CN107236483A - A kind of mesh material with transfer belt and preparation method thereof - Google Patents

A kind of mesh material with transfer belt and preparation method thereof Download PDF

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Publication number
CN107236483A
CN107236483A CN201710325131.0A CN201710325131A CN107236483A CN 107236483 A CN107236483 A CN 107236483A CN 201710325131 A CN201710325131 A CN 201710325131A CN 107236483 A CN107236483 A CN 107236483A
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China
Prior art keywords
transfer
mesh
microcrystalline cellulose
base material
film
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Granted
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CN201710325131.0A
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Chinese (zh)
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CN107236483B (en
Inventor
何建雄
杨博
王良
王一良
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Dongguan Xionglin New Materials Technology Co Ltd
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Dongguan Xionglin New Materials Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J101/00—Adhesives based on cellulose, modified cellulose, or cellulose derivatives
    • C09J101/02—Cellulose; Modified cellulose
    • C09J101/04—Oxycellulose; Hydrocellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028—Net structure, e.g. spaced apart filaments bonded at the crossing points
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • B32B9/025—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch comprising leather
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0358—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D155/00—Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
    • C09D155/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285—Polyurethanes; Polyurea; Polyguanides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/02—Dye diffusion thermal transfer printing (D2T2)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Printing Methods (AREA)

Abstract

The present invention relates to a kind of mesh material with transfer belt and preparation method thereof, the mesh material with transfer belt includes mesh base material and Transfer ribbon, the Transfer ribbon is fit together with the mesh base material by binding agent, and the binding agent includes microcrystalline cellulose and polyurethane fiber.Preparation method includes：(1) microcrystalline cellulose is dissolved by heating in ionic liquid, polyurethane fiber is scattered wherein, obtain binding agent；(2) heat transfer film is obtained after printing release ink and calligraphy and painting pattern, wink-dry on transfer membrane carrier；(3) transfer：By adhesive-coated in the printing face of the mesh base material, heat transfer film and mesh base material are overlapped, produced after being transferred more than once or twice.Figure layer and the cohesive force of mesh material reach more than 5.2N/mm, and more than 300 hours patterns of agitator treating do not drop and seminess in washing machine, at 100 DEG C water boil more than 15 hours figure layers remain in that it is intact.

Description

A kind of mesh material with transfer belt and preparation method thereof
Technical field
The present invention relates to printing technology field, more particularly to a kind of mesh material with transfer belt and preparation method thereof.
Background technology
With the development of society, mesh material is as pressed from both sides screen cloth, with mesh leather, artificial fine, with holes artificial leather with holes etc. Using more and more, while to the cosmetic requirement of mesh material also more and more higher, in order to cater to consumer demand, it is necessary to A variety of colors or pattern are generated on mesh material.
It is flexible that mesh material has permeable breathable and had, due to the specific form on mesh material, using normal The direct color application to printed of rule is extremely difficult to apparent visual effect, using traditional approach it is difficult to be printed on mesh material surface The higher pattern of brush quality, present most common method is former wire mark brush, but the outline of pattern is not clear enough, and is needed To wash repeatedly and stoving process, complex process and production cost is also very high.
Thermal transfer is that copperplate is made after design is good, then pattern point color is carved in copperplate by electric carving machinery On, then copperplate taken on printing machinery pattern printing in PET film, pattern is transferred to by thermal transfer machinery by product On, this, can be on the media such as cloth, film, envelope, common paper using thermal transfer to holding as medium is not required particularly Realize clear printing.
The tape base of Transfer ribbon is biaxial stretching polyester (BOPET) film, and BOPET film has intensity high, rigid good, saturating It is bright, the features such as glossiness is high, odorless, tasteless, colourless, nontoxic, prominent obdurability；Its tensile strength is PC films, the 3 of nylon membrane Times, impact strength is 3~5 times of BOPP film, there is fabulous wearability, folding resistance, pinhole resistance and tear resistance etc., and heat is received Contracting is minimum, 1.25% is only shunk after 15 minutes at 120 DEG C, with good antistatic behaviour.In the prior art, due to The problem of BOPET base materials, when often appearing in printing, layer of ink is attached on base material, and as a result printing effect is poor, is relatively obscured.
