CN107216835A - A kind of improved quick-drying pressure sensitive adhesive and preparation method thereof - Google Patents
A kind of improved quick-drying pressure sensitive adhesive and preparation method thereof Download PDFInfo
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- CN107216835A CN107216835A CN201710457427.8A CN201710457427A CN107216835A CN 107216835 A CN107216835 A CN 107216835A CN 201710457427 A CN201710457427 A CN 201710457427A CN 107216835 A CN107216835 A CN 107216835A
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- sensitive adhesive
- pressure sensitive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of improved quick-drying pressure sensitive adhesive, calculate by weight, alcohol-soluble resin, 50 80 parts of alkaline silica sol, 0.05 0.1 parts of levelling agents, 1 10 parts of wetting agent, 0.2 1 parts of defoamer and the 10 50 parts of alcoholic solvents being modified by 50 80 parts of newtrexes are constituted.Present invention also offers the preparation method of above-mentioned pressure sensitive adhesive.The characteristics of improved quick-drying pressure sensitive adhesive of the present invention has fast rate of drying, tack, holds viscosity and high 180 peel strengths.It can be applied to can be used for the fields such as diaper, woman article, two-sided tape, label, packaging, health care, bookbinding, surface protection film, timber processing, wallpaper and shoemaking.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of improved quick-drying pressure sensitive adhesive and its preparation side
Method.
Background technology
Pressure sensitive adhesive is that a class is slightly exerted pressure and can just be bonded at the binder on other surfaces.Pressure sensitive adhesive physical characteristic is gluing
Band is pasted on adherend, and when peeling off, pressure sensitive adhesive must completely disengage from adherend and noresidue, must meet following condition：Quickstick
Power<Bonding force<Base adhesion force<Cohesive force.It is commonly divided into solvent pressure-sensitive adhesive and solvent-free property pressure sensitive adhesive.No-solvent type pressure
Quick glue is in production without using solvent, predominantly hot-fusible pressure-sensitive adhesive and UV solidified pressure-sensitives.Hot-fusible pressure-sensitive adhesive, which need to be heated, to be applied
Cloth.UV solidified pressure-sensitives then need, by the method such as ultraviolet (UV) or electron beam (EB) irradiation, to be crosslinked oligomer
Pressure-sensitive adhesive product is made.Solvent pressure-sensitive adhesive can be divided into again according to its type of solvent emulsion based pressure sensitive using water as solvent and with
Organic solvent is the solvent pressure-sensitive adhesive of solvent.Solvent pressure-sensitive adhesive, it has excellent pressure-sensitive and cementability, and due to resistance to
Aging, light resistance, water resistance, oil resistivity are excellent, so almost no rheological parameters' change with time causes the problem of pressure-sensitive declines, and
And removability is excellent, but it is increasingly strict with environmental law, and being unsatisfactory for the solvent pressure-sensitive adhesive of environmental requirement has by other
The trend of pressure sensitive adhesive substitution.Emulsion-type pressure-sensitive have cost it is low, using it is safe and pollution-free the features such as, but because it contains emulsification
Agent, its water resistance is low, heat resistance is poor, due to making solvent with water, so drying time is long, is unsatisfactory for some industry and quickly applies
The need for work.Be badly in need of exploitation it is a kind of have fast dry characteristic, meet environmental requirement, it is easy construction, with low cost, excellent performance
Pressure sensitive adhesive.
The content of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of improved quick-drying pressure sensitive adhesive and its preparation
Method, it is water-fast that described this improved quick-drying pressure sensitive adhesive and preparation method thereof will solve emulsion-type pressure-sensitive of the prior art
The low, heat resistance of property is poor, drying time length technical problem.
The invention provides a kind of improved quick-drying pressure sensitive adhesive, calculate by weight, its raw material composition and content are as follows：
50-80 parts of the alcohol-soluble resin that newtrex is modified；
10-30 parts of alkaline silica sol；
0.05-0.1 parts of levelling agent；
1-10 parts of wetting agent；
0.2-1 parts of defoamer；
10-50 parts of alcoholic solvent；
Wherein, the alcohol-soluble resin that described newtrex is modified is the alcohol-soluble self-crosslinking acrylic ester tree that newtrex is modified
Fat；
Described alkaline silica sol is alkaline alcohol-soluble Ludox；
Described wetting agent is any one in the NP-100 or Germany's levelling agents of BYK 333 of LG-DOW company or two kinds
Mixture；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described alcoholic solvent is any one in ethanol, propyl alcohol, butanol, propane diols, glycerine or two or more mixtures；
Described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344,
Any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；Described froth breaking
Agent is in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038
Any one or two or more mixtures.
