CN107225883A - One kind decoration antibacterial type heat transfer film and preparation method thereof - Google Patents
One kind decoration antibacterial type heat transfer film and preparation method thereof Download PDFInfo
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- CN107225883A CN107225883A CN201710479532.1A CN201710479532A CN107225883A CN 107225883 A CN107225883 A CN 107225883A CN 201710479532 A CN201710479532 A CN 201710479532A CN 107225883 A CN107225883 A CN 107225883A
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- antibacterial
- heat transfer
- transfer film
- coated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38207—Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
- B41M5/38214—Structural details, e.g. multilayer systems
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- Optics & Photonics (AREA)
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Abstract
The invention belongs to printing technology, specifically related to a kind of decoration uses antibacterial type heat transfer film, its by PET basement membranes, be coated in the back coating of PET basement membrane one sides, and be coated in successively from inside to outside PET basement membrane another sides release layer, antibacterial hard formation, grain pattern layer, background color layer and glue layer composition;The antibacterial hard formation mixes coating by the raw material of following weight percentage and is made:Nano zine oxide 5-10%, antiseptic 0.5-3%, surplus is thermosetting resin.Decoration of the present invention both has various wood textures with heat transfer film, can play long-term antibacterial effect in use again.Compared with general decor film, heat transfer film of the present invention not only has good dicoration and usability, and is more beneficial for health, therefore with very high market popularization value.
Description
Technical field
The invention belongs to printing technology, and in particular to a kind of heat transfer film for dalle for having a bacteria resistance function
And preparation method thereof.
Background technology
With the fast development of decoration industry, the function to ornament materials proposes higher and higher requirement, promotes simultaneously
The technological innovation and development of building and ornament materials enterprises.Nanometer technology is widely used in building materials field.New technology
Application not only increase original material property, more assign the use function of original material newly, the i.e. high performance and height of material
Functionalization.New material not only has a good dicoration and usability, and it is harmless, pollution-free, be conducive to health.
Therefore.Environment protection health decoration material has turned into the focus that building materials develop, and environment protection health decoration material product also turns into 21 century master
The consumer products led.
Bacteriostatic agent has the advantages that high heat resistance, long-term antimicrobial efficiency, nontoxic.So ideal in building materials application.
Antibacterial material is the healthy building materials of novel environment friendly.Antibacterial material realizes sterilization or suppresses micro- by the antimicrobial component of product surface
Biological growth and breeding are so as to reach long-term hygienic, the purpose of safety.The product being made of anti-biotic material, work(is bought with health certainly
Can, its antibiotic property can be synchronous with product life.Anti-biotic material has been widely used in developed country.China is in the starting stage,
Antibacterial product will can form a new spending spree in China in the near future.At present, not yet it is related to antibacterial material
Expect the report for heat transfer film.
The content of the invention
Present invention aims to overcome that there is provided a kind of decoration antibacterial type heat transfer film, the thermal transfer for prior art defect
Film can play long-term antibacterial effect in use, beneficial to health.
Present invention also offers preparation method of the above-mentioned decoration with antibacterial type heat transfer film.
One kind decoration uses antibacterial type heat transfer film, its by PET basement membranes, be coated in the back coatings of PET basement membrane one sides, Yi Jiyou
It is coated in release layer, antibacterial hard formation, the grain pattern layer, background color layer and glue layer composition of PET basement membrane another sides successively from inside to outside;
The antibacterial hard formation mixes coating by the raw material of following weight percentage and is made:Nano zine oxide 5-10%, antiseptic 0.5-
3%, surplus is thermosetting resin, and specifically nano zine oxide, antiseptic can be dispersed in thermosetting resin, is mixed, and coating is
Can.
Specifically, the thermosetting resin is melmac, the antiseptic is A.SAP antiseptics, can be direct
Buy ordinary commercial products.
The preparation method of above-mentioned decoration antibacterial type heat transfer film, it comprises the following steps:
1)Back coating is coated with the surface of PET basement membranes side, drying enters subsequent processing;
2)Release layer is coated with the surface of PET basement membrane other sides, drying enters subsequent processing;
3)Antibacterial hard formation is coated with release layer surface, drying enters subsequent processing;
4)In antibacterial hard formation surface printing grain pattern layer, drying enters subsequent processing;
5)Background color layer is printed on grain pattern layer surface, dries, enters subsequent processing;
6)In background color layer surface brush coating water, drying produces decoration antibacterial type heat transfer film.
The present invention is in the coated on one side back coating of PET film, and another side precoats mould release, antibacterial hard formation successively, then uses
The printing-ink material of different colours is printed on antibacterial hard formation surface, prints out wood texture and obtains simulated grain patterned layer, so
After republish background color layer and glue, so that antibacterial heat transfer film truly is made.
