CN107244908A - A kind of high white jade stone polished brick adobe and its ceramic tile preparation method - Google Patents

A kind of high white jade stone polished brick adobe and its ceramic tile preparation method Download PDF

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CN107244908A
CN107244908A CN201710412200.1A CN201710412200A CN107244908A CN 107244908 A CN107244908 A CN 107244908A CN 201710412200 A CN201710412200 A CN 201710412200A CN 107244908 A CN107244908 A CN 107244908A
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white
powder
high temperature
adobe
polished brick
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CN107244908B (en
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袁红
罗凤钻
邱军
陈勇
徐正荣
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Foshan Yingpai Technology Co., Ltd
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Roc Pottery Co Ltd Of Foshan Shi Wan China
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Abstract

A kind of high white jade stone polished brick adobe and its ceramic tile preparation method, the mixed powder compacting that the adobe of the high white jade stone polished brick is made up of high temperature material and high-white transparent material are formed, and the mass ratio of the high temperature material and high-white transparent material is (40~50):100;The chemical constituent of the high temperature material, being calculated according to mass percent includes:70~74%SiO2, 17~19%Al2O3, 0.1~0.5%CaO, 0.5~1%MgO, 1~2%K2O, 3~5%Na2O ,≤0.5%Fe2O3,≤0.1%TiO2With 3~5% loss on ignitions;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:68~72%SiO2, 17~19%Al2O3, 1~2%CaO, 1~2%MgO, 2~4%K2O, 3~5%Na2O, 0.2~1%LiO2,≤0.5%Fe2O3,≤0.1%TiO2With 2~4% loss on ignitions;The adobe of high white jade stone polished brick proposed by the present invention, obtained high white jade stone polished brick, jade texture is more true to nature, and stereovision is stronger, higher with whiteness and glossiness, the characteristics of antifouling property is good, and preparation technology is simple and effect stability.

Description

A kind of high white jade stone polished brick adobe and its ceramic tile preparation method
Technical field
The present invention relates to architectural pottery technical field, more particularly to a kind of high white jade stone polished brick adobe and its ceramic tile system Preparation Method.
Background technology
For imitative stone polishing brick, the characteristics of there is the texture of wear-resisting antifouling property well and natural-like stone because of it, So as to come into huge numbers of families instead of lithotome.And the jade stone polished brick for occurring at present, existing high value jade texture, Price is also inexpensive, therefore is liked deeply by finishing owner;And using jade stone polished brick paving room, the sky of interior can be made Between seem that simpler air and elegance are honorable so that greatly improve interior style and comfortable for living sense.
But current jade stone polished brick, as the state-of-the art polished bricks of in the market, what it was pursued is the texture effect of high value jade Really, but the luster effect of most jade stone polished brick does not have the strong of common polished bricks, it there is beautiful texture and not enough force Very fine and smooth, glossiness and whiteness are relatively low, and surface is also easy to produce solution cavity, impurity, the low deficiency of anti-pollution characteristic.
The content of the invention
It is an object of the invention to propose a kind of jade texture more true to nature, the white jade stone polished brick of the stronger height of stereovision Adobe, it has whiteness and glossiness higher, antifouling property is good, environment protection health the characteristics of.
It is another object of the present invention to propose a kind of preparation method of high white jade stone polished brick, preparation technology is simple And it is easy to quality monitoring, effect stability.
For up to this purpose, the present invention uses following technical scheme:
A kind of adobe of high white jade stone polished brick, the mixed powder that the adobe is made up of high temperature material and high-white transparent material Material compacting is formed, and the mass ratio of the high temperature material and high-white transparent material is (40~50):100;
The chemical constituent of the high temperature material, being calculated according to mass percent includes:70~74%SiO2, 17~19% Al2O3, 0.1~0.5%CaO, 0.5~1%MgO, 1~2%K2O, 3~5%Na2O ,≤0.5%Fe2O3,≤0.1%TiO2With 3~5% loss on ignitions;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:68~72%SiO2、17 ~19%Al2O3, 1~2%CaO, 1~2%MgO, 2~4%K2O, 3~5%Na2O, 0.2~1%LiO2,≤0.5%Fe2O3、 ≤ 0.1%TiO2With 2~4% loss on ignitions.
