CN107216638A - A kind of temperature becomes light modulation fire proofing material, temperature control sunshade flame resistant glass and preparation method thereof - Google Patents
A kind of temperature becomes light modulation fire proofing material, temperature control sunshade flame resistant glass and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/42—Polarizing, birefringent, filtering
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to technical field of polymer materials, more particularly, to technical field of glass materials, specifically disclose a kind of temperature and become light modulation fire proofing material, its raw material components mainly include Thermo-sensitive material, photo-curing monomer, light trigger, cross-linking type water-absorbing resin, polyhydroxyl solvents, nano-silicon solution, crosslinking agent, carbon forming agent, into charcoal auxiliary agent etc., can have the advantages that color change is fast, service life length, fire protecting performance are good by environment temperature and sunshine dual regulation its light transmittance.Present invention also offers a kind of temperature control sunshade flame resistant glass for becoming light modulation fire proofing material comprising the temperature and preparation method thereof.
Description
Technical field
The present invention relates to technical field of polymer materials, more particularly, to technical field of glass materials.
Background technology
As people are continuously increased to the requirement using space level of comfort, the dimming glass with sunshading and heat-insulating function
Application field is increasingly extensive, and its development potentiality is huge.
Dimming glass on the market is nearly all electronic control type at present, and transmission of the glass to visible ray is realized by Switching Power Supply
And barrier.Electronic control type dimming glass is divided into organic lcd and inorganic film-coating type, and organic liquor crystal formation weatherability is poor, is only used for room
Interior cut-off is used；Inorganic film-coating type complex manufacturing, production equipment is expensive, and only a few countries possess production in the world
Ability；Meanwhile, electronic control type dimming glass, which need to be powered, could realize dimming function, there are problems that designing, install,.In addition,
Existing dimming glass can not resist high temperature, can be burst when occurring fire, it is difficult to stop spreading for the intensity of a fire.Therefore, adjust
Light flame resistant glass arises at the historic moment, such as the ﹑ of 201520976334 ﹑ of Chinese patent, 201610088495 ﹑ 201120270512
201621182192 etc. individually disclose the information of light modulation flame resistant glass, and above patent is using caesium potassium flame resistant glass as component
To realize its fire-proof function.Chinese patent 201510564895 discloses a kind of fire-resistant fluid, and flame resistant glass prepared therefrom does not have
There is dimming function.
Prior art such as patent 03800722.3,94190152.1,98106929.0 etc. individually discloses a kind of temperature control and adjusted
Luminescent material, is used to prepare temperature control dimming glass as interlayer, but they do not have fire-proof function.
The content of the invention
Become light modulation fire proofing material the technical problem to be solved in the present invention is to provide a kind of temperature, can be by environment temperature and the sun
Its light transmittance of light dual regulation, has the advantages that color change is fast, service life length, fire protecting performance are good.Another mesh of the present invention
Be to provide it is a kind of comprising the temperature become dim fire proofing material temperature control sunshade flame resistant glass, can be according to environment temperature and sun spoke
The transmitance of light is automatically adjusted according to intensity, the sensitive, service life that changes colour is long, while also there is fire protecting performance, using safer.
Practical present invention also offers a kind of preparation method of the temperature control sunshade flame resistant glass, production efficiency is high, the quality of production
It is good.
In order to solve the above technical problems, the technical solution used in the present invention is：
A kind of temperature becomes light modulation fire proofing material, its raw material components by weight in terms of 100 parts, including：Thermo-sensitive material 3.0~
15 parts, 2.0~15 parts of photo-curing monomer, 0.02~0.5 part of light trigger, 0.01~1 part of cross-linking type water-absorbing resin, nano silicasol
40~50 parts of liquid, 0.3~1 part of curing agent, 1~5 part of carbon forming agent, into 1~5 part of charcoal auxiliary agent, 3.5~25 parts of polyhydroxyl solvents are remaining
Measure as water；
The alkaline aqueous solution for the nanometer silicon dioxide particle that it is 20~40% containing mass fraction that the nano-silicon solution, which is,；
The raw material components are mixed to prepare the temperature and become light modulation fire proofing material.
