CN107236196A - A kind of engineering truck instrument seal - Google Patents

A kind of engineering truck instrument seal Download PDF

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Publication number
CN107236196A
CN107236196A CN201710334986.XA CN201710334986A CN107236196A CN 107236196 A CN107236196 A CN 107236196A CN 201710334986 A CN201710334986 A CN 201710334986A CN 107236196 A CN107236196 A CN 107236196A
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China
Prior art keywords
parts
mica
engineering truck
weight
mica compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201710334986.XA
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Chinese (zh)
Inventor
高凤谊
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Anhui Ruixin Automation Instrument Co Ltd
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Anhui Ruixin Automation Instrument Co Ltd
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Priority to CN201710334986.XA priority Critical patent/CN107236196A/en
Publication of CN107236196A publication Critical patent/CN107236196A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of engineering truck instrument seal, its raw material includes by weight:30 40 parts of chlorosulfonated polyethylene, 15 25 parts of methyl vinyl silicone rubber, 60 80 parts of ethylene propylene diene rubber, 46 parts of silane coupler, 50 70 parts of white carbon, 18 22 parts of nano diatomite, 12 18 parts of expanded perlite, 10 13 parts of multi-walled carbon nanotube, 60 80 parts of mica compound, 6 10 parts of stearic acid, 12 parts of epoxidized soybean oil, 24 parts of t-butyl perbenzoate, 12 parts of liquid coumarone indene resin, 24 parts of dibutyl phthalate, 1 1.5 parts of trioctyl phosphate, 24 parts of palm wax, 12 parts of DOTP, 6 12 parts of polyvinyl alcohol, 1.5 2.5 parts of antioxidant, 24 parts of vulcanizing system.Heat endurance of the present invention is fabulous, and ageing-resistant performance is excellent, and compactness and tensile strength are significantly improved, and damping effect is excellent.