Further illustrate, the raw material composition of the high temperature material, being calculated according to mass percent includes:15~25% clays, 20~23% middle temperature sand, 12~16% water mill stone flours, 10~20% feldspars, 15~18% high temperature sands, 15~25% quartz, 2~ 3% talcum and 0.3~0.5% sodium tripolyphosphate;
The raw material composition of the high-white transparent material, being calculated according to mass percent includes:15~25% clays, 8~12% The high potassium stone flour of middle temperature sand, 18~22% water mills, 15~30% feldspars, the high lithium white sand in 13~17% Jiangxi, 10~25% quartz, 2 ~3% talcum, 3~5% calcites and 0.3~0.5% sodium tripolyphosphate.
Further illustrate, the grain composition of the mixed powder, being calculated according to mass percent includes:The particle diameters of < 1% are The powder of 20 mesh, 35~45% particle diameters are that the powder of 40 mesh, 50~60% particle diameters are that the powder of 80 mesh, the particle diameters of < 3% are 100 mesh Powder above.
Further illustrate, the moisture content of mixed powder is 6.3%~7.4%.
Further illustrate, the chemical constituent of the high temperature material, being calculated according to mass percent includes:73.07%SiO2、 17.51%Al2O3, 0.35%CaO, 0.53%MgO, 1.12%K2O, 3.93%Na2O, 0.25%Fe2O3, 0.01%TiO2With 3.23% loss on ignition;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:69.64%SiO2、 17.06%Al2O3, 1.35%CaO, 1.23%MgO, 3.16%K2O, 4.28%Na2O, 0.38%LiO2, 0.16%Fe2O3、 0.01%TiO2With 2.73% loss on ignition.
A kind of preparation method of high white jade stone polished brick, comprises the following steps:
(1) preparation of mixed powder:By the raw material for matching the weigh raw material and high-white transparent material that are equipped with high temperature material, and respectively Slurry is obtained by ball milling, then carries out spray drying acquisition high temperature powder and high-white transparent powder;By the high temperature powder and institute High-white transparent powder is stated after homogenizing is old, is (40~50) according to mass ratio:100 are mixed, and obtain mixed powder;
(2) mixed powder is burnt till into acquisition adobe by cloth, compressing and high temperature;
(3) by the adobe by surface polishing edging processing, you can obtain high white jade stone polished brick.
Further illustrate, the fineness of ball milling described in step (1) is 250 mesh, tails over 0.9%;The slurry is obtained after ball milling The proportion of material is 1.69, and flow velocity is 60m/s.
Further illustrate, it is old that the homogenizing of high temperature powder and the high-white transparent powder is old described in step (1) In storehouse carry out it is old >=24 hours.
Further illustrate, the temperature burnt till described in step (2) is 1175~1190 DEG C.
Beneficial effects of the present invention:The stereovision with jade texture more true to nature, more enriched that the present invention is obtained High white jade stone polished brick, including following features:(1) limitation of the Recipe of existing jade stone polished brick has been broken, has led to Cross and adjust the rational proportion between the high temperature material and the high-white transparent material to be mixed, high-white transparent material has low temperature high The good performance of white meltbility, and in combination with matching high temperature material, so as to more set off out forcing for high-white transparent material Very beautiful texture, greatly enriches space of a whole page stereovision, the whiteness after adobe is burnt till can reach more than 60 degree;
(2) the high temperature material and the component formula system of the high-white transparent material being mutually matched using setting, effective gram Traditional jade polished bricks are taken and the problems such as easily producing solution cavity, impurity, soil pick-up, ceramic tile are combined with high-white transparent material using high temperature material Surface is without solution cavity and antifouling property is more preferable;
(3) by introducing component containing elemental lithium in the high-white transparent material, solve necessary in traditional high white formula The puzzlement of the high radiation raw material zirconium silicate of addition, has prevented radiation of traditional high white ceramic tile to human body, more environmentally-friendly health;
(4) adobe can select sheen bistrique and be processed by shot blasting that its glossiness can reach 30 degree, so that its sense of touch is more Refinement is greasy, and jade effect is more life-like naturally, the soft sensation for giving people gentle such as jade of vision.
Embodiment
Technical scheme is further illustrated below by embodiment.
