CN107216828A - A kind of preparation method of Novel environmental-friendglue glue - Google Patents
A kind of preparation method of Novel environmental-friendglue glue Download PDFInfo
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- CN107216828A CN107216828A CN201710650118.2A CN201710650118A CN107216828A CN 107216828 A CN107216828 A CN 107216828A CN 201710650118 A CN201710650118 A CN 201710650118A CN 107216828 A CN107216828 A CN 107216828A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J101/00—Adhesives based on cellulose, modified cellulose, or cellulose derivatives
- C09J101/08—Cellulose derivatives
- C09J101/26—Cellulose ethers
- C09J101/28—Alkyl ethers
- C09J101/286—Alkyl ethers substituted with acid radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
Abstract
A kind of preparation method of Novel environmental-friendglue glue, including following preparation process：A, hydrolyzing silicon tetrachloride thing is washed with ethanol water, filtered after, by filter residue and defoamer Hybrid Heating and stir, refilter, filter residue is washed with sodium hydrate aqueous solution and obtains material one；B, will starch, drier, lignin and water mix after be beaten, be added dropwise sodium hydroxide solution regulation pH value, stirring, be added dropwise oxidant, after heating add catalyst stirring obtains material two；C, agar-agar, guar gum, Arabic gum and bleeding agent be well mixed, immersion obtains material three in water；D, by material one, material two, material three, carboxymethyl cellulose, emulsifying agent and odium stearate mix, heat and stir, add thickener, diffusant, after stirring, be cooled to normal temperature.The preparation technology of the present invention is simple and convenient to operate, with good economic benefit.
Description
Technical field
The invention belongs to glue manufacture technology field, and in particular to a kind of preparation method of Novel environmental-friendglue glue.
Background technology
Glue is the intermediate for connecting two kinds of materials, is occurred more with aqua, belongs to fine chemistry industry class, species is various, mainly with
Sizing, physical aspect, the sorting technique of method for curing and adherend material.Glue is exactly that can be bonded the material of two objects,
Glue is not self-existent, and it must be coated in the chemical composition in competence exertion bonding effect between two objects, glue,
In aqueous environments, the polymer body in glue is all rounded particle, and the radius of general particle is between 0.5~5 μm.Object
Bonding, realized by the pulling force between the polymer body in glue.In glue, water is exactly the load of middle polymer body
Body, water ballast polymer body and is immersed at leisure in the tissue of object.After the moisture in glue disappears, the macromolecule in glue
Body just relies on mutual pulling force, by two objects being combined together tightly.In glue in use, glue-spread excessively will
Make polymer body in glue mutually it is crowded together；Good pulling force is can not produce between polymer body.Polymer body is mutually gathered around
Squeeze, so as to not become most strong attraction each other.
The application of current glue is very extensive, and the consumption such as industry, agricultural, manufacturing industry, decorative craft of building is very big, especially
It is that the glue that decorative craft of building is used is how in the majority with the not environmentally glue containing free formaldehyde, although this kind of glue price is low, bonding
Performance is good；But formaldehyde is a kind of colourless intense irritation gas, is defined as carcinogenic and teratogen by the World Health Organization
Matter, and it has been included in glue banned substance.Undoubtedly, formaldehyde is to the toxic effect of the mankind, particularly if used in glue
Formaldehyde, then this kind of glue is indoors by after use, and Form aldehyde release is especially slow, all may be used indoors in environment even up to after the several years
To be tested with the presence of free formaldehyde, the injury for giving people to cause is irreversible, and many diseases of the clear and definite mankind have been all now
There is formaldehyde with interior relevant.
Therefore, the exploitation and application of new Environment-friendlyglue glue are very big progress for field of Environment Protection, are particularly adopted
That is developed with new manufacturing process is free of formaldehyde, safety and environmental protection, and the Environment-friendlyglue glue that will not be caused harm to human and environment will have
Very big market prospects.
The content of the invention
It is an object of the invention to provide a kind of preparation method of Novel environmental-friendglue glue, glue prepared by the present invention is free of formaldehyde
And toxic organic solvents, air and human body will not be caused harm, and it is good, wide using scope with bonding strength height, stability
The advantages of, glue preparation technology of the invention is simple and convenient to operate, with good economic benefit.
