CN107232204A - The composition pesticide of a kind of rhamnoside containing dodecyl and thiobenzamide and application - Google Patents

The composition pesticide of a kind of rhamnoside containing dodecyl and thiobenzamide and application Download PDF

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Publication number
CN107232204A
CN107232204A CN201710549459.0A CN201710549459A CN107232204A CN 107232204 A CN107232204 A CN 107232204A CN 201710549459 A CN201710549459 A CN 201710549459A CN 107232204 A CN107232204 A CN 107232204A
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Prior art keywords
rhamnoside
dodecyl
compound
composition pesticide
thiobenzamide
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CN201710549459.0A
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陈华进
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Yangzhou Polytechnic Institute
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Yangzhou Polytechnic Institute
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to the composition pesticide and application of a kind of rhamnoside containing dodecyl and thiobenzamide, specifically related to a kind of rhamnoside containing dodecyl and the composition pesticide of thiobenzamide class compound, it is characterised in that dodecyl rhamnoside and the mass ratio of thiobenzamide class compound are 1 in the composition pesticide:2~1:20, preferably 1:5~1:10；The structure of the dodecyl rhamnoside is：The structure of the thiobenzamide class compound is：

Description

A kind of composition pesticide of rhamnoside containing dodecyl and thiobenzamide and Using
Technical field
The invention belongs to synergetic pesticide composition field, and in particular to a kind of rhamnoside containing dodecyl and thio phenyl The composition pesticide of formamide and application.
Background technology
WO2003015519 discloses the following compound Rynaxypyr with insecticidal activity.Compound commodity Change, the features such as there is ultra high efficiency, long holding effect to lepidoptera pest, but it is poor to there is dissolubility, can process the shortcomings of formulation is lacked.China Patent of invention CN103109816A, discloses the thiobenzamide class compound of Formulas I structure：Its It is used for a long time with prominent insecticidal effect, but in areal, raising of the crop pests to its resistance is produced anti- The property of medicine, it is impossible to fully meet the requirement of pest resistance and high activity.Therefore in order to delay the service life of compound of formula I, subtract The cost of few novel pesticide exploitation, is badly in need of the composition pesticide that exploitation is compounded with it.
Dodecyl rhamnoside is a kind of amphiphilic surfactant, active with stronger surface and interface, with Sugar is hydrophilic group, using dodecyl chain as hydrophobic group.Its specific effect is as follows：(1) emulsify：Similar to diglycerol bay The surfactants such as sour sodium, castor oil polyoxyethyl ether, can promote immiscible two-phase liquid to form opaque or translucent breast Turbid liquid, when surfactant concentration is more than critical micelle concentration (CMC), moreover it is possible to the micella of organic drug is carried in the middle of being formed, Increase the apparent solubility of organic matter.(2) disperse：Prevent dispersion in solid or liquid particle coalescence and maintain it in Scattered stable state；(3) transmembranal penetration：Due to the double action with surface-active and bio-compatible, dynamic plant can be increased The ability of thing cell transmembrane infiltration.Therefore, dodecyl rhamnoside and the thiobenzamide class compound of Formulas I structure are answered With using, it is expected to improve the physicochemical property of decoction, improves virulence of the agricultural chemicals to insect, reduce the consumption of agricultural chemicals, be particularly conducive to Delay the development of pest resistance.
The content of the invention
The present invention provides a kind of rhamnoside containing dodecyl and the composition pesticide of thiobenzamide class compound, It is characterized in that dodecyl rhamnoside and the mass ratio of thiobenzamide class compound are in the composition pesticide 1:2~1:20, preferably 1:5~1:10；The structure of the dodecyl rhamnoside is： The structure of the thiobenzamide class compound is：
The formulation of composition pesticide of the present invention is selected from water dispersible granules, wettable powder, suspending agent, missible oil, micro- Emulsion, aqueous emulsion or microcapsule suspending agent.
The various formulations of the above-mentioned composition pesticide of the present invention can by this area conventional pesticide combination dosage form preparation method Or in the prior art prepared by disclosed method, or prepared as follows
1) it is adjuvant used when preparing water dispersible granules：
Wetting agent can be：Sulphonyl succinate, sodium alkyl benzene sulfonate, APES, alkyl aryl sulphonic acid Salt, alkyl sulfate, fatty alcohol, lignosulfite, spaonin powder, tea seed cake powder, pull open powder etc., can be one or more Mixture.
Dispersant can be：Sodium lignin sulfonate, naphthalenesulfonic acid-formaldehyde condensate (NNO), ethoxylated dodecyl alcohol, two Octyl group sodium sulfosuccinate, alkylphenol ethoxylate etc., can be one or more mixtures.