A kind of adobe of high white jade stone polished brick, the mixed powder that the adobe is made up of high temperature material and high-white transparent material Material compacting is formed, and the mass ratio of the high temperature material and high-white transparent material is (40~50):100;
The chemical constituent of the high temperature material, being calculated according to mass percent includes:70~74%SiO2, 17~19% Al2O3, 0.1~0.5%CaO, 0.5~1%MgO, 1~2%K2O, 3~5%Na2O ,≤0.5%Fe2O3,≤0.1%TiO2With 3~5% loss on ignitions;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:68~72%SiO2、17 ~19%Al2O3, 1~2%CaO, 1~2%MgO, 2~4%K2O, 3~5%Na2O, 0.2~1%LiO2,≤0.5%Fe2O3、 ≤ 0.1%TiO2With 2~4% loss on ignitions.
The adobe of a kind of high white jade stone polished brick proposed by the present invention, mainly by described in setting and necessarily matching The composition composition of high temperature material and the high-white transparent material, and using mass ratio as (40~50):100 by the high temperature material and described High-white transparent material is uniformly mixed, and forms the mixed powder of the adobe for preparing high white jade stone polished brick;Again by it By cloth, suppress, burn till with after polishing so that obtain it is a kind of there is jade texture more true to nature, stereovision is stronger The white jade stone polished brick of height, it mainly includes following features:
(1) limitation of the Recipe of existing jade stone polished brick has been broken, by adjusting the high temperature material and described Rational proportion between high-white transparent material is mixed, and high-white transparent material has the good performance of the high white meltbility of low temperature, and together When combine matching high temperature material, so as to more set off out the beautiful texture true to nature of high-white transparent material, greatly enrich Space of a whole page stereovision, the whiteness after adobe is burnt till can reach more than 60 degree;
(2) the high temperature material and the component formula system of the high-white transparent material being mutually matched using setting, effective gram Traditional jade polished bricks are taken and the problems such as easily producing solution cavity, impurity, soil pick-up, ceramic tile are combined with high-white transparent material using high temperature material Surface is without solution cavity and antifouling property is more preferable;
(3) by introducing component containing elemental lithium in the high-white transparent material, solve necessary in traditional high white formula The puzzlement of the high radiation raw material zirconium silicate of addition, has prevented radiation of traditional high white ceramic tile to human body, more environmentally-friendly health;
(4) adobe can select sheen bistrique and be processed by shot blasting that its glossiness can reach 30 degree, so that its sense of touch is more Refinement is greasy, and jade effect is more life-like naturally, the soft sensation for giving people gentle such as jade of vision.
Further illustrate, the raw material composition of the high temperature material, being calculated according to mass percent includes:15~25% clays, 20~23% middle temperature sand, 12~16% water mill stone flours, 10~20% feldspars, 15~18% high temperature sands, 15~25% quartz, 2~ 3% talcum and 0.3~0.5% sodium tripolyphosphate;
The raw material composition of the high-white transparent material, being calculated according to mass percent includes:15~25% clays, 8~12% The high potassium stone flour of middle temperature sand, 18~22% water mills, 15~30% feldspars, the high lithium white sand in 13~17% Jiangxi, 10~25% quartz, 2 ~3% talcum, 3~5% calcites and 0.3~0.5% sodium tripolyphosphate.
The raw material of the high temperature material and high-white transparent material is mutually combined, is to further more highlight the high-white transparent The beautiful texture true to nature of material, and it also requires controlling its whiteness within the specific limits, and introduces one in the high-white transparent material Quantitative high lithium white sand is combined with other compositions, can not only improve the whiteness of adobe, and instead of the silicon with radiativity Sour zr element, so as to reach more environmentally-friendly health while more preferable brick face effect.
Further illustrate, the grain composition of the mixed powder, being calculated according to mass percent includes:The particle diameters of < 1% are The powder of 20 mesh, 35~45% particle diameters are that the powder of 40 mesh, 50~60% particle diameters are that the powder of 80 mesh, the particle diameters of < 3% are 100 mesh Powder above.
Formed after the high temperature material and high-white transparent material are mixed after mixed powder, it is further described by setting The grain composition feature of mixed powder, is uniformly mixed using the mixed powder of a certain proportion of different-grain diameter, so that not only Improve adobe space of a whole page stereovision, it is more life-like naturally, and make the adobe burn till after consistency more preferably, improve its antifouling Performance and bulk strength.
Further illustrate, the moisture content of the mixed powder is 6.3%~7.4%.
By controlling certain moisture content of the mixed powder, make adobe after compressing and high temperature is burnt till, its intensity More preferably, it is to avoid the generation of solution cavity.
