CN107216689A - A kind of dopamine surface is modified two-dimension nano materials and preparation method - Google Patents

A kind of dopamine surface is modified two-dimension nano materials and preparation method Download PDF

Info

Publication number
CN107216689A
CN107216689A CN201710483765.9A CN201710483765A CN107216689A CN 107216689 A CN107216689 A CN 107216689A CN 201710483765 A CN201710483765 A CN 201710483765A CN 107216689 A CN107216689 A CN 107216689A
Authority
CN
China
Prior art keywords
nano materials
dimension nano
dopamine
modified
dimension
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710483765.9A
Other languages
Chinese (zh)
Inventor
颜红侠
张卫东
齐暑华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northwestern Polytechnical University
Original Assignee
Northwestern Polytechnical University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Northwestern Polytechnical University filed Critical Northwestern Polytechnical University
Priority to CN201710483765.9A priority Critical patent/CN107216689A/en
Publication of CN107216689A publication Critical patent/CN107216689A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0003—Compounds of molybdenum
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/46—Graphite
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds

Abstract

Two-dimension nano materials and preparation method are modified the present invention relates to a kind of dopamine surface, the two-dimension nano materials that a kind of poly-dopamine is wrapped up are prepared for by single step reaction.The present invention solves traditional two-dimension nano materials in interstitial (water, organic matter) the problem of bad dispersibility.This feature preparation method provides a kind of method that dopamine surface is modified two-dimension nano materials, two-dimension nano materials surface is successfully introduced into functional group (hydroxyl and amino) through DOPA and not only provides the active group for continuing to react after amine-modified, and increases the compatibility between interstitial and two-dimension nano materials.Therefore, this invention has great scientific meaning, and huge actual application value is there is in terms of friction-resistant composite material, lubricant grease, heat-conductive composite material production.

