CN107245241A - It is a kind of for cable material of power system and preparation method thereof - Google Patents
It is a kind of for cable material of power system and preparation method thereof Download PDFInfo
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- CN107245241A CN107245241A CN201710479810.3A CN201710479810A CN107245241A CN 107245241 A CN107245241 A CN 107245241A CN 201710479810 A CN201710479810 A CN 201710479810A CN 107245241 A CN107245241 A CN 107245241A
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- plasticizer
- cable material
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- rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to electric power electrical materials and appliances production technical field there is provided a kind of for cable material of power system and preparation method thereof, the cable material includes the raw material of following parts by weight:30 50 parts of compounded rubber, 20 40 parts of plasticizer, 20 40 parts of toughener, 3 10 parts of fire retardant, 13 parts of lubricant, 13 parts of filler, 20 40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:20 40 parts of silicon rubber, 20 30 parts of nitrile rubber, 10 14 parts of neoprene, 8 21 parts of neoprene, 29 parts of polyisoprene rubber.Cable material prepared by the present invention is ageing-resistant, intensity is big, pliability, draftability are good.
Description
Technical field
The invention belongs to electric power electrical materials and appliances production technical field, specifically, a kind of cable material for power system and its
Preparation method.
Background technology
With developing rapidly that national grid is built, the application of high voltage power cable is more and more, and people are reliable to powering
The requirement of rate also more and more higher.To ensure cable safe and stable operation, prevent it is new go into operation and working line there is ground wire, it is coaxial
There are various safety problems in cable.But the application scenario frequently moved at some, cable is often frequently bended or stretched, and is led
The service life for sending a telegraph cable is short, and cable is easily broken or fractureed, and traditional polyvinyl chloride cable usually can not meet electric wire electricity
Anti-aging demand of the cable in practice.
In addition, countries in the world are attached great importance to the public hazards present situation of electric wire in recent years, laws and regulations electric wire has been formulated
Overall monitor is implemented in manufacturing process and the processing scrapped, it is desirable to which electric wire manufacturing enterprise is passed using the material substitution for meeting environmental protection
Commons material, the security, non-toxic index especially to product is especially strict, to reach the requirement of environmental protection.
The content of the invention
For defect of the prior art, the purpose of the present invention is on the one hand to provide a kind of cable material for power system
Material and preparation method so that the cable material of preparation is ageing-resistant, intensity is big, pliability, draftability are good.
A kind of cable material for power system provided according to an aspect of the present invention, the cable material includes as follows
The raw material of parts by weight:30-50 parts of compounded rubber, 20-40 parts of plasticizer, 20-40 parts of toughener, 3-10 parts of fire retardant, lubrication
1-3 parts of agent, 1-3 parts of filler, 20-40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:Silicon rubber
20-40 parts, 20-30 parts of nitrile rubber, 10-14 parts of neoprene, 8-21 parts of neoprene, 2-9 parts of polyisoprene rubber.
Preferably, the fire retardant is magnalium flame retardant.
Preferably, the toughener is polyvinyl butyral resin or polyether sulfone.
Preferably, the filler is mineral filler.
Preferably, the mineral filler be nano-calcium carbonate, calcined kaolin, talcum powder, magnesia in one kind or
It is several.
Preferably, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation
Fatty acid alkyl esters, second plasticizer includes epoxidation natural oil.
Preferably, the preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out
Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes
Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubrication by any described formulas of claim 1-7
Agent, filler, antioxidant, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix
Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165-185 DEG C,
Pelletizing, cooling obtains the cable material for power system.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of cable material for power system that the present invention is provided, using compounded rubber, while using plasticizer, increasing
Tough dose, fire retardant, lubricant, filler, antioxidant is modified to the compounded rubber so that the cable material of preparation is resistance to old
Change, intensity is big, pliability, draftability are good.The preparation technology of cable material provided in an embodiment of the present invention for power system
Simply, material be easy to get, effect it is notable;
(2)Major ingredient is compounded rubber, the compound rubber in a kind of cable material formula for power system that the present invention is provided
Glue is made up of silicon rubber, nitrile rubber, neoprene, neoprene, polyisoprene rubber, flexible soft and wear-resistant
Etc. characteristic, -50-65 DEG C of extreme environment is can adapt to, with the continuous reduction of environment temperature, will not substantially harden and lose
Flexibility and elasticity;
(3)Contain plasticizer in a kind of cable material formula for power system that the present invention is provided, can using this plasticizer
Enable the cable material prepared that there is good weatherability properties, pliability and elasticity, weather resistance, pliability and elasticity are not at any time
Between and change, this plasticizer reduce cable material discoloration and smell.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.