CN102145605A discloses a kind of PET heat transfer films typography, comprises the following steps：(1) intaglio process is used Dataller's skill, is first printed on PET polyester films using release ink, is then printed calligraphy and painting pattern with polyurethane ink, is finally printed Brush water-base cement；(2) heat transfer film for obtaining step (1) is laid on workpiece down by calligraphy and painting pattern is printed on, with 120 ~180 DEG C of 1~2kg/cm of silica gel roller pressure2Impressing, calligraphy and painting pattern is transferred on workpiece.But the table pair with mesh material out-of-flatness The cohesive force of face and its instable retractable property, volatile macromolecular adhesive and mesh material is not good, it is difficult to will figure Case is firmly in bonding and mesh material.
The content of the invention
In view of problems of the prior art, an object of the present invention is to develop a kind of net for having and consolidating figure layer Porous materials.
For up to this purpose, the present invention uses following technical scheme：
In a first aspect, the present invention provides a kind of mesh material with transfer belt, including mesh base material and Transfer ribbon, institute Transfer ribbon is stated to fit together by binding agent with the mesh base material, wherein, the binding agent comprising microcrystalline cellulose and Polyurethane fiber.
The mesh base material includes any one in grid cloth, leather with holes, fiber with holes, mesh plastics and leather with holes Kind or at least two combination.
Preferably, the mass ratio of the polyurethane fiber and the microcrystalline cellulose is (13~30):100, such as 13: 100、15:100、18:100、20:100、23:100、25:100、28:100 or 30:100 etc., preferably (15~18):100.
Mesh material of the present invention preferably includes mesh base material, Transfer ribbon and the protective layer fitted successively；
Preferably, the protective layer is Transparent color.
Preferably, combination of the material of the protective layer including any one in TPU, PC and ABS or at least two, It is wherein typical but non-limiting to be combined as：TPU and PC combination, PC and ABS combination, TPU and ABS combination.
Second aspect, the present invention provides a kind of preparation method of the mesh material with transfer belt as described in relation to the first aspect, Comprise the following steps：
(1) binding agent is prepared：Microcrystalline cellulose is dissolved by heating in ionic liquid, microcrystalline cellulose solution is obtained, will be poly- Urethane fiber is scattered in the microcrystalline cellulose solution, obtains binding agent；
(2) heat transfer film is prepared：Release ink is printed on transfer membrane carrier, then calligraphy and painting pattern is printed with ink, afterwards Wink-dry, obtains heat transfer film；
(3) transfer：By adhesive-coated obtained by step (1) in the printing face of the mesh base material, by heat obtained by step (2) Transfer film is overlapped with mesh base material, wherein, the one side of calligraphy and painting pattern and holding for the mesh base material are printed in the heat transfer film Print face is fitted, and is produced after being transferred more than once or twice.
The mass ratio of step (1) the of the present invention microcrystalline cellulose and the ionic liquid is preferably (2~3):100,2: 100、2.1:100、2.3:100、2.4:100、2.5:100、2.6:100、2.7:100、2.9:100 or 3:100 etc., more preferably (2.3~2.6):100.
Preferably, a diameter of 20~40nm of the microcrystalline cellulose, such as 20nm, 22nm, 25nm, 28nm, 30nm, 31nm, 32nm, 35nm, 38nm or 40nm etc., preferably 25~32nm.
Preferably, the length of the microcrystalline cellulose be 70~100nm, such as 70nm, 72nm, 73nm, 75nm, 77nm, 78nm, 79nm, 80nm, 82nm, 85nm, 88nm, 90nm, 94nm, 96nm or 100nm etc., preferably 75~80nm.