Further, the Thermo-sensitive material is amphiphilic species of the HLB value between 10~18.5.They are in a constant temperature
There is dissolving and the function of separating out under degree and concentration conditions in water, cause sunray to occur light scattering, material is by transparent turn
Become gonorrhoea sunshade state, this function be used to realize sunshade colour change function in the present invention, and its visible light transmissivity is existed
The temperature spot of reduction by 10% is defined as discoloring temperature in 0.1 DEG C.
As a preferred embodiment of the present invention, described amphiphilic species can be block polyether, alkyl phenol polyoxy
Vinethene and polyoxyethylene fatty acid ester etc., the selection of suitable amphiphilic species and proportioning can make temperature become light modulation fire proofing material
With quick color change and excellent shading performance.
The photo-curing monomer is the one or more in simple function group photo-curing monomer or polyfunctional group photo-curing monomer.
Further, the simple function group photo-curing monomer is with one of having structure：
Wherein：R1=hydrogen or methyl, R2=methoxyl group, dimethyl or isopropyl；
R3=hydrogen or methyl, R4=hydrogen, ethoxy, hydroxypropyl or polyethylene glycol.
Further, the polyfunctional group photo-curing monomer is with having structure：
Wherein：R5One or more in=hydrogen, methyl or methoxyl group.
The photo-curing monomer can for hydroxyethyl methacrylate, hydroxy-ethyl acrylate, acrylic acid, hydroxypropyl acrylate,
NMA, Methacrylamide, acrylamide, DMAA, NIPA, polyethylene glycol
One or more in mono acrylic ester, polyethyleneglycol diacrylate etc..Photo-curing monomer determines body together with light trigger
The curing rate of system, while with cross-linking type water-absorbing resin formation interpenetrating polymer networks, the service life of decision product and sunshade
Performance.But, the present invention is for one of difficult point of inventor：It is also formula design to select suitable photo-curing monomer composition
Important step, reasonable selection monomer, how from dilution property, reactivity, shrinkage, surface tension, excitant, smell and cost
It is one of difficult point of the present invention that monomer is screened etc. several respects.The temperature control that the present invention becomes light modulation fire proofing material containing temperature can be applied to
Sunshade flame resistant glass, and the good photo-curing monomer for being adapted to effect can be reached with other components in temperature control sunshade flame resistant glass
It is selective.
Further, the light trigger is in benzophenone, 4- phenyl-benzophenones, styrax, dimethoxybenzoin
One or more.
Further, the UV absorbers are BP-4.
Further, the cross-linking type water-absorbing resin is starch grafted acrylate potassium, polyacrylamide, cross-linked carboxymethyl
Cellulose, cross-linked carboxymethyl cellulose graft acrylamide, cross-linking type hydroxyethyl cellulose graft acrylamide polymer, propylene
One or more compositions in sour crosslinked resin.
Cross-linking type water-absorbing resin is a kind of high polymer material of purposes widely, but applies to present invention modified tone containing temperature
The water-absorbing resin of the temperature control sunshade flame resistant glass of light fire proofing material is selective.Cross-linking type water-absorbing resin has absorptance itself
The high water absorption function of hundreds of to thousands of times water is weighed, and water retention property is excellent, is expanded into once water-absorbing resin after hydrogel, shape
It into the solid space framework with some strength, on the one hand can increase the viscosity of the aqueous solution, prevent the temperature control after embedding from hiding
Positive flame resistant glass is in use because Action of Gravity Field produces " bulge " phenomenon；On the other hand, when the Thermo-sensitive amphiphilic in the aqueous solution
When material occurs temperature-responsive and produces volume contraction, be conducive to maintaining the dimensional stability of whole system, temperature control can be prevented
The generation of the bad phenomenons such as the cissing of sunshade flame resistant glass, the uneven, cracking of discoloration, makes whole system have very wide environment work
Make scope, its efficient working range is at -25 DEG C~+80 DEG C.