In the present invention, back coating, release layer, grain pattern layer and background color layer raw material according to this area routine techniques carry out
Preparation, wherein, the raw material composition of background color layer is preferably identical with the chromatograph ink in grain pattern layer in the present invention.The present invention
Innovative point be to add the antibacterial hard formation containing antibacterial material in heat transfer film.Decoration heat transfer film of the present invention both had
Various wood textures, long-term antibacterial effect can be played in use again.Compared with general decor film, heat transfer film of the present invention is not
But there is good dicoration and usability, and be more beneficial for health, therefore with very high market popularization value.This
Outside, it can be used after heat transfer film of the present invention is directly coated with, preparation method is simple, production efficiency is high, easy to operate.
Brief description of the drawings
Fig. 1 is the structural representation of decoration antibacterial type heat transfer film of the present invention;In figure, 1 is back coating, and 2 be release layer,
3 be antibacterial hard formation, 4 grain patterns layer, and 5 be background color layer, and 6 be glue layer.
Embodiment
With reference to specific embodiment, the present invention will be further described, but protection scope of the present invention is not limited to this.
In following embodiments, heat-curable melamine resins emulsion used is purchased from the Guangzhou still limited public affairs of river new material science and technology
Department, model MH-7303, solid content 98%.Nano zine oxide, A.SAP antiseptics are ordinary commercial products.
Embodiment 1
As shown in figure 1, a kind of decoration uses antibacterial type heat transfer film, its by PET basement membranes, be coated in the back coatings of PET basement membrane one sides
1, and it is coated in release layer 2, antibacterial hard formation 3, the grain pattern layer 4 of PET basement membrane another sides, background color layer 5 successively from inside to outside
Constituted with glue layer 6.The antibacterial hard formation mixes coating by following weight parts raw material and is made:5 parts of nano zine oxide, A.SAP resists
1 part of microbial inoculum, 94 parts of heat-curable melamine resins emulsion.
The preparation method of above-mentioned decoration antibacterial type heat transfer film, it comprises the following steps:1)Table in PET basement membranes side
Face is coated with back coating, and drying enters subsequent processing;2)Release layer is coated with the surface of PET basement membrane other sides, drying is entered
Enter to subsequent processing;3)By nano zine oxide, A.SAP antiseptics and heat-curable melamine resins emulsion in high speed dispersion condition
It is lower well mixed, then it is coated on release layer surface and forms antibacterial hard formation, dries, enter subsequent processing;4)In antibacterial hard formation
Surface printing grain pattern layer, drying enters subsequent processing;5)Background color layer is printed on grain pattern layer surface, dries, enters
Enter to subsequent processing;6)In background color layer surface brush coating water, drying produces decoration antibacterial type heat transfer film.
Embodiment 2
One kind decoration uses antibacterial type heat transfer film, its by PET basement membranes, the back coatings of PET basement membrane one sides is coated in, and by introversion
Outer release layer, antibacterial hard formation, the grain pattern layer for being coated in PET basement membrane another sides successively, background color layer and glue layer composition.It is described
Antibacterial hard formation mixes coating by following weight parts raw material and is made:10 parts of nano zine oxide, 3 parts of A.SAP antiseptics, thermosetting trimerization
87 parts of melamine resin emulsion.
Above-mentioned decoration is with the preparation method of antibacterial type heat transfer film with reference to embodiment 1.
Embodiment 3
One kind decoration uses antibacterial type heat transfer film, its by PET basement membranes, the back coatings of PET basement membrane one sides is coated in, and by introversion
Outer release layer, antibacterial hard formation, the grain pattern layer for being coated in PET basement membrane another sides successively, background color layer and glue layer composition.It is described
Antibacterial hard formation mixes coating by following weight parts raw material and is made:8 parts of nano zine oxide, 0.5 part of A.SAP antiseptics, thermosetting three
91.5 parts of cymel emulsion.
Above-mentioned decoration is with the preparation method of antibacterial type heat transfer film with reference to embodiment 1.
Using test
The decoration made according to embodiment 1-3 is with antibacterial type heat transfer film sample, and as a result the tracing detection after transfer shows:This
Invention decoration antibacterial type heat transfer film product, to staphylococcus aureus, Escherichia coli, aspergillus flavus, Aspergillus terreus after transfer
There is inhibitory action etc. a variety of moulds, and fungistatic effect is up to more than 10 years.
Contain in addition, show in particular the different percentages of raw material nano zine oxide in antibacterial hard formation, A.SAP antiseptics in table 1 below
During amount, the fungistatic effect of gained decoration antibacterial type heat transfer film product is prepared.
The antibacterial Detection results of table 1
Time | Without bacteriostatic agent | Nano zine oxide 5%, antiseptic 0.5% | Nano zine oxide 8%, antiseptic 2% | Nano zine oxide 10%, antiseptic 3% |
1 week | 60 bacterium colonies/square decimeter | 1 bacterium colony/square decimeter | 0 bacterium colony/square decimeter | 0 bacterium colony/square decimeter |
January | 105 bacterium colonies/square decimeter | 5 bacterium colonies/square decimeter | 2 bacterium colonies/square decimeter | 0 bacterium colony/square decimeter |
June | 150 bacterium colonies/square decimeter | 11 bacterium colonies/square decimeter | 6 bacterium colonies/square decimeter | 1 bacterium colony/square decimeter |
1 year | 200 bacterium colonies/square decimeter | 35 bacterium colonies/square decimeter | 12 bacterium colonies/square decimeter | 3 bacterium colonies/square decimeter |
Claims (3)
1. one kind decoration use antibacterial type heat transfer film, it is characterised in that by PET basement membranes, be coated in PET basement membrane one sides the back of the body painting
Layer, and it is coated in release layer, antibacterial hard formation, the grain pattern layer, background color layer and glue of PET basement membrane another sides successively from inside to outside
Water layer is constituted;The antibacterial hard formation mixes coating by the raw material of following weight percentage and is made:Nano zine oxide 5-10%, antibacterial
Agent 0.5-3%, surplus is thermosetting resin.
