CN107201043A - Water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve - Google Patents
Water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve Download PDFInfo
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- CN107201043A CN107201043A CN201710412364.4A CN201710412364A CN107201043A CN 107201043 A CN107201043 A CN 107201043A CN 201710412364 A CN201710412364 A CN 201710412364A CN 107201043 A CN107201043 A CN 107201043A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- G—PHYSICS
- G08—SIGNALLING
- G08G—TRAFFIC CONTROL SYSTEMS
- G08G1/00—Traffic control systems for road vehicles
- G08G1/09—Arrangements for giving variable traffic instructions
- G08G1/095—Traffic lights
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F15/00—Boards, hoardings, pillars, or like structures for notices, placards, posters, or the like
- G09F15/02—Bills, posters, or the like therefor
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F23/00—Advertising on or in specific articles, e.g. ashtrays, letter-boxes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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- Engineering & Computer Science (AREA)
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- Road Signs Or Road Markings (AREA)
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Abstract
The invention belongs to the advertisement traffic signal lamp of a kind of water-proof rubber sleeve and preparation method and the use water-proof rubber sleeve；Including the use of water-proof rubber sleeve, vertical rod and the billboard being sleeved on inside water-proof rubber sleeve；The middle part of vertical rod is provided with the lamp socket with containment vessel; the upper and lower ends of vertical rod are respectively arranged with hollow type support bar; AD is offered on the outer surface of hollow type support bar; the side of vertical rod upper support bar is provided with the billboard with water-proof rubber sleeve; the top of billboard is provided with the cross bar being connected with support bar, and several connecting rods are provided between cross bar and billboard；Red light, green light and amber light are provided with the lamp socket；With reasonable in design, identification is high and long lifespan, and for protect the water-proof rubber sleeve of billboard to have the advantages that to be difficult harden, water-impervious and not easy to break.
Description
Technical field
The invention belongs to animated advertising formula traffic lights technical field, and in particular to a kind of water-proof rubber sleeve and preparation method
With the advertisement traffic signal lamp using the water-proof rubber sleeve.
Background technology
Traffic lights are the important components in point duty, are the basic languages of road traffic.Traffic lights
Represent that no through traffic by red light, green light represents to allow to pass through, amber light represents that warning is constituted.It is divided into：Motor vehicle signal lamp, non-maneuver
Car signal lamp, pedestrian crosswalk signal lamp, lane signal lamp, direction instruction signal lamp, flashing, alarming signal lamp, road and railway are flat
Face intersection signal lamp, is the indispensable instrument of road traffic.
In addition, existing advertisement is ubiquitous, on road, the information of advertisement can always appear in the sight of people,
Furthermore, in some intown main sections, the interval time of traffic lights is usual in 2 minutes, and in this two minutes,
Some enough businessmans carry out advertisement to itself commodity, can make up driver or passenger and wait traffic lights this vacuum of two minutes
Phase, or but existing traffic lights simply simple green three indicator lamp holders of reddish yellow, no billboard, otherwise directly
Billboard is hung up on traffic lights and carries out advertisement, but directly billboard is arranged on traffic lights, can only be to list
One commodity are publicized, and its form is single, not vivid enough.
In addition, even if some have the traffic lights of advertising function, its when in use, due to being outdoor placement, easily
Damage, cause identification low and short life, case hardening fast, the easily infiltration and the problem of easy fracture for protecting billboard.
The content of the invention
The purpose of the present invention be that provided to solve the above problems it is a kind of be used to protecting billboard, it is hard with being difficult
Change, water-impervious and water-proof rubber sleeve not easy to break and high and long lifespan the water-proof rubber sleeve of reasonable in design, identification and preparation method
With the advertisement traffic signal lamp using the water-proof rubber sleeve.
The present invention is achieved through the following technical solutions above-mentioned purpose：
(1) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
30-40 parts of glue, 28-36 parts of butadiene-styrene rubber, 11-17 parts of carbon black, 10-14 parts of zinc oxide, 13-15 parts of stearic acid, boehmite 7-11
Part, 5-9 parts of sodium molybdate, 4-6 parts of nickel powder, 4-6 parts of niobium powder, 4-6 parts of zirconium powder, 4-6 parts of carbon dust, 4-6 parts of manganese powder, 3- pentanediols two pairs
1-3 parts of isobutyrate plasticizer, 2-4 parts of calcium zinc stabilizer, 4-8 parts of smoke suppressant, 5-7 parts of dimethicone and polyethers amine catalyst
3-5 parts；Described smoke suppressant is one kind or one kind in intumescent red phosphorus, magnesium hydroxide, aluminium hydroxide or metallocene polypropylene
Mixture above.
