CN107195850A - A kind of electrolyte automatic vacuum filling apparatus - Google Patents

A kind of electrolyte automatic vacuum filling apparatus Download PDF

Info

Publication number
CN107195850A
CN107195850A CN201710471479.0A CN201710471479A CN107195850A CN 107195850 A CN107195850 A CN 107195850A CN 201710471479 A CN201710471479 A CN 201710471479A CN 107195850 A CN107195850 A CN 107195850A
Authority
CN
China
Prior art keywords
msub
mrow
control
electrolyte
mfrac
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710471479.0A
Other languages
Chinese (zh)
Other versions
CN107195850B (en
Inventor
陈黎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Three Gorges University CTGU
Original Assignee
China Three Gorges University CTGU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Three Gorges University CTGU filed Critical China Three Gorges University CTGU
Priority to CN201710471479.0A priority Critical patent/CN107195850B/en
Publication of CN107195850A publication Critical patent/CN107195850A/en
Application granted granted Critical
Publication of CN107195850B publication Critical patent/CN107195850B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Filling, Topping-Up Batteries (AREA)

Abstract

A kind of electrolyte automatic vacuum filling apparatus, including frame main body, vertical beam, digital control platform, vacuum filling head, digital control computer system touch screen, electrolyte hopper, battery install fixture.Vertical beam bottom is vertically connected with frame main body, battery installs fixture and is arranged on frame main body top, and battery to be filled is arranged on battery and installed on fixture, vertical beam top connection digital control computer system touch screen, digital control platform one end connects vacuum filling head, digital control platform other end connection electrolyte hopper.Apparatus of the present invention realize the motion positions of filling head using reliable and stable two dimension NC auto platform, can be automatically performed electrolyte of the precision less than 0.5ml according to the dimension information of battery pack and fill;The computer system touch-screen of the device, can input the information such as battery size parameter and cell electrolyte volume to be filled, and the position for realizing each filler using computer is calculated.

Description

A kind of electrolyte automatic vacuum filling apparatus
Technical field
The invention belongs to electrolyte loading technique field, it is related to a kind of electrolyte automatic vacuum filling apparatus.
Background technology
With developing rapidly for electronic product, effect of the battery in life is increasing.But many large-scale producer's lifes Produce electricity pond operating efficiency low, although enter electronic age, the numerical control epoch, computer age, but many production mistakes It is by hand master mode production before still being continued to use in journey.Traditional battery production is all by artificial filling electrolyte, production effect Rate is low, and precision is low, it is impossible to grasp the capacity and liquid level of filling electrolyte in real time.The battery product produced may much reach Required less than international market.Therefore a kind of battery electrolyte automatic injecting is needed, can realizes that electrolyte vacuum adds automatically Note, fully achieves automation, refines, and can automatically control the liquid of the electrolyte of filling in battery pack at any time in process Position, while real-time monitoring alarming can be carried out to remaining electrolyte, improves industrial production efficiency, reduces production cost.
The content of the invention
The present invention provides a kind of electrolyte automatic vacuum filling apparatus, and the device uses reliable and stable two dimension NC auto platform The motion positions of filling head are realized, can be automatically performed electrolyte of the precision less than 0.5ml according to the dimension information of battery pack and add Note;The computer system touch-screen of the device, can input battery size parameter and cell electrolyte volume to be filled Etc. information, the position for realizing each filler using computer is calculated.
The technical scheme that the present invention takes is:
A kind of electrolyte automatic vacuum filling apparatus, including frame main body, vertical beam, digital control platform, vacuum filling head, numerical control Computer system touch-screen, electrolyte hopper, battery install fixture.
Vertical beam bottom is vertically connected with frame main body, and battery installs fixture and is arranged on frame main body top, battery to be filled Installed installed in battery on fixture, vertical beam top connection digital control computer system touch screen, digital control platform one end connection vacuum adds Head, digital control platform other end connection electrolyte hopper.Digital control platform:For driving height of the vacuum filling head in two dimensional surface Precision is positioned, and the input elements of a fix are that can be achieved to add being accurately positioned for vacuum filling head.