Preferably, the temperature of step (1) described heating be 80~100 DEG C, such as 80 DEG C, 82 DEG C, 85 DEG C, 88 DEG C, 90 DEG C, 92 DEG C, 95 DEG C, 99 DEG C or 100 DEG C etc., preferably 90~100 DEG C；The time of heating be 10~30min, such as 10min, 15min, 18min, 20min, 22min, 25min, 26min, 27min, 28min or 30min etc., preferably 20~27min.
Preferably, a diameter of 50~80nm of the polyurethane fiber, such as 50nm, 55nm, 60nm, 65nm, 66nm, 67nm, 68nm, 69nm, 70nm, 75nm or 80nm etc., preferably 65~70nm；
Preferably, the length of the polyurethane fiber be 500~800nm, such as 500nm, 550nm, 600nm, 650nm, 660nm, 670nm, 680nm, 690nm, 700nm, 750nm or 800nm etc., preferably such as 600~700nm.
Including for step (2) the transfer membrane carrier of the present invention is any in PET film, modified PET film and class PET functional membranes It is a kind of or at least two combination, wherein, it is typical but non-limiting to be combined as：The combination of PET film and class PET functional membranes, change The combination of the combination of property PET film and class PET functional membranes, PET film and modified PET film.
Preferably, step (2) described ink includes polyurethane ink.When needing to attach PU on mesh material, transfer belt In when containing PU, the binding agent on mesh material surface of the present invention also easily with PU formation hydrogen bonds, can PU and mesh material it Between form firm cohesive force.This point can be applied in the high technique of the appearance requirement such as wire side footwear.
Preferably, the time of step (2) described wink-dry be 7~15s, such as 7s, 8s, 9s, 10s, 11s, 12s, 13s, 14s or 15s etc., preferably 8~12s.
Preferably, the temperature of step (2) described wink-dry be 20~100 DEG C, such as 20 DEG C, 25 DEG C, 30 DEG C, 40 DEG C, 50 DEG C, 60 DEG C, 70 DEG C, 80 DEG C, 90 DEG C or 100 DEG C etc., preferably 50~80 DEG C.
Step (3) transfer of the present invention includes thermal transfer and/or vacuum forming transfer, preferably thermal transfer and vacuum forming Transfer is alternately.
Preferably, the thermal transfer is specifically included：After step (3) heat transfer film and mesh base material are overlapped again with heat Medium is overlapped, wherein, the transfer membrane carrier one side of the heat transfer film is directly contacted with the thermal medium, is carried out while heating Vacuumize.
Preferably, the thermal medium includes heating grinding tool.
Preferably, the temperature of the heating be 70~250 DEG C, such as 70 DEG C, 80 DEG C, 100 DEG C, 120 DEG C, 150 DEG C, 160 DEG C, 180 DEG C, 190 DEG C, 200 DEG C, 220 DEG C or 250 DEG C etc., preferably 150~200 DEG C.
Preferably, the time of the heating be 1~300s, such as 1s, 10s, 50s, 80s, 90s, 100s, 120s, 140s, 150s, 180s, 200s, 240s, 280s or 300s etc., preferably 90~150s.
The vacuum forming transfer is specifically included：After heat transfer film obtained by step (2) and mesh base material are overlapped, it is placed in close Close in system, vacuumized, produced.
As currently preferred technical scheme, a kind of preparation method of the mesh material with transfer belt includes following step Suddenly：
(1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is (2~3):100 by a diameter of 20 ~40nm, length heat 10~30min at 80~100 DEG C for the 70~100nm microcrystalline cellulose and are dissolved in the ion In liquid, microcrystalline cellulose solution is obtained, a diameter of 50~80nm, length are scattered in institute for 500~800nm polyurethane fiber State in microcrystalline cellulose solution, obtain binding agent；
(2) heat transfer film is prepared：Release ink is printed on transfer membrane carrier, then is drawn with polyurethane ink printed words Case, 20~100 DEG C of dry 7~15s, obtain heat transfer film afterwards；
(3) transfer：By adhesive-coated obtained by step (1) in the printing face of the mesh base material, by heat obtained by step (2) Transfer film is overlapped with mesh base material, wherein, the one side of calligraphy and painting pattern and holding for the mesh base material are printed in the heat transfer film Print face is fitted, and is produced after being transferred more than once or twice.
