CN107236248A - A kind of polyether-ether-ketone modified composite material and its manufacture method - Google Patents
A kind of polyether-ether-ketone modified composite material and its manufacture method Download PDFInfo
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- CN107236248A CN107236248A CN201710609743.2A CN201710609743A CN107236248A CN 107236248 A CN107236248 A CN 107236248A CN 201710609743 A CN201710609743 A CN 201710609743A CN 107236248 A CN107236248 A CN 107236248A
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- ether
- polyether
- ketone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The invention discloses a kind of polyether-ether-ketone modified composite material, belong to polymeric material field, include the component of following mass parts：100~120 parts of polyether-ether-ketone powder；5~35 parts of carborundum powder；5~25 parts of zirconia powder；0.1~3 part of lubricant；The melting viscosity of the polyether-ether-ketone powder is 100~650Pas.The invention discloses a kind of polyether-ether-ketone modified composite material and preparation method thereof.Polyether-ether-ketone modified composite material disclosed by the invention, it is modified by adding carborundum and zirconium oxide, the polyether-ether-ketone modified composite material prepared, coefficient of friction can at least reduce by 0.06, and tensile strength can at least improve 21MPa, compared to pure polyetheretherketonematerials materials, service life and temperature in use have lifting, and the out-of-service time can at least extend 148h, and temperature in use can improve 50 DEG C, maximum operation (service) temperature so have also been enlarged application field up to 310 DEG C while cost is reduced.
Description
Technical field
The present invention relates to polymeric material field, more particularly to a kind of polyether-ether-ketone modified composite material and its system
Make method.
Background technology
Polyether-ether-ketone is a kind of thermoplastic engineering plastic of all aromatic hemicrystalline, due to containing rigidity on macromolecular chain
Phenyl ring, submissive ehter bond and the carboxyl for improving intermolecular force, compound with regular structure, thus with high-fire resistance, high intensity, height
The excellent combination property such as modulus, high-fracture toughness, can be in 250 DEG C of long-term uses.
But, pure polyetheretherketonematerials materials cost is higher, and product temperature in use is relatively low, and heat-resistant, wear-resistant intensity does not reach portion
Divide the standard requirement of product, application is narrow.
The content of the invention
In order to overcome the defect of prior art, the invention discloses a kind of modification of the high intensity polyether-ether-ketone of heat resistant and wear resistant
Composite, improves the heat-resisting quantity wearability and tensile strength of polyether-ether-ketone composite material, compared to pure polyether-ether-ketone material
Material, temperature in use and service life have lifting, so have also been enlarged application field while cost is reduced.
For up to this purpose, the present invention uses following technical scheme：
The invention provides a kind of polyether-ether-ketone modified composite material, include the component of following mass parts：
The melting viscosity of the polyether-ether-ketone powder is 100~650Pas.
Also include in the present invention preferably in technical scheme, in the component of the modified composite material mass parts be 0.1~
0.5 part of antioxidant；The antioxidant is primary antioxidant four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythrite
Ester, auxiliary anti-oxidant N, N'- double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionyl] hydrazine English, 2,8- di-t-butyl -4- methylbenzenes
One or both of phenol；The mass ratio of the primary antioxidant and auxiliary anti-oxidant is 2:1.
It is 1~2 part also to include mass parts in the present invention preferably technical scheme, in the component of the modified composite material
Coupling agent；The coupling agent is sulfonated polyether-ether-ketone；The sulfonation degree of the sulfonated polyether-ether-ketone is 30%~50%.
In the present invention preferably technical scheme, the carborundum powder average grain diameter is less than 10 μm.
In the present invention preferably technical scheme, below 10 μm of the average grain diameter of the zirconia powder.
In the present invention preferably technical scheme, the lubricant is the polysiloxanes that molecular weight is not less than 5000.
In the present invention preferably technical scheme, the polyether-ether-ketone modified composite material preparation method is real as follows
Apply：
§ 1 is dried：Each raw material powder is respectively put into moisture eliminating drying box in 160 DEG C of dry 4h；
§ 2 is mixed：Dried each raw material powder is sequentially placed into high mixer, mixed on low speed is after 1~2 minute, at 105 DEG C
Mixed at high speed 15~25 minutes, blowing, obtain mixed ingredients at a temperature of~115 DEG C；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.
