CN107204216A - The super soft mineral insulated cable of graphene - Google Patents
The super soft mineral insulated cable of graphene Download PDFInfo
- Publication number
- CN107204216A CN107204216A CN201710407267.6A CN201710407267A CN107204216A CN 107204216 A CN107204216 A CN 107204216A CN 201710407267 A CN201710407267 A CN 201710407267A CN 107204216 A CN107204216 A CN 107204216A
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- China
- Prior art keywords
- layer
- conductor
- graphene
- cable
- graphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/04—Flexible cables, conductors, or cords, e.g. trailing cables
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
- H01B1/026—Alloys based on copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
- H01B7/22—Metal wires or tapes, e.g. made of steel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses a kind of super soft mineral insulated cable of graphene, the super soft mineral insulated cable of graphene is used as conductor using graphene, and graphene conductor is placed in ceramic polyolefin insulation layer, one is that can improve the signal transmission of cable, and two be that conductive effect is good.Graphene conductor of the present invention at least includes two kinds of materials of graphene and conducting resinl, and conducting resinl is used to combine graphene powder, and from the stronger sticking conducting resinl of tool, graphene conductor is prepared into the conductor wire of super flexible energy.Wired signal transmission and conductive capability of the present invention are eager to excel than traditional cable.Cable of the present invention except signal transmission and conductive capability by force in addition to, also with very strong fire resistance property.
Description
Technical field
The present invention relates to field of cable technology, a kind of super soft mineral insulated cable of graphene is particularly related to.
Background technology
The structure of conventional insulator cable is generally two layers, and internal layer is metal conducting layer, and outer layer is non-metallic insulation layer.So
Cable be only used for common place, and, easy aging inflammable with insulating barrier, it is difficult to be resistant to high temperature, the short grade of service life lacks
Point.
Generally using copper as conductive layer in cable, and copper is easily aoxidized and corroded in itself, and copper quality compared with
Soft, ductility is not good.In the prior art, in order to solve the problem of copper is oxidized and corroded, generally carried out on the surface of conductive copper
Electroplating processes, plate the oxidation resistant material of last layer.But this electroplating technology causes the raising of cable production cost, and easily
Pollute environment.In order to strengthen the ductility of cable, can resist bending be set between conductor and insulating barrier, with good ductility
Material layer.But this material needs to consider cost and performance, it is not easy to find.Therefore, insulated cable one at present on the market
As be difficult to while having good electric conductivity and stronger anti-flammability.
Graphene is a kind of two-dimensional material, is made up of pure carbon atom.Its molecular structure is fine and close, the thing in addition to hydrogen atom
Matter can not be passed through.Therefore acidproof, resistance to oxidation.In all material, it has highest carrier transport speed, and its electronics is passed
Conductance 15000cmol/L/ (V.s), superpower resistance to high current ability is a kind of excellent conductor.In addition, grapheme material can be with
It is mixed into well in other materials so that corrosion-resistant, wearability that the material of synthesis has had.
Graphene-structured is highly stable, so far, and researcher does not have found the situation for having carbon atom to lack in graphene yet.
Connection in graphene between each carbon atom is very flexible, when apply external mechanical force when, carbon atom face with regard to flexural deformation so that
Make carbon atom to be rearranged to adapt to external force, be also maintained for Stability Analysis of Structures.The lattice structure of this stabilization makes carbon atom
With outstanding electric conductivity., will not be because of lattice defect or introducing foreign atom when electronics in graphene is moved in track
Scatter.Because interatomic force is very strong, at normal temperatures, even if surrounding carbon atom is telescoped, electronics in graphene
The interference being subject to is also very small, meanwhile, graphene be in the world it is most thin be also most hard nano material, it is almost fully transparent
, the light of an absorption 2.3%；Thermal conductivity factor is up to 5300W/ (mK), higher than CNT and diamond, its electronics under normal temperature
Mobility is and higher than CNT or silicon crystal more than 15000cm2/ (Vs), and resistivity only about 10-6 Ω cm, compares copper
It is the minimum material of world resistivity or silver is lower.Because its resistivity is extremely low, the speed that electronics is run is exceedingly fast, and graphene is
The best material of electric conductivity in the world, the movement velocity of electronics wherein has reached the 1/300 of the light velocity, existed considerably beyond electronics
Movement velocity in general conductor.
In the field of communications, some cables it is also desirable to have higher anti-interference, and conventional cable is typically set
Conductor shield and insulation screen are equipped with, to reach the effect of homogenizing electric field.But existing screen layer is typically in rubber
Middle addition conductive carbon black.Distribution, size and the carbon black of carbon black granules and the fusion degree of rubber all affect anti-jamming effectiveness.