Present invention also offers a kind of preparation method of above-mentioned improved quick-drying pressure sensitive adhesive, comprise the following steps：According to
Formula, adds wetting agent, levelling agent, defoamer in high speed dispersor, will after disperseing 15-20min under 600r/min rotating speeds
Rotating speed is down to 300r/min, adds alcohol-soluble resin, alkaline alcohol-soluble Ludox and alcoholic solvent that newtrex is modified, continues to divide
5-10min is dissipated, is well mixed, that is, obtains improved quick-drying pressure sensitive adhesive.
The present invention is by glass transition temperature due to the alcohol-soluble self-crosslinking acrylic ester resin that the newtrex of addition is modified
Relatively low soft monomer, glass transition temperature and have hardness hard monomer, monomer's copolymerization it is aggregated it is Abietyl modified form, make pressure-sensitive
Glue plays adhesive attraction, possesses pressure-sensitive, cohesive performance is greatly improved, and monomer makes pressure sensitive adhesive strand produce crosslinking, right
The raising of cohesive strength and adhesive property serves not small.Alkaline alcohol-soluble Ludox adds the rate of drying of pressure sensitive adhesive, carries
Rise the cohesive strength of pressure sensitive adhesive and hold viscosity.
When the present invention determines the drying of pressure sensitive adhesive according to GB/T 1728-1979 " paint film, putty membrane drying time determination method "
Between be 25-47min.
The present invention is according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., oblique in self-control
On face (30o), a series of not equal steel balls of diameter are rolled down from big to small, by the pressure-sensitive adhesive for being placed on skewback lower end
Band, the maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.It is right
The initial adhesion force of made improved quick-drying pressure sensitive adhesive is measured, and initial adhesion force is 18-19 steel balls.
180 ° of peel strengths newly think carefully the CMT5104 electronic tension testers of company at room temperature according to GB/ using Shenzhen
T 2792-1998 standards " 180 ° of peeling strength test methods of pressure-sensitive tape " are determined.Pressure sensitive adhesive tape is attached to stainless steel substrate
（50 mm×125 mm）On, rolled back and forth three times with the Manual pressure roller of 2 kg weights, peel test carried out after placing 20 min,
Peeling rate is 300mm/min, and reading is simultaneously recorded.Parallel testing five times, averages.Improved quick-drying to preparation is pressure-sensitive
Glue carries out 180 ° of peel strength tests, and peel strength is 15.3-17.8N/25mm.
The present invention is surveyed according to GB/T 4851-1998 " pressure-sensitive tape holds viscosity test method " standard using holding power
Instrument is tried to determine.By pressure sensitive adhesive tape patch on stainless steel, rolled back and forth three times with 2 kg Manual pressure roller, place 20 min
Vertically hang afterwards on test stand, lower end hangs 1 kg counterweight, the time that record sample is completely disengaged from.Parallel testing three times,
Average.Viscous force is held for 15-19h.
The present invention is compared with prior art, and its technological progress is significant.The present invention have rate of drying fast, tack,
The characteristics of holding viscosity and high 180 peel strengths；It is easy to control and the technique of the present invention is simple, quick, environmental protection.Can be applied to can
For diaper, woman article, two-sided tape, label, packaging, health care, bookbinding, surface protection film, timber processing, wall
The field such as paper and shoemaking.
Embodiment
The present invention is described in further detail below by embodiment, but is not intended to limit the present invention.
In raw material used in various embodiments of the present invention in addition to the special producer shown and specification, other raw materials be it is commercially available,
Specification is that chemistry is pure.
The model of various equipment used in the present invention and the information of manufacturer are as follows：
GFJ-0.4 type high speed dispersors, the new promise experimental instruments and equipment limited production in Shanghai.