(2) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
33 parts of glue, 35 parts of butadiene-styrene rubber, 12 parts of carbon black, 11 parts of zinc oxide, 14.5 parts of stearic acid, 10 parts of boehmite, 8 parts of sodium molybdate, nickel
4 parts of powder, 6 parts of niobium powder, 5.5 parts of zirconium powder, 4.5 parts of carbon dust, 4 parts of manganese powder, 3 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc
5 parts of 4 parts of stabilizer, 5 parts of smoke suppressant, 7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is metallocene poly- third
Alkene.
(3) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
39 parts of glue, 29 parts of butadiene-styrene rubber, 15 parts of carbon black, 13 parts of zinc oxide, 13.5 parts of stearic acid, 9 parts of boehmite, 6 parts of sodium molybdate, nickel powder
5.6 parts, 5 parts of niobium powder, 4 parts of zirconium powder, 5 parts of carbon dust, 6 parts of manganese powder, 1 part of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc it is stable
4 parts of 3 parts of agent, 7 parts of smoke suppressant, 6.7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is intumescent red phosphorus, hydrogen
The mixture of magnesia and aluminium hydroxide.
(4) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
38 parts of glue, 30 parts of butadiene-styrene rubber, 13 parts of carbon black, 10 parts of zinc oxide, 15 parts of stearic acid, 7 parts of boehmite, 9 parts of sodium molybdate, nickel powder 6
Part, 4 parts of niobium powder, 6 parts of zirconium powder, 6 parts of carbon dust, 4.5 parts of manganese powder, 2 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc stabilizer
4.5 parts of 2 parts, 6 parts of smoke suppressant, 5.5 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is aluminium hydroxide and cyclopentadienyl gold
Belong to polyacrylic mixture.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of described in any one of above-mentioned (one)-(four)
Water-proof rubber sleeve, vertical rod and the billboard being sleeved on inside water-proof rubber sleeve；The middle part of vertical rod is provided with the lamp socket with containment vessel,
The upper and lower ends of vertical rod are respectively arranged with hollow type support bar, the outer surface of hollow type support bar and offer AD, vertical rod
The side of upper support bar is provided with the billboard with water-proof rubber sleeve, and the top of billboard is provided with the cross bar being connected with support bar, horizontal
Several connecting rods are provided between bar and billboard；Red light, green light and amber light are provided with the lamp socket.
Preferably, the hollow type support bar of the vertical rod and upper and lower ends is structure as a whole.
Preferably, red light, green light and amber light are followed successively by from the bottom to top in the lamp socket.
Preferably, described connecting rod is placed equidistant between cross bar and billboard.
Preferably, it is connected by screw bolts between described lamp socket and containment vessel；Adopted between billboard and hollow type support bar
It is connected with.
The technology of the present invention effect major embodiment is in the following areas：By setting billboard in vertical rod, pass through billboard energy
It is enough to carry out road conditions in front of advertising and prompting in driver and conductor's spare time while traffic is guided, in addition, for protecting
The water-proof rubber sleeve of billboard by methyl vinyl silicone rubber, butadiene-styrene rubber, carbon black, zinc oxide, stearic acid, boehmite, sodium molybdate,
Nickel powder, niobium powder, zirconium powder, carbon dust, manganese powder, 3- pentanediols two pairs of isobutyrate plasticizer, calcium zinc stabilizer, smoke suppressant, dimethyl
Silicone oil and polyethers amine catalyst, which are made to have, is difficult hardening, water-impervious and water-proof rubber sleeve not easy to break, with suitable for animation
The characteristics of advertisement type traffic lights.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Embodiment
In order to which technical characteristic, purpose and effect to the present invention are more clearly understood from, now control illustrates this hair
Bright embodiment, in the various figures identical label represent identical part.It is only schematic in simplified form, each figure to make
Ground indicates the part related to invention, and they do not represent it as the practical structures of product.