The invention provides following technical scheme：
A kind of preparation method of Novel environmental-friendglue glue, including following preparation process：
A, the ethanol water for being 30-45% with mass concentration by hydrolyzing silicon tetrachloride thing are washed 3-5 times, after filtering, by filter residue
Mixed with defoamer, heat and stir 30-40min, temperature is 60-80 DEG C, is refiltered 2-3 times, by filter residue sodium hydroxide water
It is 7-7.5 that solution, which is washed to pH value, obtains material one；
B, will starch, drier, lignin and water mix after be beaten, control temperature at 80-90 DEG C, then be added dropwise sodium hydroxide it is molten
Liquid, regulation pH value is 8-9, after stirring reaction 15-20min, and oxidant is added dropwise, and is warming up to 90-100 DEG C of reaction 20-25min, it
After add catalyst stirring 10-20min, obtain material two；
C, agar-agar, guar gum, Arabic gum and bleeding agent be well mixed, 5-8h is soaked in water, material three is obtained；
D, by material one, material two, material three, carboxymethyl cellulose, emulsifying agent and odium stearate mix, at 80-100 DEG C plus
Heat is simultaneously stirred, and mixing speed is 240-300r/min, after stirring 20-25min, and rise temperature adds thickening to 120-150 DEG C
Agent, diffusant, accelerate mixing speed to 500-600r/min, stir after 40-50min, be cooled to normal temperature, you can obtain finished product.
It is preferred that, the Novel environmental-friendglue glue includes the raw material of following parts by weight：17-24 parts of hydrolyzing silicon tetrachloride thing, disappear
8-13 parts of infusion, 25-35 parts of starch, 24-36 parts of drier, 18-24 parts of lignin, 23-30 parts of water, 12-15 parts of oxidant, urge
10-13 parts of agent, 14-17 parts of agar-agar, 8-12 parts of guar gum, 12-15 parts of Arabic gum, 13-16 parts of bleeding agent, carboxymethyl are fine
Tie up 7-11 parts of 22-28 parts of element, 13-15 parts of emulsifying agent, 17-19 parts of odium stearate, 11-14 parts of thickener and diffusant.
It is preferred that, the defoamer of the step a is any of dimethicone, higher alcohols and polyether-modified silicon or several
The mixture planted.
It is preferred that, the starch of the step b is times in cornstarch, tapioca, farina and wheaten starch
One or more of mixtures.
It is preferred that, the drier of the step b is any of calcium carbonate, silica, coarse whiting and bentonite or several
The mixture planted.
It is preferred that, the oxidant of the step b is any of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide or several
Mixture.
It is preferred that, the catalyst of the step b is any of boric acid, zirconium carbonate ammonium and potassium zirconium carbonate or several mixed
Compound.
It is preferred that, the bleeding agent of the step c is NPE, AEO, polyethylene glycol
With any of polypropylene glycol or several mixtures.
The beneficial effects of the invention are as follows：
Glue prepared by the present invention is free of formaldehyde and toxic organic solvents, and air and human body will not be caused harm, and with viscous
Close that intensity is high, stability is good, using scope it is wide the advantages of, glue preparation technology of the invention is simple and convenient to operate, can with
The fields such as people's life closely bound up fitting-up, furniture, building materials are widely used, with good economic benefit.
Agar-agar in the present invention has good coagulability, stability, can be complexed with the formation of some materials, play fine
Cohesive, main component be dietary fiber and protein, without any toxicity and side effects.
Guar gum in the present invention is macromolecular Natural hydrophilic colloid, and highly viscous solution can be formed with water.
Arabic gum main component in the present invention is high molecular polysaccharide and its calcium, magnesium and sylvite, and it is a kind of safety
Harmless carbohydrate polymer thickener, can improve the bonding strength of glue.
Embodiment
Embodiment 1
A kind of preparation method of Novel environmental-friendglue glue, including following preparation process：
A, hydrolyzing silicon tetrachloride thing washed 3 times, after filtering with mass concentration for 35% ethanol water, by filter residue and froth breaking
Agent is mixed, and is heated and is stirred 30min, and temperature is 60 DEG C, refilters 2 times, filter residue is washed with sodium hydrate aqueous solution to pH value
For 7, material one is obtained；
B, will starch, drier, lignin and water mix after be beaten, control temperature at 80 DEG C, sodium hydroxide solution is then added dropwise,
Regulation pH value is 8-9, after stirring reaction 20min, and oxidant is added dropwise, and is warming up to 100 DEG C of reaction 25min, catalysis is added afterwards
10min is stirred in agent, obtains material two；
C, agar-agar, guar gum, Arabic gum and bleeding agent be well mixed, 8h is soaked in water, material three is obtained；
D, by material one, material two, material three, carboxymethyl cellulose, emulsifying agent and odium stearate mix, at 100 DEG C heat
And stir, mixing speed is 240r/min, after stirring 25min, and rise temperature adds thickener, diffusant to 150 DEG C, accelerates
Mixing speed stirs after 50min to 500r/min, is cooled to normal temperature, you can obtain finished product.