High-precision liquid metering control, the high-precision liquid measure control dress are installed in the electrolyte hopper Put including non-contact liquid sensor, measuring cup, control valve;Measuring cup connects electrolysis liquid material by being provided with the pipeline of control valve Non-contact liquid sensor is set in bucket, measuring cup.Electrolyte hopper top connects negative pressure by being provided with the pipeline of baroceptor Air pump.The non-contact liquid sensor, control valve, baroceptor, negative pressure air pump are all connected with industrial computer system, Industrial computer system connects digital control platform, and industrial computer system is used to realize:Vacuum filling first 4, upper and lower motion control; High-precision liquid metering, control;Control is coordinated in filling pumping;The safe stable-pressure device control of pneumatic means.
The vacuum filling head connects miniature explosion-proof low-noise pneumatic control device, realizes the upper and lower motion control of filling head System, filling process uses air positive pressure, and realization enters the liquid filling in measuring cup in battery to be filled.
The frame main body is made using 309 stainless steel materials, and the frame main body bottom is provided with pulley, can be real Now mobile production filling.
The digital control platform is by longitudinal axis guide rail, transverse axis guide rail, two dimension NC auto platform, data line interface composition;Longitudinal axis guide rail, is used In realizing that vacuum filling head vertically moves;Transverse axis guide rail, for realizing vacuum filling head transverse shifting;Data line interface, is used for Realize the communication between two dimension NC auto platform and computer system.
A kind of electrolyte automatic vacuum filling apparatus of the present invention, technique effect is as follows:
1:Frame lathe bed is made using 309 stainless steel materials, and thickness is 2mm, with explosion-proof noise control function.The equipment bottom Portion is also equipped with pulley, and mobile production filling can be achieved.
2:Degree digital control platform mainly realizes the high accuracy positioning for driving filling head in two dimensional surface, it is only necessary to input positioning Coordinate is that being accurately positioned for filling head can be achieved.Explosion-proof high-precision two-dimensional digital control platform, positioning precision are used in the present invention Better than 0.1mm, operation can be completed to the platform by digital control computer input coordinate data during use;
3:High precision numerical control platform is main by longitudinal axis guide rail, vacuum filling head, transverse axis guide rail, two dimension NC auto platform and data Line interface is constituted.The longitudinal axis guide rail mainly realizes that filling head is vertically moved, and the transverse axis guide rail mainly realizes that filling head is horizontal Mobile, the data line interface mainly realizes the communication between two dimension NC auto platform and computer system.The two-dimension high-precision Digital control platform can drive vacuum filling head or battery pack to realize the filling of each cell electrolyte in battery pack, But if using the motion of battery pack to realize when, because battery size volume is larger, it is therefore desirable to which larger motion is empty Between, and can just be taken to if needing to use hydraulic means when battery weight is larger, hydraulic means size is larger, there is greasy dirt etc. Shortcoming, therefore this equipment by the two dimensional motion and up and down motion that control filling head using realizing electrolyte automatic filling.
4:Computer system uses industrial computer system, mainly realizes above and below two-dimension high-precision digital control platform, filling head Motion control, high-precision liquid metering and control, control is coordinated in filling pumping and the safe stable-pressure device of pneumatic means is controlled.
5:Filling head motion control and filling realize that device uses gas to control, used because filling head quality is small Pneumatic power is smaller, realizes the up and down motion control of filling head in the present invention using miniature explosion-proof low-noise pneumatic control device System, filling process is realized to enter the liquid filling in measuring cup in battery pack using air positive pressure.
6:High-precision liquid metering control is installed, because the high accuracy directly to electrolyte is moved in electrolyte hopper State metering difficulty is larger, and electrolyte is a kind of corrosive liquids, and level sensing can be real when noncontact is used in the present invention Existing high-precision liquid level detection replaces high-precision flow monitoring.The present invention is using the liquid level of flux control system with feedback, as long as smart The liquid level of true controlled quentity controlled variable, it is possible to control the volume of the electrolyte in measuring cup.This equipment uses precision to be connect for the non-of 0.1mm Touch the control valve of liquid sensor, a diameter of 60mm measuring cup and resistance to alkali corrosion.