Further, the nano-silicon solution is the hydroxide that nanometer silicon dioxide particle is 50% with mass percentage concentration
Aqueous solutions of potassium is mixed to prepare.
Further, the carbon forming agent is the one or more in sucrose, fructose, glucose and granulated sugar；It is described to be helped into charcoal
Agent is the one or more in potassium dihydrogen phosphate, potassium hydrogen phosphate, sodium dihydrogen phosphate and dibastic sodium phosphate.They are at high temperature can be with
The material of long-chain charcoal insulating barrier is formed, when glue-line of preventing fires foams generation hole at high temperature, they carbonize into carbide, deposition
In above-mentioned hole, amount of heat, the fire protecting performance of reinforcing glass are absorbed.Fire prevention glue-line refers to that temperature becomes light modulation fire proofing material and passed through
Glued membrane after photocuring.
The curing agent is sodium pyrophosphate, potassium fluosilicate, the one or more of prodan, and it is water miscible silicon solution
Curing agent, on the premise of not influenceing temperature to become light modulation fire proofing material transparency, can improve temperature and become after light modulation fire proofing material solidification
Fire prevention glue-line intensity.
The polyhydroxyl solvents are one kind in ethylene glycol, propane diols, glycerine, polyethylene glycol, polypropylene glycol, polyglycereol
Or two kinds, wherein the molecular weight of the polyethylene glycol, polypropylene glycol, polyglycereol is 200~600.Made using above-mentioned polyalcohol
The anti-high and low-temp performance that temperature becomes light modulation fire proofing material can be improved for solvent, can also further be improved temperature as carbon forming agent and become
Dim the fire protecting performance of fire proofing material.
Temperature of the invention becomes the preparation method of light modulation fire proofing material, and step is as follows：
It is put into high-speed mixer and stirs after each raw material components in addition to cross-linking type water-absorbing resin and water are weighed by proportioning
Mix 30~60 minutes, obtain mixture；Cross-linking type water-absorbing resin and water are added into the mixture of above-mentioned gained, 60~90 points are stirred
Clock, is produced.
Temperature control sunshade flame resistant glass of the present invention, including temperature as described above become light modulation fire proofing material.
Present invention also offers a kind of preparation method of temperature control sunshade flame resistant glass, specific steps include：
Edge of the glass that small one and large one two panels was cleaned along the small sheet glass parallel bonding of glue, makes two sheet glass
Between leave the closing gap with encapsulating mouthful and steam vent；
Light modulation fire proofing material is become to the filling temperature of the closing gap between two sheet glass by the encapsulating mouthful；
Canned glass is subjected to roll-in sizing with roll squeezer, then shaped through photocuring, sealing is produced.
Pass through the fire prevention glue-line of temperature control sunshade flame resistant glass made from the preparation method of above-mentioned temperature control sunshade flame resistant glass
Thickness is 2mm~4mm.
Compared with prior art, beneficial effects of the present invention are shown：
(1) present invention gained temperature change light modulation fire proofing material is a kind of by temperature and sunshine dual regulation material transmittance
Novel intelligent material, its color change is fast, and service life is long, and preparation method is simple, safe and pollution-free, environmental protection, simultaneously
With good fire protecting performance；
(2) the temperature control sunshade flame resistant glass of present invention gained change containing temperature light modulation fire proofing material is one kind by temperature and sun spoke
Penetrate intensity double condition regulation ultraviolet, visible ray, the intelligent glass of infrared light transmission rate, it is not necessary to artificially give signal (as led to
Electricity) purpose that sunshade is dimmed is reached, therefore be a kind of intelligent artifact truly；Add nano-silicon solution and carbon forming agent
Deng improving the solid content of material, water content reduction, the influence reduction to the apparent mass of glass, hardness and toughness, Neng Gouxian
The fire protecting performance for improving glass is write, the using effect of glass is improved, extends service life；
(3) preparation method of temperature control sunshade flame resistant glass of the present invention be it is a kind of can serialization, the production that automates, clean
The production technology of the highly effective of large scale light modulation flame resistant glass；
(4) temperature control sunshade flame resistant glass of the present invention can automatically adjust sunlight transmittance rate, and summer eliminates indoor sunlight and burnt
Thermal sensation, reduces air conditioner refrigerating energy consumption, while sunshade, still keeps indoor lightness, and indoor light is soft, refrigerant；Winter
High printing opacity, can daylighting complementary energy, can reduce heating energy consumption, reduce the environmental pollution that power generation is caused；Fire protecting performance is excellent, uses
It is safer.
