CN107227088A - Showcase specialty waterborne epoxy modified acrylic decorative paint and preparation method thereof - Google Patents
Showcase specialty waterborne epoxy modified acrylic decorative paint and preparation method thereof Download PDFInfo
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- CN107227088A CN107227088A CN201710473954.8A CN201710473954A CN107227088A CN 107227088 A CN107227088 A CN 107227088A CN 201710473954 A CN201710473954 A CN 201710473954A CN 107227088 A CN107227088 A CN 107227088A
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- epoxy modified
- waterborne epoxy
- modified acrylic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
Abstract
The invention provides professional waterborne epoxy modified acrylic decorative paint of a kind of showcase and preparation method thereof, the decorative paint is in parts by mass, including 40 60 parts of waterborne epoxy modified acrylic emulsions, 20 30 parts of silicone acrylic emulsions, 8 24 parts of pigment, 6 20 parts of auxiliary agents and 15 25 parts of deionized waters, wherein the mass ratio of the waterborne epoxy modified acrylic emulsion and silicone acrylic emulsion is 1.8 2.2:1, the waterborne epoxy modified acrylic emulsion is polymerized by 24 parts of methacrylate glycidol ethers, 36 parts of hard monomers and 48 parts of soft monomers.The decorative paint excellent performance, both there is the decorative effect of finish paint, high glaze and richness, the features such as there is fast, the good adhesive force of the rate of drying of priming paint, excellent chemical-resistance and physical and mechanical properties again simultaneously, excellent storage stability, environmental pollution is small, is a kind of product with development prospect.
Description
Technical field
The present invention relates to functional environment-friendly paint field, and in particular to a kind of professional waterborne epoxy modified acrylic dress of showcase
Decorations paint and preparation method thereof.
Background technology
Showcase is mainly used in some shops such as market, supermarket, for showing the place of commodity, storing articles, strong possessing
While big application function, it is necessary to certain innovative appearance design, to reach the mesh for boosting consumption, publicizing
's.In today of rapid economic development, the material life of people is increasingly enriched, and the demand for commodity is more and more finer, with
The showcase brought design and manufacture demand also more and more higher.In traditional showcase makes, what is used is usually oil
Paint, including nitrate paint and alkyd paint, it is expensive although nitrate paint rate of drying is fast, hardness is high, although alkyd paint price is just
Preferably, but hardness is low, the short ageing-resistant time, long construction period the problems such as.These oil paint VOC contents are high simultaneously, pollute big, in paint
The harmful substances such as the benzene, the formaldehyde that contain cause to have a strong impact on to the health of constructor.
Therefore need to provide a kind of new decorative paint to meet the diversified demand of people.
The content of the invention
An object of the present invention is to provide a kind of professional waterborne epoxy modified acrylic decorative paint of showcase, and the decorative paint is
One-component coating, excellent performance, excellent storage stability, environmental pollution is small, both the decorative effect with finish paint, high plentiful
Degree, while the spy such as fast, good adhesive force, excellent chemical-resistance and physical and mechanical properties of the rate of drying with priming paint again
Point, can be widely applied to different substrate materials showcase, be a kind of product with preferable development prospect.
An aspect of of the present present invention provides a kind of professional waterborne epoxy modified acrylic decorative paint of showcase, in parts by mass,
Including following components：
40-60 parts of waterborne epoxy modified acrylic emulsions, 20-30 parts of silicone acrylic emulsions, 8-24 parts of pigment, 6-20 parts of auxiliary agents and
15-25 parts of deionized waters,
The mass ratio of the waterborne epoxy modified acrylic emulsion and silicone acrylic emulsion is 1.8-2.2:1,
The waterborne epoxy modified acrylic emulsion by 2-4 parts of methacrylate glycidol ethers, 3-6 parts of hard monomers and
4-8 parts of soft monomers are polymerized.
In certain embodiments of the present invention, the hard monomer is methyl methacrylate, methyl acrylate, vinyl acetate
At least one of ester, styrene, acrylonitrile and acrylamide,
The soft monomer is at least one of ethyl acrylate, butyl acrylate and Isooctyl acrylate monomer.
In certain embodiments of the present invention, in parts by mass, the auxiliary agent includes：
In certain embodiments of the present invention, the mass ratio of the hard monomer and the soft monomer is 3:4.