Description

A kind of dopamine surface is modified two-dimension nano materials and preparation method
Technical field
The invention belongs to composite and technical field of fine, it is related to a kind of dopamine surface and is modified two-dimensional nano material Material and preparation method.
Background technology
Two-dimension nano materials (molybdenum disulfide, tungsten disulfide, two selenizing molybdenums, two tungsten selenides, titanium carbide, boron nitride) are due to it Unique structure is all the study hotspot of researcher all the time, in the field such as conduction, heat conduction, rub resistance, electromagnetic shielding table Reveal outstanding performance.
Domestic and international many researchers both know about, and two-dimension nano materials have class graphene-structured, are showed in terms of friction Go out excellent characteristic.Therefore, two-dimension nano materials and high molecular polymer, resin are combined by many researchers, are prepared Many composites, these materials show excellent performance in terms of rub resistance.But, because two-dimension nano materials are all Inorganic matter, it is the problem of poor compatibility always occurs when with organic high molecular polymer, resin progress, final to cause again Two-dimension nano materials disperse uneven in condensation material, cause the performance of composite undesirable.In addition, boron nitride comes out in 100 Many years ago, earliest application is the hexagonal boron nitride as high-temperature lubricant, h-BN not only its structure but also its performance also with stone Ink is very much like, and itself is pure white, so being commonly called as：White graphite.Recent research indicate that, boron nitride shows outstanding person in terms of heat conduction The performance gone out, as current study hotspot.But the bottleneck studied at present is how to improve boron nitride in the composite Dispersiveness.
The content of the invention
The technical problem to be solved
In order to avoid the shortcomings of the prior art, the present invention propose a kind of dopamine surface be modified two-dimension nano materials and Preparation method.
Technical scheme
A kind of dopamine surface is modified two-dimension nano materials, it is characterised in that component includes dopamine and two-dimensional nano material Material, the mass percent that wherein dopamine occupies is 17~37%, and surplus is two-dimension nano materials.The two-dimension nano materials exist Acted under specific reaction condition with dopamine, finally cause its surface fully wrapped around by poly-dopamine.
The two-dimension nano materials be graphene, molybdenum disulfide, tungsten disulfide, two selenizing molybdenums, two tungsten selenides, titanium carbide or Boron nitride.
It is a kind of to prepare the method that the dopamine surface is modified two-dimension nano materials, it is characterised in that step is as follows：
Step 1：Trishydroxymethylaminomethane is dissolved in deionized water, the pH for then adding watery hydrochloric acid regulation solution is 7.5-9.5；
Step 2：Two-dimension nano materials powder and straight alcohol are added into ultrasonic disperse 30-60min in above-mentioned system to be formed Mixed solution；
Step 3：Dopamine hydrochloride is added in mixed liquor, control system temperature is between 15-35 DEG C, stirring reaction 10-15 hours
Step 4：The solution of reflection is centrifuged and obtains solid powder, washs many with deionized water and ethanol respectively Secondary, freeze-drying, obtained black solid powder is the nanometer powder two-dimension nano materials that poly-dopamine is wrapped up.
Beneficial effect
A kind of dopamine surface proposed by the present invention is modified two-dimension nano materials and preparation method, is prepared by single step reaction A kind of two-dimension nano materials of poly-dopamine parcel.It is (water, organic in interstitial that the present invention solves traditional two-dimension nano materials Thing) in bad dispersibility the problem of.This feature preparation method provides a kind of method that dopamine surface is modified two-dimension nano materials, Two-dimension nano materials surface is successfully introduced into functional group (hydroxyl and amino) through DOPA and not only provided after amine-modified continues what is reacted Compatibility between active group, and increase interstitial and two-dimension nano materials.Therefore, this invention is anticipated with great science Justice, huge actual application value is had in terms of friction-resistant composite material, lubricant grease, heat-conductive composite material production.