Novel environmental-friendglue glue includes the raw material of following parts by weight：24 parts of hydrolyzing silicon tetrachloride thing, 13 parts of defoamer, starch 25
Part, 24 parts of drier, 18 parts of lignin, 23 parts of water, 15 parts of oxidant, 13 parts of catalyst, 17 parts of agar-agar, 12 parts of guar gum,
15 parts of Arabic gum, 16 parts of bleeding agent, 28 parts of carboxymethyl cellulose, 15 parts of emulsifying agent, 17 parts of odium stearate, 11 parts of thickener and
7 parts of diffusant.
Step a defoamer is the mixture of dimethicone, higher alcohols and polyether-modified silicon.
Step b starch is the mixture of cornstarch, tapioca, farina and wheaten starch.
Step b drier is calcium carbonate, silica, coarse whiting and bentonitic mixture.
Step b oxidant is the mixture of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide.
Step b catalyst is the mixture of boric acid, zirconium carbonate ammonium and potassium zirconium carbonate.
Step c bleeding agent is in NPE, AEO, polyethylene glycol and polypropylene glycol
Any one or several mixtures.
Embodiment 2
A kind of preparation method of Novel environmental-friendglue glue, including following preparation process：
A, hydrolyzing silicon tetrachloride thing washed 5 times, after filtering with mass concentration for 35% ethanol water, by filter residue and froth breaking
Agent is mixed, and is heated and is stirred 40min, and temperature is 60-80 DEG C, refilters 3 times, filter residue is washed with sodium hydrate aqueous solution to pH
It is worth for 7.5, obtains material one；
B, will starch, drier, lignin and water mix after be beaten, control temperature at 80 DEG C, sodium hydroxide solution is then added dropwise,
It is 9 to adjust pH value, after stirring reaction 20min, and oxidant is added dropwise, and is warming up to 100 DEG C of reaction 20min, catalyst is added afterwards
20min is stirred, material two is obtained；
C, agar-agar, guar gum, Arabic gum and bleeding agent be well mixed, 8h is soaked in water, material three is obtained；
D, by material one, material two, material three, carboxymethyl cellulose, emulsifying agent and odium stearate mix, heated simultaneously at 80 DEG C
Stirring, mixing speed is 300r/min, after stirring 20min, and rise temperature adds thickener, diffusant, accelerate to stir to 120 DEG C
Speed is mixed to 600r/min, stirs after 50min, is cooled to normal temperature, you can obtain finished product.
Novel environmental-friendglue glue includes the raw material of following parts by weight：19 parts of hydrolyzing silicon tetrachloride thing, 8 parts of defoamer, starch 35
Part, 24 parts of drier, 18 parts of lignin, 23 parts of water, 12 parts of oxidant, 10 parts of catalyst, 14 parts of agar-agar, 8 parts of guar gum, Ah
Draw primary 15 parts of glue, 16 parts of bleeding agent, 28 parts of carboxymethyl cellulose, 15 parts of emulsifying agent, 17 parts of odium stearate, 14 parts of thickener and expand
7 parts of powder.
Step a defoamer is the mixture of dimethicone, higher alcohols and polyether-modified silicon.
Step b starch is the mixture of cornstarch, tapioca, farina and wheaten starch.
Step b drier is calcium carbonate, silica, coarse whiting and bentonitic mixture.
Step b oxidant is the mixture of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide.
Step b catalyst is the mixture of boric acid, zirconium carbonate ammonium and potassium zirconium carbonate.
Step c bleeding agent is NPE, AEO, polyethylene glycol and polypropylene glycol
Mixture.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of preparation method of Novel environmental-friendglue glue, it is characterised in that including following preparation process：
A, the ethanol water for being 30-45% with mass concentration by hydrolyzing silicon tetrachloride thing are washed 3-5 times, after filtering, by filter residue
Mixed with defoamer, heat and stir 30-40min, temperature is 60-80 DEG C, is refiltered 2-3 times, by filter residue sodium hydroxide water
It is 7-7.5 that solution, which is washed to pH value, obtains material one；
B, will starch, drier, lignin and water mix after be beaten, control temperature at 80-90 DEG C, then be added dropwise sodium hydroxide it is molten
Liquid, regulation pH value is 8-9, after stirring reaction 15-20min, and oxidant is added dropwise, and is warming up to 90-100 DEG C of reaction 20-25min, it
After add catalyst stirring 10-20min, obtain material two；
C, agar-agar, guar gum, Arabic gum and bleeding agent be well mixed, 5-8h is soaked in water, material three is obtained；
D, by material one, material two, material three, carboxymethyl cellulose, emulsifying agent and odium stearate mix, at 80-100 DEG C plus
Heat is simultaneously stirred, and mixing speed is 240-300r/min, after stirring 20-25min, and rise temperature adds thickening to 120-150 DEG C
Agent, diffusant, accelerate mixing speed to 500-600r/min, stir after 40-50min, be cooled to normal temperature, you can obtain finished product.