In certain embodiments of the present invention, the thickener is the swollen association thickener of alkali soluble.
In certain embodiments of the present invention, the anti-settling agent is the organobentonite aqueous solution.
Another aspect provides the preparation method of the professional waterborne epoxy modified acrylic decorative paint of the showcase,
Comprise the following steps：
Step a, according to raw material proportioning by the 60% of deionized water, the 50% of pH adjusting agent, defoamer, dispersant, environmental protection
Cosolvent 20%, pigment and anti-settling agent be added sequentially to get the raw materials ready under 500-800r/min rotating speeds in pot, after stirring, enter
Row is ground to fineness≤30um, obtains early stage slurry,
Step b, by waterborne epoxy modified acrylic emulsion, remaining deionized water, remaining pH adjusting agent and remaining
Environmentally friendly cosolvent is added sequentially in paint mixing tank, and 300-600r/min rotating speeds stir,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 500-800r/min, stirred,
Step d, adds anti-flash rusting agent, substrate wetting agents and levelling agent into paint mixing tank successively, will finally be painted with thickener
The viscosity of liquid is transferred to regulation viscosity and can obtain the professional waterborne epoxy modified acrylic decorative paint of showcase.
Beneficial effect：
The professional waterborne epoxy modified acrylic decorative paint of showcase that the present invention is provided is in waterborne epoxy modified acrylic breast
The water-borne decorative paint that auxiliary agent of the addition with environmental-protecting performance is made in liquid.The decorative paint excellent performance, has priming paint and finish paint concurrently
Advantage, the both decorative effect with finish paint, high glaze and richness, while the rate of drying with priming paint is fast, good again
The features such as adhesive force, excellent chemical-resistance and physical and mechanical properties, and coating process is simple, short construction period, VOC contain
Amount is low, can be widely applied to showcase different substrate materials.And the professional waterborne epoxy modified acrylic decorative paint of the showcase is one pack system
Coating, excellent storage stability, environmental pollution is small, is a kind of product with development prospect.
Embodiment
By explaining the preferred embodiment of following the application, other objects of the present invention and advantage will be clear.
It should be understood that heretofore described term is only to be to describe special embodiment, this hair is not intended to limit
It is bright.In addition, for the number range in the present invention, it is thus understood that it is also specifically disclosed that between the higher limit and lower limit of the scope
Each median.Median and any other statement value in any statement value or stated ranges or in the scope
Median between each less scope be also included in the present invention.These small range of higher limits and lower limit can be only
On the spot include or exclude in the range of.
In addition, in order to better illustrate the present invention, being given in specific embodiment below numerous specific
Details.It will be appreciated by those skilled in the art that without some details, the present invention can equally be implemented.It is real in other
Apply in example, be not described in detail for method well known to those skilled in the art, means, in order to highlight the purport of the present invention.
In the present invention, represent that the unit of material content is based on weight in terms of part, unless otherwise indicated.In addition, the skill on the present invention
The assay method of art index is to use standard method in the art, for details, reference can be made to newest national standard, unless said in addition
It is bright.
In the present invention, vocabulary of terms both includes singulative, also including plural form, unless context separately clearly refers to
Go out.Heretofore described " at least one " refers not only to the situation comprising " one " or " one kind ", prior also comprising " many
It is individual " or " a variety of " situation.
The silicone acrylic emulsion is that the organic silicon monomer containing unsaturated bond and acrylic monomer are added into suitable auxiliary agent,
The emulsion that polymerization technique is polymerized is coated by nucleocapsid.It combines organosilicon fire-resistant, weatherability, chemical-resistant,
Hydrophobic, surface can low not v ulnerability and acrylic compounds high colour retention, pliability, the advantage of tack, be a kind of high durable,
High water-fast, resistant to pollution environmental-friendly type emulsion.In embodiments of the invention, the silicone acrylic emulsion can be bought with market, can also be certainly
Oneself prepares, and can specifically be prepared by seed emulsion polymerization.