Carrier has：White carbon, kaolin, precipitated calcium carbonate, diatomite, montmorillonite etc., can be one or more mix Compound.
Disintegrant has：Urea, ammonium sulfate, sodium chloride, chloride of calcium and aluminium etc., can be one or more mixing Thing.
Adhesive has：Polyethylene glycol, polyvinyl alcohol, soybean lecithin, gelatin, cyclodextrin, starch etc., can be it is a kind of or A variety of mixtures.
2) it is adjuvant used when preparing wettable powder：
Wetting agent can be：Neopelex, the series of agriculture breast 2000, Span20, polysorbate60, alkyl phenol polyoxy second Alkene ether, alkylaryl sulfonates, pull open powder etc., can be one or more mixtures.
Dispersant can be：Sodium lignin sulfonate, calcium lignosulfonate, polyoxyethylene polyoxypropylene base ether block copolymerization Thing, alkylphenol-polyethenoxy base phosphate, CMC etc., can be one or more mixtures.
Stabilizer can be：Alkyl phosphate and its alkoxide, polyvinyl alcohol, potassium phosphate, wetting and penetrating agent JFC etc., Can be one or more mixtures.
Carrier can be：Clay, attapulgite, kaolin, diatomite, precipitated calcium carbonate, mud coal, white carbon etc., can be with It is one or more mixtures.
3) it is adjuvant used when preparing suspending agent：
Wetting agent can be：Neopelex, dodecyl phenenyl sulfate, excellent sour potassium, dioctyl succinate sulphur Sour sodium, alkyl polyoxyethylene ether sulfonate, agriculture breast 100, agriculture breast 600, sorbitol polyoxyethylene ether etc., can be one or more Mixture.
Dispersant can be：Sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate formaldehyde condensation products, dibutyl Sodium naphthalene sulfonate, alkylpolyoxyethylene phosphate, polycarboxylate sodium salt, polyarylphenol-polyoxyethylene ether phosphate etc., can To be one or more mixtures.
Thickener can be：Xanthans, heteroglycan, sodium carboxymethylcellulose, polyvinyl alcohol, gelatin, agar, soluble shallow lake Powder and its derivative etc., can be one or more mixtures.
Stabilizer can be：Bentonite, precipitated calcium carbonate, white carbon, diatomite, crushed crude pearlite etc., can be it is a kind of or A variety of mixtures.
Antifreezing agent can be：Ethylene glycol, propane diols, glycerine, sucrose, polyethylene glycol 400, polyvinylpyrrolidone etc..
Preservative can be：Sodium salicylate, sodium benzoate, formaldehyde etc..
Defoamer can be：Oxirane fluidized polymer, silicic acid class, the C of glycerine8~C10Fatty alcohol, laurate, palm Acid, sulfonamide etc..
4) it is adjuvant used when preparing missible oil：
Emulsifying agent can be：Agriculture breast 0204, agriculture breast 2201, agriculture breast 0201, calcium dodecyl benzene sulfonate, OP-10, OP- 20th, agriculture breast 600, By-15, Polyethylene Octylphenol Ether, dodecyl phenol polyethenoxy ether etc., can be one or more Mixture.
Stabilizer can be：Alkyl phosphate, aryl phosphate ester, phosphorous acid esters, polyalcohol, alkyl sulfonic ester and its take For ammonium salt, substituted epoxide etc..
5) it is adjuvant used when preparing microemulsion：
Emulsifying agent can be：Calcium dodecyl benzene sulfonate, triphenyl vinyl phenol oxirane nitranol salt, alkane The polyoxy vinyl sulfonate of base two, styrenated phenol APEO, biphenyl phenol polyethenoxy ether, lauryl sodium sulfate, octyl Phenol polyethenoxy ether etc., can be one or more mixtures.
Stabilizer can be：Aryl phosphate ester, polyalcohol, alkyl sulfonic ester and its substituted ammonium salt, substituted epoxide, alkane Base phosphate etc..
Antifreezing agent can be：Ethylene glycol, propane diols, glycerine, polyethylene glycol, sucrose etc..
Preservative can be：Sodium salicylate, sodium benzoate, formaldehyde etc..
6) it is adjuvant used when preparing aqueous emulsion：
Emulsifying agent can be：Ethylene oxide-propylene oxide block copolymer, polyoxyethylene alkylphenyl ether, polyoxyethylene alkane Base ether, alkyl benzene calcium sulfonate, oxirane-fat primary amine condensation product, polyoxyethylene sorbitol glycosides ester, polyoxyethylene fatty acid Ester etc., can be one or more mixtures.