The content of the invention
For deficiency of the prior art, the technical problem to be solved in the present invention is the provision of a kind of super soft ore deposit of graphene
Thing insulated cable.
In order to solve the above technical problems, the present invention is realized by following scheme：The super soft mineral-insulated fireproof electricity of graphene
Cable, the cable includes：
Sheath, the sheath is placed in outermost layer, and the sheath is halogen-free and low-smoke flame-retardant polyolefin sheathed；
The chain armor of copper strips, the chain armor of copper strips is placed in sheath；
Separation layer, the isolation is placed in copper ribbon continuous lock armor, and the separation layer is ceramic polyolefin separators；
At least one cable core, the outer layer of the cable core and intermediate layer be respectively ceramic polyolefin insulation layer,
The wrapped flame retardant coating of synthetic mica, innermost layer is copper conductor；
The dilute conductor of graphite is provided with the anchor ring of the ceramic polyolefin insulation layer, the dilute conductor of graphite is in annular
Array is distributed in ceramic polyolefin insulation layer；
The cable core is placed in separation layer, and the gap location between the cable core and the separation layer is filled with
Glass cord；
The glass cord outer layer is wound with least one layer of glass fiber tape.
Further, the chain armor of the copper strips is layers of copper or albronze layer or aluminium lamination.
Further, the copper conductor includes folded tight many copper wires together.
Further, the cable core is provided with five, and its circular array is placed in separation layer.
Further, the glass fiber tape is provided with two layers, and layer glass fiber band is in braided by glass fiber strand
Tightly.
A kind of cable core, including the dilute conductor of graphite, the dilute conductor of graphite include the material of following mass parts：
Graphite dilute 99%；
Conducting resinl 1%.
A kind of cable core preparation method, this method comprises the following steps：
Step one：The preparation of the dilute conductor of graphite, the liquid that the dilute powder of graphite for being 99% by mass parts is 1% with mass parts
Conducting resinl 1% is mixed, and the dilute conductor wire body of graphite is prepared by expressing technique；
Step 2：Copper conductor is placed in the wrapped flame retardant coating of synthetic mica by crust coating technology, forms internal layer core；
Step 3：Internal layer core in step 2 is placed in down to the center of rubber moulding, rubber moulding is clamping, by step one
Some dilute conductor wire bodies of graphite are put into ring array in rubber moulding, and ceramic polyolefin insulation layer is prepared by way of reverse mould；
Step 4：After solidification, the finished product in step 3, as cable core are taken out.
Relative to prior art, the beneficial effects of the invention are as follows：The super soft mineral insulated cable of graphene of the present invention is adopted
With graphene as conductor, and graphene conductor is placed in ceramic polyolefin insulation layer, and one is that the signal that can improve cable is passed
Defeated, two be that conductive effect is good.Graphene conductor of the present invention at least includes two kinds of materials of graphene and conducting resinl, and conducting resinl is used to tie
Graphene powder is closed, from the stronger sticking conducting resinl of tool, graphene conductor is prepared into the conductor wire of super flexible energy.This
Invention wired signal transmission and conductive capability are eager to excel than traditional cable.Cable of the present invention is except signal transmission and conductive energy
Power is outer by force, also with very strong fire resistance property.
Brief description of the drawings
Fig. 1 is fireproof cable structural representation of the present invention.
Marked in accompanying drawing：The wrapped flame retardant coating 2 of copper conductor 1, synthetic mica, ceramic polyolefin insulation layer 3, glass cord
4th, the chain armor 7 of glass fiber tape 5, separation layer 6, copper strips, sheath 8, the dilute conductor 9 of graphite.
Embodiment
The preferred embodiments of the present invention are described in detail below in conjunction with the accompanying drawings, so that advantages and features of the invention energy
It is easier to be readily appreciated by one skilled in the art, apparent is clearly defined so as to be made to protection scope of the present invention.
Embodiment 1：
Accompanying drawing 1 is refer to, the super soft mineral insulated cable of graphene of the invention, the cable includes：
Sheath 8, the sheath 8 is placed in outermost layer, and the sheath 8 is halogen-free and low-smoke flame-retardant polyolefin sheathed；The sheath 8 is prevented fires
Ability is strong；It is halogen-free and low-smoke flame-retardant polyolefin sheathed not allow easy firing, even if it produces few smog, fire proofing energy after burning
Enough prevent the condition of a fire from expanding；
The chain armor 7 of copper strips, the chain armor 7 of copper strips is placed in sheath 8；The chain armor 7 of the copper strips has
Destroyed ability is prevented, the layer is screen layer；The chain armor of copper strips is layers of copper or albronze layer or aluminium lamination.