The third aspect, the present invention provides the mesh material with transfer belt as described in relation to the first aspect and printed in PU printing and dyeing, TPU Application in dye, PVC printing and dyeing and leather printing and dyeing.
Compared with prior art, the present invention at least has the advantages that：
(1) hydrogen bond is formed between polyurethane fiber and microcrystalline cellulose, the cohesive force and weatherability of binding agent is improved, this Figure layer and the cohesive force of mesh material reach more than 5.2N/mm in the invention mesh material with transfer belt, in washing machine More than 300 hours patterns of agitator treating do not drop and seminess, and water boils more than 15 hours figure layers and remained in that at 100 DEG C It is good.
(2) binding agent of the fibre structure in preparation process in the present invention can produce good contact with mesh material, Improve mutual cohesive force, on the other hand, gas permeability also due to liquid phase solidification after macromolecule adhesive.
Embodiment
The present invention is described in more detail below.But following examples is only the simple example of the present invention, not generation Table or limitation the scope of the present invention, protection scope of the present invention are defined by claims.
Embodiment 1
Mesh material A with transfer belt, including grid cloth, Transfer ribbon and the transparent TPU protective layer fitted successively.Its In, the binding agent is 13 comprising mass ratio:100 microcrystalline cellulose and polyurethane fiber.
The preparation of mesh material A with transfer belt：
1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is 2:100 by a diameter of 20nm, length It is dissolved in for the 70nm microcrystalline cellulose in 80 DEG C of heating 10min in the ionic liquid, obtains microcrystalline cellulose solution, will A diameter of 50nm, length are scattered in the microcrystalline cellulose solution for 500nm polyurethane fiber, obtain binding agent；
2) heat transfer film is prepared：Release ink is printed on a pet film, then prints calligraphy and painting pattern with polyurethane ink, afterwards 20 DEG C of dry 15s, obtain heat transfer film；
3) transfer：By step 1) gained adhesive-coated in the printing face of grid cloth, by step 2) gained heat transfer film with Grid cloth is overlapped, wherein, the one side that calligraphy and painting pattern is printed in the heat transfer film is fitted with the printing face of the mesh base material, heat The PET film one side of transfer film is directly contacted with heating grinding tool, is vacuumized while 70 DEG C of heating 300s；So transfer once Produce.
Figure layer and the cohesive force of mesh material reach 5.2N/mm in mesh material A with transfer belt, are stirred in washing machine Washing 303 hours patterns do not drop and seminess, at 100 DEG C water boil 16 hours figure layers remain in that it is intact.
Embodiment 2
Mesh material B with transfer belt, including leather with holes, Transfer ribbon and the transparent PC protective layers fitted successively. Wherein, the binding agent is 30 comprising mass ratio:100 microcrystalline cellulose and polyurethane fiber.
The preparation of mesh material B with transfer belt：
1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is 3:100 by a diameter of 40nm, length It is dissolved in for the 100nm microcrystalline cellulose in 100 DEG C of heating 10min in the ionic liquid, obtains microcrystalline cellulose solution, A diameter of 80nm, length are scattered in the microcrystalline cellulose solution for 800nm polyurethane fiber, binding agent is obtained；
2) heat transfer film is prepared：Release ink is printed on modified PET film, then calligraphy and painting pattern is printed with polyurethane ink, 100 DEG C of dry 7s, obtain heat transfer film afterwards；
3) transfer：By step 1) gained adhesive-coated is in the printing face of leather with holes, by step 2) gained heat transfer film Overlapped with leather with holes, wherein, the one side of calligraphy and painting pattern is printed in the heat transfer film and is pasted with the printing face of the mesh base material Close, the modified PET film one side of heat transfer film is directly contacted with heating grinding tool, is vacuumized while 250 DEG C of heating 1s；So Transfer is produced afterwards twice.