2. a kind of preparation method of Novel environmental-friendglue glue according to claim 1, it is characterised in that the novel environment friendly glue
Water includes the raw material of following parts by weight：17-24 parts of hydrolyzing silicon tetrachloride thing, 8-13 parts of defoamer, 25-35 parts of starch, drier
24-36 parts, 18-24 parts of lignin, 23-30 parts of water, 12-15 parts of oxidant, 10-13 parts of catalyst, 14-17 parts of agar-agar, melon
Your 8-12 part of glue, 12-15 parts of Arabic gum, 13-16 parts of bleeding agent, 22-28 parts of carboxymethyl cellulose, 13-15 parts of emulsifying agent, firmly
7-11 parts of 17-19 parts of resin acid sodium, 11-14 parts of thickener and diffusant.
3. the preparation method of a kind of Novel environmental-friendglue glue according to claim 1, it is characterised in that the step a's disappears
Infusion is any of dimethicone, higher alcohols and polyether-modified silicon or several mixtures.
4. a kind of preparation method of Novel environmental-friendglue glue according to claim 1, it is characterised in that the shallow lake of the step b
Powder is any of cornstarch, tapioca, farina and wheaten starch or several mixtures.
5. the preparation method of a kind of Novel environmental-friendglue glue according to claim 1, it is characterised in that the step b's urges
Dry agent is any of calcium carbonate, silica, coarse whiting and bentonite or several mixtures.
6. a kind of preparation method of Novel environmental-friendglue glue according to claim 1, it is characterised in that the oxygen of the step b
Agent is any of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide or several mixtures.
7. the preparation method of a kind of Novel environmental-friendglue glue according to claim 1, it is characterised in that the step b's urges
Agent is any of boric acid, zirconium carbonate ammonium and potassium zirconium carbonate or several mixtures.
8. the preparation method of a kind of Novel environmental-friendglue glue according to claim 1, it is characterised in that the step c's oozes
Saturating agent is any of NPE, AEO, polyethylene glycol and polypropylene glycol or several
Mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710650118.2A CN107216828A (en) | 2017-08-02 | 2017-08-02 | A kind of preparation method of Novel environmental-friendglue glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710650118.2A CN107216828A (en) | 2017-08-02 | 2017-08-02 | A kind of preparation method of Novel environmental-friendglue glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107216828A true CN107216828A (en) | 2017-09-29 |
Family
ID=59954989
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710650118.2A Withdrawn CN107216828A (en) | 2017-08-02 | 2017-08-02 | A kind of preparation method of Novel environmental-friendglue glue |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611020A (en) * | 2018-03-28 | 2018-10-02 | 广西艾尚嘉家居有限公司 | A kind of three-ply board adhesive and preparation method thereof |
| CN110903781A (en) * | 2019-11-27 | 2020-03-24 | 南京格润包装材料有限公司 | Environment-friendly glue and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS526741A (en) * | 1975-06-30 | 1977-01-19 | Philadelphia Quartz Co | Starchhsilicic acid adhesive and production method |
| CN101050342A (en) * | 2006-04-05 | 2007-10-10 | 张龙 | Method for preparing environmental protection type binder in use for wood processing |
| CN106497439A (en) * | 2016-10-13 | 2017-03-15 | 潍坊学院 | A kind of Natural plant environment-friendlyand glue and preparation method thereof |
-
2017
- 2017-08-02 CN CN201710650118.2A patent/CN107216828A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS526741A (en) * | 1975-06-30 | 1977-01-19 | Philadelphia Quartz Co | Starchhsilicic acid adhesive and production method |
| CN101050342A (en) * | 2006-04-05 | 2007-10-10 | 张龙 | Method for preparing environmental protection type binder in use for wood processing |
| CN106497439A (en) * | 2016-10-13 | 2017-03-15 | 潍坊学院 | A kind of Natural plant environment-friendlyand glue and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611020A (en) * | 2018-03-28 | 2018-10-02 | 广西艾尚嘉家居有限公司 | A kind of three-ply board adhesive and preparation method thereof |
| CN110903781A (en) * | 2019-11-27 | 2020-03-24 | 南京格润包装材料有限公司 | Environment-friendly glue and production process thereof |
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Application publication date: 20170929 |
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