2. decoration as claimed in claim 1 uses antibacterial type heat transfer film, it is characterised in that the thermosetting resin is melamine
Polyimide resin, the antiseptic is A.SAP antiseptics.
3. the preparation method of decoration antibacterial type heat transfer film described in claim 1 or 2, it is characterised in that comprise the following steps:
1)Back coating is coated with the surface of PET basement membranes side, drying enters subsequent processing;
2)Release layer is coated with the surface of PET basement membrane other sides, drying enters subsequent processing;
3)Antibacterial hard formation is coated with release layer surface, drying enters subsequent processing;
4)In antibacterial hard formation surface printing grain pattern layer, drying enters subsequent processing;
5)Background color layer is printed on grain pattern layer surface, dries, enters subsequent processing;
6)In background color layer surface brush coating water, drying produces decoration antibacterial type heat transfer film.
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CN201710479532.1A CN107225883A (en) | 2017-06-22 | 2017-06-22 | One kind decoration antibacterial type heat transfer film and preparation method thereof |
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CN201710479532.1A CN107225883A (en) | 2017-06-22 | 2017-06-22 | One kind decoration antibacterial type heat transfer film and preparation method thereof |
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CN1737681A (en) * | 2004-08-16 | 2006-02-22 | 富士施乐株式会社 | Sheet for forming process and method for manufacturing the same, image forming method, method for manufacturing forming processed product and the forming processed product |
CN101554811A (en) * | 2008-08-25 | 2009-10-14 | 义乌市鼎盛印刷有限公司 | Water-based heat transfer film |
CN101570090A (en) * | 2009-06-01 | 2009-11-04 | 莫国平 | Production method of environment-friendly water-soluble gum electrochemical aluminothermic transfer printing film |
CN101676120A (en) * | 2008-09-16 | 2010-03-24 | 株式会社理光 | Thermosensitive recording medium with antibacterial property |
US20140141182A1 (en) * | 2011-10-24 | 2014-05-22 | Precision Dynamics Corporation | Identification device having antimicrobial properties |
CN203844435U (en) * | 2014-05-15 | 2014-09-24 | 库尔兹压烫科技(合肥)有限公司 | Anti-scrubbing wood grain hot stamping foil |
CN104129186A (en) * | 2014-07-09 | 2014-11-05 | 河南卓立膜材料股份有限公司 | Technology transfer film with unsmooth hand feeling and manufacturing method thereof |
CN105398247A (en) * | 2015-12-08 | 2016-03-16 | 广西北流神通镭射装饰材料有限公司 | High bright leather transfer film process |
CN205970443U (en) * | 2016-08-26 | 2017-02-22 | 苏州工业园区莱博特瑞新材料科技有限公司 | Membrane material printing surface is from type coating |
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2017
- 2017-06-22 CN CN201710479532.1A patent/CN107225883A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1737681A (en) * | 2004-08-16 | 2006-02-22 | 富士施乐株式会社 | Sheet for forming process and method for manufacturing the same, image forming method, method for manufacturing forming processed product and the forming processed product |
CN101554811A (en) * | 2008-08-25 | 2009-10-14 | 义乌市鼎盛印刷有限公司 | Water-based heat transfer film |
CN101676120A (en) * | 2008-09-16 | 2010-03-24 | 株式会社理光 | Thermosensitive recording medium with antibacterial property |
CN101570090A (en) * | 2009-06-01 | 2009-11-04 | 莫国平 | Production method of environment-friendly water-soluble gum electrochemical aluminothermic transfer printing film |
US20140141182A1 (en) * | 2011-10-24 | 2014-05-22 | Precision Dynamics Corporation | Identification device having antimicrobial properties |
CN203844435U (en) * | 2014-05-15 | 2014-09-24 | 库尔兹压烫科技(合肥)有限公司 | Anti-scrubbing wood grain hot stamping foil |
CN104129186A (en) * | 2014-07-09 | 2014-11-05 | 河南卓立膜材料股份有限公司 | Technology transfer film with unsmooth hand feeling and manufacturing method thereof |
CN105398247A (en) * | 2015-12-08 | 2016-03-16 | 广西北流神通镭射装饰材料有限公司 | High bright leather transfer film process |
CN205970443U (en) * | 2016-08-26 | 2017-02-22 | 苏州工业园区莱博特瑞新材料科技有限公司 | Membrane material printing surface is from type coating |
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Application publication date: 20171003 |