Brief description of the drawings
Fig. 1 is temperature control sunshade flame resistant glass visible ray and red at varying environment temperature and solar irradiation intensity in the present invention
The change curve of outside line transmitance.
Embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by
It will be appreciated by those skilled in the art that apparent clearly being defined so as to be made to protection scope of the present invention.
Weatherability test, test event and evaluation criterion row have been carried out for temperature control sunshade flame resistant glass produced by the present invention
In table 1：
The weatherability evaluation of the temperature control sunshade flame resistant glass of table 1
By the test to begin a project, temperature control sunshade flame resistant glass of the invention has steady under -25 DEG C~+80 DEG C environment
Fixed performance and long-term service life.
As seen from Figure 1, temperature control sunshade flame resistant glass of the invention has with environment temperature and solar irradiation intensity certainly
The performance of dynamic adjustment light transmittance, so as to realize intelligent dimming.
Embodiment 1：Temperature becomes light modulation fire proofing material, becomes temperature control shading flame resistant glass and the preparation side of light modulation fire proofing material containing temperature
Method
The component that the present embodiment temperature becomes light modulation fire proofing material is as shown in table 2：
Table 2：The present embodiment temperature becomes the component of light modulation fire proofing material
| Material | Parts by weight |
| Block polyether HLB=12.0 | 3 |
| Hydroxy-ethyl acrylate | 1.5 |
| Polyethyleneglycol diacrylate | 0.5 |
| 4- phenyl-benzophenones | 0.5 |
| Polyacrylamide | 0.01 |
| Macrogol 600 | 25 |
| Sodium pyrophosphate | 0.3 |
| 40%wt nano-silicon solution | 30 |
| Sucrose | 1 |
| Potassium hydrogen phosphate | 1 |
| Water | 37.19 |
The present embodiment temperature becomes the preparation method of light modulation fire proofing material, and step is as follows：
(1) it is put into high-speed mixer and stirs after each raw material in addition to cross-linking type water-absorbing resin and water is weighed by proportioning
30 minutes, obtain mixture；
(2) cross-linking type water-absorbing resin and water are added into mixture obtained by step (1), stirs 60 minutes, produces.
The present embodiment becomes the light modulation temperature control sunshade flame resistant glass ECDC piece of fire proofing material containing temperature, dispensing, filling, rolling, solid
Change, edge sealing process is prepared from, step is as follows：
Described temperature is become light modulation fire proofing material and pours into high-order storage tank by S1；
S2 arrives first large-size glass band lifting universal wheel changeover portion after glass cleaning machine, into being automatically positioned conjunction
Glass is picked up by the automatic sucking disc lifting frame of top after piece machine；
Enter band lifting universal wheel changeover portion after second cleaned machine of small size glass of S3 to stop, universal Luntai rises,
In glass edge dispensing, and leave encapsulating mouthful and steam vent；
S4 positions the small size glass of the good glue of step S3 points into automatic sheet binding machine, by the step on automatic sucking disc lifting frame
S2 large-size glass is completed through automatic decline with small size glass conjunction piece；
The glass of step S4 conjunction plates is conveyed into another changeover portion of lifting universal wheel by S5 to be stopped, and rises universal Luntai,
Shift glass onto left and right roll-over table described temperature change light modulation fire proofing material progress is filling；
The canned glass of step S5 is pushed back another changeover portion of universal wheel by S6, and roll-in sizing is carried out into roll squeezer；
S7 shapes the qualified glass of step S6 roll-ins through changeover portion into curing photocuring：
Glass after S8 solidifies step S7 carries out secondary sealing, produces.