The present invention is water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve；Wherein marine glue
Set includes：
(1) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
30-40 parts of glue, 28-36 parts of butadiene-styrene rubber, 11-17 parts of carbon black, 10-14 parts of zinc oxide, 13-15 parts of stearic acid, boehmite 7-11
Part, 5-9 parts of sodium molybdate, 4-6 parts of nickel powder, 4-6 parts of niobium powder, 4-6 parts of zirconium powder, 4-6 parts of carbon dust, 4-6 parts of manganese powder, 3- pentanediols two pairs
1-3 parts of isobutyrate plasticizer, 2-4 parts of calcium zinc stabilizer, 4-8 parts of smoke suppressant, 5-7 parts of dimethicone and polyethers amine catalyst
3-5 parts；Described smoke suppressant is one kind or one kind in intumescent red phosphorus, magnesium hydroxide, aluminium hydroxide or metallocene polypropylene
Mixture above.
(2) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
33 parts of glue, 35 parts of butadiene-styrene rubber, 12 parts of carbon black, 11 parts of zinc oxide, 14.5 parts of stearic acid, 10 parts of boehmite, 8 parts of sodium molybdate, nickel
4 parts of powder, 6 parts of niobium powder, 5.5 parts of zirconium powder, 4.5 parts of carbon dust, 4 parts of manganese powder, 3 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc
5 parts of 4 parts of stabilizer, 5 parts of smoke suppressant, 7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is metallocene poly- third
Alkene.
(3) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
39 parts of glue, 29 parts of butadiene-styrene rubber, 15 parts of carbon black, 13 parts of zinc oxide, 13.5 parts of stearic acid, 9 parts of boehmite, 6 parts of sodium molybdate, nickel powder
5.6 parts, 5 parts of niobium powder, 4 parts of zirconium powder, 5 parts of carbon dust, 6 parts of manganese powder, 1 part of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc it is stable
4 parts of 3 parts of agent, 7 parts of smoke suppressant, 6.7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is intumescent red phosphorus, hydrogen
The mixture of magnesia and aluminium hydroxide.
(4) a kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene silicon rubber
38 parts of glue, 30 parts of butadiene-styrene rubber, 13 parts of carbon black, 10 parts of zinc oxide, 15 parts of stearic acid, 7 parts of boehmite, 9 parts of sodium molybdate, nickel powder 6
Part, 4 parts of niobium powder, 6 parts of zirconium powder, 6 parts of carbon dust, 4.5 parts of manganese powder, 2 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc stabilizer
4.5 parts of 2 parts, 6 parts of smoke suppressant, 5.5 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is aluminium hydroxide and cyclopentadienyl gold
Belong to polyacrylic mixture.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
As shown in figure 1, a kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned (one)-(fours')
Water-proof rubber sleeve 21, vertical rod 1 described in any one and the billboard 2 being sleeved on inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is set
There is the lamp socket 12 with containment vessel 13, the upper and lower ends of vertical rod 1 are respectively arranged with hollow type support bar 11, hollow type support bar 11
AD 111 is offered on outer surface, the side of the upper support bar 11 of vertical rod 1 is provided with the billboard 2 with water-proof rubber sleeve 21, advertisement
The top of board 2 is provided with the cross bar 22 being connected with support bar 11, and several connecting rods 23 are provided between cross bar 22 and billboard 2；Institute
State and red light 121, green light 122 and amber light 123 are provided with lamp socket 12.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are
Integrative-structure.Red light 121, green light 122 and amber light 123 are followed successively by the lamp socket 12 from the bottom to top.Described connecting rod 23 etc.
Away from being arranged between cross bar 22 and billboard 2.It is connected by screw bolts between described lamp socket 12 and containment vessel 13；Billboard 2 with
It is connected by screw bolts between hollow type support bar 11.