Embodiment
In conjunction with embodiment, the invention will be further described：
Preparation method is sketched by taking graphene as an example：
First, 1.2114g trishydroxymethylaminomethanes are dissolved in 150mL deionized waters, pH is adjusted with watery hydrochloric acid (1M) ≈7.5-9.5.Then, 0.5g graphene powders and 50mL straight alcohols are added to ultrasonic disperse 30-60min in above-mentioned system.Most Afterwards, 0.4g Dopamine hydrochlorides are added in mixed liquor, and control system temperature is between 15-35 DEG C, stirring reaction 10-15 hours. Stop reaction centrifuging, washed respectively with deionized water and ethanol, is freeze-dried, obtain the graphene two of poly-dopamine parcel Dimension nano material.
Embodiment 1：
First, 1.2114g trishydroxymethylaminomethanes are dissolved in 150mL deionized waters, pH is adjusted with watery hydrochloric acid (1M) =8.5, continue to stir 20min.Then, 1g makes molybdenum disulfide powder by oneself and 50mL straight alcohols are added to ultrasound point in above-mentioned system Dissipate 60min.Finally, 0.4g Dopamine hydrochlorides are weighed to be added in mixed liquor, 10min are quickly stirred, control system temperature is 20 DEG C or so, stirring reaction 12 hours.Stop reaction and be centrifugally separating to obtain black solid powder, washed respectively with deionized water and ethanol Wash 3 times, be freeze-dried, obtained black solid powder is the molybdenum disulfide two-dimension nano materials of poly-dopamine parcel.
Embodiment 2：
First, 2g trishydroxymethylaminomethanes are dissolved in 250mL deionized waters, pH=8.5 are adjusted with watery hydrochloric acid (1M), Continue to stir 20min.Then, boron nitride white powder and 50mL straight alcohols after 1g is peeled off through ultrasound are added in above-mentioned system Ultrasonic disperse 40min.Finally, 0.8g Dopamine hydrochlorides are weighed to be added in mixed liquor, 10min, control system temperature is quickly stirred Degree is in 20 DEG C or so, stirring reaction 15 hours.Stop reaction and be centrifugally separating to obtain black solid powder, with deionized water and ethanol Wash 3 times respectively, freeze-drying, obtained black solid powder is the boron nitride two-dimension nano materials of poly-dopamine parcel.
Embodiment 3：
First, 1.2114g trishydroxymethylaminomethanes are dissolved in 150mL deionized waters, pH is adjusted with watery hydrochloric acid (1M) =8.5, continue to stir 20min.Then, 0.8g makes titanium carbide grey powder by oneself and 50mL straight alcohols are added in above-mentioned system and surpassed Sound disperses 60min.Finally, 0.4g Dopamine hydrochlorides are weighed to be added in mixed liquor, 10min, control system temperature is quickly stirred In 20 DEG C or so, stirring reaction 12 hours.Stop reaction and be centrifugally separating to obtain black solid powder, with deionized water and ethanol point Xi Di not be 3 times, freeze-drying, obtained black solid powder is the titanium carbide two-dimension nano materials of poly-dopamine parcel.
Embodiment 4：
First, 1.2114g trishydroxymethylaminomethanes are dissolved in 150mL deionized waters, pH is adjusted with watery hydrochloric acid (1M) =8.5, continue to stir 20min.Then, 0.4g makes graphene powder by oneself and 50mL straight alcohols are added to ultrasound point in above-mentioned system Dissipate 60min.Finally, 0.4g Dopamine hydrochlorides are weighed to be added in mixed liquor, 10min are quickly stirred, control system temperature is 25 DEG C or so, stirring reaction 12 hours.Stop reaction and be centrifugally separating to obtain black solid powder, washed respectively with deionized water and ethanol Wash 3 times, be freeze-dried, obtained black solid powder is the graphene two-dimension nano materials of poly-dopamine parcel.