Embodiment 1
A kind of improved quick-drying pressure sensitive adhesive, is calculated by weight, and its raw material composition and content are as follows：
50 parts of the alcohol-soluble resin that newtrex is modified
10 parts of alkaline silica sol
0.05 part of levelling agent
1 part of wetting agent
0.2 part of defoamer
10 parts of alcoholic solvent
The alcohol-soluble resin that wherein described newtrex is modified is calculated by weight, and it is constituted and content is as follows：
10 parts of mix monomer
3 parts of newtrex
60 parts of solvent
0.2 part of thermal initiator
The alcohol-soluble resin that described newtrex is modified is prepared as follows：Equipped with stirring, four mouthfuls of burnings of condensing reflux
All 60 parts of absolute ethyl alcohols are added in bottle and are used as solvent and 3 parts of mix monomers（Butyl acrylate, methyl methacrylate, methyl
Acrylic acid, VTES in mass ratio 45：11：10：3）, nitrogen protection is passed through, it is 300r/ to control mixing speed
min.3 parts of newtrexes are dissolved with remaining mix monomer and thermal initiator BPO is configured to initiator solution.When temperature rises to 80 DEG C
When, first add a quarter initiator solution.Supplement remaining initiator solution in 3 hours in batches, initiator completion of dropping with
Afterwards, then react after one hour.Question response is cooled to room temperature afterwards completely, produces the alcohol-soluble resin of newtrex modification.
Described alkaline silica sol is alkaline alcohol-soluble Ludox；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described alcoholic solvent is ethanol and propane diols in mass ratio 1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of improved quick-drying pressure sensitive adhesive specifically includes following steps：
According to formula, in GFJ-0.4 type high speed dispersors（The new promise experimental instruments and equipment limited in Shanghai）Middle 1 part of wetting agent of addition,
0.05 part of levelling agent, 0.2 part of defoamer, 300r/min is down to after disperseing 15min under 600r/min rotating speeds by rotating speed, adds 50
Alcohol-soluble resin, 10 parts of alkaline silica sols, 10 parts of alcoholic solvents that part newtrex is modified, continue scattered 10min, are well mixed,
Obtain improved quick-drying pressure sensitive adhesive.
Further, drying time GB/T 1728-1979 " paint film, putty membrane drying time determination method " determine pressure sensitive adhesive
Drying time be 25min；
According to by according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., on self-control inclined-plane
On (30o), a series of not equal steel balls of diameter are rolled down from big to small, by being placed on the pressure-sensitive tape of skewback lower end,
The maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.To made
The initial adhesion force of improved quick-drying pressure sensitive adhesive is measured, and the results are shown in Table 1.
Further, determined according to GB/T 2792-1998 standards " the peeling strength test method of pressure-sensitive tape 180 ".
Pressure sensitive adhesive tape is attached to stainless steel substrate（50 mm×125 mm）On, rolled three times, put back and forth with the Manual pressure roller of 2 kg weights
Put and peel test is carried out after 20 min, peeling rate is 300mm/min, reading is simultaneously recorded.Parallel testing five times, is averaged
Value.180 ° of peel strength tests are carried out to the improved quick-drying pressure sensitive adhesive of preparation, 1 is the results are shown in Table.
According to GB/T 4851-1998, " pressure-sensitive tape holds sticky examination to improved quick-drying pressure sensitive adhesive obtained by the present embodiment
Proved recipe method " standard, is determined using holding power tester.By pressure sensitive adhesive tape patch on stainless steel, with 2 kg Manual pressure roller come
Rollback is pressed three times, is vertically hung after placing 20 min on test stand, and lower end hangs 1 kg counterweight, and record sample is complete
The time of disengaging.Parallel testing three times, averages.Testing result is shown in Table 1.
Improved quick-drying pressure sensitive adhesive drying time of the gained of above example 1 is short, tack, hold viscosity and 180 peel off it is strong
Degree is higher.
