second plasticizer, first plasticizer include epoxidized fat acid alkyl ester, the second plasticizer bag Natural oil containing epoxidation.
7. a kind of cable material for power system according to claim 6, it is characterised in that:The system of the plasticizer Preparation Method is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
8. a kind of preparation method of cable material for power system as described in claim any one of 1-7, its feature exists In:Comprise the following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubrication by any described formulas of claim 1-7 Agent, filler, antioxidant, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165-185 DEG C, Pelletizing, cooling obtains the cable material for power system.
CN201710479810.3A 2017-06-22 2017-06-22 It is a kind of for cable material of power system and preparation method thereof Withdrawn CN107245241A (en)

Priority Applications (1)

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CN201710479810.3A CN107245241A (en) 2017-06-22 2017-06-22 It is a kind of for cable material of power system and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710479810.3A CN107245241A (en) 2017-06-22 2017-06-22 It is a kind of for cable material of power system and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852026A (en) * 2021-03-10 2021-05-28 江苏中柔电缆有限公司 Aging-resistant and cracking-resistant sheath material for mineral insulated cable and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945701A (en) * 2015-07-31 2015-09-30 苏州新区特氟龙塑料制品厂 Durable modified chloroprene rubber for cables
CN104974448A (en) * 2015-07-08 2015-10-14 常州市诚天电子有限公司 Cable material based on PVC material and preparation method thereof
CN105017676A (en) * 2015-04-21 2015-11-04 江苏中超电缆股份有限公司 Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable
CN105348594A (en) * 2015-12-14 2016-02-24 苏州鑫德杰电子有限公司 Scraping-resistant cable sheath material and preparing method thereof
CN105348801A (en) * 2015-11-26 2016-02-24 王威淞 Elastic wear-resistant cable material
CN105860353A (en) * 2016-05-05 2016-08-17 成都君禾天成科技有限公司 Cable material based on PVC material and preparation method of cable material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105017676A (en) * 2015-04-21 2015-11-04 江苏中超电缆股份有限公司 Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable
CN104974448A (en) * 2015-07-08 2015-10-14 常州市诚天电子有限公司 Cable material based on PVC material and preparation method thereof
CN104945701A (en) * 2015-07-31 2015-09-30 苏州新区特氟龙塑料制品厂 Durable modified chloroprene rubber for cables
CN105348801A (en) * 2015-11-26 2016-02-24 王威淞 Elastic wear-resistant cable material
CN105348594A (en) * 2015-12-14 2016-02-24 苏州鑫德杰电子有限公司 Scraping-resistant cable sheath material and preparing method thereof
CN105860353A (en) * 2016-05-05 2016-08-17 成都君禾天成科技有限公司 Cable material based on PVC material and preparation method of cable material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112852026A (en) * 2021-03-10 2021-05-28 江苏中柔电缆有限公司 Aging-resistant and cracking-resistant sheath material for mineral insulated cable and preparation method thereof

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