Embodiment 1
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight
Material:50 parts of compounded rubber, 20 parts of plasticizer, 40 parts of toughener, 3 parts of fire retardant, 3 parts of lubricant, 1 part of filler, antioxidant 40
Part, the compounded rubber includes the raw material of following parts by weight:40 parts of silicon rubber, 20 parts of nitrile rubber, 14 parts of neoprene, chlorine
8 parts of buna, 9 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone
Wherein, the filler is mineral filler.Preferably, the mineral filler uses nano-calcium carbonate, cunning
The mixture of stone flour, magnesia.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat
Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out
Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes
Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula
Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix
Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 175 DEG C, pelletizing,
Cooling, obtains the cable material for power system.
Embodiment 2
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight
Material:30 parts of compounded rubber, 40 parts of plasticizer, 20 parts of toughener, 10 parts of fire retardant, 1 part of lubricant, 3 parts of filler, antioxidant 20
Part, the compounded rubber includes the raw material of following parts by weight:20 parts of silicon rubber, 30 parts of nitrile rubber, 10 parts of neoprene, chlorine
21 parts of buna, 2 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone
Wherein, the filler is mineral filler.Preferably, the mineral filler uses nano-calcium carbonate, forged
Burn kaolin mixture.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat
Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out
Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes
Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula
Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix
Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165 DEG C, pelletizing,
Cooling, obtains the cable material for power system.
Embodiment 3
A kind of cable material for power system that the present embodiment is provided, the cable material includes the original of following parts by weight
Material:35 parts of compounded rubber, 30 parts of plasticizer, 23 parts of toughener, 7 parts of fire retardant, 2 parts of lubricant, 2 parts of filler, antioxidant 28
Part, the compounded rubber includes the raw material of following parts by weight:22 parts of silicon rubber, 24 parts of nitrile rubber, 12 parts of neoprene, chlorine
11 parts of buna, 4 parts of polyisoprene rubber.
Wherein, the fire retardant is magnalium flame retardant.Magnesium hydroxide can specifically be selected.
Wherein, the toughener is polyvinyl butyral resin or polyether sulfone.
Wherein, the filler is mineral filler.Preferably, the mineral filler uses talcum powder, hardship
The mixture of native powder.
Wherein, the plasticizer includes the first plasticizer and the second plasticizer, and first plasticizer includes epoxidation fat
Fat acid alkyl ester, second plasticizer includes epoxidation natural oil.The preparation method of the plasticizer is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out
Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
Another aspect of the present invention also provides a kind of preparation method of the cable material for power system, and methods described includes
Following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubricant, filler, antioxygen according to a formula
Agent, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix
Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 185 DEG C, pelletizing,
Cooling, obtains the cable material for power system.
Embodiment 4
Performance test:
According to the raw material and proportioning described in embodiment 1-3, the cable material for power system is prepared, while choosing commercially available general
Logical cable material, labeled as 1 group of experiment, 2 groups of experiment, experiment 3 groups, control group, using specified specified in UL758 and UL1581
105 DEG C of polyvinyl chloride cable testing standards of temperature, to forced ventilation as defined in embodiment and the cable material UL standards of control group
Formula constant temperature(136+/-1℃)Accelerated ageing test 168h is carried out in ageing oven, test result is shown in Table 1.
The performance test situation list of table 1
Data from table 1, the cable material of the present embodiment is ageing-resistant, intensity is big, pliability, draftability are good, more typically
Cable material it is good.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of cable material for power system, it is characterised in that:The cable material includes the original of following parts by weight
Material:30-50 parts of compounded rubber, 20-40 parts of plasticizer, 20-40 parts of toughener, 3-10 parts of fire retardant, 1-3 parts of lubricant, filling
1-3 parts of agent, 20-40 parts of antioxidant, the compounded rubber includes the raw material of following parts by weight:20-40 parts of silicon rubber, butyronitrile rubber
20-30 parts of glue, 10-14 parts of neoprene, 8-21 parts of neoprene, 2-9 parts of polyisoprene rubber.
2. a kind of cable material for power system according to claim 1, it is characterised in that:The fire retardant is aluminium
Magnesium flame retardant.
3. a kind of cable material for power system according to claim 1, it is characterised in that:The toughener is poly-
Vinyl butyral or polyether sulfone.
4. a kind of cable material for power system according to claim 1, it is characterised in that:The filler is ore deposit
Thing filler.
5. a kind of cable material for power system according to claim 4, it is characterised in that:The mineral filler
For the one or more in nano-calcium carbonate, calcined kaolin, talcum powder, magnesia.