Further illustrate, the chemical constituent of the high temperature material, being calculated according to mass percent includes:73.07%SiO2、 17.51%Al2O3, 0.35%CaO, 0.53%MgO, 1.12%K2O, 3.93%Na2O, 0.25%Fe2O3, 0.01%TiO2With 3.23% loss on ignition;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:69.64%SiO2、 17.06%Al2O3, 1.35%CaO, 1.23%MgO, 3.16%K2O, 4.28%Na2O, 0.38%LiO2, 0.16%Fe2O3、 0.01%TiO2With 2.73% loss on ignition.
A kind of preparation method of high white jade stone polished brick, comprises the following steps:
(1) preparation of mixed powder:By the raw material for matching the weigh raw material and high-white transparent material that are equipped with high temperature material, and respectively Slurry is obtained by ball milling, then carries out spray drying acquisition high temperature powder and high-white transparent powder;By the high temperature powder and institute High-white transparent powder is stated after homogenizing is old, is (40~50) according to mass ratio:100 are mixed, and obtain mixed powder;
(2) mixed powder is burnt till into acquisition adobe by cloth, compressing and high temperature;
(3) by the adobe by surface polishing edging processing, you can obtain high white jade stone polished brick.
The preparation method of high white jade stone polished brick proposed by the present invention, prepares high temperature according to respective proportioning respectively first The raw material of material and the raw material of high-white transparent material, then by ball milling, granulation and it is old after, and mix available according to certain ratio Uniform and stable mixed powder, so as to carry out preparation adobe using the mixed powder, just can obtain Gao Bai after polishing Jade stone polished brick, its space of a whole page stereovision is stronger, and jade effect is more naturally, high whiteness and anti-fouling effect are more preferable, prepared by entirety Technique is simple and is easy to quality monitoring, effect stability.
Further illustrate, the fineness of ball milling described in step (1) is 250 mesh, tails over 0.9%;The slurry is obtained after ball milling The proportion of material is 1.69, and flow velocity is 60m/s.
The proportion of the slurry after the fineness and ball milling of raw material ball milling is controlled, makes the mobility of slurry more preferable, so that more The particle powder for being conducive to the mist projection granulating in the later stage to obtain is more uniform, each particle powder stable homogeneous, readily available difference The mixed powder that level is matched somebody with somebody.
Further illustrate, it is old that the homogenizing of high temperature powder and the high-white transparent powder is old described in step (1) In storehouse carry out it is old >=24 hours.
Further illustrate, the temperature burnt till described in step (2) is 1175~1190 DEG C.
A kind of preparation methods of high white jade stone polished brick of embodiment 1-, comprise the following steps:
(1) preparation of mixed powder:By proportioning weigh be equipped with high temperature material raw material and high-white transparent material raw material, i.e., according to Mass percent is calculated, by 15% clay, 20% middle temperature sand, 12% water mill stone flour, 10% feldspar, 18% high temperature sand, 21.5% Quartz, 3% talcum and 0.5% sodium tripolyphosphate as high temperature material composition of raw materials;By 25% clay, 12% middle temperature sand, The high potassium stone flour of 19.7% water mill, 15% feldspar, the high lithium white sand in 13% Jiangxi, 10% quartz, 2% talcum, 3% calcite and 0.3% sodium tripolyphosphate as high-white transparent material composition of raw materials;
The raw material of the raw material of high temperature material and high-white transparent material is obtained into slurry respectively through ball milling sieving, wherein, ball milling Fineness is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s;Again by the slurry Spray drying is carried out respectively obtains high temperature powder and high-white transparent powder;The high temperature powder and the high-white transparent powder are passed through Cross in ageing tower carry out >=24 hours homogenizing it is old after, according to mass ratio be 45:100 are mixed, and obtain mixed powder, The moisture content of the mixed powder is 6.8%;
The grain composition of the mixed powder, being calculated according to mass percent includes:0.5% particle diameter for 20 mesh powder, 40.5% particle diameter is that the powder of 40 mesh, 57% particle diameter are that the powder of 80 mesh, 2% particle diameter are more than 100 mesh powder;
(2) mixed powder is carried out after cloth by material distributing machine, be pressed by press, then by molding blank Enter burning kiln progress high temperature after drying kiln drying to burn till, its temperature burnt till is 1183 DEG C, you can obtain adobe, adobe Thickness be 11.3mm;
(3) adobe is subjected to surface polishing edging processing by sheen bistrique, you can obtain high white jade stone polishing Brick 1.