Waterborne epoxy modified acrylic emulsion of the present invention is by 2-4 parts of methacrylate glycidol ethers, 3-6
What part hard monomer and 4-8 parts of soft monomers were polymerized.The height of glass transition temperature is that reflection polymer flexible is soft and hard brittle
Important indicator.Homopolymer glass transition temperature the higher person of monomer is referred to as hard monomer.It can improve the hardness of copolymer and stretch strong
Degree, for example, hard monomer methacrylate is because alpha-position is with the presence of methyl, disturbs the rotary motion of carbon-carbon skeletal chain, therefore poly- first
The glass transition temperature of base acrylate is higher, and brittle temperature and tensile strength are also larger.In an embodiment of the present invention, it is described
Hard monomer includes but is not limited to methyl acrylate, vinylacetate, styrene, acrylonitrile, methyl methacrylate, acrylamide
Etc..Described soft monomer includes but is not limited to ethyl acrylate, butyl acrylate, Isooctyl acrylate monomer etc..
Wherein, because methacrylate glycidol ether contains epoxy radicals and unsaturated double-bond, with greater activity, make
For bridging property function monomer, the weatherability and filming performance of coating can be significantly improved so that film have good water resistance,
Acid resistance and alkali burnout resistance and salting-out resistance, simultaneously as epoxy radicals and carboxyl participate in all having remnants after polymerisation
Hydroxyl exist, the GMA monomer used has specific content so that residual hydroxy groups are not enough to shape
Into hydrophilic solidification polymer, but their polarity is enough to make polymer bonding to substrate surface, so as to improve painting
The adhesive force and adhesive property of material.
In the present invention, the waterborne epoxy modified acrylic emulsion and silicone acrylic emulsion of extra fine quality ratio are added to coating
Performance has considerable influence, when silicone acrylic emulsion too high levels, is easily caused paint film and crackle occurs, and when waterborne epoxy modified propylene
During the too high levels of yogurt liquid, the pliability and richness of paint film can then be deteriorated, therefore maintain waterborne epoxy modified the third of addition
The mass ratio of olefin(e) acid emulsion and silicone acrylic emulsion is in 1.8-2.2:It ensure that the performance of paint film reaches most preferably between 1.
In the present invention, various components can select oneself preparation or market to be commercially available as needed.In the present invention
Embodiment in, the waterborne epoxy modified acrylic emulsion, which is prepared by the following method, to be obtained, equipped with electric stirring
Appropriate distilled water, the hard monomer of proper content, soft list are added in device, thermometer, the four-hole boiling flask of condenser pipe and dropping funel
Body and methacrylate glycidol ether, and compound emulsifying agent, stirring, pre-emulsification.Heating simultaneously will be remaining in 2 hours
Mix monomer, initiator are added drop-wise in reactor, and hour is then kept at this temperature, obtain waterborne epoxy modified acrylic breast
Liquid, is filtered with 100 mesh sieve, saved backup.
In the section Example of the present invention, the silicone acrylic emulsion purchase is from BASF AG, and the pH adjusting agent is two
One or both of methylethanolamine or hexamethylene diamine, the environmentally friendly cosolvent are industrial alcohol, propandiol butyl ether, DPG
One or more in methyl ether, the dispersant for Bi Ke companies one or both of BYK-190 or BYK-194, it is described
Defoamer for Bi Ke companies one or both of BYK-024 or BYK-028, the levelling agent be the BYK-333 that first creates or
One or both of BYK-346, described substrate wetting agents in TEGO Tego-100, Tego-510, tego-4100
One or more, the anti-flash rusting agent is one in a kind of modified solution on the basis of natrium nitrosum, ED-617F, corrosion inhibiter 510
Plant or several, the thickener is the swollen association thickener of alkali soluble, buy from ROHM AND HAAS, described anti-settling agent is organic swelling
The aqueous solution of soil, the one or more in EW, DE, LT, described pigment is titanium dioxide R-706, MH-RC (bright red),
One or more in 1019 (middle Huangs).