In order to more clearly explain the present invention, it is further described in conjunction with specific embodiment.It is specific real
Under applying for example：
Embodiment one
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 30
Part, 28 parts of butadiene-styrene rubber, 11 parts of carbon black, 10 parts of zinc oxide, 13 parts of stearic acid, 7 parts of boehmite, 5 parts of sodium molybdate, 4 parts of nickel powder, niobium
4 parts of powder, 4 parts of zirconium powder, 4 parts of carbon dust, 4 parts of manganese powder, 1 part of the isobutyrate plasticizer of 3- pentanediols two pairs, 2 parts of calcium zinc stabilizer, suppression
3 parts of 4 parts of fumicants, 5 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is intumescent red phosphorus.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Embodiment two
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 40
Part, 36 parts of butadiene-styrene rubber, 17 parts of carbon black, 14 parts of zinc oxide, 15 parts of stearic acid, 11 parts of boehmite, 9 parts of sodium molybdate, 6 parts of nickel powder,
6 parts of niobium powder, 6 parts of zirconium powder, 6 parts of carbon dust, 6 parts of manganese powder, 3 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, 4 parts of calcium zinc stabilizer,
5 parts of 8 parts of smoke suppressant, 7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is magnesium hydroxide.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Embodiment three
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 35
Part, 32 parts of butadiene-styrene rubber, 14 parts of carbon black, 12 parts of zinc oxide, 14 parts of stearic acid, 9 parts of boehmite, 7 parts of sodium molybdate, 5 parts of nickel powder, niobium
5 parts of powder, 5 parts of zirconium powder, 5 parts of carbon dust, 5 parts of manganese powder, 2 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, 3 parts of calcium zinc stabilizer, suppression
4 parts of 6 parts of fumicants, 6 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is aluminium hydroxide.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Example IV
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 33
Part, 35 parts of butadiene-styrene rubber, 12 parts of carbon black, 11 parts of zinc oxide, 14.5 parts of stearic acid, 10 parts of boehmite, 8 parts of sodium molybdate, nickel powder 4
Part, 6 parts of niobium powder, 5.5 parts of zirconium powder, 4.5 parts of carbon dust, 4 parts of manganese powder, 3 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc are stable
5 parts of 4 parts of agent, 5 parts of smoke suppressant, 7 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is metallocene polypropylene.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Embodiment five
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 39
Part, 29 parts of butadiene-styrene rubber, 15 parts of carbon black, 13 parts of zinc oxide, 13.5 parts of stearic acid, 9 parts of boehmite, 6 parts of sodium molybdate, nickel powder 5.6
Part, 5 parts of niobium powder, 4 parts of zirconium powder, 5 parts of carbon dust, 6 parts of manganese powder, 1 part of the isobutyrate plasticizer of 3- pentanediols two pairs, calcium zinc stabilizer 3
Part, 7 parts of smoke suppressant, 6.7 parts of dimethicone and 4 parts of polyethers amine catalyst；Described smoke suppressant is intumescent red phosphorus, hydroxide
The mixture of magnesium and aluminium hydroxide.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Embodiment six
A kind of water-proof rubber sleeve, the raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl vinyl silicone rubber 38
Part, 30 parts of butadiene-styrene rubber, 13 parts of carbon black, 10 parts of zinc oxide, 15 parts of stearic acid, 7 parts of boehmite, 9 parts of sodium molybdate, 6 parts of nickel powder, niobium
4 parts of powder, 6 parts of zirconium powder, 6 parts of carbon dust, 4.5 parts of manganese powder, 2 parts of the isobutyrate plasticizer of 3- pentanediols two pairs, 2 parts of calcium zinc stabilizer,
4.5 parts of 6 parts of smoke suppressant, 5.5 parts of dimethicone and polyethers amine catalyst；Described smoke suppressant is that aluminium hydroxide and metallocene are poly-
The mixture of propylene.