Description

A kind of engineering truck instrument seal
Technical field
The present invention relates to instrument seal technical field, more particularly to a kind of engineering truck instrument seal.
Background technology
At present, in the market generally uses electri forklift or engineering truck instrument, is generally directly to be arranged on instrument with screw On platform, or using structural member rebound under instrument desk, then coordinate again with instrument desk gap;But instrument joins with extraneous The connector of system is generally that open gap coordinates, and meter movement electric part is easily damaged, and greatly reduces making for instrument With the time, how to prepare that a kind of resistance to ag(e)ing is good, damping effect is excellent, and the good instrument encapsulant of heat endurance, it would be highly desirable to Solve.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of engineering truck instrument seal, and heat is steady Qualitative fabulous, ageing-resistant performance is excellent, and compactness and tensile strength are significantly improved, and damping effect is excellent.
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 30-40 parts, 15-25 parts of methyl vinyl silicone rubber, 60-80 parts of ethylene propylene diene rubber, 4-6 parts of silane coupler, white carbon 50- 70 parts, 18-22 parts of nano diatomite, 12-18 parts of expanded perlite, 10-13 parts of multi-walled carbon nanotube, mica compound 60-80 Part, 6-10 parts of stearic acid, 1-2 parts of epoxidized soybean oil, 2-4 parts of t-butyl perbenzoate, 1-2 parts of liquid coumarone indene resin, adjacent benzene 2-4 parts of dibutyl carboxylic acid, 1-1.5 parts of trioctyl phosphate, 2-4 parts of palm wax, 1-2 parts of DOTP, polyethylene 6-12 parts of alcohol, 1.5-2.5 parts of antioxidant, 2-4 parts of vulcanizing system.
Preferably, mica compound is prepared using following technique:Jute stalk, mica powder are well mixed, heating carries out charcoal Change is handled, and is down to room temperature, is crushed, and adds titanate esters, silica gel, chlorosulfonated polyethylene acid, humic acid, water mixed grinding, and spraying is dry It is dry to obtain mica compound.
Preferably, mica compound is prepared using following technique:By weight by 10-20 parts of jute stalks, 30-50 parts of micas Powder is well mixed, and heating carries out charing process, is down to room temperature, is crushed, and adds 0.6-1 parts of titanate esters, 1-4 parts of silica gel, 1-2 parts of chlorine Sulfonated polyethylene acid, 3-6 parts of humic acids, 40-60 parts of water mixed grindings, spray drying obtain mica compound.
Preferably, mica compound is prepared using following technique:By weight by 10-20 parts of jute stalks, 30-50 parts of micas Powder is well mixed, and is warming up to 500-550 DEG C of charing process 30-40min, is down to room temperature, is crushed, and adds 0.6-1 parts of titanate esters, 1- 4 parts of silica gel, 1-2 parts of chlorosulfonated polyethylenes are sour, 3-6 parts of humic acids, 40-60 parts of water mixed grinding 20-30min, and grinding temperature is 90-95 DEG C, spray drying obtains mica compound.
Preferably, antioxidant is antioxidant AT-215.
Preferably, vulcanizing system includes by weight:1-2 parts of di-t-butyl peroxide, 0.5-0.8 parts of ammonium dichromate sodium, 0.8-1.6 parts of captax, 0.7-1 parts of Vulcanization accelerator TMTD.
The present invention, as base material, makes this using ethylene propylene diene rubber, methyl vinyl silicone rubber, chlorosulfonated polyethylene compounding Invention heat endurance is fabulous, and ageing-resistant performance is excellent;And mica compound, jute stalk, mica powder compounding are through charing process, hole Structure is flourishing, and specific surface area is big, under the cooperation of titanate esters, with silica gel, chlorosulfonated polyethylene acid, humic acid combination degree pole Height, makes the present invention to be effectively dispersed in the compounding base material of ethylene propylene diene rubber, methyl vinyl silicone rubber, chlorosulfonated polyethylene In, compatibility is good, can not only give full play to the strengthening action of mica compound, and can improve mixed refining process performance and extension sizing material Resting period, it is difficult structuring, cost is low, after di-t-butyl peroxide, ammonium dichromate sodium are cross-linking vulcanized, send out this Bright heat endurance is good, and compactness and tensile strength are significantly improved, and ageing-resistant performance is excellent.In the cooperation of silane coupler Under, white carbon, multi-walled carbon nanotube, nano diatomite, expanded perlite can be grafted on mica composite surface, make the present invention's Crosslink density is further enhanced, good waterproof performance, and elongation at break is high, and ageing-resistant performance is extremely excellent, mica compound and poly- second Enol, dibutyl phthalate, liquid coumarone indene resin compounding, compatibility are good, are reached promoting the toughness of the present invention with hardness To under the premise of in a balanced way, elongation at break is further enhanced, and is suitable for adverse circumstances compared to conventional instrument, is greatly improved The reliability of the present invention.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 30 parts, 25 parts of methyl vinyl silicone rubber, 60 parts of ethylene propylene diene rubber, 6 parts of silane coupler, 50 parts of white carbon, nanometer diatom 22 parts of soil, 12 parts of expanded perlite, 13 parts of multi-walled carbon nanotube, 60 parts of mica compound, 10 parts of stearic acid, epoxidized soybean oil 1 Part, 4 parts of t-butyl perbenzoate, 1 part of liquid coumarone indene resin, 4 parts of dibutyl phthalate, 1 part of trioctyl phosphate, palm 4 parts of wax, 1 part of DOTP, 12 parts of polyvinyl alcohol, 1.5 parts of antioxidant, 4 parts of vulcanizing system.