7:The reason for using feedback control system is due to that with filling process, its liquid level is to decline to electrolyte hopper, because This pipe flow speed can not be controlled to judge the volume of outflow directly passage time also in change.This equipment utilization fluid Gravity realize electrolyte hopper to the quantifying feed of measuring cup, and eliminate liquid pump.Because existing market is difficult to find resistance to highly basic Corrode the liquid pump without there is impurity to pollute electrolyte during abrasion.In order to thorough in electrolyte flow control process Valve and liquid pump are abandoned in bottom, and this equipment realizes the flowing control of fluid using gas pressure.
8:Realize that the flow control principle of fluid is as follows using gas pressure:1) using negative pressure air pump to electrolyte hopper The control of internal upper part point air pressure can realize the flowing and stopping of fluid;2) high-precision pressure sensor and negative pressure air pump Can realize that hopper first half air pressure is accurately controlled;3) reduction hopper is then made to measuring cup if necessary to filling electrolyte Upper air negative pressure, can gradually reduce negative pressure until negative pressure is zero, now maximum flow during increase flow;4) liquid in measuring cup Position may gradually increase negative pressure when the liquid level of design, so as to reduce flow until fluid stops flowing;5) to the detection of liquid level Control and constitute a typical closed-loop control system for the detection control of negative pressure, can essence using closed loop Liquid level algorithm The liquid level of true control measuring cup, so as to be accurately obtained the volume of electrolyte;6) this equipment is very low to negative pressure requirements, using a work( The vavuum pump of rate very little can be completed;7) flow velocity that electrolyte flows to measuring cup can be controlled by accurate Stress control, from And accurate Liquid level is realized, also it is achieved that the accurate fixing fabric structure of electrolyte;8) highest and minimum liquid level warning line are The detection of equipment automatic liquid level is realized, if liquid has crossed warning liquid level, automatic eliminate of being alarmed after the solution that can alarm;9) work Making personnel can be with the position of sets itself alarming line.
Brief description of the drawings
Fig. 1 is the overall structure figure of the present invention.
Fig. 2 is industrial computer system control minor structure figure of the present invention.
Fig. 3 is the two-dimension high-precision digital control platform structure chart of the present invention.
Fig. 4 is the pneumatic shuttle liquid filling schematic diagram of the present invention.
Fig. 5 is the utilization gas pressure flow of fluid control principle drawing of the present invention.
Fig. 6 is the utilization gas pressure flow of fluid state of a control figure of the present invention.
Fig. 7 is closed loop controlling structure figure.
Fig. 8 is high water tank control system figure.
Embodiment
As shown in figure 1, a kind of electrolyte automatic vacuum filling apparatus, including it is frame main body 1, vertical beam 2, digital control platform 3, true Empty filling head 4, digital control computer system touch screen 5, electrolyte hopper 6, battery install fixture 7.The bottom of vertical beam 2 and frame main body 1 is vertically connected, and battery installs fixture 7 and is arranged on the top of frame main body 1, and battery 8 to be filled is arranged on battery and installed on fixture 7, The top of vertical beam 2 connection digital control computer system touch screen 5, the one end of digital control platform 3 connection vacuum filling first 4, digital control platform 3 is another End connection electrolyte hopper 6.Digital control platform 3 is used to drive first 4 high accuracy positioning in two dimensional surface of vacuum filling, and input is fixed Position coordinate is that can be achieved to add being accurately positioned for vacuum filling first 4.
