CN107216649A - It is a kind of to exempt from spraying daiamid composition and preparation method thereof with metallic luster - Google Patents
It is a kind of to exempt from spraying daiamid composition and preparation method thereof with metallic luster Download PDFInfo
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- CN107216649A CN107216649A CN201710369749.7A CN201710369749A CN107216649A CN 107216649 A CN107216649 A CN 107216649A CN 201710369749 A CN201710369749 A CN 201710369749A CN 107216649 A CN107216649 A CN 107216649A
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- China
- Prior art keywords
- daiamid composition
- exempting
- metallic luster
- sprays
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 229920003656 Daiamid® Polymers 0.000 title claims abstract description 42
- 239000002932 luster Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims description 19
- 238000005507 spraying Methods 0.000 title claims description 8
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 36
- 239000004952 Polyamide Substances 0.000 claims abstract description 31
- 229920002647 polyamide Polymers 0.000 claims abstract description 30
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000012745 toughening agent Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 14
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 12
- 238000012360 testing method Methods 0.000 claims description 30
- 239000007921 spray Substances 0.000 claims description 23
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 22
- -1 acrylonitrile-polyethylene Chemical group 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 229920001577 copolymer Polymers 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 2
- 229920000891 common polymer Polymers 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 17
- 239000000463 material Substances 0.000 abstract description 9
- 238000007493 shaping process Methods 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 abstract description 4
- 229920001893 acrylonitrile styrene Polymers 0.000 abstract description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003607 modifier Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 17
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 12
- 239000000843 powder Substances 0.000 description 12
- 229910000906 Bronze Inorganic materials 0.000 description 9
- 239000010974 bronze Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 9
- 230000002596 correlated effect Effects 0.000 description 8
- 230000006872 improvement Effects 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 8
- 239000004411 aluminium Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 235000019260 propionic acid Nutrition 0.000 description 6
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical group [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000013068 control sample Substances 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- UNMYWSMUMWPJLR-UHFFFAOYSA-L Calcium iodide Chemical compound [Ca+2].[I-].[I-] UNMYWSMUMWPJLR-UHFFFAOYSA-L 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910001640 calcium iodide Inorganic materials 0.000 description 2
- 229940046413 calcium iodide Drugs 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 2
- 229910001641 magnesium iodide Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 235000009518 sodium iodide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0831—Gold
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0856—Iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Daiamid composition is sprayed the invention discloses a kind of exempting from metallic luster, it includes the following raw material component by weight：0.2~2 part of 100 parts of polyamide, 4~20 parts of acrylonitrile styrene copolymer, 0.2~2 part of metallic pigments, 2~10 parts of compatilizer, 0~25 part of filler, 0.2~6 part of toughener, 0.2~2 part of dispersing aid and processing aid.The present invention compounds acrylonitrile styrene copolymer as modifier and polyamide the matrix resin as composition, adjust other material compositions simultaneously, be aided with the compatilizer, dispersing aid and toughener of specific proportioning, thus optimize the daiamid composition processing characteristics and shaping after mechanical property and apparent effect.
Description
Technical field
The present invention relates to polymeric material field, more particularly to a kind of exempting from metallic luster sprays daiamid composition
And preparation method thereof.
Background technology
Polyamide (Polyamides, abbreviation PA) is as one of wide variety of engineering plastics, and itself has excellent synthesis
Performance, such as good mechanical property, chemical resistance and heat resistance, but polyamide also has case hardness not high simultaneously,
The deficiencies such as easy scratch.By modified such as alloying or enhancing, the performance of polyamide is improved, it is met different uses
Condition, expands the application field of polyamide.Acrylonitritrile-styrene resin (acrylonitrile-styrene copolymer
Abbreviation AS), have the advantages that transparent, resistant to chemical etching, modulus is high, processing fluidity is good, but the impact property of AS resins is poor,
Limit its extensive use.Exempt from sprayed on material and generally refer to surface there is the product of good surface effect, surface is not required to carry out again
Spray and sprayed surface effect can be reached, PA exempts from sprayed product has metal-like strong, heat-resist and chemical resistance is good etc.
Feature, with larger application potential.Patent CN104629348A discloses a kind of exempting from special decorative effects and sprays PA,
It uses master batch encapsulation techniques, with metal-like effect, but its complex manufacturing technology, and cost is higher.PA/AS classes alloy is such as
Patent CN102010591A and patent CN106433112A are concern is primarily with the mechanical performance of material and hot property, and to its table
Face performance then pays close attention to less, is particularly also not concerned with terms of spraying-free metal effect PA/AS alloys.