A kind of preparation method of water-proof rubber sleeve, comprises the following steps：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor
It is interior, and the temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber are in reactor
It is interior to be fused into glue rapidly by stearic acid activation and by polyethers amine catalyst progress catalytic reaction, and pass through smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced is reduced, rubber master batch mixing liquid is made, it is standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium
Powder, zirconium powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby
With；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below
Powder, filler is made, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then by stirring
Mix machine to mix filler with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, simultaneously
The temperature of reactor is improved to 240-260 DEG C, and starts the mixer in reactor with 25r/pm rotating speed by filler slurries
Stirred with rubber master batch mixing liquid, it is standby；
5) two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone is taken to be added to step 4) middle use
In the reactor of stirring reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by
25r/pm is improved to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch
Mixing liquid is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
A kind of advertisement traffic signal lamp using the water-proof rubber sleeve, including the use of above-mentioned water-proof rubber sleeve 21, vertical rod 1 and
It is sleeved on the billboard 2 inside water-proof rubber sleeve 21；The middle part of vertical rod 1 is provided with the lamp socket 12 with containment vessel 13, up and down the two of vertical rod 1
End, which is respectively arranged with hollow type support bar 11, the outer surface of hollow type support bar 11, offers AD 111, the top of vertical rod 1
The side of support bar 11 is provided with the billboard 2 with water-proof rubber sleeve 21, and the top of billboard 2 is provided with the cross bar being connected with support bar 11
22, several connecting rods 23 are provided between cross bar 22 and billboard 2；Red light 121, green light 122 and Huang are provided with the lamp socket 12
Lamp 123.The vertical rod 1 and the hollow type support bar 11 of upper and lower ends are structure as a whole.In the lamp socket 12 from the bottom to top successively
For red light 121, green light 122 and amber light 123.Described connecting rod 23 is placed equidistant between cross bar 22 and billboard 2.Described
It is connected by screw bolts between lamp socket 12 and containment vessel 13；It is connected by screw bolts between billboard 2 and hollow type support bar 11.
Experimental example
Experimental subjects：Using the water-proof rubber sleeve and this Shen that propylene is fine, polytrifluorochloroethylene and polytetrafluoroethylene (PTFE) are respectively prepared
Water-proof rubber sleeve that please be in example IV is contrasted.
Requirement of experiment：The water-proof rubber sleeve that above-mentioned propylene is fine, polytrifluorochloroethylene and polytetrafluoroethylene (PTFE) are respectively prepared and sheet
Apply for the consistency of thickness of the water-proof rubber sleeve in example IV, and area is consistent.
Experimental method：By to propylene is fine, polytrifluorochloroethylene and polytetrafluoroethylene (PTFE) are respectively prepared water-proof rubber sleeve and this
Water-proof rubber sleeve in the embodiment of the present application four carries out durability degree test, in this experimental example, and durability degree test includes resistance to ag(e)ing
Energy, heat-resisting and resistance to low temperature etc. are tested.
Concrete outcome is as shown in the table：
With reference to upper table, the data of different rubber gained under identical experimental method, the water-proof rubber sleeve of the application are contrasted
Test data be above for water-proof rubber sleeve made from the various raw materials of contrast, therefore, embody the water-proof rubber sleeve of the present invention
Good weatherability, performance is more stablized, and is more applicable for protecting animated advertising formula traffic lights.
The present invention can be multiplied by billboard 2 by setting billboard 2 in vertical rod 1 while traffic is guided in department
Personnel's spare time carries out advertising and reminds front road conditions, in addition, for protecting the water-proof rubber sleeve 21 of billboard 2 by methyl
Vinylsiloxane rubber, butadiene-styrene rubber, carbon black, zinc oxide, stearic acid, boehmite, sodium molybdate, nickel powder, niobium powder, zirconium powder, carbon dust, manganese
Powder, two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer, smoke suppressant, dimethicone and polyethers amine catalyst are made
With being difficult hardening, water-impervious and water-proof rubber sleeve not easy to break, it is adaptable to the characteristics of animated advertising formula traffic lights；Pass through
The present invention that aforesaid way is made has the advantages that reasonable in design, identification is high and long lifespan.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, the original for simply illustrating the present invention described in above-described embodiment and specification
Reason, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes and improvements
It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its Xiao Wu circle
It is fixed.
Claims (10)
1. a kind of water-proof rubber sleeve, it is characterised in that：The raw material that the water-proof rubber sleeve includes following parts by weight is made：Methyl ethylene
30-40 parts of silicon rubber, 28-36 parts of butadiene-styrene rubber, 11-17 parts of carbon black, 10-14 parts of zinc oxide, 13-15 parts of stearic acid, boehmite
7-11 parts, 5-9 parts of sodium molybdate, 4-6 parts of nickel powder, 4-6 parts of niobium powder, 4-6 parts of zirconium powder, 4-6 parts of carbon dust, 4-6 parts of manganese powder, 3- pentanediols
Two pairs of 1-3 parts of the isobutyrate plasticizer, 2-4 parts of calcium zinc stabilizer, 4-8 parts of smoke suppressant, 5-7 parts of dimethicone and polyetheramine are urged
3-5 parts of agent；Described smoke suppressant be intumescent red phosphorus, magnesium hydroxide, aluminium hydroxide or metallocene polypropylene in one kind or
More than one mixture.