In the present invention preferably technical scheme, in the § 1 dryings, moisture eliminating drying box is constant-temperature vacuum removal moisture drying
Case.
In the present invention preferably technical scheme, the double screw extruder, screw compression ratio is 2.5:1~3.5:1, spiral shell
Bar rotating speed is 20~60r/min.
In the present invention preferably technical scheme, the double screw extruder includes six heating zones, its Zhong-1 block temperature
Be 315 DEG C~335 DEG C for 300 DEG C~320 DEG C, two area's temperature, three area's temperature be 335 DEG C~355 DEG C, four area's temperature be 355 DEG C
~375 DEG C, five area's temperature be 370 DEG C~385 DEG C, six area's temperature be 375 DEG C~385 DEG C.
Beneficial effects of the present invention are：
The polyether-ether-ketone modified composite material that the present invention is provided, is modified by adding carborundum and zirconium oxide, is prepared
Go out a kind of high intensity polyether-ether-ketone modified composite material of heat resistant and wear resistant, improve the heat-proof aging of polyether-ether-ketone composite material
Performance and tensile strength.
The polyether-ether-ketone modified composite material that the present invention is provided, compared to pure polyetheretherketonematerials materials, temperature in use and makes
There is lifting with the life-span, the out-of-service time can at least extend 148h, and temperature in use can improve 50 DEG C, and maximum operation (service) temperature is up to 310
DEG C, coefficient of friction can at least reduce by 0.06, and tensile strength can at least improve 21MPa, so also expand while cost is reduced
Application field.
Embodiment
Technical scheme is further illustrated with reference to embodiment.
The polyether-ether-ketone modified composite material of embodiment one, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 100Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment one：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder and the lubricant polysiloxanes are sequentially placed into high mixer, first mixed on low speed 1 minute, then at a temperature of 105 DEG C
Mixed at high speed blowing after 15 minutes, obtains mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 2.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 315
DEG C, two area's temperature be 328 DEG C, three area's temperature be 338 DEG C, four area's temperature be 355 DEG C, five area's temperature be 370 DEG C, six area's temperature be
380 DEG C, screw speed is 30r/min.
The polyether-ether-ketone modified composite material prepared using the formula of embodiment one can be used for manufacture printer to separate
Pawl.
The polyether-ether-ketone modified composite material of embodiment two, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 605Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment two：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder and the lubricant polysiloxanes are sequentially placed into high mixer, first mixed on low speed 1 minute, then at a temperature of 115 DEG C
Mixed at high speed blowing after 20 minutes, obtains mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 3.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 320
DEG C, two area's temperature be 335 DEG C, three area's temperature be 345 DEG C, four area's temperature be 365 DEG C, five area's temperature be 375 DEG C, six area's temperature be
385 DEG C, screw speed is 35r/min.
The polyether-ether-ketone modified composite material prepared using the formula of embodiment two can be used for manufacture sealing gasket.
The polyether-ether-ketone modified composite material of embodiment three, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 300Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment three：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder and the lubricant polysiloxanes are sequentially placed into high mixer, first mixed on low speed 1 minute, then at a temperature of 110 DEG C
Mixed at high speed blowing after 15 minutes, obtains mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 3:1, the melt extruder includes six heating zones, its Zhong-1 block temperature is 320 DEG C,
Two area's temperature are 335 DEG C, three area's temperature are 348 DEG C, four area's temperature are 365 DEG C, five area's temperature are 378 DEG C, six area's temperature are 385
DEG C, screw speed is 40r/min.
The polyether-ether-ketone modified composite material prepared using the formula of embodiment three can be used for manufacture axle sleeve.Embodiment
Four polyether-ether-ketone modified composite materials, include the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 650Pas.