The general pigment by adding metal effect of sprayed product of exempting from metal effect is realized, but metallic pigments exist
It is orientated and accumulates in polymeric matrix and easily produce some cosmetic issues, such as there is the PA classes product of metallic luster easily on surface
Trace and weld marks are produced, this product structure species is single to be designed and handle, it is necessary to be aided with special shape, but weld mark
Problem is still present, and cost is higher.How so that the PA resin combinations with metallic luster are with good apparent property
Can, while preparation technology flow is simple, production finished product is low, as industry urgent problem.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided a kind of apparent property is good, mechanical property is excellent
And production cost it is low exempt from spray daiamid composition, while invention further provides a kind of preparation method of the polymer.
The technical solution used in the present invention is：A kind of exempting from metallic luster sprays daiamid composition, and it is by weight
Amount part meter includes the following raw material component：
Specifically, polyamide and acrylonitritrile-styrene resin, which are combined, has certain consistency problem, and metal
The problem of pigment has dispersed not good enough again in polyamide in itself, thus the functional aid in its daiamid composition
Addition such as compatilizer, dispersing aid and toughener is particularly important.
As the further improvement of such scheme, the addition of the acrylonitritrile-styrene resin and compatilizer is by original
Material parts by weight are calculated as 0.4~10:1.Specifically, when both acrylonitritrile-styrene resin and compatilizer ratio are more than 10:When 1
Composition surface gloss is not good；When both ratios are less than 0.4:The post-production processability of composition is poor when 1.
As the further improvement of such scheme, the addition of the acrylonitritrile-styrene resin and dispersing aid is pressed
Parts by weight of raw materials is calculated as 2~100:1.Specifically, the ratio of both acrylonitritrile-styrene resin and dispersing aid is more than 100:
1 or less than 2:The surface metal luster effect of composition is not good when 1.
As the further improvement of such scheme, the melt flow rate (MFR) of the acrylonitrile-polyethylene and ethylene copolymers is 200
DEG C/10kg test condition under be 20~40g/10min.
As the further improvement of such scheme, the polyamide is selected from least one of PA66, PA6 and PA12.
As the further improvement of such scheme, the compatilizer is selected from the styrene-Malaysia acyl being grafted through maleic anhydride
Imine copolymer, the styrene-ethylene-butylene-styrene copolymer being grafted through maleic anhydride, the propylene being grafted through maleic anhydride
In nitrile-BS, the acrylonitritrile-styrene resin being grafted through maleic anhydride, and their hydride
At least one.Specifically, the acrylonitritrile-styrene resin that is preferably grafted through maleic anhydride of the present invention, grafting rate is 0.8~
1.5%, further preferred maleic anhydride grafting ratio is 1.2% acrylonitritrile-styrene resin.Spy of the present invention to compatilizer
It is different to limit, it is formed specific compound system with polyamide and acrylonitritrile-styrene resin, efficiently solve poly-
Amide resin is used as consistency problem during resin matrix with acrylonitritrile-styrene resin compounding.
As the further improvement of such scheme, the dispersant is from the end that acid value is 200~300mgKOH/g
Carboxyl polymer, it can effectively improve the dispersive property of metallic pigments, improve surface gloss after daiamid composition shaping.Tool
Body, the end carboxyl polymer of the present invention preferably spherical structure.
As the further improvement of such scheme, the filler is selected from aluminum oxide, clay, montmorillonite, kaolin, carbonic acid
At least one of calcium, diatomite, mica, silica, talcum, wollastonite and blanc fixe.Specifically, the filler of addition can be carried
Case hardness after super polyamide composition molding, the present invention further preferably particle size range is upper between 2500~5000 mesh
Filler is stated, it can be effectively improved warpage performance and shrinkage after polyamide polymer shaping.
As the further improvement of such scheme, the toughener be selected from be grafted through maleic anhydride ethylene-acrylate-
Copolymer-maleic anhydride or ethylene-propylene-copolymer-maleic anhydride.