High-precision liquid metering control, the high-precision liquid measure control are installed in the electrolyte hopper 6 Device includes non-contact liquid sensor 9, measuring cup 10, control valve.Measuring cup 10 connects electricity by being provided with the pipeline of control valve Solve and non-contact liquid sensor 9 is set in liquid material bucket 6, measuring cup 10.The top of electrolyte hopper 6 is by being provided with baroceptor 11 Pipeline connection negative pressure air pump 12.The non-contact liquid sensor 9, control valve, baroceptor 11, negative pressure air pump 12 are equal Industrial computer system is connected, industrial computer system control minor structure figure is as shown in Fig. 2 industrial computer system connects numerical control Platform 3, industrial computer system is used to realize:Vacuum filling first 4, upper and lower motion control;High-precision liquid metering, control;Plus Control is coordinated in note pumping;The safe stable-pressure device control of pneumatic means.
Selection 8AM1 models in the first 4 connection miniature explosion-proof low-noise pneumatic control device of vacuum filling, the present invention Piston type pneumatic motor, realizes the upper and lower motion control of filling head, and filling process uses air positive pressure, realizes in measuring cup 10 Liquid filling enter in battery 8 to be filled.
It is made using 309 stainless steel materials, the bottom of frame main body 1 is provided with pulley, mobile production can be achieved Filling.Two-dimension high-precision digital control platform structure chart is as shown in figure 3, the digital control platform 3 is by longitudinal axis guide rail 3.1, transverse axis guide rail 3.2, two dimension NC auto platform 3.3, data line interface 3.4 are constituted;Longitudinal axis guide rail 3.1, for realizing that vacuum filling first 4 is vertically moved; Transverse axis guide rail 3.2, for realizing first 4 transverse shifting of vacuum filling;Data line interface 3.4, for realizing the He of two dimension NC auto platform 3.3 Communication between computer system.Two-dimension high-precision digital control platform can drive vacuum filling head or battery pack to realize battery The filling of each cell electrolyte in group, but if using the motion of battery pack to realize when, due to battery pack chi Very little volume is larger, it is therefore desirable to larger space, and if needs to use hydraulic means when battery weight is larger Can take to, hydraulic means size is larger, there is greasy dirt, thus this equipment use two dimensional motion by controlling filling head and Electrolyte automatic filling is realized in up and down motion.
A kind of electrolyte automatic vacuum filing provision of the present invention, its pneumatic shuttle liquid filling schematic diagram is as shown in Figure 4.Figure (a) electrolyte process is filled to measuring cup for electrolyte hopper in, when the liquid level in measuring cup reaches the liquid level of design, fluid stops Fluid stopping is moved;In figure (b), the air positive pressure above measuring cup is increased by pneumatic shuttle, piston is moved down, realized liquid in measuring cup Body is filled in battery;Scheme (c), after liquid filling is into battery in measuring cup, gradually reduce malleation, piston is moved up; Scheme (d), until malleation is reduced to minimum, when piston is moved to top, system is prepared to enter into electrolyte hopper and measuring cup is filled Process, into circulation.
A kind of electrolyte automatic vacuum filing provision of the present invention, its using gas pressure flow of fluid control principle such as Fig. 5, Shown in 6.Because electrolyte has severe corrosive, general valve and liquid pump can not flow to it to be controlled, and corrosion is brought Impurity can pollute electrolyte, realize that flowing to fluid is controlled using negative pressure air pump 12.
It is to realize electrolyte hopper to accurate measuring cup filling process by negative pressure air pump in figure (a);Scheme in (b), when being When system sends filling measuring cup instruction, the electricity in the negative pressure above electrolyte hopper, electrolyte hopper is increased by negative pressure air pump Solution liquid is flowed into measuring cup by pipeline;Scheme in (c), continue to increase the negative pressure above electrolyte hopper by negative pressure air pump, Electrolyte hopper continues electrolyte and is injected into measuring cup and until the liquid level of setting;Scheme in (d), when electrolyte is filled in measuring cup To setting liquid level when, pass through negative pressure air pump and reduce negative pressure, electrolyte hopper stop vector cup filling electrolyte.