The preparation method of example IV polyether-ether-ketone modified composite material：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes and the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionyl] the hydrazine English of auxiliary anti-oxidant N, N'-, mass ratio is 2:
1) it is sequentially placed into high mixer, first mixed on low speed 2 minutes, then mixed at high speed blowing after 25 minutes at a temperature of 115 DEG C, is obtained
To mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 3.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 320
DEG C, two area's temperature be 335 DEG C, three area's temperature be 348 DEG C, four area's temperature be 365 DEG C, five area's temperature be 378 DEG C, six area's temperature be
385 DEG C, screw speed is 60r/min.
The polyether-ether-ketone modified composite material of embodiment five, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 225Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment five：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes and the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, auxiliary anti-oxidant 2,8- di-tert-butyl-4-methy phenols, mass ratio is 2:1) it is sequentially placed into high mixer, first
Mixed on low speed 1 minute, then mixed at high speed blowing after 15 minutes at a temperature of 105 DEG C, obtains mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 2.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 300
DEG C, two area's temperature be 315 DEG C, three area's temperature be 335 DEG C, four area's temperature be 355 DEG C, five area's temperature be 370 DEG C, six area's temperature be
375 DEG C, screw speed is 20r/min.
The polyether-ether-ketone modified composite material of embodiment six, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 300Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment six：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes and the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionyl] the hydrazine English of auxiliary anti-oxidant N, N'- and the uncle of 2,8- bis-
Butyl -4- methylphenols, mass ratio is 4:1:1) it is sequentially placed into high mixer, first mixed on low speed 1.5 minutes, then at 110 DEG C
At a temperature of mixed at high speed blowing after 15 minutes, obtain mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 2.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 315
DEG C, two area's temperature be 332 DEG C, three area's temperature be 355 DEG C, four area's temperature be 365 DEG C, five area's temperature be 370 DEG C, six area's temperature be
385 DEG C, screw speed is 40r/min.
The polyether-ether-ketone modified composite material prepared using the formula of embodiment three can be used for manufacture axle sleeve.Embodiment
Seven polyether-ether-ketone modified composite materials, include the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 250Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment seven：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes, the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionyl] the hydrazine English of auxiliary anti-oxidant N, N'-, mass ratio is 2:
1) it is sequentially placed into the coupling agent sulfonated polyether-ether-ketone (sulfonation degree 50%) in high mixer, first mixed on low speed 2 minutes, Ran Hou
Mixed at high speed blowing after 25 minutes, obtains mixed ingredients at a temperature of 115 DEG C；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 3.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 320
DEG C, two area's temperature be 336 DEG C, three area's temperature be 348 DEG C, four area's temperature be 365 DEG C, five area's temperature be 378 DEG C, six area's temperature be
385 DEG C, screw speed is 40r/min.
The polyether-ether-ketone modified composite material of embodiment eight, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 400Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment eight：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes, the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, auxiliary anti-oxidant 2,8- di-tert-butyl-4-methy phenols, mass ratio is 2:1) gather with the coupling agent sulfonation
Ether ether ketone (sulfonation degree 40%) is sequentially placed into high mixer, first mixed on low speed 1 minute, is then mixed at a high speed at a temperature of 105 DEG C
Blowing after closing 15 minutes, obtains mixed ingredients；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 2.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 300
DEG C, two area's temperature be 326 DEG C, three area's temperature be 348 DEG C, four area's temperature be 365 DEG C, five area's temperature be 370 DEG C, six area's temperature be
378 DEG C, screw speed is 30r/min.
The polyether-ether-ketone modified composite material of embodiment nine, includes the component of following mass parts：
The melting viscosity for measuring the polyether-ether-ketone powder at random is 400Pas.