2. water-proof rubber sleeve according to claim 1, it is characterised in that：The water-proof rubber sleeve includes the raw material of following parts by weight
It is made：33 parts of methyl vinyl silicone rubber, 35 parts of butadiene-styrene rubber, 12 parts of carbon black, 11 parts of zinc oxide, 14.5 parts of stearic acid, Bo Mu
10 parts of stone, 8 parts of sodium molybdate, 4 parts of nickel powder, 6 parts of niobium powder, 5.5 parts of zirconium powder, 4.5 parts of carbon dust, 4 parts of manganese powder, two pairs of isobutyls of 3- pentanediols
5 parts of 3 parts of acid ester plasticizer, 4 parts of calcium zinc stabilizer, 5 parts of smoke suppressant, 7 parts of dimethicone and polyethers amine catalyst；Described suppression
Fumicants is metallocene polypropylene.
3. water-proof rubber sleeve according to claim 1, it is characterised in that：The water-proof rubber sleeve includes the raw material of following parts by weight
It is made：39 parts of methyl vinyl silicone rubber, 29 parts of butadiene-styrene rubber, 15 parts of carbon black, 13 parts of zinc oxide, 13.5 parts of stearic acid, Bo Mu
9 parts of stone, 6 parts of sodium molybdate, 5.6 parts of nickel powder, 5 parts of niobium powder, 4 parts of zirconium powder, 5 parts of carbon dust, 6 parts of manganese powder, two pairs of isobutyric acids of 3- pentanediols
4 parts of 1 part of ester plasticiser, 3 parts of calcium zinc stabilizer, 7 parts of smoke suppressant, 6.7 parts of dimethicone and polyethers amine catalyst；Described suppression
Fumicants is the mixture of intumescent red phosphorus, magnesium hydroxide and aluminium hydroxide.
4. water-proof rubber sleeve according to claim 1, it is characterised in that：The water-proof rubber sleeve includes the raw material of following parts by weight
It is made：38 parts of methyl vinyl silicone rubber, 30 parts of butadiene-styrene rubber, 13 parts of carbon black, 10 parts of zinc oxide, 15 parts of stearic acid, boehmite 7
Part, 9 parts of sodium molybdate, 6 parts of nickel powder, 4 parts of niobium powder, 6 parts of zirconium powder, 6 parts of carbon dust, 4.5 parts of manganese powder, two pairs of isobutyrates of 3- pentanediols increase
Mould 4.5 parts of 2 parts of agent, 2 parts of calcium zinc stabilizer, 6 parts of smoke suppressant, 5.5 parts of dimethicone and polyethers amine catalyst；Described suppression cigarette
Agent is the mixture of aluminium hydroxide and metallocene polypropylene.