The performance of the pressure sensitive adhesive of table 1
| Embodiment | Drying time, min | Tack/steel ball number | Hold viscosity/h | 180 peel strengths（N/25mm） |
| Embodiment 1 | 25 | 18 | 15 | 15.3 |
| Embodiment 2 | 47 | 19 | 19 | 17.8 |
Embodiment 2
A kind of improved quick-drying pressure sensitive adhesive, is calculated by weight, and its raw material composition and content are as follows：
80 parts of the alcohol-soluble resin that newtrex is modified
30 parts of alkaline silica sol
0.1 part of levelling agent
10 parts of wetting agent
1 part of defoamer
50 parts of alcoholic solvent
The alcohol-soluble resin that wherein described newtrex is modified is calculated by weight, and it is constituted and content is as follows：
10 parts of mix monomer
5 parts of newtrex
60 parts of solvent
0.2 part of thermal initiator
The alcohol-soluble resin that described newtrex is modified is prepared as follows：Equipped with stirring, four mouthfuls of burnings of condensing reflux
All 60 parts of absolute ethyl alcohols are added in bottle and are used as solvent and 3 parts of mix monomers（Butyl acrylate, methyl methacrylate, methyl
Acrylic acid, VTES in mass ratio 45：11：10：3）, nitrogen protection is passed through, it is 300r/ to control mixing speed
min.5 parts of newtrexes are dissolved with remaining mix monomer and thermal initiator BPO is configured to initiator solution.When temperature rises to 80 DEG C
When, first add a quarter initiator solution.Supplement remaining initiator solution in 3 hours in batches, initiator completion of dropping with
Afterwards, then react after one hour.Question response is cooled to room temperature afterwards completely, produces the alcohol-soluble resin of newtrex modification.
Described alkaline silica sol is alkaline alcohol-soluble Ludox；
Described levelling agent is the high Tego Glide 410 of enlightening；
Described wetting agent is the NP-100 of LG-DOW company；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described alcoholic solvent is ethanol and propane diols in mass ratio 1:The mixture of 1 composition；
In the present embodiment, a kind of preparation method of improved quick-drying pressure sensitive adhesive specifically includes following steps：
According to formula, in GFJ-0.4 type high speed dispersors（The new promise experimental instruments and equipment limited in Shanghai）Middle 10 parts of wetting agents of addition,
0.1 part of levelling agent, 1 part of defoamer, 300r/min is down to after disperseing 15min under 600r/min rotating speeds by rotating speed, adds 80 parts
Alcohol-soluble resin, 30 parts of alkaline silica sols, the 50 parts of alcoholic solvents of newtrex modification, continue scattered 10min, are well mixed, i.e.,
Obtain improved quick-drying pressure sensitive adhesive.
Further, drying time GB/T 1728-1979 " paint film, putty membrane drying time determination method " determine pressure sensitive adhesive
Drying time be 47min；
According to by according to GB/T4852-2002 " pressure-sensitive tape tack test method (rolling ball method) ", i.e., on self-control inclined-plane
On (30o), a series of not equal steel balls of diameter are rolled down from big to small, by being placed on the pressure-sensitive tape of skewback lower end,
The maximum steel ball on inclined-plane can wherein be stopped at completely by finding out, and the initial cohesiveness of pressure sensitive adhesive is measured with the number N of steel ball.To made
The initial adhesion force of improved quick-drying pressure sensitive adhesive is measured, and the results are shown in Table 1.
Further, determined according to GB/T 2792-1998 standards " the peeling strength test method of pressure-sensitive tape 180 ".
Pressure sensitive adhesive tape is attached to stainless steel substrate（50 mm×125 mm）On, rolled three times, put back and forth with the Manual pressure roller of 2 kg weights
Put and peel test is carried out after 20 min, peeling rate is 300mm/min, reading is simultaneously recorded.Parallel testing five times, is averaged
Value.180 ° of peel strength tests are carried out to the improved quick-drying pressure sensitive adhesive of preparation, 1 is the results are shown in Table.
According to GB/T 4851-1998, " pressure-sensitive tape holds sticky examination to improved quick-drying pressure sensitive adhesive obtained by the present embodiment
Proved recipe method " standard, is determined using holding power tester.By pressure sensitive adhesive tape patch on stainless steel, with 2 kg Manual pressure roller come
Rollback is pressed three times, is vertically hung after placing 20 min on test stand, and lower end hangs 1 kg counterweight, and record sample is complete
The time of disengaging.Parallel testing three times, averages.Test result is shown in Table 1.
Improved quick-drying pressure sensitive adhesive drying time of the gained of above example 2 is short, tack, hold viscosity and 180 peel strengths compared with
It is high.