Figure layer and the cohesive force of mesh material reach 5.4N/mm in mesh material B with transfer belt, are stirred in washing machine Washing 304 hours patterns do not drop and seminess, at 100 DEG C water boil 18 hours figure layers remain in that it is intact.
Embodiment 3
Mesh material C with transfer belt, including fiber with holes, Transfer ribbon and the transparent ABS protective layer fitted successively. Wherein, the binding agent is 15 comprising mass ratio:100 microcrystalline cellulose and polyurethane fiber.
The preparation of mesh material C with transfer belt：
1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is 2.3:100 by a diameter of 25nm, length The microcrystalline cellulose spent for 75nm heats 27min at 90 DEG C and is dissolved in the ionic liquid, obtains microcrystalline cellulose solution, A diameter of 65nm, length are scattered in the microcrystalline cellulose solution for 600nm polyurethane fiber, binding agent is obtained；
2) heat transfer film is prepared：Release ink is printed on class PET functional membranes, then is drawn with polyurethane ink printed words Case, 50 DEG C of dry 12s, obtain heat transfer film afterwards；
3) transfer：By step 1) gained adhesive-coated is in the printing face of fiber with holes, by step 2) gained heat transfer film Overlapped with fiber with holes, wherein, the one side of calligraphy and painting pattern is printed in the heat transfer film and is pasted with the printing face of the mesh base material Close, the class PET functional membranes one side of heat transfer film is directly contacted with heating grinding tool, is vacuumized while 200 DEG C of heating 90s； So transfer is once produced afterwards.
Figure layer and the cohesive force of mesh material reach 6.3N/mm in mesh material C with transfer belt, are stirred in washing machine Washing 306 hours patterns do not drop and seminess, at 100 DEG C water boil 22 hours figure layers remain in that it is intact.
Embodiment 4
Mesh material D with transfer belt, including fit successively mesh base material leather with holes, Transfer ribbon and transparent TPU protective layers.Wherein, the binding agent is 18 comprising mass ratio:100 microcrystalline cellulose and polyurethane fiber.
The preparation of mesh material D with transfer belt：
1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is 2.6:100 by a diameter of 32nm, length The microcrystalline cellulose spent for 80nm heats 20min at 100 DEG C and is dissolved in the ionic liquid, obtains microcrystalline cellulose molten Liquid, a diameter of 70nm, length are scattered in the microcrystalline cellulose solution for 700nm polyurethane fiber, binding agent is obtained；
2) heat transfer film is prepared：Release ink is printed on a pet film, then prints calligraphy and painting pattern with polyurethane ink, afterwards 80 DEG C of dry 8s, obtain heat transfer film；
3) transfer：By step 1) gained adhesive-coated is in the printing face of leather with holes, by step 2) gained heat transfer film Overlapped with leather with holes, wherein, the one side of calligraphy and painting pattern is printed in the heat transfer film and is pasted with the printing face of the mesh base material Close, be placed in closed system, vacuumized, produced.
Figure layer and the cohesive force of mesh material reach 5.8N/mm in mesh material D with transfer belt, are stirred in washing machine Washing 309 hours patterns do not drop and seminess, at 100 DEG C water boil 23 hours figure layers remain in that it is intact.
Embodiment 5
Mesh material E with transfer belt, including mesh base material leather with holes, Transfer ribbon and the transparent PC fitted successively Protective layer.Wherein, the binding agent is 17 comprising mass ratio:100 microcrystalline cellulose and polyurethane fiber.