Embodiment 1
Step a, by 12 parts of deionized waters, 0.2 part of pH adjusting agent, 0.2 part of defoamer, 1 part of dispersant, 1 part of environmentally friendly hydrotropy
Agent, 16 parts of pigment and 3 portions of anti-settling agents are added sequentially to get the raw materials ready in pot under 600r/min rotating speeds, after stirring, are ground
Early stage slurry is obtained to fineness≤30um,
Step b, 50 parts of waterborne epoxy modified acrylic emulsions, 25 parts of silicone acrylic emulsions, 8 parts of deionized waters, 0.2 part of pH are adjusted
Section agent and 4 parts of environmentally friendly cosolvents are added sequentially in paint mixing tank, and 500r/min rotating speeds stir, wherein the water-base epoxy changes
Property acrylic emulsion is polymerized by 3 parts of methacrylate glycidol ethers, 4.5 parts of hard monomers and 6 parts of soft monomers,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 600r/min, stirred,
Step d, adds 1 part of anti-flash rusting agent, 0.4 part of substrate wetting agents and 0.4 part of levelling agent, finally into paint mixing tank successively
The viscosity for painting liquid is transferred to regulation viscosity with 1.5 parts of thickeners and can obtain the professional waterborne epoxy modified acrylic decoration of showcase
Paint.
Embodiment 2
Step a, by 9 parts of deionized waters, 0.15 part of pH adjusting agent, 0.1 part of defoamer, 2 parts of dispersants, 1 part of environmentally friendly hydrotropy
Agent, 20 parts of pigment and 2 portions of anti-settling agents are added sequentially to get the raw materials ready in pot under 500/min rotating speeds, after stirring, be ground to
Fineness≤30um obtains early stage slurry,
Step b, by 40 parts of waterborne epoxy modified acrylic emulsions, 20 parts of silicone acrylic emulsions, 6 parts of deionized waters, 0.15 part of pH
Conditioning agent and 4 parts of environmentally friendly cosolvents are added sequentially in paint mixing tank, and 600r/min rotating speeds stir, wherein the water-base epoxy
Modified acrylic acid emulsion is polymerized by 3 parts of methacrylate glycidol ethers, 6 parts of hard monomers and 8 parts of soft monomers,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 500r/min, stirred,
Step d, adds 2 parts of anti-flash rusting agent, 0.3 part of substrate wetting agents and 0.3 part of levelling agent, finally into paint mixing tank successively
The viscosity for painting liquid is transferred to regulation viscosity with 2 parts of thickeners and can obtain the professional waterborne epoxy modified acrylic decorative paint of showcase.
Embodiment 3
Step a, by 15 parts of deionized waters, 0.25 part of pH adjusting agent, 0.05 part of defoamer, 0.5 part of dispersant, 1.5 parts of rings
Protect cosolvent, 8 parts of pigment and 2 portions of anti-settling agents to be added sequentially to get the raw materials ready under 500r/min rotating speeds in pot, after stirring, carry out
It is ground to fineness≤30um and obtains early stage slurry,
Step b, by 60 parts of waterborne epoxy modified acrylic emulsions, 30 parts of silicone acrylic emulsions, 10 parts of deionized waters, 0.25 part of pH
Conditioning agent and 6 parts of environmentally friendly cosolvents are added sequentially in paint mixing tank, and 300r/min rotating speeds stir, wherein the water-base epoxy
Modified acrylic acid emulsion is polymerized by 2 parts of methacrylate glycidol ethers, 4 parts of hard monomers and 4 parts of soft monomers,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 500r/min, stirred,
Step d, adds 1 part of anti-flash rusting agent, 0.4 part of substrate wetting agents and 0.3 part of levelling agent, finally into paint mixing tank successively
The viscosity for painting liquid is transferred to regulation viscosity with 1.5 parts of thickeners and can obtain the professional waterborne epoxy modified acrylic decoration of showcase
Paint.
Embodiment 4
Step a, by 12 parts of deionized waters, 0.2 part of pH adjusting agent, 0.2 part of defoamer, 1 part of dispersant, 1 part of environmentally friendly hydrotropy
Agent, 22 parts of pigment and 2.5 portions of anti-settling agents are added sequentially to get the raw materials ready in pot under 800r/min rotating speeds, after stirring, are ground
It is milled to fineness≤30um and obtains early stage slurry,
Step b, 55 parts of waterborne epoxy modified acrylic emulsions, 26 parts of silicone acrylic emulsions, 8 parts of deionized waters, 0.2 part of pH are adjusted
Section agent and 4 parts of environmentally friendly cosolvents are added sequentially in paint mixing tank, and 500r/min rotating speeds stir, wherein the water-base epoxy changes
Property acrylic emulsion is polymerized by 3 parts of methacrylate glycidol ethers, 3 parts of hard monomers and 4 parts of soft monomers,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 600r/min, stirred,
Step d, adds 1 part of anti-flash rusting agent, 0.4 part of substrate wetting agents and 0.3 part of levelling agent, finally into paint mixing tank successively
The viscosity for painting liquid is transferred to regulation viscosity with 1.5 parts of thickeners and can obtain the professional waterborne epoxy modified acrylic decoration of showcase
Paint.