The embodiment of the present invention 1 becomes the performance parameter test result of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature such as
Shown in table 3.
Table 3：Become the performance parameter of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature
| Project | Index |
| Discoloring temperature | 15℃ |
| Shading coefficient | 0.35 |
| Weatherability is evaluated | Without infiltration, bubble, degumming, grow dim, shrink lamination |
Embodiment 2：Temperature becomes light modulation fire proofing material, becomes temperature control sunshade flame resistant glass and the preparation of light modulation fire proofing material containing temperature
The component that the present embodiment temperature becomes light modulation fire proofing material is as shown in table 4：
Table 4：The present embodiment temperature becomes the component of light modulation fire proofing material
Temperature becomes the preparation method of light modulation fire proofing material, and step is as follows：
(1) it is put into high-speed mixer and stirs after each raw material in addition to cross-linking type water-absorbing resin and water is weighed by proportioning
40 minutes, obtain mixture；
(2) cross-linking type water-absorbing resin and water are added into mixture obtained by step (1), stirs 70 minutes, produces.
Become the temperature control sunshade flame resistant glass ECDC piece for dimming fire proofing material, dispensing, filling, rolling, solidification, edge sealing work containing temperature
Skill is prepared from, method such as embodiment 1.
The embodiment of the present invention 2 becomes the performance parameter test result of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature such as
Shown in table 5.
Table 5：Become the performance parameter of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature
| Project | Index |
| Discoloring temperature | 55℃ |
| Shading coefficient | 0.25 |
| Weatherability is evaluated | Without infiltration, bubble, degumming, grow dim, shrink lamination |
Embodiment 3：Temperature becomes light modulation fire proofing material, becomes temperature control sunshade flame resistant glass and the preparation of light modulation fire proofing material containing temperature
The raw material components that the present embodiment temperature becomes light modulation fire proofing material are as shown in table 6：
Table 6：The present embodiment temperature becomes the component of light modulation fire proofing material
| Material | Parts by weight |
| Dodecyl phenol polyethenoxy ether HLB=14.5 | 10 |
| Methacrylic acid | 10 |
| Methoxy poly (ethylene glycol) mono acrylic ester | 5 |
| Styrax | 0.01 |
| Benzophenone | 0.01 |
| Cross-linked carboxymethyl cellulose | 0.5 |
| Polypropylene glycol 400 | 3.5 |
| Potassium fluosilicate | 1 |
| 20%wt nano-silicon solution | 40 |
| Glucose | 2 |
| Granulated sugar | 3 |
| Potassium hydrogen phosphate | 2 |
| Water | 22.98 |
Temperature becomes the preparation method of light modulation fire proofing material, and step is as follows：
(1) it is put into high-speed mixer and stirs after each raw material in addition to cross-linking type water-absorbing resin and water is weighed by proportioning
35 minutes, obtain mixture；
(2) cross-linking type water-absorbing resin and water are added into mixture obtained by step (1), stirs 80 minutes, produces.
Become the temperature control sunshade flame resistant glass ECDC piece for dimming fire proofing material, dispensing, filling, rolling, solidification, edge sealing work containing temperature
Skill is prepared from, method such as embodiment 1.
The embodiment of the present invention 3 becomes the performance parameter test result of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature such as
Shown in table 7.