A kind of preparation methods of high white jade stone polished brick of embodiment 2-, comprise the following steps:
(1) preparation of mixed powder:By proportioning weigh be equipped with high temperature material raw material and high-white transparent material raw material, i.e., according to Mass percent is calculated, by 15% clay, 23% middle temperature sand, 12% water mill stone flour, 16.1% feldspar, 16% high temperature sand, 15% Quartz, 2.5% talcum and 0.4% sodium tripolyphosphate as high temperature material composition of raw materials;By 15% clay, 8% middle temperature sand, The high potassium stone flour of 18.7% water mill, 30% feldspar, the high lithium white sand in 13% Jiangxi, 10% quartz, 2% talcum, 3% calcite and 0.3% sodium tripolyphosphate as high-white transparent material composition of raw materials;
The raw material of the raw material of high temperature material and high-white transparent material is obtained into slurry respectively through ball milling sieving, wherein, ball milling Fineness is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s;Again by the slurry Spray drying is carried out respectively obtains high temperature powder and high-white transparent powder;The high temperature powder and the high-white transparent powder are passed through Cross in ageing tower carry out >=24 hours homogenizing it is old after, according to mass ratio be 45:100 are mixed, and obtain mixed powder, The moisture content of the mixed powder is 6.8%;
The grain composition of the mixed powder, being calculated according to mass percent includes:0.5% particle diameter for 20 mesh powder, 40.5% particle diameter is that the powder of 40 mesh, 57% particle diameter are that the powder of 80 mesh, 2% particle diameter are more than 100 mesh powder;
(2) mixed powder is carried out after cloth by material distributing machine, be pressed by press, then by molding blank Enter burning kiln progress high temperature after drying kiln drying to burn till, its temperature burnt till is 1183 DEG C, you can obtain adobe, adobe Thickness be 11.3mm;
(3) adobe is subjected to surface polishing edging processing by sheen bistrique, you can obtain high white jade stone polishing Brick 2.
A kind of preparation methods of high white jade stone polished brick of embodiment 3-, comprise the following steps:
(1) preparation of mixed powder:By proportioning weigh be equipped with high temperature material raw material and high-white transparent material raw material, i.e., according to Mass percent is calculated, by 25% clay, 20% middle temperature sand, 12.7% water mill stone flour, 10% feldspar, 15% high temperature sand, 15% Quartz, 2% talcum and 0.3% sodium tripolyphosphate as high temperature material composition of raw materials;By 15% clay, 8% middle temperature sand, 18% water Grind high potassium stone flour, 20% feldspar, the high lithium white sand in 17% Jiangxi, 13.5% quartz, 3% talcum, 5% calcite and 0.5% trimerization Sodium phosphate as high-white transparent material composition of raw materials;
The raw material of the raw material of high temperature material and high-white transparent material is obtained into slurry respectively through ball milling sieving, wherein, ball milling Fineness is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s;Again by the slurry Spray drying is carried out respectively obtains high temperature powder and high-white transparent powder;The high temperature powder and the high-white transparent powder are passed through Cross in ageing tower carry out >=24 hours homogenizing it is old after, according to mass ratio be 45:100 are mixed, and obtain mixed powder, The moisture content of the mixed powder is 6.8%;
The grain composition of the mixed powder, being calculated according to mass percent includes:0.5% particle diameter for 20 mesh powder, 40.5% particle diameter is that the powder of 40 mesh, 57% particle diameter are that the powder of 80 mesh, 2% particle diameter are more than 100 mesh powder;
(2) mixed powder is carried out after cloth by material distributing machine, be pressed by press, then by molding blank Enter burning kiln progress high temperature after drying kiln drying to burn till, its temperature burnt till is 1183 DEG C, you can obtain adobe, adobe Thickness be 11.3mm;
(3) adobe is subjected to surface polishing edging processing by sheen bistrique, you can obtain high white jade stone polishing Brick 3.