6. a kind of cable material for power system according to claim 1, it is characterised in that:The plasticizer includes
First plasticizer and the second plasticizer, first plasticizer include epoxidized fat acid alkyl ester, the second plasticizer bag
Natural oil containing epoxidation.
7. a kind of cable material for power system according to claim 6, it is characterised in that:The system of the plasticizer
Preparation Method is:
Step 1: by the first plasticizer and the second plasticizer in mass ratio 1:2 weighings are standby;
Step 2: making first plasticizer and second plasticizer be reacted respectively with oxide interface, color dodge is carried out
Processing, the oxide is potassium permanganate powder, and the potassium permanganate powder is mounted in venting bags;
Step 3: the first plasticizer and the second plasticizer after the color dodge processing by step 2 are mixed, you can.
8. a kind of preparation method of cable material for power system as described in claim any one of 1-7, its feature exists
In:Comprise the following steps:
Step 1: weighing compounded rubber, plasticizer, toughener, fire retardant, lubrication by any described formulas of claim 1-7
Agent, filler, antioxidant, it is standby;
Step 2: the compounded rubber is mixed with the plasticizer, mixture one is obtained;
Step 3: adding toughener, fire retardant, lubricant, filler, antioxidant mixing into the mixture one, it must mix
Thing two;
Step 4: the melting extrusion of mixture two is carried out into plastics processing, the temperature of the melting extrusion plasticizing is 165-185 DEG C,
Pelletizing, cooling obtains the cable material for power system.
Priority Applications (1)
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CN201710479810.3A CN107245241A (en) | 2017-06-22 | 2017-06-22 | It is a kind of for cable material of power system and preparation method thereof |
Applications Claiming Priority (1)
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CN201710479810.3A CN107245241A (en) | 2017-06-22 | 2017-06-22 | It is a kind of for cable material of power system and preparation method thereof |
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Publication Number | Publication Date |
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CN107245241A true CN107245241A (en) | 2017-10-13 |
Family
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CN201710479810.3A Withdrawn CN107245241A (en) | 2017-06-22 | 2017-06-22 | It is a kind of for cable material of power system and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112852026A (en) * | 2021-03-10 | 2021-05-28 | 江苏中柔电缆有限公司 | Aging-resistant and cracking-resistant sheath material for mineral insulated cable and preparation method thereof |
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CN104945701A (en) * | 2015-07-31 | 2015-09-30 | 苏州新区特氟龙塑料制品厂 | Durable modified chloroprene rubber for cables |
CN104974448A (en) * | 2015-07-08 | 2015-10-14 | 常州市诚天电子有限公司 | Cable material based on PVC material and preparation method thereof |
CN105017676A (en) * | 2015-04-21 | 2015-11-04 | 江苏中超电缆股份有限公司 | Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable |
CN105348594A (en) * | 2015-12-14 | 2016-02-24 | 苏州鑫德杰电子有限公司 | Scraping-resistant cable sheath material and preparing method thereof |
CN105348801A (en) * | 2015-11-26 | 2016-02-24 | 王威淞 | Elastic wear-resistant cable material |
CN105860353A (en) * | 2016-05-05 | 2016-08-17 | 成都君禾天成科技有限公司 | Cable material based on PVC material and preparation method of cable material |
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2017
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CN105017676A (en) * | 2015-04-21 | 2015-11-04 | 江苏中超电缆股份有限公司 | Graphene-containing high heat conduction polyvinyl chloride sheath material for cable, and cable |
CN104974448A (en) * | 2015-07-08 | 2015-10-14 | 常州市诚天电子有限公司 | Cable material based on PVC material and preparation method thereof |
CN104945701A (en) * | 2015-07-31 | 2015-09-30 | 苏州新区特氟龙塑料制品厂 | Durable modified chloroprene rubber for cables |
CN105348801A (en) * | 2015-11-26 | 2016-02-24 | 王威淞 | Elastic wear-resistant cable material |
CN105348594A (en) * | 2015-12-14 | 2016-02-24 | 苏州鑫德杰电子有限公司 | Scraping-resistant cable sheath material and preparing method thereof |
CN105860353A (en) * | 2016-05-05 | 2016-08-17 | 成都君禾天成科技有限公司 | Cable material based on PVC material and preparation method of cable material |
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CN112852026A (en) * | 2021-03-10 | 2021-05-28 | 江苏中柔电缆有限公司 | Aging-resistant and cracking-resistant sheath material for mineral insulated cable and preparation method thereof |
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