The preparation of mesh material E with transfer belt：
1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is 2.5:100 by a diameter of 28nm, length The microcrystalline cellulose spent for 78nm heats 24min at 95 DEG C and is dissolved in the ionic liquid, obtains microcrystalline cellulose solution, A diameter of 68nm, length are scattered in the microcrystalline cellulose solution for 650nm polyurethane fiber, binding agent is obtained；
2) heat transfer film is prepared：Release ink is printed on a pet film, then prints calligraphy and painting pattern with polyurethane ink, afterwards 70 DEG C of dry 10s, obtain heat transfer film；
3) transfer：By step 1) gained adhesive-coated is in the printing face of leather with holes, by step 2) gained heat transfer film Overlapped with leather with holes, wherein, the one side of calligraphy and painting pattern is printed in the heat transfer film and is pasted with the printing face of the mesh base material Close, the PET film one side of heat transfer film is directly contacted with heating grinding tool, is vacuumized while 180 DEG C of heating 120s；So turn Produced after printing three times.
Figure layer and the cohesive force of mesh material reach 6.5N/mm in mesh material E with transfer belt, are stirred in washing machine Washing 320 hours patterns do not drop and seminess, at 100 DEG C water boil 32 hours figure layers remain in that it is intact.
Comparative example 1
With differing only in for embodiment 5：Save no-bonder.
Figure layer and the cohesive force of mesh material are 2.7N/mm in mesh material E with transfer belt, are stirred in washing machine Then there is seminess in 5 hours patterns of washing, and there being figure layer after 10 hours substantially drops phenomenon, and water, which boils 2 hours figure layers, at 100 DEG C has Substantially drop phenomenon.
Comparative example 2
With differing only in for embodiment 5：With the binding agent in water-base cement alternative embodiment 5.
Figure layer and the cohesive force of mesh material are 3.4N/mm in mesh material E with transfer belt, are stirred in washing machine Then there is seminess in 20 hours patterns of washing, and figure layer has water at the phenomenon that substantially drops, 100 DEG C to boil 12 hours figure layers after 28 hours There is the phenomenon that substantially drops.
Applicant states that the present invention illustrates the detailed construction feature of the present invention by above-described embodiment, but the present invention is simultaneously Above-mentioned detailed construction feature is not limited to, that is, does not mean that the present invention has to rely on above-mentioned detailed construction feature and could implemented.Institute Belong to those skilled in the art it will be clearly understood that any improvement in the present invention, to the equivalence replacement of part selected by the present invention And increase, the selection of concrete mode of accessory etc., within the scope of all falling within protection scope of the present invention and being open.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should equally be considered as content disclosed in this invention.

Claims (10)

1. a kind of mesh material with transfer belt, it is characterised in that including mesh base material and Transfer ribbon, the Transfer ribbon Fit together with the mesh base material by binding agent, wherein, the binding agent includes microcrystalline cellulose and polyurethane fiber.
2. as claimed in claim 1 carry transfer belt mesh material, it is characterised in that the mesh base material include grid cloth, In leather with holes, fiber with holes, mesh plastics and leather with holes any one or at least two combination；
Preferably, the mass ratio of the polyurethane fiber and the microcrystalline cellulose is (13~30):100, preferably (15~18): 100。
3. the mesh material of transfer belt is carried as claimed in claim 1 or 2, it is characterised in that the mesh material is included successively Mesh base material, Transfer ribbon and the protective layer of laminating；
Preferably, the protective layer is Transparent color；
Preferably, combination of the material of the protective layer including any one in TPU, PC and ABS or at least two.