Claims (3)

1. a kind of dopamine surface is modified two-dimension nano materials, it is characterised in that component includes dopamine and two-dimension nano materials, The mass percent that wherein dopamine occupies is 17~37%, and surplus is two-dimension nano materials.
2. dopamine surface is modified two-dimension nano materials according to claim 1, it is characterised in that：The two-dimension nano materials For graphene, molybdenum disulfide, tungsten disulfide, two selenizing molybdenums, two tungsten selenides, titanium carbide or boron nitride.
3. a kind of prepare the method that dopamine surface described in claim 1 or 2 is modified two-dimension nano materials, it is characterised in that step It is as follows：
Step 1：Trishydroxymethylaminomethane is dissolved in deionized water, the pH for then adding watery hydrochloric acid regulation solution is 7.5- 9.5；
Step 2：Two-dimension nano materials powder and straight alcohol are added to ultrasonic disperse 30-60min formation mixing in above-mentioned system Solution；
Step 3：Dopamine hydrochloride is added in mixed liquor, control system temperature is between 15-35 DEG C, stirring reaction 10-15 Hour
Step 4：The solution of reflection is centrifuged and obtains solid powder, is washed repeatedly with deionized water and ethanol respectively, Freeze-drying, obtained black solid powder is the nanometer powder two-dimension nano materials that poly-dopamine is wrapped up.
CN201710483765.9A 2017-06-23 2017-06-23 A kind of dopamine surface is modified two-dimension nano materials and preparation method Pending CN107216689A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710483765.9A CN107216689A (en) 2017-06-23 2017-06-23 A kind of dopamine surface is modified two-dimension nano materials and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710483765.9A CN107216689A (en) 2017-06-23 2017-06-23 A kind of dopamine surface is modified two-dimension nano materials and preparation method

Publications (1)

Publication Number Publication Date
CN107216689A true CN107216689A (en) 2017-09-29

Family

ID=59950387

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710483765.9A Pending CN107216689A (en) 2017-06-23 2017-06-23 A kind of dopamine surface is modified two-dimension nano materials and preparation method

Country Status (1)

Country Link
CN (1) CN107216689A (en)

Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107739643A (en) * 2017-10-18 2018-02-27 黑龙江省华升石墨股份有限公司 A kind of lubricating oil of carbon nanomaterial being modified containing surface and preparation method thereof
CN107955669A (en) * 2017-11-17 2018-04-24 中国科学院兰州化学物理研究所 Molybdenum disulfide or tungsten disulfide-alkyl mercaptan compound and its application
CN108172782A (en) * 2017-12-13 2018-06-15 郑州大学 A kind of preparation method and application with shell-core structure carbon package porous oxidation Asia cobalt nano material
CN108251195A (en) * 2017-12-29 2018-07-06 赵建平 A kind of preparation method of binding type solid dry lubricant
CN108408780A (en) * 2018-03-12 2018-08-17 南京邮电大学 A kind of Transition-metal dichalcogenide nanometer sheet and preparation method thereof of poly-dopamine modification
CN108531029A (en) * 2018-04-28 2018-09-14 福建宸琦新材料科技有限公司 A kind of dopamine coats the preparation method of three-dimensional porous graphene/acrylic ester aquosity anticorrosive paint
CN108559579A (en) * 2018-05-14 2018-09-21 西北工业大学 A kind of preparation method of nanosizing liquid metal lube oil additive
CN108642862A (en) * 2018-05-04 2018-10-12 苏州大学 A kind of surface modification of aramid fiber and preparation method thereof
CN109181592A (en) * 2018-07-25 2019-01-11 佛山市高明区爪和新材料科技有限公司 A kind of preparation method of heat-conducting glue
CN109273281A (en) * 2018-08-27 2019-01-25 重庆大学 A kind of NiSe2/Ti3C2TxThe preparation method of high-performance ultra-capacitor nanocomposite
CN109943310A (en) * 2019-04-02 2019-06-28 侯吉瑞 A kind of modified MoS2Nano material and preparation method thereof
CN110229518A (en) * 2019-06-21 2019-09-13 陕西科技大学 Modified hexagonal boron nitride/p-aramid fiber nano-fiber composite material of a kind of dopamine and preparation method thereof
CN110394871A (en) * 2019-07-18 2019-11-01 北京林业大学 It is a kind of to regulate and control method by the energy storage timber and semi-intercrossing network of filler of boron nitride
CN110405883A (en) * 2019-07-24 2019-11-05 北京林业大学 It is a kind of to be alkylated energy storage timber of the boron nitride as filler
CN110676068A (en) * 2019-10-28 2020-01-10 熊洪涛 Polydopamine-coated MoS2-porous carbon supercapacitor material and method for producing the same
CN111074539A (en) * 2019-12-27 2020-04-28 武汉纺织大学 Fabric with core-shell structure photothermal conversion material and preparation method thereof
CN111117746A (en) * 2020-01-06 2020-05-08 北京科技大学 Preparation of nano MoS by dopamine polymerization2-Al2O3Method for compounding rolling lubricant
WO2020124396A1 (en) * 2018-12-18 2020-06-25 南通纺织丝绸产业技术研究院 Flame-retardant ultraviolet-resistant aramid fiber
CN111440653A (en) * 2020-04-17 2020-07-24 清华大学 Application of polydopamine nanoparticles in water-based lubricating fluid
CN111454592A (en) * 2020-04-08 2020-07-28 浙江恒澜科技有限公司 Modified titanium dioxide and preparation method and application thereof
CN111748255A (en) * 2020-06-30 2020-10-09 陕西科技大学 Photo-thermal insulation type composite leather finishing agent based on Pickering emulsion polymerization method and preparation method thereof
CN111978839A (en) * 2020-08-28 2020-11-24 陕西科技大学 Antistatic leather finishing agent and preparation method and application thereof
CN112011384A (en) * 2020-09-01 2020-12-01 安徽省路驰环保科技有限公司 Antifriction agent containing modified nano hexagonal boron nitride, preparation method thereof and lubricating oil
CN112280541A (en) * 2019-07-24 2021-01-29 天津大学 Preparation method of high-thermal-conductivity composite material based on graphitized poly-dopamine-coated metal particles
CN112608644A (en) * 2020-12-02 2021-04-06 浙江万丰摩轮有限公司 Motorcycle hub with multicolor coating and preparation method thereof
CN112618784A (en) * 2020-12-11 2021-04-09 北京化工大学常州先进材料研究院 Sports colloid dressing
CN112724677A (en) * 2020-12-29 2021-04-30 中山大学 Dopamine modified boron nitride heat-conducting silicone grease and preparation method thereof
CN112772670A (en) * 2020-12-17 2021-05-11 南京师范大学 Preparation method of quaternary composite nano controlled release system
CN112941543A (en) * 2021-01-28 2021-06-11 西北工业大学 Multistage tungsten-based dopamine hybrid material and preparation method thereof
CN113549334A (en) * 2021-08-18 2021-10-26 鄂尔多斯市路泰新材料科技发展有限公司 High-elasticity high-weather-resistance modified asphalt and preparation method thereof
CN113621420A (en) * 2021-07-29 2021-11-09 清华大学 Preparation method of composite lubricating material
CN113637383A (en) * 2021-07-21 2021-11-12 潍坊东方钢管有限公司 Preparation method of polydopamine modified molybdenum disulfide composite epoxy powder coating
CN113736537A (en) * 2021-10-10 2021-12-03 河北工程大学 Preparation method of nano boron nitride-copper oxide lubricating additive
CN113861828A (en) * 2021-11-20 2021-12-31 福州大学 Method for preparing KM-SiO2@ PDA @ MoS2 wear-resistant super-hydrophobic coating by utilizing slag
CN113861679A (en) * 2021-09-18 2021-12-31 陕西科技大学 Polydopamine nanosphere/boron nitride quantum dot/graphene solid lubricant, preparation method and application thereof, and composite material
CN114213850A (en) * 2021-12-28 2022-03-22 江苏达胜高聚物股份有限公司 High-thermal-conductivity silicone rubber cable material and preparation method and application thereof
CN114645451A (en) * 2022-04-25 2022-06-21 中国科学院兰州化学物理研究所 Layered composite material and preparation method thereof, self-lubricating fiber fabric composite material and preparation method and application thereof
CN115505439A (en) * 2022-09-22 2022-12-23 中国科学院兰州化学物理研究所 Surface modification method of universal micro-nano powder material
CN115651403A (en) * 2022-10-19 2023-01-31 扬州天启新材料股份有限公司 Flame-retardant cyanate ester and preparation method thereof
CN116425463A (en) * 2023-04-06 2023-07-14 徐州世威隆盛建设工程有限公司 Early-strength cold-resistant concrete material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017209A (en) * 2014-06-17 2014-09-03 北京航空航天大学 Method for preparing tough integrated biomimetic layered graphene composite material
CN104399090A (en) * 2014-11-12 2015-03-11 深圳先进技术研究院 Poly dopamine-modified reduced graphene oxide and preparation method and application thereof
CN106554514A (en) * 2016-10-28 2017-04-05 上海大学 A kind of method for modifying boron nitride nanosheet surface with poly-dopamine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017209A (en) * 2014-06-17 2014-09-03 北京航空航天大学 Method for preparing tough integrated biomimetic layered graphene composite material
CN104399090A (en) * 2014-11-12 2015-03-11 深圳先进技术研究院 Poly dopamine-modified reduced graphene oxide and preparation method and application thereof
CN106554514A (en) * 2016-10-28 2017-04-05 上海大学 A kind of method for modifying boron nitride nanosheet surface with poly-dopamine