Embodiment 2
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 40 parts, 15 parts of methyl vinyl silicone rubber, 80 parts of ethylene propylene diene rubber, 4 parts of silane coupler, 70 parts of white carbon, nanometer diatom 18 parts of soil, 18 parts of expanded perlite, 10 parts of multi-walled carbon nanotube, 80 parts of mica compound, 6 parts of stearic acid, epoxidized soybean oil 2 Part, 2 parts of t-butyl perbenzoate, 2 parts of liquid coumarone indene resin, 2 parts of dibutyl phthalate, 1.5 parts of trioctyl phosphate, palm fibre 2 parts of palmitic acid wax, 2 parts of DOTP, 6 parts of polyvinyl alcohol, 2.5 parts of antioxidant AT-215,2 parts of vulcanizing system.
Mica compound is prepared using following technique:Jute stalk, mica powder are well mixed, heating carries out charing process, Room temperature is down to, is crushed, titanate esters, silica gel, chlorosulfonated polyethylene acid, humic acid, water mixed grinding is added, spray drying obtains cloud Female compound.
Embodiment 3
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 32 parts, 22 parts of methyl vinyl silicone rubber, 65 parts of ethylene propylene diene rubber, 5.5 parts of silane coupler, 55 parts of white carbon, nano-silicon 21 parts of diatomaceous earth, 14 parts of expanded perlite, 12 parts of multi-walled carbon nanotube, 65 parts of mica compound, 9 parts of stearic acid, epoxidized soybean oil 1.2 parts, 3.5 parts of t-butyl perbenzoate, 1.2 parts of liquid coumarone indene resin, 3.5 parts of dibutyl phthalate, tricresyl phosphate is pungent 1.2 parts of ester, 3.5 parts of palm wax, 1.2 parts of DOTP, 10 parts of polyvinyl alcohol, 1.8 parts of antioxidant AT-215, sulphur 3.5 parts of change system.
Mica compound is prepared using following technique:15 parts of jute stalks, 40 parts of mica powders are well mixed by weight, risen Temperature carries out charing process, is down to room temperature, crushes, add 0.8 part of titanate esters, 2.5 parts of silica gel, 1.5 parts of chlorosulfonated polyethylene acid, 4.5 parts of humic acids, 50 parts of water mixed grindings, spray drying obtain mica compound.
Vulcanizing system includes by weight:1 part of di-t-butyl peroxide, 0.8 part of ammonium dichromate sodium, 0.8 part of captax, 1 part of Vulcanization accelerator TMTD.
Embodiment 4
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 35 parts, 18 parts of methyl vinyl silicone rubber, 75 parts of ethylene propylene diene rubber, 4.5 parts of silane coupler, 65 parts of white carbon, nano-silicon 19 parts of diatomaceous earth, 16 parts of expanded perlite, 11 parts of multi-walled carbon nanotube, 75 parts of mica compound, 7 parts of stearic acid, epoxidized soybean oil 1.5 parts, 2.5 parts of t-butyl perbenzoate, 1.8 parts of liquid coumarone indene resin, 2.5 parts of dibutyl phthalate, tricresyl phosphate is pungent 1.4 parts of ester, 2.5 parts of palm wax, 1.8 parts of DOTP, 8 parts of polyvinyl alcohol, 2.2 parts of antioxidant AT-215, vulcanization 2.5 parts of system.
Mica compound is prepared using following technique:10 parts of jute stalks, 50 parts of mica powders are well mixed by weight, risen Temperature is down to room temperature to 500 DEG C of charing process 40min, crushes, and adds 0.6 part of titanate esters, 4 parts of silica gel, 1 part of chlorosulfonated polyethylene Acid, 6 parts of humic acids, 40 parts of water mixed grinding 30min, grinding temperature are 90 DEG C, and spray drying obtains mica compound.
Vulcanizing system includes by weight:2 parts of di-t-butyl peroxide, 0.5 part of ammonium dichromate sodium, 1.6 parts of captax, 0.7 part of Vulcanization accelerator TMTD.
Embodiment 5
A kind of engineering truck instrument seal proposed by the present invention, its raw material includes by weight:Chlorosulfonated polyethylene 34 parts, 20 parts of methyl vinyl silicone rubber, 70 parts of ethylene propylene diene rubber, 5 parts of silane coupler, 60 parts of white carbon, nanometer diatom 20 parts of soil, 15 parts of expanded perlite, 11.2 parts of multi-walled carbon nanotube, 70 parts of mica compound, 8 parts of stearic acid, epoxidized soybean oil 1.3 parts, 3 parts of t-butyl perbenzoate, 1.5 parts of liquid coumarone indene resin, 3 parts of dibutyl phthalate, trioctyl phosphate 1.3 Part, 3 parts of palm wax, 1.5 parts of DOTP, 9 parts of polyvinyl alcohol, 2 parts of antioxidant AT-215,3 parts of vulcanizing system.
Mica compound is prepared using following technique:20 parts of jute stalks, 30 parts of mica powders are well mixed by weight, risen Temperature is down to room temperature to 550 DEG C of charing process 30min, crushes, add 1 part of titanate esters, 1 part of silica gel, 2 parts of chlorosulfonated polyethylene acid, 3 parts of humic acids, 60 parts of water mixed grinding 20min, grinding temperature are 95 DEG C, and spray drying obtains mica compound.
Vulcanizing system includes by weight:1.5 parts of di-t-butyl peroxide, 0.65 part of ammonium dichromate sodium, captax 1.2 Part, 0.85 part of Vulcanization accelerator TMTD.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (6)