Metallic pigments of the present invention in aluminium powder, copper powder, bronze, silver powder, zinc powder, glass putty, iron powder and nickel powder extremely
Lack one kind, further at least one of preferred aluminium powder, bronze, silver powder and zinc powder.Preferable particle size scope of the present invention be 10~
250 μm of metallic pigments.
Processing aid of the present invention is selected from least one of antioxidant, lubricant, heat oxygen aging resistance agent.Wherein,
The antioxidant be selected from β-positive octadecanol ester of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid, four [β-(3,5- di-t-butyls-
4- hydroxy phenyls) propionic acid] pentaerythritol ester, N, N'- is double-(3- (3,5- di-tert-butyl-hydroxy phenyls) propiono) hexamethylene diamine,
Double (2,4- di-tert-butyl-phenyls) pentaerythrites, 2,6- di-t-butyl -4-4 cresols and three (2,4- di-tert-butyl-phenyls) phosphorous
At least one of acid esters.The lubricant is selected from silicone powder, pentaerythrite stearate, calcium stearate, zinc stearate, tristearin
At least one of sour aluminium, ethylene bis stearamide.The heat oxygen aging resistance auxiliary agent is selected from sodium bromide, sodium iodide, cupric iodide, bromine
Change at least one of calcium, calcium iodide, magnesium bromide, magnesium iodide, KBr, KI.
Another technical scheme for being taken of the present invention is：A kind of exempting from metallic luster as described above sprays polyamides
The preparation method of amine polymer：Each raw material components are weighed by weight, using homogenizer by dried polyamide, third
Alkene nitrile-styrol copolymer, filler, compatilizer, toughener, dispersing aid, processing aid and metallic pigments are well mixed, from double
Screw Extrusion owner feeds mouth and added, temperature be 210~280 DEG C, vacuum be 0.05~0.08MPa, rotating speed be 300~
Under 500rp/min process conditions by double screw extruder melting extrusion, granulate, graininess exempt from spray daiamid composition
Finished product.
The beneficial effects of the invention are as follows：The present invention regard acrylonitritrile-styrene resin as modifier and polyamide
Compound the matrix resin as composition, while adjust other material compositions, be aided with the compatilizer of specific proportioning, dispersing aid and
Toughener, thus optimize the daiamid composition processing characteristics and shaping after mechanical property and apparent effect.
The present invention further passes through the restriction to polyamide melt flow rate (MFR), the acrylonitrile being preferably adapted for-benzene second
Alkene copolymer, and for the deficiency of both compatibilities, specific compatilizer is selected, specific compound system is formed, is aided with simultaneously
Corresponding auxiliary agent, makes the daiamid composition have higher mechanical property, surface property and preferably color effect, and passing through
Add the inorganic filler of proper ratio to improve the warpage and dimensional stability of material, make its subsequent preparation process that there is condition
It is easily-controllable, to the less demanding of equipment, preparation flow is simple, production cost is relatively low the advantages of, be adapted to large-scale industrial production.
There is excellent glossiness and extremely strong metallic luster after the daiamid composition shaping that the present invention is prepared into, its
60 ° of glossiness are more than 93 degree, and surface, without current mark, melt weld metallic pigments weld bond is slight, and satisfaction exempts from sprayed on material
Use requirement.
Apparent excellent effect after the daiamid composition shaping that the present invention is prepared into, case hardness height and heat distortion temperature
Height, is adapted to some occasions with particular/special requirement, can be applied to household electrical appliances, automobile and electronic apparatus etc., other exempt from sprayed on material application
Field.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of exempting from metallic luster sprays daiamid composition, and it includes the following raw material component by weight：
Wherein, polyamide is PA6；The melt flow rate (MFR) of acrylonitritrile-styrene resin is 200 DEG C/10kg's
It is 40g/10min under test condition；Mixing of the metallic pigments by particle diameter for 250 μm of bronze and zinc powder is constituted；Compatilizer is horse
Maleic anhydride grafted rate is 1.2% acrylonitritrile-styrene resin；Toughener is the ethylene-acrylic acid being grafted through maleic anhydride
Ester-copolymer-maleic anhydride；Dispersing aid is the end carboxyl polymer that acid number is 200mgKOH/g；Processing aid includes N, N'-
Double-(3- (3,5- di-tert-butyl-hydroxy phenyls) propiono) hexamethylene diamine and double (2,4- di-tert-butyl-phenyls) pentaerythrites
Mixture and sodium iodide.Preparation method：
Each raw material components are weighed by weight, using homogenizer by dried polyamide and remaining each original
Expect that component is well mixed, feeding mouth from twin-screw extrusion owner adds, temperature be 210~280 DEG C, vacuum be 0.05~
0.08MPa, rotating speed for 300~500rp/min process conditions under by double screw extruder melting extrusion, granulate, particle
Shape exempts to spray daiamid composition finished product.