A kind of electrolyte automatic vacuum charging method, vacuum filling is realized using miniature explosion-proof low-noise pneumatic control device First 4 upper and lower motion control, filling process uses air positive pressure, and the liquid filling in measuring cup 10 is entered battery 8 to be filled by realization In.Realized using the gravity of fluid, electrolyte hopper 6 arrives the quantifying feed of measuring cup 10, and fluid is realized using gas pressure Flowing control.
A kind of electrolyte automatic vacuum charging method,
1), the control using negative pressure air pump 12 to the internal upper part point air pressure of electrolyte hopper 6, realizes the flowing of fluid And stopping;
2), using baroceptor 11 and negative pressure air pump 12, realize that the first half air pressure of electrolyte hopper 6 is accurately controlled System;If necessary to filling electrolyte to measuring cup 10, then make the upper air negative pressure of reduction electrolyte hopper 6, increase flow
When can gradually reduce negative pressure until negative pressure is zero, now maximum flow;
Liquid level may gradually increase negative pressure when the liquid level of design in measuring cup 10, so as to reduce flow until fluid stops Fluid stopping is moved;
3), the detection to liquid level controls and constitutes a typical closed-loop control system for the detection control of negative pressure, adopts With Liquid level algorithm is closed, the liquid level of measuring cup 10 is accurately controlled, so as to be accurately obtained the volume of electrolyte;By accurately pressing Power control can control the flow velocity that electrolyte flows to measuring cup 10, so as to realize the Liquid level of precision, also be achieved that electrolysis The accurate fixing fabric structure of liquid.
It is described to close Liquid level algorithm, for realizing liquid level data detection and liquid level prediction, the tank level control system base This function is set after liquid level, by controlling transmitter, automatically adjusts liquid level to arranges value;If automatically adjusted out During existing mistake, it is switched to and is adjusted and diagnoses manually;The steady-state error, overshoot, tune of analysis system are gone by real-time curve The dynamic performance indexs such as whole time,
Close Liquid level algorithm and mainly realize liquid level data detection and liquid level prediction, the tank level control system basic function It is to set after liquid level, by controlling transmitter, automatically adjusts liquid level to arranges value.There is mistake if automatically adjusted When, it can be switched to and be adjusted and diagnose manually.Can be gone by real-time curve the steady-state error of analysis system, overshoot, The dynamic performance indexs such as adjustment time.Invention system of the present invention is made up of four basic links, i.e. controlled device, measurement Pick-up device, controller and actuator.Closed loop controlling structure is as shown in Figure 7.Can be according to Close-loop Control System Design water tank Tank level control system, the high water tank control system of design is as shown in Figure 8.
Tank level control system in the present invention, Single Loop Control System is usually with a regulation on a controlled plant Device keeps the constant of parameter, and adjuster only receives a measurement signal, and it is exported also only controls an executing agency. Computer control is different from traditional Analog control, it be using a kind of controlling of sampling, can only be according to the deviation of sampling instant Value carries out calculating control.Continuous output controlling amount contact control can not be carried out as Analog control.Therefore, to analog quantity control Integral term and differential term in system must carry out sliding-model control.It can be seen from Digital Signal Processing relevant knowledge, at discretization Reason:Discrete sampling time KT correspond to continuous time (wherein K is sampling sequence number, and T is the sampling period), be replaced with the form of summation Integration, differential is replaced in the form of increment, approximate transform can be carried out and obtain:
In formula, K is sampling sequence number, K=0,1,2,3 ...;ukFor the input deviation value of kth sampling instant;ek-1 For the input deviation value of the K-1 times sampling instant;K1=KPT/T1;KDPosition derivative constant;KD=KPTD/T;u0For control constant.When Sampling period, T was sufficiently small, and above-mentioned result of calculation can reach enough accurately, and discrete control process can be regarded as approximately as continuous control Process processed.Said process employs whole controlled quentity controlled variables, therefore is referred to as full dose formula or positional PID control calculation.Because being complete Amount output, so output result is relevant with past state every time, calculating formula is to ekAdded up, workload is big and controller is defeated The u gone outkThe physical location of corresponding executing agency, when controller breaks down, if output is widely varied, can draw Being widely varied for executing agency is played, serious production accident is likely to result in.Increment type PID refers to the output of digitial controller only It is the increment △ u of controlled quentity controlled variablek, when the controlled quentity controlled variable that actuator needs is increment rather than position, increment type PID can be used to calculate Method is controlled.Can obtain controller by (1) formula is in the output valve of the K-1 sampling instant:
Subtracted each other and arranged by two formulas, can obtain incremental timestamp algorithmic formula is:
In formula,
In above formula, △ ukIt can also be write as following form:
In formula, △ ek=ek-ek-1;I=ek-2ek-1+ek-2=△ ek-△ek-2;I=T/TI;D=TD/T
If there is above formula to can be seen that computer control system using constant sampling period T, once it is determined that A, B, C, As long as using the deviation of front and rear three measurements, it is possible to obtain controlling increment, compared with position model algorithm, amount of calculation is small A lot.