Dispersant can be：Polyvinyl alcohol, gum arabic, alkyl polyoxyethylene ether phosphate etc., can be it is a kind of or A variety of mixtures.
Co-emulsifier can be：The alkanols such as butanol, isobutanol, dodecanol -1, tetradecanol -1, octadecanol -1.
Antifreezing agent can be：Ethylene glycol, glycerine, urea, ammonium sulfate, sodium chloride etc..
Preservative can be：Sodium benzoate, parahydroxyben-zaldehyde, 1,2- benzothiazoline -3- ketone (BIT) etc.
Thickener can be：Polyacrylate, natural polysaccharide, aluminium-magnesium silicate, xanthans, gelatin etc., can be it is a kind of or A variety of mixtures.
7) it is adjuvant used when preparing microcapsule suspending agent：
Wetting agent can be：Diisooctyl succinic acid sodium sulfonate, Nekal BX (5,6- dibutyl naphthalene-2-sulfonic acids sodium), ten Dialkyl benzene sulfonic acids sodium, dodecyl phenenyl sulfate, potassium oleate, dioctyl sodium sulfosuccinate, alkyl polyoxyethylene ether sulfonic acid Salt, sorbitol polyoxyethylene ether etc., can be one or more mixtures.
Dispersant can be：Sodium lignin sulfonate, calcium lignosulfonate, alkylnaphthalene sulfonate formaldehyde condensation products, pull open powder BX (5,6- dibutyl naphthalene-2-sulfonic acids sodium), oleic acid methylaminoethyl sodium sulfonate, polycarboxylate sodium salt, dodecyl polyoxy second Alkene ether phosphate, polyarylphenol-polyoxyethylene ether phosphate etc., can be one or more mixtures.
Thickener can be：It is methylcellulose, alginic acid, silicic acid class, xanthans, heteroglycan, sodium carboxymethylcellulose, poly- Vinyl alcohol, gelatin, agar, soluble starch and its derivative etc., can be one or more mixtures.
Stabilizer can be：Talcum powder, bentonite, precipitated calcium carbonate, white carbon, diatomite, crushed crude pearlite etc., Ke Yishi One or more mixtures.
Antifreezing agent can be：Urea, calcium chloride, ethylene glycol, propane diols, glycerine, sucrose, polyethylene glycol 400, poly- second Alkene pyrrolidone etc..
Preservative can be：Sodium salicylate, sodium benzoate, formaldehyde etc..
Defoamer can be：Stearic acid, the oxirane fluidized polymer of glycerine, silicic acid class, C8~C10Fatty alcohol, bay Acid, palmitic acid, sulfonamide etc..
Another embodiment of the present invention provides application of the composition pesticide in terms of control of insect, and the insect is Aphid, aleyrodid, plant hopper, leafhopper, scale insect, thrips, stinkbug, cecidomyiia.
Another embodiment of the present invention provide the water dispersible granules of the composition pesticide, wettable powder, suspending agent, The application of missible oil, microemulsion, aqueous emulsion or microcapsule suspending agent in terms of control of insect, the insect be aphid, aleyrodid, plant hopper, Leafhopper, scale insect, thrips, stinkbug, cecidomyiia.
Another embodiment of the present invention provides the dodecyl rhamnoside in agricultural chemicals synergist is prepared Using.
Another embodiment of the present invention provides the dodecyl rhamnoside as the application of agricultural chemicals synergist. The above-mentioned preferred reactive compound of agricultural chemicals is the agricultural chemicals of thiobenzamide class compound.
Compared with prior art, the advantage of the invention is that：(1) present invention uses dodecyl rhamnoside as increasing Auxiliary agent is imitated, enhance decoction soaks, disperses and open up ability, and the thiobenzamide class compound to Formulas I structure has Significant synergistic effect, reduces the usage amount of compound of formula I；(2) preventing and treating of the composition pesticide of the present invention to cotten aphid has bright Aobvious synergistic effect, has the advantages that efficient, low toxicity；(3) present invention is by dodecyl rhamnoside and compound of formula I The exploration of ratio, it was found that the optimal use ratio of the two.
Embodiment
For the ease of a further understanding of the present invention, examples provided below has done more detailed description to it.But It is that these embodiments only are not used for limiting the scope of the present invention or implementation principle, reality of the invention for being better understood from invention The mode of applying is not limited to herein below.