The gained graininess of embodiment 1 is exempted from into spraying daiamid composition finished product through 90~130 DEG C of dry 4~6h, injection temperature
Degree control obtains the sample 1 needed for test correlated performance by injection molding at 240~290 DEG C.
Embodiment 2
A kind of exempting from metallic luster sprays daiamid composition, and it includes the following raw material component by weight：
Wherein, polyamide is PA66 and PA6 hybrid resin；The melt flows speed of acrylonitritrile-styrene resin
Rate is 20g/10min under 200 DEG C/10kg test condition；Metallic pigments are 50 μm of aluminium powder, bronze and silver powder by particle diameter
Mixing composition；Compatilizer is the styrene-maleimide copolymer being grafted through maleic anhydride；Filler is 3000 purposes by particle diameter
Talcum, mica and diatomite are mixed；Toughener is ethylene-propylene-copolymer-maleic anhydride；Dispersing aid is that acid number is
300mgKOH/g end carboxyl polymer；Processing aid includes β-positive 18 carbon of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid
Alcohol ester and silicone powder.
Preparation method is same as Example 1.
The gained graininess of embodiment 2 is exempted from into spraying daiamid composition finished product through 90~130 DEG C of dry 4~6h, injection temperature
Degree control obtains the sample 2 needed for test correlated performance by injection molding at 240~290 DEG C.
Embodiment 3
A kind of exempting from metallic luster sprays daiamid composition, and it includes the following raw material component by weight：
Wherein, polyamide is PA66；The melt flow rate (MFR) of acrylonitritrile-styrene resin is 200 DEG C/10kg's
It is 30g/10min under test condition；Metallic pigments are 10 μm of bronze by particle diameter；Compatilizer is the propylene being grafted through maleic anhydride
The mixture of nitrile-BS and the acrylonitritrile-styrene resin being grafted through maleic anhydride；Filler is by grain
Footpath mixes for aluminum oxide, kaolin, calcium carbonate and the wollastonite of 5000 mesh；Toughener is that ethylene-propylene-maleic anhydride is common
Polymers；Dispersing aid is the end carboxyl polymer that acid number is 250mgKOH/g；Processing aid includes three (2,4- di-tert-butyls
Base) phosphite ester, pentaerythrite stearate and sodium bromide.
Preparation method is same as Example 1.
The gained graininess of embodiment 3 is exempted from into spraying daiamid composition finished product through 90~130 DEG C of dry 4~6h, injection temperature
Degree control obtains the sample 3 needed for test correlated performance by injection molding at 240~290 DEG C.
Embodiment 4
A kind of exempting from metallic luster sprays daiamid composition, and it includes the following raw material component by weight：
Wherein, polyamide is PA12；The melt flow rate (MFR) of acrylonitritrile-styrene resin is 200 DEG C/10kg's
It is 40g/10min under test condition；Metallic pigments are mixed by particle diameter for 200 μm of bronze, iron powder, nickel powder and copper powder；Phase
It is the acrylonitrile-butadiene-styrene copolymer being grafted through maleic anhydride to hold agent；Filler by particle diameter for 2500 mesh aluminum oxide,
Kaolin, montmorillonite, calcium carbonate and wollastonite are mixed；Toughener is the ethylene-acrylate-horse being grafted through maleic anhydride
Carry out acid anhydride copolymer；Dispersing aid is the end carboxyl polymer that acid number is 300mgKOH/g；Processing aid includes double (uncles of 2,4- bis-
Butyl phenyl) pentaerythrite, aluminum stearate and calcium iodide.
Preparation method is same as Example 1.
The gained graininess of embodiment 4 is exempted from into spraying daiamid composition finished product through 90~130 DEG C of dry 4~6h, injection temperature
Degree control obtains the sample 4 needed for test correlated performance by injection molding at 240~290 DEG C.