4. a kind of preparation method of the mesh material with transfer belt as described in any one of claims 1 to 3, it is characterised in that Comprise the following steps：
(1) binding agent is prepared：Microcrystalline cellulose is dissolved by heating in ionic liquid, microcrystalline cellulose solution is obtained, by polyurethane Fiber is scattered in the microcrystalline cellulose solution, obtains binding agent；
(2) heat transfer film is prepared：Release ink is printed on transfer membrane carrier, then calligraphy and painting pattern is printed with ink, afterwards moment Dry, obtain heat transfer film；
(3) transfer：By adhesive-coated obtained by step (1) in the printing face of the mesh base material, by thermal transfer obtained by step (2) Film is overlapped with mesh base material, wherein, one side and the printing face of the mesh base material of calligraphy and painting pattern are printed in the heat transfer film Laminating, obtains the mesh material for carrying transfer belt after being transferred more than once or twice.
5. preparation method as claimed in claim 4, it is characterised in that step (1) microcrystalline cellulose and the ionic liquid The mass ratio of body is (2~3):100, preferably (2.3~2.6):100；
Preferably, a diameter of 20~40nm of the microcrystalline cellulose, preferably 25~32nm；
Preferably, the length of the microcrystalline cellulose is 70~100nm, preferably 75~80nm；
Preferably, the temperature of step (1) described heating is 80~100 DEG C, preferably 90~100 DEG C；The time of heating be 10~ 30min, preferably 20~27min；
Preferably, a diameter of 50~80nm of the polyurethane fiber, preferably 65~70nm；
Preferably, the length of the polyurethane fiber is 500~800nm, preferably 600~700nm.
6. the preparation method as described in claim 4 or 5, it is characterised in that step (2) the transfer membrane carrier includes PET In film, modified PET film and class PET functional membranes any one or at least two combination；
Preferably, step (2) described ink includes polyurethane ink；
Preferably, the time of step (2) described wink-dry is 7~15s, preferably 8~12s；
Preferably, the temperature of step (2) described wink-dry is 20~100 DEG C, preferably 50~80 DEG C.
7. the preparation method as described in any one of claim 4~6, it is characterised in that step (3) transfer includes thermal transfer And/or vacuum forming transfer, preferably thermal transfer and vacuum forming transfer are alternately；
Preferably, the thermal transfer is specifically included：After heat transfer film obtained by step (2) and mesh base material are overlapped again with thermal medium Overlapping, wherein, the transfer membrane carrier one side of the heat transfer film is directly contacted with the thermal medium, carries out taking out true while heating It is empty；
Preferably, the thermal medium includes heating grinding tool；
Preferably, the temperature of the heating is 70~250 DEG C, preferably 150~200 DEG C；
Preferably, the time of the heating is 1~300s, preferably 90~150s.
8. preparation method as claimed in claim 7, it is characterised in that the vacuum forming transfer is specifically included：By step (2) Gained heat transfer film is with after mesh base material overlapping, being placed in closed system, being vacuumized, produced.
9. the preparation method as described in any one of claim 4~8, it is characterised in that comprise the following steps：
(1) binding agent is prepared：Mass ratio according to microcrystalline cellulose and ionic liquid is (2~3):100 by a diameter of 20~ 40nm, length heat 10~30min at 80~100 DEG C for the 70~100nm microcrystalline cellulose and are dissolved in the ionic liquid In body, microcrystalline cellulose solution is obtained, a diameter of 50~80nm, length are scattered in for 500~800nm polyurethane fiber described In microcrystalline cellulose solution, binding agent is obtained；
(2) heat transfer film is prepared：Release ink is printed on transfer membrane carrier, then calligraphy and painting pattern is printed with polyurethane ink, it 20~100 DEG C of dry 7~15s, obtain heat transfer film afterwards；
(3) transfer：By adhesive-coated obtained by step (1) in the printing face of the mesh base material, by thermal transfer obtained by step (2) Film is overlapped with mesh base material, wherein, one side and the printing face of the mesh base material of calligraphy and painting pattern are printed in the heat transfer film Laminating, is produced after being transferred more than once or twice.
10. as described in any one of claims 1 to 3 with transfer belt mesh material PU printing and dyeing, TPU printing and dyeing, PVC printing and dyeing, Application in being printed and dyed with leather.
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