The preparation method of the polyether-ether-ketone modified composite material of embodiment nine：
§ 1 is dried：The polyether-ether-ketone powder, the carborundum powder, the zirconia powder are respectively put into moisture eliminating drying box
In 160 DEG C of dry 4h；
§ 2 is mixed：By the dried polyether-ether-ketone powder, the dried carborundum powder, the dried oxidation
Zirconium powder, the lubricant polysiloxanes, the antioxidant ([β-(3,5- three-level butyl -4- hydroxy phenyls) third of primary antioxidant four
Acid] pentaerythritol ester, double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionyl] the hydrazine English of auxiliary anti-oxidant N, N'-, mass ratio is 2:
1) it is sequentially placed into the coupling agent sulfonated polyether-ether-ketone (sulfonation degree 30%) in high mixer, first mixed on low speed 2 minutes, Ran Hou
Mixed at high speed blowing after 25 minutes, obtains mixed ingredients at a temperature of 115 DEG C；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.It is described molten
Melt in extruder, screw compression ratio is 3.5:1, the melt extruder includes six heating zones, and its Zhong-1 block temperature is 320
DEG C, two area's temperature be 335 DEG C, three area's temperature be 348 DEG C, four area's temperature be 365 DEG C, five area's temperature be 378 DEG C, six area's temperature be
385 DEG C, screw speed is 40r/min.
In order to cost-effective, it is to avoid waste, polyether-ether-ketone powder of the present invention can be used alone melting viscosity 400 after tested
Polyether-ether-ketone in the range of~650Pas reclaims feed powder.
In order to obtain the polyether-ether-ketone composite material that melting extrusion performance is more excellent, the carborundum powder and zirconia powder added
Average grain diameter below 10 μm.
Addition antioxidant can improve the weatherability of modified polyetheretherketonefiber composite.
In order to improve the compatibility of carborundum and polyether-ether-ketone, and the reunion of carborundum is reduced, in the modification of the present invention
Coupling agent sulfonated polyether-ether-ketone can be added in polyether-ether-ketone composite material.
By add lubricant polysiloxanes improve dispersiveness in polyether-ether-ketone composite material of carborundum and zirconium oxide,
Improve in the processing characteristics of polyether-ether-ketone composite material, reduction composite processing to the abrasion of process equipment, improve composite wood
The glossiness of material, the lubricant polysiloxanes is the polysiloxanes that molecular weight is not less than 5000.
Polyether-ether-ketone composite material made from Example one to nine and pure polyether-ether-ketone powder carry out performance test respectively, survey
Examination project includes heat aging property, coefficient of friction and the tensile strength of these materials, and wherein heat aging property uses 310
DEG C baking oven, investigate the remnants rates of intensity after its same time and out-of-service time when intensity is less than 30%.Specific test result is such as
Following table：
Method of testing is tested using GB/T 7141 the heat ageing out-of-service time in upper table, and friction coefficient testing method makes
Tested with GB 10006-1988, tensile strength method of testing is tested using GB/T 1041.
As can be seen from the table, in the present invention the new purer polyether-ether-ketone powder of composite have more preferable heat resistance, it is wear-resisting
Property and tensile strength, reduce material cost, expand its application field.
The present invention is described with reference to the preferred embodiments, and those skilled in the art know, is not departing from the present invention's
In the case of spirit and scope, various changes or equivalence replacement can be carried out to these features and embodiment.The present invention is not by this
The limitation of specific embodiment disclosed in place, other embodiments fallen into claims hereof belong to protection of the present invention
Scope.
Claims (10)
1. a kind of polyether-ether-ketone modified composite material, it is characterised in that include the component of following mass parts：
The melting viscosity of the polyether-ether-ketone powder is 100~650Pas.
2. polyether-ether-ketone modified composite material according to claim 1, it is characterised in that：
Also include the antioxidant that mass parts are 0.1~0.5 part in the component of the modified composite material；
The antioxidant is primary antioxidant four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol ester, auxiliary antioxygen
One in agent N, N'- double [β-(3,5- di-tert-butyl-hydroxy phenyls) propionyl] hydrazine English, 2,8- di-tert-butyl-4-methy phenols
Plant or two kinds；
The mass ratio of the primary antioxidant and auxiliary anti-oxidant is 2:1.
3. polyether-ether-ketone modified composite material according to claim 2, it is characterised in that：
Also include the coupling agent that mass parts are 1~2 part in the component of the modified composite material；
The coupling agent is sulfonated polyether-ether-ketone；
The sulfonation degree of the sulfonated polyether-ether-ketone is 30%~50%.