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
任思明等: "聚多巴胺修饰六方氮化硼及其环氧复合涂层的腐蚀行为", 《中国表面工程》 *
南倩: "氧化石墨烯复合膜的制备及其性能研究", 《中国优秀硕士学位论文全文数据库》 *
李创等: "PDA/RGO复合材料对水中Fe(Ⅲ)的吸附行为", 《化工学报》 *

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107739643A (en) * 2017-10-18 2018-02-27 黑龙江省华升石墨股份有限公司 A kind of lubricating oil of carbon nanomaterial being modified containing surface and preparation method thereof
CN107739643B (en) * 2017-10-18 2020-07-10 黑龙江省华升石墨股份有限公司 Lubricating oil containing surface-modified carbon nano material and preparation method thereof
CN107955669A (en) * 2017-11-17 2018-04-24 中国科学院兰州化学物理研究所 Molybdenum disulfide or tungsten disulfide-alkyl mercaptan compound and its application
CN108172782B (en) * 2017-12-13 2021-06-04 郑州大学 Preparation method and application of carbon-coated porous cobaltous oxide nano material with shell-core structure
CN108172782A (en) * 2017-12-13 2018-06-15 郑州大学 A kind of preparation method and application with shell-core structure carbon package porous oxidation Asia cobalt nano material
CN108251195A (en) * 2017-12-29 2018-07-06 赵建平 A kind of preparation method of binding type solid dry lubricant
CN108408780A (en) * 2018-03-12 2018-08-17 南京邮电大学 A kind of Transition-metal dichalcogenide nanometer sheet and preparation method thereof of poly-dopamine modification
CN108531029A (en) * 2018-04-28 2018-09-14 福建宸琦新材料科技有限公司 A kind of dopamine coats the preparation method of three-dimensional porous graphene/acrylic ester aquosity anticorrosive paint
WO2019210529A1 (en) * 2018-05-04 2019-11-07 南通纺织丝绸产业技术研究院 Surface-modified aramid fiber and preparation method therefor
CN108642862B (en) * 2018-05-04 2020-04-03 苏州大学 Surface modified aramid fiber and preparation method thereof
US20210222358A1 (en) * 2018-05-04 2021-07-22 Soochow University Surface-modified aramid fiber and preparation method therefor
US11898303B2 (en) * 2018-05-04 2024-02-13 Soochow University Surface-modified aramid fiber and preparation method therefor
CN108642862A (en) * 2018-05-04 2018-10-12 苏州大学 A kind of surface modification of aramid fiber and preparation method thereof
CN108559579A (en) * 2018-05-14 2018-09-21 西北工业大学 A kind of preparation method of nanosizing liquid metal lube oil additive
CN109181592A (en) * 2018-07-25 2019-01-11 佛山市高明区爪和新材料科技有限公司 A kind of preparation method of heat-conducting glue
CN109273281A (en) * 2018-08-27 2019-01-25 重庆大学 A kind of NiSe2/Ti3C2TxThe preparation method of high-performance ultra-capacitor nanocomposite
WO2020124396A1 (en) * 2018-12-18 2020-06-25 南通纺织丝绸产业技术研究院 Flame-retardant ultraviolet-resistant aramid fiber
CN109943310A (en) * 2019-04-02 2019-06-28 侯吉瑞 A kind of modified MoS2Nano material and preparation method thereof
CN109943310B (en) * 2019-04-02 2022-05-24 侯吉瑞 Modified MoS2Nano material and preparation method thereof
CN110229518A (en) * 2019-06-21 2019-09-13 陕西科技大学 Modified hexagonal boron nitride/p-aramid fiber nano-fiber composite material of a kind of dopamine and preparation method thereof
CN110394871A (en) * 2019-07-18 2019-11-01 北京林业大学 It is a kind of to regulate and control method by the energy storage timber and semi-intercrossing network of filler of boron nitride
CN110405883A (en) * 2019-07-24 2019-11-05 北京林业大学 It is a kind of to be alkylated energy storage timber of the boron nitride as filler
CN112280541A (en) * 2019-07-24 2021-01-29 天津大学 Preparation method of high-thermal-conductivity composite material based on graphitized poly-dopamine-coated metal particles
CN110676068B (en) * 2019-10-28 2021-12-03 江西高信前沿科技有限公司 Polydopamine-coated MoS2-porous carbon supercapacitor material and method for producing the same
CN110676068A (en) * 2019-10-28 2020-01-10 熊洪涛 Polydopamine-coated MoS2-porous carbon supercapacitor material and method for producing the same
CN111074539A (en) * 2019-12-27 2020-04-28 武汉纺织大学 Fabric with core-shell structure photothermal conversion material and preparation method thereof
CN111074539B (en) * 2019-12-27 2022-04-12 武汉纺织大学 Fabric with core-shell structure photothermal conversion material and preparation method thereof
CN111117746A (en) * 2020-01-06 2020-05-08 北京科技大学 Preparation of nano MoS by dopamine polymerization2-Al2O3Method for compounding rolling lubricant
CN111454592A (en) * 2020-04-08 2020-07-28 浙江恒澜科技有限公司 Modified titanium dioxide and preparation method and application thereof
CN111454592B (en) * 2020-04-08 2021-11-12 浙江恒澜科技有限公司 Modified titanium dioxide and preparation method and application thereof
CN111440653B (en) * 2020-04-17 2021-11-30 清华大学 Application of polydopamine nanoparticles in water-based lubricating fluid
CN111440653A (en) * 2020-04-17 2020-07-24 清华大学 Application of polydopamine nanoparticles in water-based lubricating fluid
CN111748255A (en) * 2020-06-30 2020-10-09 陕西科技大学 Photo-thermal insulation type composite leather finishing agent based on Pickering emulsion polymerization method and preparation method thereof
CN111748255B (en) * 2020-06-30 2022-04-12 陕西科技大学 Photo-thermal insulation type composite leather finishing agent based on Pickering emulsion polymerization method and preparation method thereof
CN111978839A (en) * 2020-08-28 2020-11-24 陕西科技大学 Antistatic leather finishing agent and preparation method and application thereof