The chemical constituent such as table 1 below institute of the high white jade stone polished brick obtained by embodiment 1~3 is counted respectively Show;And the high white jade stone polished brick obtained respectively from embodiment 1~3 carries out grab sample product, and often implements The white jade stone polished brick of height that example is obtained each is divided into 10 experimental groups, by 20 experimenters respectively by it compared with real jade Fidelity relatively is distinguished sentence, the accuracy of discrimination is finally counted;
Table 1:The chemical constituent table of different high white jade stone polished bricks
Table 2:The white jade stone polished brick of height of each embodiment distinguishes the degree of accuracy
From Tables 1 and 2, the white jade stone polished brick 2 of height obtained by embodiment 2 is compared to embodiment 1 and embodiment 3 The white jade stone polished brick of height, it distinguishes that degree of accuracy is minimum, and its accuracy rate is only 50% or so, therefore its emulator is higher, Higher simulated effect is reached, its jade texture is more life-like;Therefore constituted by changing its raw material, so as to set mutually Matching the high temperature material and the high-white transparent material component formula system, reduce produce solution cavity, impurity, soil pick-up the problem of and Cause fidelity to reduce, make ceramic tile surface jade texture more preferably, stereovision more enrich;Understood additionally by table 1, in institute State and elemental lithium component also add in high-white transparent material, make adobe burn till after whiteness more preferably, polishing after-vision it is softer.
A kind of preparation methods of high white jade stone polished brick of embodiment 4-, comprise the following steps:
(1) preparation of mixed powder:By proportioning weigh be equipped with high temperature material raw material and high-white transparent material raw material, i.e., according to Mass percent is calculated, by 15% clay, 23% middle temperature sand, 12% water mill stone flour, 16.1% feldspar, 16% high temperature sand, 15% Quartz, 2.5% talcum and 0.4% sodium tripolyphosphate as high temperature material composition of raw materials;By 15% clay, 8% middle temperature sand, The high potassium stone flour of 18.7% water mill, 30% feldspar, the high lithium white sand in 13% Jiangxi, 10% quartz, 2% talcum, 3% calcite and 0.3% sodium tripolyphosphate as high-white transparent material composition of raw materials;
The raw material of the raw material of high temperature material and high-white transparent material is obtained into slurry respectively through ball milling sieving, wherein, ball milling Fineness is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s;Again by the slurry Spray drying is carried out respectively obtains high temperature powder and high-white transparent powder;The high temperature powder and the high-white transparent powder are passed through Cross in ageing tower carry out >=24 hours homogenizing it is old after, according to mass ratio be 40:100 are mixed, and obtain mixed powder, The moisture content of the mixed powder is 6.3%;
The grain composition of the mixed powder, being calculated according to mass percent includes:0.5% particle diameter for 20 mesh powder, 37.5% particle diameter is that the powder of 40 mesh, 60% particle diameter are that the powder of 80 mesh, 2% particle diameter are more than 100 mesh powder;
(2) mixed powder is carried out after cloth by material distributing machine, be pressed by press, then by molding blank Enter burning kiln progress high temperature after drying kiln drying to burn till, its temperature burnt till is 1175 DEG C, you can obtain adobe, adobe Thickness be 11.3mm;
(3) adobe is subjected to surface polishing edging processing by sheen bistrique, you can obtain high white jade stone polishing Brick 4.
A kind of preparation methods of high white jade stone polished brick of embodiment 5-, comprise the following steps:
(1) preparation of mixed powder:By proportioning weigh be equipped with high temperature material raw material and high-white transparent material raw material, i.e., according to Mass percent is calculated, by 15% clay, 23% middle temperature sand, 12% water mill stone flour, 16.1% feldspar, 16% high temperature sand, 15% Quartz, 2.5% talcum and 0.4% sodium tripolyphosphate as high temperature material composition of raw materials;By 15% clay, 8% middle temperature sand, The high potassium stone flour of 18.7% water mill, 30% feldspar, the high lithium white sand in 13% Jiangxi, 10% quartz, 2% talcum, 3% calcite and 0.3% sodium tripolyphosphate as high-white transparent material composition of raw materials;
The raw material of the raw material of high temperature material and high-white transparent material is obtained into slurry respectively through ball milling sieving, wherein, ball milling Fineness is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s;Again by the slurry Spray drying is carried out respectively obtains high temperature powder and high-white transparent powder;The high temperature powder and the high-white transparent powder are passed through Cross in ageing tower carry out >=24 hours homogenizing it is old after, according to mass ratio be 50:100 are mixed, and obtain mixed powder, The moisture content of the mixed powder is 7.4%;
The grain composition of the mixed powder, being calculated according to mass percent includes:0.5% particle diameter for 20 mesh powder, 45% particle diameter is that the powder of 40 mesh, 52% particle diameter are that the powder of 80 mesh, 2.5% particle diameter are more than 100 mesh powder;
(2) mixed powder is carried out after cloth by material distributing machine, be pressed by press, then by molding blank Enter burning kiln progress high temperature after drying kiln drying to burn till, its temperature burnt till is 1190 DEG C, you can obtain adobe, adobe Thickness be 11.3mm;
(3) adobe is subjected to surface polishing edging processing by sheen bistrique, you can obtain high white jade stone polishing Brick 5.