Separation layer 6, the separation layer 6 is placed in the chain armor 7 of copper strips, and the separation layer 6 is isolated for ceramic polyolefin
Layer；Because ceramics have the cold fast function of effect, it therefore, it can the heat inside absorbing cable to outside, while for isolating
With heat sinking function；
At least one cable core, the outer layer of the cable core and intermediate layer be respectively ceramic polyolefin insulation layer 3,
The wrapped flame retardant coating 2 of synthetic mica, innermost layer is copper conductor 1；Preferred scheme, the cable core is provided with five, its battle array in a ring
Row are placed in separation layer 6, and the copper conductor 1 includes folded tight many copper wires together.
The dilute conductor 9 of graphite is provided with the anchor ring of the ceramic polyolefin insulation layer 3, the dilute conductor 9 of graphite is in circle
Annular array type is distributed in ceramic polyolefin insulation layer 3；
The cable core is placed in separation layer 6, the gap location filling between the cable core and the separation layer 6
There is glass cord 4；
The outer layer of glass cord 4 is wound with least one layer of glass fiber tape 5.
The glass fiber tape 5 is provided with two layers, and layer glass fiber band 5 tightens glass cord 4 in braided.
Embodiment 2：
A kind of cable core, including the dilute conductor 9 of graphite, the dilute conductor 9 of graphite include the material of following mass parts：
Graphite dilute 99%；
Conducting resinl 1%.
The above two material of the dilute conductor 9 of graphite of the present invention is only main material, does not limit it and there was only both materials.
Embodiment 3：
A kind of cable core preparation method, this method comprises the following steps：
Step one：The preparation of the dilute conductor 9 of graphite, the liquid that the dilute powder of graphite for being 99% by mass parts is 1% with mass parts
Body conducting resinl 1% is mixed, and the dilute wire body of conductor 9 of graphite is prepared by expressing technique；
Step 2：Copper conductor 1 is placed in the wrapped flame retardant coating 2 of synthetic mica by crust coating technology, forms internal layer core；
Step 3：Internal layer core in step 2 is placed in down to the center of rubber moulding, rubber moulding is clamping, by step one
Some dilute wire bodies of conductor 9 of graphite are put into ring array in rubber moulding, and ceramic polyolefin insulation layer is prepared by way of reverse mould
3；
Step 4：After solidification, the finished product in step 3, as cable core are taken out.
The preferred embodiment of the present invention is the foregoing is only, is not intended to limit the scope of the invention, every profit
The equivalent structure or equivalent flow conversion made with description of the invention and accompanying drawing content, or directly or indirectly it is used in other phases
The technical field of pass, is included within the scope of the present invention.
Claims (7)
1. the super soft mineral insulated cable of graphene, it is characterised in that the cable includes：
Sheath (8), the sheath (8) is placed in outermost layer, and the sheath (8) is halogen-free and low-smoke flame-retardant polyolefin sheathed；
The chain armor of copper strips (7), the chain armor of copper strips (7) is placed in sheath (8)；
Separation layer (6), the separation layer (6) is placed in the chain armor of copper strips (7), and the separation layer (6) is ceramic polyolefin
Separation layer；
At least one cable core, the outer layer of the cable core and intermediate layer are ceramic polyolefin insulation layer (3), conjunction respectively
Into the wrapped flame retardant coating of mica (2), innermost layer is copper conductor (1)；
The dilute conductor of graphite (9) is provided with the anchor ring of the ceramic polyolefin insulation layer (3), the dilute conductor of graphite (9) is in
Circular array formula is distributed in ceramic polyolefin insulation layer (3)；
The cable core is placed in separation layer (6), the gap location filling between the cable core and the separation layer (6)
There is glass cord (4)；
Glass cord (4) outer layer is wound with least one layer of glass fiber tape (5).
2. the super soft mineral insulated cable of graphene according to claim 1, it is characterised in that the chain armour of copper strips
It is layers of copper or albronze layer or aluminium lamination to fill layer (7).
3. the super soft mineral insulated cable of graphene according to claim 1, it is characterised in that the copper conductor (1)
Including folded tight many copper wires together.
4. the super soft mineral insulated cable of graphene according to claim 1, it is characterised in that the cable core is set
There are five, its circular array is placed in separation layer (6).
5. the super soft mineral insulated cable of graphene according to claim 1, it is characterised in that the glass fiber tape
(5) it is provided with two layers, layer glass fiber band (5) tightens glass cord (4) in braided.