Embodiment 5
A kind of exempting from metallic luster sprays daiamid composition, and it includes the following raw material component by weight：
Wherein, polyamide is PA6 and crowd PA12 hybrid resin；The melt flows of acrylonitritrile-styrene resin
Speed is 30g/10min under 200 DEG C/10kg test condition；Metallic pigments are 150 μm of iron powder, nickel powder and copper by particle diameter
Powder is mixed；Compatilizer is the acrylonitrile-butadiene-styrene copolymer being grafted through maleic anhydride；Filler is by particle diameter
The calcium carbonate and wollastonite of 5000 mesh are mixed；Toughener is the ethylene-acrylate-maleic anhydride being grafted through maleic anhydride
Copolymer；Dispersing aid is the end carboxyl polymer that acid number is 250mgKOH/g；Processing aid includes double (2,4- di-tert-butyls
Base) pentaerythrite, calcium stearate and magnesium iodide.
Preparation method is same as Example 1.
The gained graininess of embodiment 5 is exempted from into spraying daiamid composition finished product through 90~130 DEG C of dry 4~6h, injection temperature
Degree control obtains the sample 5 needed for test correlated performance by injection molding at 240~290 DEG C.
Comparative example 1
A kind of daiamid composition, it includes the following raw material component by weight：
Wherein, polyamide is PA66 and PA6 hybrid resin；The melt flows speed of acrylonitritrile-styrene resin
Rate is 20g/10min under 200 DEG C/10kg test condition；Metallic pigments are 50 μm of aluminium powder, bronze and silver powder by particle diameter
Mixing composition；Compatilizer is the styrene-maleimide copolymer being grafted through maleic anhydride；Filler is 3000 purposes by particle diameter
Talcum, mica and diatomite are mixed；Toughener is ethylene-propylene-copolymer-maleic anhydride；Dispersing aid is that acid number is
300mgKOH/g end carboxyl polymer；Processing aid includes β-positive 18 carbon of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid
Alcohol ester and silicone powder.
Preparation method is same as Example 1.
By the gained graininess daiamid composition finished product of comparative example 1 through 90~130 DEG C of dry 4~6h, injection temperature control
At 240~290 DEG C, the control sample 1 needed for test correlated performance is obtained by injection molding.
Comparative example 2
A kind of daiamid composition, it includes the following raw material component by weight：
Wherein, polyamide is PA66 and PA6 hybrid resin；The melt flows speed of acrylonitritrile-styrene resin
Rate is 20g/10min under 200 DEG C/10kg test condition；Metallic pigments are 50 μm of aluminium powder, bronze and silver powder by particle diameter
Mixing composition；Compatilizer is the styrene-maleimide copolymer being grafted through maleic anhydride；Filler is 3000 purposes by particle diameter
Talcum, mica and diatomite are mixed；Toughener is ethylene-propylene-copolymer-maleic anhydride；Dispersing aid is that acid number is
300mgKOH/g end carboxyl polymer；Processing aid includes β-positive 18 carbon of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid
Alcohol ester and silicone powder.
Preparation method is same as Example 1.
By the gained graininess daiamid composition finished product of comparative example 2 through 90~130 DEG C of dry 4~6h, injection temperature control
At 240~290 DEG C, the control sample 2 needed for test correlated performance is obtained by injection molding.
Comparative example 3
A kind of daiamid composition, it includes the following raw material component by weight：
Wherein, polyamide is PA66 and PA6 hybrid resin；The melt flows speed of acrylonitritrile-styrene resin
Rate is 20g/10min under 200 DEG C/10kg test condition；Metallic pigments are 50 μm of aluminium powder, bronze and silver powder by particle diameter
Mixing composition；Compatilizer is the styrene-maleimide copolymer being grafted through maleic anhydride；Filler is 3000 purposes by particle diameter
Talcum, mica and diatomite are mixed；Toughener is ethylene-propylene-copolymer-maleic anhydride；Dispersing aid is that acid number is
300mgKOH/g end carboxyl polymer；Processing aid includes β-positive 18 carbon of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid
Alcohol ester and silicone powder.
Preparation method is same as Example 1.
By the gained graininess daiamid composition finished product of comparative example 3 through 90~130 DEG C of dry 4~6h, injection temperature control
At 240~290 DEG C, the control sample 3 needed for test correlated performance is obtained by injection molding.