The preparation of preparation
Example of formulations 1：The quality proportioning of water dispersible granules each component
Carrier, wetting agent, dispersant, disintegrant, builder, active compound are mixed by above-mentioned formula rate, ultra-fine grinding After mix, by wettable powder and quantitative water (in advance that binding agent is soluble in water), at the same into kneader mediate, being made can The material of plasticity, finally sends material into Squeezinggranulator, is granulated, and by drying, screening, obtains stablizing qualified 48% Compound of formula I dodecyl rhamnoside water dispersible granules.
Example of formulations 2：The quality proportioning of wettable powder each component
A certain amount of active compound, auxiliary agent and filling adsorption are weighed by above-mentioned formula to be well mixed, and pass through airslide disintegrating mill, adjustment Operating pressure and stream pressure are crushed, you can obtain stablizing 44% qualified change compound of formula I dodecyl sandlwood Glucosides wettable powder.
Example of formulations 3：The quality proportioning of suspending agent each component
Quantitative active compound, auxiliary agent and water are weighed by above-mentioned formula to add in sand mill, in 2000r/min sand milling condition Under, work 3h, you can obtains stablizing 42% qualified compound of formula I dodecyl rhamnoside suspending agent.
Example of formulations 4：The quality proportioning of missible oil each component
Active compound, emulsifying agent and solvent are put into modulation kettle successively according to above-mentioned formula and mixed, you can stabilization is obtained 60% qualified compound of formula I dodecyl rhamnoside missible oil.
Example of formulations 5：The quality proportioning of microemulsion each component
According to above-mentioned Formulations Formula, aqueous phase is made after synergist, emulsifying agent and glycerine are mixed with water, by dissolution type I Lower addition aqueous phase is stirred in the xylene solution of compound active compound, you can the transparent Formulas I compound of oil-in-water 48% is being made just Dodecyl rhamnoside microemulsion.
Insecticidal activity is tested
(1) compound of formula I compounds with dodecyl rhamnoside and the indoor virulence of cotten aphid is tested
Experiment uses cotten aphid for test object, and specific method is：Pesticidal combination is determined to cotten aphid using band worm leaf dipping method Co-toxicity effect.According to equal difference or wait than method reagent agent is diluted to the decoction of series concentration, cotten aphid will be carried Rose of Sharon blade be separately immersed in decoction after 10s and take out nature and dry, be then placed in the culture dish for being lined with filter paper, with fresh-keeping Film is sealed, and is breathed freely with pin bundle hole.Often processing is repeated 4 times, and blank control is used as using clear water.By culture dish be placed in temperature for 25 ± 1 DEG C, periodicity of illumination is L:D=16:8, relative humidity is raising in 60-70% incubator.Dead borer population is checked after 24h.Determine Data calculate corrected mortality with Abbott formula, and LC is calculated with DPS DAS50And virulence regression equation, and according to Formula calculates the synergic ratio (SR) of complex preparation.
Synergic ratio (the SR)=alone LC of medicament50Value/medicament and the united LC of builder50Value.
Dodecyl rhamnoside does not have an insecticidal effect to cotten aphid in itself it can be seen from the result of table 1, but positive ten Dialkyl group rhamnoside can significantly improve virulence of the compound of formula I to cotten aphid, when compound of formula I and dodecyl rhamnoside Mass ratio be 2:1、5:1、10:1、20:1、40:When 1, synergic ratio is respectively 1.74,2.18,2.35,1.67,1.09, it is seen that When the mass ratio of compound of formula I and dodecyl rhamnoside is 2:1~20:Its synergistic effect is obvious when 1, and especially 5:1 ~10:When 1, the present invention has also investigated compound of formula I and the compounding effect of rhamnolipid, as a result shows to work as compound of formula I and mouse The mass ratio of Lee's sugar ester is 5:1、10:Synergistic effect is not obvious when 1, and the rhamnolipid structure that the present invention is used is：
Synergistic effect result of the dodecyl rhamnoside of table 1 to compound of formula I
(2) field control effect of the compound pesticide composition preparation of the present invention to cotton Bemisia tabaci
Inventor has carried out example of formulations 1 and the preventing and treating cotton Bemisia tabaci of example of formulations 2 field in Xinxiang City, Henan Province Experiment.Choose the cotton field that water and fertilizer condition is good, Bemisia tabaci generation is serious.Reagent agent dilutes 1000 times, by 667m2Use water 45kg, with the type of workers and peasants -16 sprayer to cotton leaf positive and negative even spraying.Each processing is repeated 4 times, and is 50 per plot area Square metre, random district's groups arrangement.Investigation insect population, takes 5 point samplings before spray, and every takes 10 cotton leafs, and in 1,3,7 and 14d investigates insect population number respectively after medicine, calculates killed strain Revision insect recluced rate and preventive effect.