Properties of product are detected
The white jade stone polished brick product of height and existing anti-jade in examples detailed above 1~5 after polishing are taken respectively Stone brick carries out the detection of whiteness, glossiness, solution cavity and the performance such as antifouling respectively, and obtained testing result is as shown in the table:
As seen from the above table, the white jade stone polished brick of height being prepared into by embodiment 1~5, brick face is not substantially molten after polishing Hole, coats to wipe after ink and does not find soil pick-up situation, detection whiteness at 60 degree and more than, glossiness reaches more than 30 degree, brick Face stereovision is strong, and vision is soft, with beautiful texture true to nature.
The technical principle of the present invention is described above in association with specific embodiment.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention can not be construed in any way.Based on explanation herein, the technology of this area Personnel, which would not require any inventive effort, can associate other embodiments of the present invention, and these modes are fallen within Within protection scope of the present invention.

Claims (9)

1. a kind of adobe of high white jade stone polished brick, it is characterised in that:The adobe is by high temperature material and high-white transparent material group Into mixed powder compacting form, the mass ratio of the high temperature material and high-white transparent material is (40~50):100;
The chemical constituent of the high temperature material, being calculated according to mass percent includes:70~74%SiO2, 17~19%Al2O3、0.1 ~0.5%CaO, 0.5~1%MgO, 1~2%K2O, 3~5%Na2O ,≤0.5%Fe2O3,≤0.1%TiO2Burnt with 3~5% Vector;The chemical constituent of the high-white transparent material, being calculated according to mass percent includes:68~72%SiO2, 17~19% Al2O3, 1~2%CaO, 1~2%MgO, 2~4%K2O, 3~5%Na2O, 0.2~1%LiO2,≤0.5%Fe2O3、≤ 0.1%TiO2With 2~4% loss on ignitions.
2. a kind of adobe of high white jade stone polished brick according to claim 1, it is characterised in that:The original of the high temperature material Material composition, being calculated according to mass percent includes:15~25% clays, 20~23% middle temperature sand, 12~16% water mill stone flours, 10 ~20% feldspar, 15~18% high temperature sands, 15~25% quartz, 2~3% talcums and 0.3~0.5% sodium tripolyphosphate;
The raw material composition of the high-white transparent material, being calculated according to mass percent includes:15~25% clays, 8~12% middle temperature The high potassium stone flour of sand, 18~22% water mills, 15~30% feldspars, the high lithium white sand in 13~17% Jiangxi, 10~25% quartz, 2~3% Talcum, 3~5% calcites and 0.3~0.5% sodium tripolyphosphate.
3. a kind of adobe of high white jade stone polished brick according to claim 1 or 2, it is characterised in that:The mixed powder The grain composition of material, being calculated according to mass percent includes:The particle diameters of < 1% are that the powder of 20 mesh, 35~45% particle diameters are 40 mesh Powder, 50~60% particle diameters be that the powder of 80 mesh, the particle diameters of < 3% are more than 100 mesh powder.
4. a kind of adobe of high white jade stone polished brick according to claim 1 or 2, it is characterised in that:Mixed powder Moisture content is 6.3%~7.4%.
5. a kind of adobe of high white jade stone polished brick according to claim 1, it is characterised in that:The change of the high temperature material Component is learned, being calculated according to mass percent includes:73.07%SiO2, 17.51%Al2O3, 0.35%CaO, 0.53%MgO, 1.12%K2O, 3.93%Na2O, 0.25%Fe2O3, 0.01%TiO2With 3.23% loss on ignition;The chemistry of the high-white transparent material Component, being calculated according to mass percent includes:69.64%SiO2, 17.06%Al2O3, 1.35%CaO, 1.23%MgO, 3.16%K2O, 4.28%Na2O, 0.38%LiO2, 0.16%Fe2O3, 0.01%TiO2With 2.73% loss on ignition.