A kind of electrolyte automatic vacuum charging method, comprises the following steps:
1) automatic detection device power supply, is opened, from screen display self-detection result is touched, enters next step after self-inspection success, If self-inspection is unsuccessful, overhauled according to self-inspection error message;
If 2), during the alarm of electrolyte hopper residue, need to add electrolyte, equipment can then automatically terminate alarm;
3), battery pack to be filled is loaded manually;
4) the dimensional parameters information of battery pack to be filled, is selected:Battery size, appearance and size, cell size and row Row;If continuing to use the information of last filling battery, then number and add " 1 " automatically, remaining selection default value.
5) filling process, is started;
6) after filling is finished, device systems automatically save the every terms of information of filling battery pack:Battery pack information, filling starting And the end time;It can be consulted by touch-screen.If continuing to fill next battery pack, return 2), otherwise can select Select standby and shutdown.

Claims (10)

1. a kind of electrolyte automatic vacuum filling apparatus, it is characterised in that including:Frame main body (1), vertical beam (2), digital control platform (3), vacuum filling head (4), digital control computer system touch screen (5), electrolyte hopper (6), battery install fixture (7);Vertical beam (2) bottom is vertically connected with frame main body (1), and battery installs fixture (7) and is arranged on frame main body (1) top, battery to be filled (8) it is arranged on battery to install on fixture (7), vertical beam (2) top connection digital control computer system touch screen (5), digital control platform (3) One end connection vacuum filling head (4), digital control platform (3) other end connection electrolyte hopper (6);Digital control platform (3), for driving High accuracy positioning of the vacuum filling head (4) in two dimensional surface, the input elements of a fix are the essence that can be achieved to add vacuum filling head (4) It is determined that position.
2. a kind of electrolyte automatic vacuum filling apparatus according to claim 1, it is characterised in that:The electrolyte hopper (6) high-precision liquid metering control is installed, the high-precision liquid metering control is sensed including non-contact liquid in Device (9), measuring cup (10), control valve;
Measuring cup (10) connects setting non-contact liquid in electrolyte hopper (6), measuring cup (10) by being provided with the pipeline of control valve Sensor (9);
Electrolyte hopper (6) top connects negative pressure air pump (12) by being provided with the pipeline of baroceptor (11);
The non-contact liquid sensor (9), control valve, baroceptor (11), negative pressure air pump (12) are all connected with industrial meter Calculation machine system, industrial computer system connection digital control platform (3), industrial computer system is used to realize:
Vacuum filling head (4), upper and lower motion control;
High-precision liquid metering, control;
Control is coordinated in filling pumping;
The safe stable-pressure device control of pneumatic means.
3. a kind of electrolyte automatic vacuum filling apparatus according to claim 1, it is characterised in that:The vacuum filling head (4) miniature explosion-proof low-noise pneumatic control device is connected, the upper and lower motion control of filling head is realized, filling process uses air Malleation, realization enters the liquid filling in measuring cup (10) in battery to be filled (8).
4. a kind of electrolyte automatic vacuum filling apparatus according to claim 1, it is characterised in that:The frame main body (1) It is made using 309 stainless steel materials, frame main body (1) bottom is provided with pulley, mobile production filling can be achieved.