Example of formulations 1 is respectively 80.7% to Bemisia tabaci the 1st, the preventive effect of 3,7,14 days, 85.8%, 86.9%, 82.3%；Example of formulations 2 is respectively 82.4% to Bemisia tabaci the 1st, the preventive effect of 3,7,14 days, 87.9%, 88.3%, 85.8%；Compare single dose and (remove dodecyl rhamnoside according to the formula in example of formulations 1 and prepare single dose) dilution 1000 times, the 1st, 3,7, the preventive effect of 14 days be respectively 20.2%, 28.5%, 29.4%, 29.8%.Can from above-mentioned result of the test To learn that compound pesticide composition of the present invention is significantly increased to the prevention effect of Bemisia tabaci, show good mixture synergy and make With and lasting effect.Meanwhile, field investigation result shows, cotten aphid insect density relatively compares field and significantly dropped in the present embodiment processing cotton field It is low, show that compound pesticide composition of the present invention can significantly reduce the harm of cotten aphid, play and simultaneous control effect.
(3) field control effect of the compound pesticide composition preparation of the present invention to grape leafhopper
Inventor has carried out example of formulations 3 in the vineyard of Turpan, Xinjiang Shanshan County grape melon developmental research center Grape leafhopper field test is prevented and treated with example of formulations 4, water and fertilizer condition is good, and grape variety is that crith is gloomy.According to supplying reagent 1000 times of dilution agent, 667m2Water 60kg is used, with the type of workers and peasants -16 sprayer to grape leaf positive and negative even spraying.Each processing weight It is multiple 4 times, per 100 square metres of plot area, random district's groups arrangement.Insect population is investigated before spray, using 5 point samplings, often Point takes 10 grape leaves, and investigates insect population number respectively in after medicine 1,3,7 and 14d, calculates killed strain Revision insect recluced rate and preventive effect.
As a result show：Example of formulations 3 is respectively 91.2% to grape leafhopper the 1st, the preventive effect of 3,7,14 days, 94.1%th, 97.4%, 90.4%；Example of formulations 4 is respectively 86.3% to grape leafhopper the 1st, the preventive effect of 3,7,14 days, 91.6%th, 93.5%, 89.8%；Compare single dose and (remove dodecyl rhamnoside system according to the formula in example of formulations 3 Standby single dose) 1000 times of dilution, the 1st, 3,7, the preventive effect of 14 days be respectively 33.6%, 39.7%, 40.4%, 28.7%.Above-mentioned examination Test result to show, compound pesticide composition of the present invention significantly increases the prevention effect of grape leafhopper, show well Mixed synergies and lasting effect.

Claims (7)

1. a kind of rhamnoside containing dodecyl and the composition pesticide of thiobenzamide class compound, it is characterised in that institute It is 1 to state dodecyl rhamnoside and the mass ratio of thiobenzamide class compound in composition pesticide:2~1:20；Institute The structure for stating dodecyl rhamnoside is：The knot of the thiobenzamide class compound Structure is：
2. the composition pesticide described in claim 1, it is characterised in that dodecyl rhamnoside and thiobenzamide class The mass ratio of compound is 1:5~1:10.
3. the composition pesticide described in claim any one of 1-2, it is characterised in that the formulation of described composition pesticide is selected from Water dispersible granules, wettable powder, suspending agent, missible oil, microemulsion, aqueous emulsion or microcapsule suspending agent.
4. application of the composition pesticide described in claim any one of 1-3 in terms of control of insect, the insect is aphid, powder Lice, plant hopper, leafhopper, scale insect, thrips, stinkbug, cecidomyiia.
5. application of the dodecyl rhamnoside in agricultural chemicals synergist is prepared, the dodecyl rhamnoside structure It is identical with claim 1.
6. dodecyl rhamnoside is used as the application of agricultural chemicals synergist, the dodecyl rhamnoside structure and power Profit requires identical in 1.
7. the application described in claim any one of 5-6, it is characterised in that it is thio phenyl first that the agricultural chemicals, which is selected from reactive compound, The agricultural chemicals of amides compound.
CN201710549459.0A 2017-07-06 2017-07-06 The composition pesticide of a kind of rhamnoside containing dodecyl and thiobenzamide and application Pending CN107232204A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103109816A (en) * 2013-01-25 2013-05-22 青岛科技大学 Thiobenzamide compounds and application thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103109816A (en) * 2013-01-25 2013-05-22 青岛科技大学 Thiobenzamide compounds and application thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴虹 等: "鼠李糖脂生物表面活性剂的研究进展", 《微生物学通报》 *

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Application publication date: 20171010