Table 7：Become the performance parameter of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature
Embodiment 4：Temperature becomes light modulation fire proofing material, becomes temperature control sunshade flame resistant glass and the preparation of light modulation fire proofing material containing temperature
The raw material components that the present embodiment temperature becomes light modulation fire proofing material are as shown in table 8：
Table 8：The present embodiment temperature becomes the component of light modulation fire proofing material
| Material | Parts by weight |
| Block polyether HLB=16.0 | 2 |
| Dodecyl phenol polyethenoxy ether HLB=11.5 | 3 |
| Hydroxypropyl acrylate | 5 |
| Polyethylene glycol monoacrylate | 5 |
| Dimethoxybenzoin | 0.1 |
| Cross-linked carboxymethyl cellulose graft acrylamide | 0.5 |
| Acrylic acid crosslinked resin | 0.5 |
| Ethylene glycol | 5 |
| Propane diols | 5 |
| Potassium fluosilicate | 0.5 |
| 20%wt nano-silicon solution | 45 |
| Carbon forming agent fructose | 3 |
| Sodium dihydrogen phosphate | 3 |
| Water | 22.4 |
Temperature becomes the preparation method of light modulation fire proofing material, and step is as follows：
(1) it is put into high-speed mixer and stirs after each raw material in addition to cross-linking type water-absorbing resin and water is weighed by proportioning
45 minutes, obtain mixture；
(2) cross-linking type water-absorbing resin and water are added into mixture obtained by step (1), stirs 80 minutes, produces.
Become the temperature control sunshade flame resistant glass ECDC piece for dimming fire proofing material, dispensing, filling, rolling, solidification, edge sealing work containing temperature
Skill is prepared from, preparation method such as embodiment 1.
The embodiment of the present invention 4 becomes the performance parameter test result of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature such as
Shown in table 9.
Table 9：Become the performance parameter of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature
| Project | Index |
| Discoloring temperature | 32℃ |
| Shading coefficient | 0.30 |
| Weatherability is evaluated | Without infiltration, bubble, degumming, grow dim, shrink lamination |
Embodiment 5：Temperature becomes light modulation fire proofing material, becomes temperature control sunshade flame resistant glass and the preparation of light modulation fire proofing material containing temperature
The raw material components that the present embodiment temperature becomes light modulation fire proofing material are as shown in table 10：
Table 10：The present embodiment temperature becomes the component of light modulation fire proofing material
Temperature becomes the preparation method of light modulation fire proofing material, and step is as follows：
(1) it is put into high-speed mixer and stirs after each raw material in addition to cross-linking type water-absorbing resin and water is weighed by proportioning
35 minutes, obtain mixture；
(2) cross-linking type water-absorbing resin and water are added into mixture obtained by step (1), stirs 90 minutes, produces.
Become the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature, by above-mentioned temperature change material ECDC piece, dispensing, it is filling,
Rolling, solidification, edge sealing process are prepared from, preparation method such as embodiment 1.
The embodiment of the present invention 5 becomes the performance parameter test result of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature such as
Shown in table 11.
Table 11：Become the performance parameter of the temperature control sunshade flame resistant glass of light modulation fire proofing material containing temperature
| Project | Index |
| Discoloring temperature | 20℃ |
| Shading coefficient | 0.20 |
| Weatherability is evaluated | Without infiltration, bubble, degumming, grow dim, shrink lamination |
Fire resistance test experience is carried out to above-mentioned 5 blocks of flame resistant glasses according to GB/T12513-2006 standards, obtains each
The fire prevention time of composite fireproof glass, experiment takes parallel sample 3, takes its statistical average as experimental result, parameter is referred to
Table 12.
Table 12：The fire protecting performance parameter list of temperature control sunshade flame resistant glass
| Sample | Fireproof gum thickness/mm | The fire prevention time/min |
| Embodiment 1 | 2 | 55 |
| Embodiment 2 | 3 | 61 |
| Embodiment 3 | 3.5 | 65 |
| Embodiment 4 | 4 | 74 |
| Embodiment 5 | 4 | 76 |
It can be drawn by the data of above-mentioned not be the same as Example：Gained of the invention becomes the temperature control sunshade of light modulation fire proofing material containing temperature
Flame resistant glass can automatically adjust sunlight exposure intensity, and summer eliminates indoor sunlight burning heat sensation, reduces air conditioner refrigerating energy consumption,
While sunshade, indoor lightness is still kept, indoor light is soft, refrigerant；Winter high printing opacity, can daylighting complementary energy, can reduce
Heating energy consumption.With excellent weather resistance, fire protecting performance, no infiltration, bubble, degumming, grow dim, shrink lamination.