Comparative example 1
50 parts of waterborne epoxy modified acrylic emulsions in embodiment 1,25 parts of silicone acrylic emulsions are changed to 60 parts of water-base epoxies
Modified acrylic acid emulsion, 20 parts of silicone acrylic emulsions, other conditions keep constant, prepare the waterborne epoxy modified propylene of showcase specialty
Sour decorative paint.
Comparative example 2
50 parts of waterborne epoxy modified acrylic emulsions in embodiment 1,25 parts of silicone acrylic emulsions are changed to 40 parts of water-base epoxies
Modified acrylic acid emulsion, 30 parts of silicone acrylic emulsions, other conditions keep constant, prepare the waterborne epoxy modified propylene of showcase specialty
Sour decorative paint.
Comparative example 3
Waterborne epoxy modified acrylic emulsion in embodiment 1 is changed to by 1 part of methacrylate glycidol ether, 5
Part hard monomer and 6 parts of soft monomers are polymerized, and other conditions keep constant, prepare the waterborne epoxy modified propylene of showcase specialty
Sour decorative paint.
The decorative paint that above-described embodiment and comparative example are prepared is coated on showcase and tested and analyzed, gained performance
Test result is as shown in table 1.
Table 1
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, the present invention
Claimed scope is by appended claims, specification and its equivalent thereof.
Claims (7)
1. a kind of professional waterborne epoxy modified acrylic decorative paint of showcase, in parts by mass, including following components：
40-60 parts of waterborne epoxy modified acrylic emulsions, 20-30 parts of silicone acrylic emulsions, 8-24 parts of pigment, 6-20 parts of auxiliary agents and 15-
25 parts of deionized waters,
The mass ratio of the waterborne epoxy modified acrylic emulsion and silicone acrylic emulsion is 1.8-2.2:1,
The waterborne epoxy modified acrylic emulsion is by 2-4 parts of methacrylate glycidol ethers, 3-6 parts of hard monomers and 4-8
Part soft monomer is polymerized.
2. the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim 1, wherein,
The hard monomer is methyl methacrylate, methyl acrylate, vinylacetate, styrene, acrylonitrile and acrylamide
At least one of,
The soft monomer is at least one of ethyl acrylate, butyl acrylate and Isooctyl acrylate monomer.
3. the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim 1, wherein,
The mass ratio of the hard monomer and the soft monomer is 3:4.
4. the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim 1, wherein, in parts by mass, institute
Stating auxiliary agent includes：
5. the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim 4, wherein,
The thickener is the swollen association thickener of alkali soluble.
6. the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim 4, wherein,
The anti-settling agent is the organobentonite aqueous solution.
7. a kind of preparation side of the professional waterborne epoxy modified acrylic decorative paint of showcase according to claim any one of 1-6
Method, comprises the following steps：
Step a, according to raw material proportioning by the 60% of deionized water, the 50% of pH adjusting agent, defoamer, dispersant, environmentally friendly hydrotropy
Agent 20%, pigment and anti-settling agent be added sequentially to get the raw materials ready under 500-800r/min rotating speeds in pot, after stirring, ground
Fineness≤30um is milled to, early stage slurry is obtained,
Step b, by waterborne epoxy modified acrylic emulsion, remaining deionized water, remaining pH adjusting agent and remaining environmental protection
Cosolvent is added sequentially in paint mixing tank, and 300-600r/min rotating speeds stir,
Step c, the early stage slurry prepared is poured into after paint mixing tank, by adjustment of rotational speed to 500-800r/min, stirred,
Step d, adds anti-flash rusting agent, substrate wetting agents and levelling agent into paint mixing tank successively, finally will paint liquid with thickener
Viscosity is transferred to regulation viscosity and can obtain the professional waterborne epoxy modified acrylic decorative paint of showcase.