Embodiment 6：Performance test
Every test mode is as follows：
Glossiness is tested：Reference standard GB8807-1988 is tested, the Multi- of KONICA MINOLTA companies is used
The glossiness testers of Gloss 268 are tested, and collect 60 ° of test datas.
Mechanics Performance Testing：Tensile strength is with reference to ISO 527-2 standard testings, and bending strength is with bending modulus with reference to ISO
178 standard testings, impact strength is with reference to the standard testings of ISO 180.
Acid number performance test：Test reference standard GB/T 1668-2008；
Melt finger performance test：Test reference standard GB/T 3682-2000；
Relative viscosity is tested：Relative viscosity test reference standard GB/T1632-1993 test, using Ubbelohde viscometer,
25 DEG C of constant temperature 15min, record flow time, are computed that viscosity can be obtained.
Embodiment 1~5 and the prepared sample obtained of comparative example 1~3 are subjected to properties test respectively, its test result
It is as shown in table 1 below.
The performance test results of the embodiment 1~5 of table 1 and the prepared sample obtained of comparative example 1~3
Wherein：I represents that surface effect is excellent, no current mark or dissolving line；
II represents surface effect between I and III；
III represents that surface effect is medium, there is slighter current mark or dissolving line；
IV represents surface effect between III and V；
V represents that surface effect is poor, there is serious current mark or dissolving line.
It can be obtained according to the data of table 1, the daiamid composition shows good mechanical property and surface property, comparative example 1
Each component ratio does not go out mechanical property in restriction range performance in~3 or surface property is slightly worse.Polyamide prepared by the present invention
The product of composition production has good mechanical property and metallic luster concurrently substantially without current mark and weld mark.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (10)
1. a kind of exempting from metallic luster sprays daiamid composition, it is characterised in that by weight including the following raw material
Component：
2. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
The addition of acrylonitritrile-styrene resin and compatilizer is calculated as 0.4~10 by parts by weight of raw materials:1.
3. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
The addition of acrylonitritrile-styrene resin and dispersing aid is calculated as 2~100 by parts by weight of raw materials:1.
4. a kind of exempting from metallic luster according to any one of claims 1 to 3 sprays daiamid composition, its feature
It is：The melt flow rate (MFR) of the acrylonitrile-polyethylene and ethylene copolymers is 20~40g/ under 200 DEG C/10kg test condition
10min。
5. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
Polyamide is selected from least one of PA66, PA6 and PA12.
6. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
Compatilizer is selected from the styrene-maleimide copolymer being grafted through maleic anhydride, the styrene-second being grafted through maleic anhydride
Alkene-butylene-styrene copolymers, the acrylonitrile-butadiene-styrene copolymer being grafted through maleic anhydride, connect through maleic anhydride
At least one of the acrylonitritrile-styrene resin of branch, and their hydride.
7. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
Dispersant is from the end carboxyl polymer that acid value is 200~300mgKOH/g.
8. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
Filler is selected from aluminum oxide, clay, montmorillonite, kaolin, calcium carbonate, diatomite, mica, silica, talcum, wollastonite and precipitated sulfur
At least one of sour barium.
9. a kind of exempting from metallic luster according to claim 1 sprays daiamid composition, it is characterised in that：It is described
Toughener is selected from the ethylene-acrylate-copolymer-maleic anhydride being grafted through maleic anhydride or ethylene-propylene-maleic anhydride is common
Polymers.