1. a kind of engineering truck instrument seal, it is characterised in that its raw material includes by weight:Chlorosulfonated polyethylene 30- 40 parts, 15-25 parts of methyl vinyl silicone rubber, 60-80 parts of ethylene propylene diene rubber, 4-6 parts of silane coupler, white carbon 50-70 Part, 18-22 parts of nano diatomite, 12-18 parts of expanded perlite, 10-13 parts of multi-walled carbon nanotube, 60-80 parts of mica compound, 6-10 parts of stearic acid, 1-2 parts of epoxidized soybean oil, 2-4 parts of t-butyl perbenzoate, 1-2 parts of liquid coumarone indene resin, O-phthalic 2-4 parts of dibutyl phthalate, 1-1.5 parts of trioctyl phosphate, 2-4 parts of palm wax, 1-2 parts of DOTP, polyvinyl alcohol 6- 12 parts, 1.5-2.5 parts of antioxidant, 2-4 parts of vulcanizing system.
2. engineering truck instrument seal according to claim 1, it is characterised in that mica compound uses following technique Prepare:Jute stalk, mica powder are well mixed, heating carry out charing process, be down to room temperature, crush, add titanate esters, silica gel, Chlorosulfonated polyethylene acid, humic acid, water mixed grinding, spray drying obtain mica compound.
3. engineering truck according to claim 1 or claim 2 instrument seal, it is characterised in that mica compound is using as follows It is prepared by technique:10-20 parts of jute stalks, 30-50 parts of mica powders are well mixed by weight, heating carries out charing process, is down to Room temperature, is crushed, add sour 0.6-1 part titanate esters, 1-4 parts of silica gel, 1-2 parts of chlorosulfonated polyethylenes, 3-6 parts of humic acids, 40-60 parts Water mixed grinding, spray drying obtains mica compound.
4. according to any one of claim 1-3 engineering truck instrument seals, it is characterised in that mica compound is used It is prepared by following technique:10-20 parts of jute stalks, 30-50 parts of mica powders are well mixed by weight, 500-550 DEG C of charcoal is warming up to Change processing 30-40min, be down to room temperature, crush, add 0.6-1 part titanate esters, 1-4 parts of silica gel, 1-2 parts of chlorosulfonated polyethylenes it is sour, 3-6 parts of humic acids, 40-60 parts of water mixed grinding 20-30min, grinding temperature are 90-95 DEG C, and spray drying obtains mica and is combined Thing.
5. according to any one of claim 1-4 engineering truck instrument seals, it is characterised in that antioxidant is antioxidant AT-215。
6. according to any one of claim 1-5 engineering truck instrument seals, it is characterised in that vulcanizing system is by weight Part includes:1-2 parts of di-t-butyl peroxide, 0.5-0.8 parts of ammonium dichromate sodium, 0.8-1.6 parts of captax, Vulcanization accelerator TMTD 0.7-1 parts.
CN201710334986.XA 2017-05-12 2017-05-12 A kind of engineering truck instrument seal Withdrawn CN107236196A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110258886A1 (en) * 2010-04-26 2011-10-27 Ku Do Moon Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole
CN103360687A (en) * 2013-06-20 2013-10-23 安徽春辉仪表线缆集团有限公司 High-durability sealing gasket made of kaolin/ethylene-propylene-diene monomer rubber and production method of high-durability sealing gasket
CN103724827A (en) * 2013-12-13 2014-04-16 芜湖佳诚电子科技有限公司 Automobile air conditioning expansion valve series seal ring

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110258886A1 (en) * 2010-04-26 2011-10-27 Ku Do Moon Slip-Resistant Rubber Composition, Outsole Using the Rubber Composition and Method of Manufacturing the Outsole
CN103360687A (en) * 2013-06-20 2013-10-23 安徽春辉仪表线缆集团有限公司 High-durability sealing gasket made of kaolin/ethylene-propylene-diene monomer rubber and production method of high-durability sealing gasket
CN103724827A (en) * 2013-12-13 2014-04-16 芜湖佳诚电子科技有限公司 Automobile air conditioning expansion valve series seal ring

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Application publication date: 20171010

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