CN112011384A (en) * 2020-09-01 2020-12-01 安徽省路驰环保科技有限公司 Antifriction agent containing modified nano hexagonal boron nitride, preparation method thereof and lubricating oil
CN112608644A (en) * 2020-12-02 2021-04-06 浙江万丰摩轮有限公司 Motorcycle hub with multicolor coating and preparation method thereof
CN112618784A (en) * 2020-12-11 2021-04-09 北京化工大学常州先进材料研究院 Sports colloid dressing
CN112772670A (en) * 2020-12-17 2021-05-11 南京师范大学 Preparation method of quaternary composite nano controlled release system
CN112724677A (en) * 2020-12-29 2021-04-30 中山大学 Dopamine modified boron nitride heat-conducting silicone grease and preparation method thereof
CN112941543A (en) * 2021-01-28 2021-06-11 西北工业大学 Multistage tungsten-based dopamine hybrid material and preparation method thereof
CN113637383A (en) * 2021-07-21 2021-11-12 潍坊东方钢管有限公司 Preparation method of polydopamine modified molybdenum disulfide composite epoxy powder coating
CN113621420A (en) * 2021-07-29 2021-11-09 清华大学 Preparation method of composite lubricating material
CN113549334A (en) * 2021-08-18 2021-10-26 鄂尔多斯市路泰新材料科技发展有限公司 High-elasticity high-weather-resistance modified asphalt and preparation method thereof
CN113861679A (en) * 2021-09-18 2021-12-31 陕西科技大学 Polydopamine nanosphere/boron nitride quantum dot/graphene solid lubricant, preparation method and application thereof, and composite material
CN113861679B (en) * 2021-09-18 2023-09-22 陕西科技大学 Polydopamine nanosphere/boron nitride quantum dot/graphene solid lubricant, preparation method and application thereof, and composite material
CN113736537A (en) * 2021-10-10 2021-12-03 河北工程大学 Preparation method of nano boron nitride-copper oxide lubricating additive
CN113861828A (en) * 2021-11-20 2021-12-31 福州大学 Method for preparing KM-SiO2@ PDA @ MoS2 wear-resistant super-hydrophobic coating by utilizing slag
CN114213850A (en) * 2021-12-28 2022-03-22 江苏达胜高聚物股份有限公司 High-thermal-conductivity silicone rubber cable material and preparation method and application thereof
CN114645451A (en) * 2022-04-25 2022-06-21 中国科学院兰州化学物理研究所 Layered composite material and preparation method thereof, self-lubricating fiber fabric composite material and preparation method and application thereof
CN115505439A (en) * 2022-09-22 2022-12-23 中国科学院兰州化学物理研究所 Surface modification method of universal micro-nano powder material
CN115651403A (en) * 2022-10-19 2023-01-31 扬州天启新材料股份有限公司 Flame-retardant cyanate ester and preparation method thereof
CN115651403B (en) * 2022-10-19 2023-11-10 扬州天启新材料股份有限公司 Flame-retardant cyanate and preparation method thereof
CN116425463A (en) * 2023-04-06 2023-07-14 徐州世威隆盛建设工程有限公司 Early-strength cold-resistant concrete material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107216689A (en) A kind of dopamine surface is modified two-dimension nano materials and preparation method
Yang et al. Novel segregated-structure phase change materials composed of paraffin@ graphene microencapsules with high latent heat and thermal conductivity
CN101864005A (en) Method for preparing polymer/graphene composite material
CN106810818B (en) A kind of graphene modified epoxy and preparation method thereof
CN107033854A (en) A kind of novel heat-conducting material and preparation method thereof
CN105036558B (en) Micro-nano is combined glaze
CN104861662B (en) Nano composite soy protein plastic and preparation method thereof
CN111218113B (en) g-C3N4CNT (carbon nano tube) nano hybrid material modified PPESK (Polytetrafluoroethylene-styrene-ethylene-styrene) lubricating film and preparation method thereof
CN101942233B (en) Surface treatment method of inorganic nano-particles and application
CN103627374B (en) A kind of drilling fluid thinner
CN108424753A (en) A kind of high admittance rice conduction oil and preparation method thereof
CN109399609A (en) A kind of preparation method and application of biomass fluorescence carbon quantum dot dispersion liquid
CN112442216A (en) Oriented high-thermal-conductivity rubber composite material and preparation method thereof
CN108358668A (en) A kind of graphene-SiO 2-ceramic composite granule and preparation method thereof
CN109021932A (en) Graphene oxide/silver particles complex intensifying paraffin wax type phase-changing energy storage material and preparation method thereof
CN115403931A (en) Flexible heat conducting pad and preparation method thereof
CN109880169B (en) In-situ polymerization modified white graphene nylon composite slice and preparation method thereof
CN109370493B (en) Thermal interface material and preparation method thereof
CN107022345A (en) Preparation method, composite and the application of graphene/graphite powder composite material
CN108424752A (en) A kind of conduction oil and preparation method thereof of graphene-containing and nano-particle
CN107460021B (en) Preparation method of low-temperature graphene-based nano borate composite material
CN111534178B (en) Preparation method of photo-thermal insulation type leather finishing agent
CN103113697A (en) Creep-resistant inorganic nano-particle/polymer composite material and preparation method thereof
CN112062979A (en) Organic-inorganic core-shell structure self-lubricating composite material and preparation method thereof
CN101671495B (en) Calcium carbonate modifier and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170929