10. a kind of preparation side for exempting from spraying polyamide polymer with metallic luster as described in any one of claim 1~9
Method, it is characterised in that：Weigh each raw material components by weight, using homogenizer by dried polyamide, acrylonitrile-
Styrol copolymer, filler, compatilizer, toughener, dispersing aid, processing aid and metallic pigments are well mixed, from twin-screw
Extruder main is fed mouth and added, temperature be 210~280 DEG C, vacuum be that 0.05~0.08MPa, rotating speed are 300~500rp/
Under min process conditions by double screw extruder melting extrusion, granulate, graininess exempt from spray daiamid composition finished product.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674413A (en) * | 2017-10-27 | 2018-02-09 | 上海金发科技发展有限公司 | One kind is exempted to spray polyamide resin fat complexes and preparation method thereof |
| CN107722620A (en) * | 2017-10-27 | 2018-02-23 | 上海金发科技发展有限公司 | A kind of low smell high glaze exempts to spray daiamid composition and preparation method thereof |
| CN107793754A (en) * | 2017-10-27 | 2018-03-13 | 上海金发科技发展有限公司 | A kind of environmentally friendly low smell exempts to spray daiamid composition and preparation method thereof |
| CN109897368A (en) * | 2018-11-14 | 2019-06-18 | 深圳市华盈工程塑料有限公司 | A kind of LED illumination product is with exempting to spray heat-conduction nylon material and preparation method |
| EP3789456A4 (en) * | 2018-06-20 | 2021-07-07 | Shanghai Kumhosunny Plastics Co., Ltd | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition |
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| CN102516789A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Resin composition for temperature control indication |
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| CN102516789A (en) * | 2011-12-09 | 2012-06-27 | 上海锦湖日丽塑料有限公司 | Resin composition for temperature control indication |
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| CN107674413A (en) * | 2017-10-27 | 2018-02-09 | 上海金发科技发展有限公司 | One kind is exempted to spray polyamide resin fat complexes and preparation method thereof |
| CN107722620A (en) * | 2017-10-27 | 2018-02-23 | 上海金发科技发展有限公司 | A kind of low smell high glaze exempts to spray daiamid composition and preparation method thereof |
| CN107793754A (en) * | 2017-10-27 | 2018-03-13 | 上海金发科技发展有限公司 | A kind of environmentally friendly low smell exempts to spray daiamid composition and preparation method thereof |
| CN107722620B (en) * | 2017-10-27 | 2021-04-13 | 上海金发科技发展有限公司 | Low-odor high-gloss spraying-free polyamide composition and preparation method thereof |
| CN107793754B (en) * | 2017-10-27 | 2021-04-13 | 上海金发科技发展有限公司 | Environment-friendly low-odor spraying-free polyamide composition and preparation method thereof |
| EP3789456A4 (en) * | 2018-06-20 | 2021-07-07 | Shanghai Kumhosunny Plastics Co., Ltd | Polyamide resin composition having high metal texture and preparation method of polyamide resin composition |
| CN109897368A (en) * | 2018-11-14 | 2019-06-18 | 深圳市华盈工程塑料有限公司 | A kind of LED illumination product is with exempting to spray heat-conduction nylon material and preparation method |
| WO2022043149A1 (en) * | 2020-08-31 | 2022-03-03 | Imerys Usa, Inc. | Scratch resistant mineral-filled polymer compositions, production methods and uses |
| CN113698759A (en) * | 2021-08-26 | 2021-11-26 | 金旸（厦门）新材料科技有限公司 | Reinforced and toughened high-temperature-resistant nylon material and preparation method thereof |
| CN113698759B (en) * | 2021-08-26 | 2022-11-18 | 金旸（厦门）新材料科技有限公司 | Reinforced and toughened high-temperature-resistant nylon material and preparation method thereof |
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Address after: 528322 Guangdong City, Shunde District Leliu street even Du Tian Ren Ren Industrial Park (self) plant No. 10 Applicant after: Guangdong harmony new materials Co. Ltd. Address before: 528322 No. 10 factory building of Tian Ren Industrial Park (DU Gang) in Leliu village, Leliu Town, Foshan City, Guangdong Province Applicant before: Guangdong harmony new materials Co. Ltd. |
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Inventor after: Yi Qingfeng Inventor after: Lan Chengdong Inventor after: Wang Canyao Inventor after: Yu Haiou Inventor after: Sang Jie Inventor before: Yi Qingfeng Inventor before: Lan Chengdong Inventor before: Wang Canyao Inventor before: Yu Haiou Inventor before: He Jihui Inventor before: Sang Jie |
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Address after: 528300 Longchuang Road, Malong Village Committee, Beijiao Town, Shunde District, Foshan City, Guangdong Province Applicant after: Guangdong harmony new materials Co. Ltd. Address before: 528322 No. 10 Factory Building of Tianren Industrial Park, Liandu Village, Leliu Street, Shunde District, Foshan City, Guangdong Province Applicant before: Guangdong harmony new materials Co. Ltd. |
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| CB03 | Change of inventor or designer information |
Inventor after: Lan Chengdong Inventor after: Sang Jie Inventor before: Yi Qingfeng Inventor before: Lan Chengdong Inventor before: Wang Canyao Inventor before: Yu Haiou Inventor before: Sang Jie |
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Application publication date: 20170929 |