4. polyether-ether-ketone modified composite material according to claim 3, it is characterised in that：
The carborundum powder average grain diameter is less than 10 μm.
5. polyether-ether-ketone modified composite material according to claim 4, it is characterised in that：
The average grain diameter of the zirconia powder is less than 10 μm.
6. polyether-ether-ketone modified composite material according to claim 5, it is characterised in that：
The lubricant is the polysiloxanes that molecular weight is not less than 5000.
7. a kind of preparation method of the polyether-ether-ketone modified composite material described in any one of claim 1 to 6, it is characterised in that
Implement as follows：
§ 1 is dried：Each raw material powder is respectively put into moisture eliminating drying box in 160 DEG C of dry 4h；
§ 2 is mixed：Dried each raw material powder is sequentially placed into high mixer, mixed on low speed is after 1~2 minute, 105 DEG C~115
Mixed at high speed 15~25 minutes, blowing, obtain mixed ingredients at a temperature of DEG C；
The extrusion moldings of § 3：By the mixed ingredients by double screw extruder, melting extrusion, cooling obtains product.
8. the preparation method of polyether-ether-ketone modified composite material according to claim 6, it is characterised in that：
In the § 1 dryings, moisture eliminating drying box is constant-temperature vacuum moisture eliminating drying box.
9. the preparation method of polyether-ether-ketone modified composite material according to claim 7, it is characterised in that：
The double screw extruder, screw compression ratio is 2.5:1~3.5:1, screw speed is 20~60r/min.
10. the preparation method of polyether-ether-ketone modified composite material according to claim 8, it is characterised in that：
The double screw extruder includes six heating zones, and its Zhong-1 block temperature is 300 DEG C~320 DEG C, two area's temperature are 315 DEG C
~335 DEG C, three area's temperature be 335 DEG C~355 DEG C, four area's temperature be 355 DEG C~375 DEG C, five area's temperature be 370 DEG C~385 DEG C,
Six area's temperature are 375 DEG C~385 DEG C.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108250670A (en) * | 2017-12-05 | 2018-07-06 | 宜宾天原集团股份有限公司 | A kind of multiphase composite strengthening polyether-ether-ketone wear-resistant material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134385A (en) * | 2011-05-05 | 2011-07-27 | 刘立文 | Calcium sulfate whisker-modified polyether-ether-ketone composite material and preparation process thereof |
| CN102757635A (en) * | 2011-04-27 | 2012-10-31 | 合肥杰事杰新材料股份有限公司 | Polyether ether ketone composite material and preparation method thereof |
| CN105492516A (en) * | 2013-03-22 | 2016-04-13 | 3M创新有限公司 | Friction-reducing polymer material with dry-running capability and mechanical end-face seal with dry-running capability |
| CN106883551A (en) * | 2017-03-24 | 2017-06-23 | 合肥羿振电力设备有限公司 | A kind of power equipment electromagnetic shielding material and preparation method thereof |
-
2017
- 2017-07-25 CN CN201710609743.2A patent/CN107236248A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757635A (en) * | 2011-04-27 | 2012-10-31 | 合肥杰事杰新材料股份有限公司 | Polyether ether ketone composite material and preparation method thereof |
| CN102134385A (en) * | 2011-05-05 | 2011-07-27 | 刘立文 | Calcium sulfate whisker-modified polyether-ether-ketone composite material and preparation process thereof |
| CN105492516A (en) * | 2013-03-22 | 2016-04-13 | 3M创新有限公司 | Friction-reducing polymer material with dry-running capability and mechanical end-face seal with dry-running capability |
| CN106883551A (en) * | 2017-03-24 | 2017-06-23 | 合肥羿振电力设备有限公司 | A kind of power equipment electromagnetic shielding material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108250670A (en) * | 2017-12-05 | 2018-07-06 | 宜宾天原集团股份有限公司 | A kind of multiphase composite strengthening polyether-ether-ketone wear-resistant material and preparation method thereof |
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