6. a kind of cable core with described in claim 1-5 any one, it is characterised in that：Including the dilute conductor of graphite (9), institute
Stating the dilute conductor of graphite (9) includes the material of following mass parts：
Graphite dilute 99%；
Conducting resinl 1%.
7. a kind of cable core preparation method with described in claim 6, it is characterised in that this method comprises the following steps：
Step one：The preparation of the dilute conductor of graphite (9), the liquid that the dilute powder of graphite for being 99% by mass parts is 1% with mass parts
Conducting resinl 1% is mixed, and the dilute conductor of graphite (9) wire body is prepared by expressing technique；
Step 2：Copper conductor (1) is placed in the wrapped flame retardant coating of synthetic mica (2) by crust coating technology, forms internal layer core；
Step 3：Internal layer core in step 2 is placed in down to the center of rubber moulding, rubber moulding is clamping, by some of step one
The dilute conductor of graphite (9) wire body is put into ring array in rubber moulding, and ceramic polyolefin insulation layer is prepared by way of reverse mould
(3)；
Step 4：After solidification, the finished product in step 3, as cable core are taken out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710407267.6A CN107204216A (en) | 2017-06-02 | 2017-06-02 | The super soft mineral insulated cable of graphene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710407267.6A CN107204216A (en) | 2017-06-02 | 2017-06-02 | The super soft mineral insulated cable of graphene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107204216A true CN107204216A (en) | 2017-09-26 |
Family
ID=59906760
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710407267.6A Pending CN107204216A (en) | 2017-06-02 | 2017-06-02 | The super soft mineral insulated cable of graphene |
Country Status (1)
| Country | Link |
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| CN (1) | CN107204216A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107887060A (en) * | 2017-11-20 | 2018-04-06 | 中天科技装备电缆有限公司 | The data center power sources light-duty fire-resisting flexible cable of graphene copper composite core |
| CN117198585A (en) * | 2023-09-06 | 2023-12-08 | 广东日鸿电缆有限公司 | Flexible graphene cable and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102592720A (en) * | 2012-03-14 | 2012-07-18 | 于庆文 | Non-metallic cable, manufacturing method and application thereof |
| US20130101747A1 (en) * | 2011-07-08 | 2013-04-25 | General Cable Technologies Corporation | Method for shielding cable components |
| CN203490982U (en) * | 2013-08-26 | 2014-03-19 | 安徽航天电缆集团有限公司 | Compensating cable for thermocouples |
| CN105314626A (en) * | 2014-06-03 | 2016-02-10 | 伊思幕有限公司 | Methods of manufacturing graphene and conductor |
| CN205247972U (en) * | 2015-12-08 | 2016-05-18 | 禾达材料科技股份有限公司 | Use nano -material's signal and cable conductor structure for power transmission |
| WO2016153480A1 (en) * | 2015-03-24 | 2016-09-29 | Schlumberger Canada Limited | Nano-material structure for electric power transmission |
| CN206058991U (en) * | 2016-08-19 | 2017-03-29 | 四川兴川泰线缆有限公司 | A kind of mineral insulation is from lock armo flexible fire-proof cable |
-
2017
- 2017-06-02 CN CN201710407267.6A patent/CN107204216A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130101747A1 (en) * | 2011-07-08 | 2013-04-25 | General Cable Technologies Corporation | Method for shielding cable components |
| CN102592720A (en) * | 2012-03-14 | 2012-07-18 | 于庆文 | Non-metallic cable, manufacturing method and application thereof |
| CN203490982U (en) * | 2013-08-26 | 2014-03-19 | 安徽航天电缆集团有限公司 | Compensating cable for thermocouples |
| CN105314626A (en) * | 2014-06-03 | 2016-02-10 | 伊思幕有限公司 | Methods of manufacturing graphene and conductor |
| WO2016153480A1 (en) * | 2015-03-24 | 2016-09-29 | Schlumberger Canada Limited | Nano-material structure for electric power transmission |
| CN205247972U (en) * | 2015-12-08 | 2016-05-18 | 禾达材料科技股份有限公司 | Use nano -material's signal and cable conductor structure for power transmission |
| CN206058991U (en) * | 2016-08-19 | 2017-03-29 | 四川兴川泰线缆有限公司 | A kind of mineral insulation is from lock armo flexible fire-proof cable |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107887060A (en) * | 2017-11-20 | 2018-04-06 | 中天科技装备电缆有限公司 | The data center power sources light-duty fire-resisting flexible cable of graphene copper composite core |
| CN117198585A (en) * | 2023-09-06 | 2023-12-08 | 广东日鸿电缆有限公司 | Flexible graphene cable and preparation method thereof |
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Application publication date: 20170926 |
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| RJ01 | Rejection of invention patent application after publication |