5. a kind of preparation method of water-proof rubber sleeve as described in claim any one of 1-4, it is characterised in that：Including following step
Suddenly：
1) methyl vinyl silicone rubber, butadiene-styrene rubber, stearic acid, smoke suppressant and polyethers amine catalyst is taken to be put into reactor, and
The temperature of reactor is gradually heated to 180-220 DEG C so that methyl vinyl silicone rubber and butadiene-styrene rubber lead in reactor
Perstearic acid activates and carries out catalytic reaction by polyethers amine catalyst and be fused into glue rapidly, and is reduced by smoke suppressant
The smoke that methyl vinyl silicone rubber and butadiene-styrene rubber heating melting are produced, is made rubber master batch mixing liquid, standby；
2) take carbon black, zinc oxide, boehmite and sodium molybdate to be ground repeatedly by grinder three times, then add nickel powder, niobium powder, zirconium
Powder, carbon dust and manganese powder mixing, and carry out the 4th grinding so that above-mentioned material is well mixed, and mixed fillers are made, standby；
3) take filter opening be 50 mesh filter screen to step 2) made from mixed fillers carry out filtering screening, and collect 50 mesh below powder
End, is made filler, and the filler of collection is put into agitator, by weight 3: 5 ratio addition water, then passes through mixer
Filler is mixed with water with 55r/pm rotating speed, filler slurries are made, it is standby；
4) by step 3) made from filler slurries be added to step 1) in the reactor for being placed with rubber master batch mixing liquid, while will be anti-
Answer the temperature of kettle to improve to 240-260 DEG C, and start the mixer in reactor with 25r/pm rotating speed by filler slurries and mother
Glue mixing liquid stirs, standby；
5) take two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and dimethicone to be added to step 4) in be used for stir
In the reactor for mixing reaction, and keep 240-260 DEG C of heating-up temperature, by by the rotating speed of the mixer in reactor by 25r/pm
Improve to 60r/pm so that two pairs of isobutyrate plasticizer of 3- pentanediols, calcium zinc stabilizer and methyl-silicone oil and rubber master batch mixed liquor
Body is mixed so that filler can be merged mutually with rubber master batch mixing liquid, and glue is made, standby；
6) by step 5) made from glue extruded by extruder, be made gum cover, then stand natural cooling, produce.
6. a kind of advertisement traffic signal lamp using the water-proof rubber sleeve, it is characterised in that：Any including the use of claim 1-4
Water-proof rubber sleeve (21), vertical rod (1) described in and it is sleeved on the internal billboard (2) of water-proof rubber sleeve (21)；Vertical rod (1)
Middle part is provided with the lamp socket (12) with containment vessel (13), and the upper and lower ends of vertical rod (1) are respectively arranged with hollow type support bar (11), in
AD (111) is offered on the outer surface of casement support bar (11), the side of vertical rod (1) upper support bar (11) is provided with band and prevented
The billboard (2) of gelatine sleeve (21), the top of billboard (2) is provided with the cross bar (22) being connected with support bar (11), cross bar (22)
Several connecting rods (23) are provided between billboard (2)；Red light (121), green light (122) and Huang are provided with the lamp socket (12)
Lamp (123).
7. a kind of advertisement traffic signal lamp using the water-proof rubber sleeve according to claim 6, it is characterised in that：It is described vertical
Bar (1) and the hollow type support bar (11) of upper and lower ends are structure as a whole.
8. a kind of advertisement traffic signal lamp using the water-proof rubber sleeve according to claim 6, it is characterised in that：The lamp
Red light (121), green light (122) and amber light (123) are followed successively by from the bottom to top in seat (12).
9. a kind of advertisement traffic signal lamp using the water-proof rubber sleeve according to claim 6, it is characterised in that：Described
Connecting rod (23) is placed equidistant between cross bar (22) and billboard (2).
10. a kind of advertisement traffic signal lamp using the water-proof rubber sleeve according to claim 6, it is characterised in that：It is described
Lamp socket (12) and containment vessel (13) between be connected by screw bolts；Spiral shell is used between billboard (2) and hollow type support bar (11)
Tether and connect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710412364.4A CN107201043A (en) | 2017-05-22 | 2017-05-22 | Water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710412364.4A CN107201043A (en) | 2017-05-22 | 2017-05-22 | Water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve |
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| Publication Number | Publication Date |
|---|---|
| CN107201043A true CN107201043A (en) | 2017-09-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710412364.4A Pending CN107201043A (en) | 2017-05-22 | 2017-05-22 | Water-proof rubber sleeve and preparation method and the advertisement traffic signal lamp using the water-proof rubber sleeve |
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| CN104751656A (en) * | 2013-12-28 | 2015-07-01 | 余学明 | Traffic signal lamp with advertisement display screen |
| CN103819758A (en) * | 2014-02-26 | 2014-05-28 | 秦荣勤 | Flame-retardant fire-resistant rubber composition and preparation method thereof, and flame-retardant fire-resistant rubber wrapping tape |
| CN104277162A (en) * | 2014-09-10 | 2015-01-14 | 宿迁市鸿大化工有限公司 | Medium/high chlorinated metallocene polypropylene synthesis technique by water-phase suspension process |
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Application publication date: 20170926 |