In summary, improved quick-drying pressure sensitive adhesive of the invention uses alcohol-soluble formula, and the high speed volatilization of ethanol is carried
Its curing rate, only a few minutes, the problem of effectively overcoming pressure sensitive adhesive slow drying speed are risen.A modification of the present invention
Quick-drying pressure sensitive adhesive, as main film forming substance newtrex be modified alcohol-soluble resin molecular structure be organosilicon structures,
With very low surface energy, the interaction between film and base material is reduced, is allowed to embody preferably from fissility, is not required to add again
Plus stripping auxiliary agent,
Above said content is only the basic explanation under present inventive concept, and according to technical scheme made it is any etc.
Effect conversion, all should belong to protection scope of the present invention.
Claims (2)
1. a kind of improved quick-drying pressure sensitive adhesive, it is characterised in that calculate by weight, its raw material composition and content are as follows：
50-80 parts of the alcohol-soluble resin that newtrex is modified；
10-30 parts of alkaline silica sol；
0.05-0.1 parts of levelling agent；
1-10 parts of wetting agent；
0.2-1 parts of defoamer；
10-50 parts of alcoholic solvent；
Wherein, the alcohol-soluble resin that described newtrex is modified is the alcohol-soluble self-crosslinking acrylic ester tree that newtrex is modified
Fat；
Described alkaline silica sol is alkaline alcohol-soluble Ludox；
Described wetting agent is any one in the NP-100 or Germany's levelling agents of BYK 333 of LG-DOW company or two kinds
Mixture；
Described defoamer is the Nopco NXZ of Henkel KGaA company；
Described alcoholic solvent is any one in ethanol, propyl alcohol, butanol, propane diols, glycerine or two or more mixtures；
Described levelling agent be selected from the high Tego Glide 410 of enlightening, Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344,
Any one in BYK-345, BYK-346, BYK-347 or BYK-348 or two or more mixtures；Described froth breaking
Agent is in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038
Any one or two or more mixtures.
2. the preparation method of a kind of improved quick-drying pressure sensitive adhesive described in claim 1, it is characterised in that comprise the following steps：Press
According to formula, wetting agent, levelling agent, defoamer are added in high speed dispersor, after disperseing 15-20min under 600r/min rotating speeds
Rotating speed is down to 300r/min, alcohol-soluble resin, alkaline alcohol-soluble Ludox and alcoholic solvent that newtrex is modified is added, continues
Scattered 5-10min, is well mixed, that is, obtains improved quick-drying pressure sensitive adhesive.
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| CN201710457427.8A CN107216835A (en) | 2017-06-16 | 2017-06-16 | A kind of improved quick-drying pressure sensitive adhesive and preparation method thereof |
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| CN102226067A (en) * | 2011-05-16 | 2011-10-26 | 永一胶粘(中山)有限公司 | Acrylate solvent-based pressure sensitive adhersive and product thereof |
| CN102516906A (en) * | 2011-12-16 | 2012-06-27 | 北京石油化工学院 | Method for preparing ethanol-soluble laminating adhesive |
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2017
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| CN101613434A (en) * | 2009-07-15 | 2009-12-30 | 华南理工大学 | A kind of alcohol soluble polyacrylate resin and preparation method thereof and application |
| CN101818033A (en) * | 2010-01-22 | 2010-09-01 | 北京高盟新材料股份有限公司 | Alcohol-soluble composite film adhesive and preparation method thereof |
| CN102226067A (en) * | 2011-05-16 | 2011-10-26 | 永一胶粘(中山)有限公司 | Acrylate solvent-based pressure sensitive adhersive and product thereof |
| CN102516906A (en) * | 2011-12-16 | 2012-06-27 | 北京石油化工学院 | Method for preparing ethanol-soluble laminating adhesive |
| CN103254857A (en) * | 2013-05-11 | 2013-08-21 | 北京化工大学 | Alcohol-soluble self-crosslinking acrylic resin adhesive and preparation method thereof |
| CN106118285A (en) * | 2016-06-20 | 2016-11-16 | 青岛乐化科技有限公司 | A kind of skin recoating heat-reflecting insulating coating and preparation method thereof |
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| 马榴强: "《精细化工工艺学》", 29 February 2008, 化学工业出版社 * |
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Application publication date: 20170929 |