6. a kind of preparation method of the white jade stone polished brick of height as described in any one in Claims 1 to 5, its feature exists In:Comprise the following steps:
(1) preparation of mixed powder:By the raw material for matching the weigh raw material and high-white transparent material that are equipped with high temperature material, and respectively through Ball milling obtains slurry, then carries out spray drying acquisition high temperature powder and high-white transparent powder;By the high temperature powder and the height White transparent powder is (40~50) according to mass ratio after homogenizing is old:100 are mixed, and obtain mixed powder;
(2) mixed powder is burnt till into acquisition adobe by cloth, compressing and high temperature;
(3) by the adobe by surface polishing edging processing, you can obtain high white jade stone polished brick.
7. a kind of preparation method of high white jade stone polished brick according to claim 6, it is characterised in that:In step (1) The fineness of the ball milling is 250 mesh, tails over 0.9%;The proportion that the slurry is obtained after ball milling is 1.69, and flow velocity is 60m/s.
8. a kind of preparation method of high white jade stone polished brick according to claim 6, it is characterised in that:In step (1) The homogenizing of the high temperature powder and the high-white transparent powder is old be carried out in ageing tower it is old >=24 hours.
9. a kind of preparation method of high white jade stone polished brick according to claim 6, it is characterised in that:In step (2) The temperature burnt till is 1175~1190 DEG C.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892481A (en) * 2018-08-01 2018-11-27 广东博德精工建材有限公司 A kind of ecology stone and preparation method thereof
CN110963793A (en) * 2019-11-21 2020-04-07 佛山欧神诺陶瓷有限公司 Jade-imitating ceramic tile and preparation method thereof
CN113135734A (en) * 2021-04-28 2021-07-20 景德镇陶瓷大学 Colored glaze stoneware tile and preparation method thereof
CN115745582A (en) * 2022-09-29 2023-03-07 河源市东源鹰牌陶瓷有限公司 High-strength ivory ceramic tile and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1053983A2 (en) * 1999-05-19 2000-11-22 NGK Spark Plug Company Limited Translucent polycrystalline ceramic and method for making same
CN1927763A (en) * 2006-09-19 2007-03-14 关润启 High-white transparent material formulation and manufacture method of crystal full transparency polishing brick
CN101070240A (en) * 2006-05-11 2007-11-14 霍镰泉 Super-white polished brick
CN103708811A (en) * 2013-12-16 2014-04-09 广州锦盈新型材料有限公司 Polished tile, and preparation method and application thereof
CN105777089A (en) * 2016-04-01 2016-07-20 蒙娜丽莎集团股份有限公司 Light-permeable tile and preparation method thereof
EP3165989A2 (en) * 2015-10-13 2017-05-10 Ditter Plastic GmbH + Co. KG Functional element and method for producing same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1053983A2 (en) * 1999-05-19 2000-11-22 NGK Spark Plug Company Limited Translucent polycrystalline ceramic and method for making same
CN101070240A (en) * 2006-05-11 2007-11-14 霍镰泉 Super-white polished brick
CN1927763A (en) * 2006-09-19 2007-03-14 关润启 High-white transparent material formulation and manufacture method of crystal full transparency polishing brick
CN103708811A (en) * 2013-12-16 2014-04-09 广州锦盈新型材料有限公司 Polished tile, and preparation method and application thereof
EP3165989A2 (en) * 2015-10-13 2017-05-10 Ditter Plastic GmbH + Co. KG Functional element and method for producing same
CN105777089A (en) * 2016-04-01 2016-07-20 蒙娜丽莎集团股份有限公司 Light-permeable tile and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
胡俊等: ""建筑陶瓷放射性的原因分析、检测及对策"", 《中国陶瓷》 *
蔡飞虎等: "《陶瓷墙地砖生产技术》", 31 July 2011, 武汉理工大学出版社 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892481A (en) * 2018-08-01 2018-11-27 广东博德精工建材有限公司 A kind of ecology stone and preparation method thereof
CN108892481B (en) * 2018-08-01 2022-03-29 广东博德精工建材有限公司 Ecological stone and preparation method thereof
CN110963793A (en) * 2019-11-21 2020-04-07 佛山欧神诺陶瓷有限公司 Jade-imitating ceramic tile and preparation method thereof
CN110963793B (en) * 2019-11-21 2022-02-11 佛山欧神诺陶瓷有限公司 Jade-imitating ceramic tile and preparation method thereof
CN113135734A (en) * 2021-04-28 2021-07-20 景德镇陶瓷大学 Colored glaze stoneware tile and preparation method thereof
CN115745582A (en) * 2022-09-29 2023-03-07 河源市东源鹰牌陶瓷有限公司 High-strength ivory ceramic tile and preparation method thereof

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