The present invention is described in detail above, embodiments of the present invention carried out using specific case in the present invention
Illustrate, the explanation of above example is only intended to help and understands the present invention, it is noted that for the technology people of the art
For member, under the premise without departing from the principles of the invention, some improvement can be also carried out to the present invention, these improvement also fall into this hair
In bright scope of the claims.
Claims (11)
1. a kind of temperature becomes light modulation fire proofing material, it is characterised in that：Its raw material components by weight in terms of 100 parts, including：Thermo-sensitive
3.0~15 parts of material, 2.0~15 parts of photo-curing monomer, 0.02~0.5 part of light trigger, cross-linking type water-absorbing resin 0.01~1
Part, 40~50 parts of nano-silicon solution, 0.3~1 part of curing agent, 1~5 part of carbon forming agent, into 1~5 part of charcoal auxiliary agent, polyhydroxyl solvents
3.5~25 parts, surplus is water；
The alkaline aqueous solution for the nanometer silicon dioxide particle that it is 20~40% containing mass fraction that the nano-silicon solution, which is,；
The raw material components are mixed to prepare the temperature and become light modulation fire proofing material.
2. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The Thermo-sensitive material is that HLB value exists
Amphiphilic species between 10~18.5.
3. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The photo-curing monomer is simple function group
One or more in photo-curing monomer or polyfunctional group photo-curing monomer.
4. temperature according to claim 3 becomes light modulation fire proofing material, it is characterised in that：The simple function group photo-curing monomer is
With one of having structure：
Wherein：R1=hydrogen or methyl, R2=methoxyl group, dimethyl or isopropyl；
R3=hydrogen or methyl, R4=hydrogen, ethoxy, hydroxypropyl or polyethylene glycol.
5. temperature according to claim 3 becomes light modulation fire proofing material, it is characterised in that：The polyfunctional group photo-curing monomer is
With having structure：
Wherein：R5One or more in=hydrogen, methyl or methoxyl group.
6. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The light trigger be benzophenone,
One or more in 4- phenyl-benzophenones, styrax, dimethoxybenzoin；The UV absorbers are 2- hydroxyls -4-
Methoxy benzophenone -5- sulfonic acid.
7. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The cross-linking type water-absorbing resin is starch
Grafted propylene hydrochlorate potassium, polyacrylamide, cross-linked carboxymethyl cellulose, cross-linked carboxymethyl cellulose graft acrylamide, crosslinking
One or more in type hydroxyethyl cellulose graft acrylamide, acrylic acid crosslinked resin；The polyhydroxyl solvents are second two
One or two kinds of in alcohol, propane diols, glycerine, polyethylene glycol, polypropylene glycol, polyglycereol, wherein the polyethylene glycol, poly-
Propane diols, the molecular weight of polyglycereol are 200~600.
8. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The nano-silicon solution is nano-silica
Silicon carbide particle is mixed to prepare with mass percentage concentration for 50% potassium hydroxide aqueous solution.
9. temperature according to claim 1 becomes light modulation fire proofing material, it is characterised in that：The curing agent is sodium pyrophosphate, fluorine
The one or more of potassium silicate, prodan；The carbon forming agent is the one or more in sucrose, fructose, glucose and granulated sugar；
It is described into charcoal auxiliary agent be potassium dihydrogen phosphate, potassium hydrogen phosphate, sodium dihydrogen phosphate and dibastic sodium phosphate in one or more.
10. a kind of temperature control sunshade flame resistant glass, it is characterised in that：Including temperature modified tone as claimed in any one of claims 1-9 wherein
Light fire proofing material.
11. a kind of preparation method of temperature control sunshade flame resistant glass as claimed in claim 10, it is characterised in that：Including：
Side of the glass that small one and large one two panels was cleaned along the small sheet glass parallel bonding of glue, makes to stay between two sheet glass
There is the closing gap with encapsulating mouthful and steam vent；
Light modulation fire proofing material is become to the filling temperature of the closing gap between two sheet glass by the encapsulating mouthful；
Canned glass is subjected to roll-in sizing with roll squeezer, then shaped through photocuring, sealing is produced.
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