Priority Applications (1)
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| CN201710473954.8A CN107227088A (en) | 2017-06-21 | 2017-06-21 | Showcase specialty waterborne epoxy modified acrylic decorative paint and preparation method thereof |
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| CN201710473954.8A CN107227088A (en) | 2017-06-21 | 2017-06-21 | Showcase specialty waterborne epoxy modified acrylic decorative paint and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359354A (en) * | 2018-01-24 | 2018-08-03 | 河北晨阳工贸集团有限公司 | A kind of mechanical equipment anti-corrosion sealing wax and preparation method thereof |
| CN109468000A (en) * | 2018-08-31 | 2019-03-15 | 杭州立威化工涂料有限公司 | High-performance environment-friendly aqueous one-component finishing coat and production technology on a kind of plastic rubber substrate |
| CN109608957A (en) * | 2018-11-20 | 2019-04-12 | 河北晨阳工贸集团有限公司 | Special-purpose aqueous quick-drying single-component epoxy paint of house ornamentation and preparation method thereof |
| CN109913099A (en) * | 2019-03-07 | 2019-06-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous one-component epoxy-based lacquers and preparation method thereof |
| CN110093082A (en) * | 2019-04-23 | 2019-08-06 | 常州达奥新材料科技有限公司 | A kind of preparation method of metal furniture aqueous composite paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528835A (en) * | 2003-10-14 | 2004-09-15 | 顺德鸿昌化工有限公司 | Single-component room-temperature industrial water crosslinked coating |
| CN101544717A (en) * | 2009-04-27 | 2009-09-30 | 华南理工大学 | Styrene-acrylic microemulsion surface sizing agent with high solid content and core shell structure and preparation method and application thereof |
| CN103145913A (en) * | 2013-03-19 | 2013-06-12 | 西北师范大学 | Epoxy acrylate copolymer emulsion and preparation and use thereof in production of humidifying paint for internal wall |
| CN106221458A (en) * | 2016-08-30 | 2016-12-14 | 河北晨阳工贸集团有限公司 | A kind of steel construction special anti-corrosion sealing wax and preparation method thereof |
| CN106833299A (en) * | 2017-02-24 | 2017-06-13 | 广州集泰化工股份有限公司 | A kind of single-component water-based container intermediate coat and its preparation technology |
-
2017
- 2017-06-21 CN CN201710473954.8A patent/CN107227088A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528835A (en) * | 2003-10-14 | 2004-09-15 | 顺德鸿昌化工有限公司 | Single-component room-temperature industrial water crosslinked coating |
| CN101544717A (en) * | 2009-04-27 | 2009-09-30 | 华南理工大学 | Styrene-acrylic microemulsion surface sizing agent with high solid content and core shell structure and preparation method and application thereof |
| CN103145913A (en) * | 2013-03-19 | 2013-06-12 | 西北师范大学 | Epoxy acrylate copolymer emulsion and preparation and use thereof in production of humidifying paint for internal wall |
| CN106221458A (en) * | 2016-08-30 | 2016-12-14 | 河北晨阳工贸集团有限公司 | A kind of steel construction special anti-corrosion sealing wax and preparation method thereof |
| CN106833299A (en) * | 2017-02-24 | 2017-06-13 | 广州集泰化工股份有限公司 | A kind of single-component water-based container intermediate coat and its preparation technology |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359354A (en) * | 2018-01-24 | 2018-08-03 | 河北晨阳工贸集团有限公司 | A kind of mechanical equipment anti-corrosion sealing wax and preparation method thereof |
| CN109468000A (en) * | 2018-08-31 | 2019-03-15 | 杭州立威化工涂料有限公司 | High-performance environment-friendly aqueous one-component finishing coat and production technology on a kind of plastic rubber substrate |
| CN109608957A (en) * | 2018-11-20 | 2019-04-12 | 河北晨阳工贸集团有限公司 | Special-purpose aqueous quick-drying single-component epoxy paint of house ornamentation and preparation method thereof |
| CN109913099A (en) * | 2019-03-07 | 2019-06-21 | 河北晨阳工贸集团有限公司 | A kind of aqueous one-component epoxy-based lacquers and preparation method thereof |
| CN110093082A (en) * | 2019-04-23 | 2019-08-06 | 常州达奥新材料科技有限公司 | A kind of preparation method of metal furniture aqueous composite paint |
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