5. a kind of electrolyte automatic vacuum filling apparatus according to claim 1, it is characterised in that:The digital control platform (3) By longitudinal axis guide rail (3.1), transverse axis guide rail (3.2), two dimension NC auto platform (3.3), data line interface (3.4) composition;
Longitudinal axis guide rail (3.1), for realizing that vacuum filling head (4) is vertically moved;
Transverse axis guide rail (3.2), for realizing vacuum filling head (4) transverse shifting;
Data line interface (3.4), for realizing communication of the two dimension NC auto platform (3.3) between computer system.
6. a kind of electrolyte automatic vacuum charging method, it is characterised in that:It is real using miniature explosion-proof low-noise pneumatic control device The upper and lower motion control of existing vacuum filling head (4), filling process uses air positive pressure, and realization adds the liquid in measuring cup (10) Inject in battery to be filled (8).
7. a kind of electrolyte automatic vacuum charging method, it is characterised in that:Realized using the gravity of fluid, electrolyte hopper (6) To the quantifying feed of measuring cup (10), the flowing control of fluid is realized using gas pressure.
8. a kind of electrolyte automatic vacuum charging method, it is characterised in that:
1), the control using negative pressure air pump (12) to electrolyte hopper (6) internal upper part point air pressure, realizes the flowing of fluid And stopping;
2), using baroceptor (11) and negative pressure air pump (12), realize that electrolyte hopper (6) first half air pressure is accurate Control;
If necessary to filling electrolyte to measuring cup (10), then make reduction electrolyte hopper (6) upper air negative pressure, during increase flow Negative pressure can be gradually reduced until negative pressure is zero, now maximum flow;
Liquid level may gradually increase negative pressure when the liquid level of design in measuring cup (10), so as to reduce flow until fluid stops Flowing;
3), the detection to liquid level controls and constitutes a typical closed-loop control system for the detection control of negative pressure, using closing Liquid level algorithm, is accurately controlled the liquid level of measuring cup (10), so as to be accurately obtained the volume of electrolyte;Pass through accurate pressure Control can control the flow velocity that electrolyte flows to measuring cup (10), so as to realize the Liquid level of precision, also be achieved that electrolysis The accurate fixing fabric structure of liquid.
9. a kind of electrolyte automatic vacuum charging method according to claim 8, it is characterised in that:It is described to close Liquid level calculation Method, for realizing liquid level data detection and liquid level prediction, the tank level control system basic function is set after liquid level, is led to Control transmitter is crossed, liquid level is automatically adjusted to arranges value;If automatically adjust appearance mistake, it is switched to and is adjusted manually Section and diagnosis;The dynamic performance indexs such as the steady-state error, overshoot, adjustment time of analysis system are removed by real-time curve, liquid is closed Bit-steering algorithm is made up of four basic links, i.e. controlled device, measurement pick-up device, controller and actuator;
In tank level control system in the present invention, Single Loop Control System is usually with an adjuster on a controlled plant To keep the constant of parameter, and adjuster only receives a measurement signal, and it, which is exported, also only controls an executing agency;Meter The control of calculation machine is different from traditional Analog control, it be using a kind of controlling of sampling, can only be according to the deviation of sampling instant Carry out calculating control;Continuous output controlling amount contact control can not be carried out as Analog control;Therefore, to Analog control In integral term and differential term must carry out sliding-model control, it can be seen from Digital Signal Processing relevant knowledge, sliding-model control: Discrete sampling time KT correspond to continuous time, and wherein K is sampling sequence number, and T is the sampling period, and product is replaced with the form of summation Point, differential is replaced in the form of increment, approximate transform can be carried out and obtained:
<mrow> <msub> <mi>u</mi> <mi>k</mi> </msub> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mo>&amp;lsqb;</mo> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>+</mo> <mfrac> <mi>T</mi> <msub> <mi>T</mi> <mi>I</mi> </msub> </mfrac> <munderover> <mo>&amp;Sigma;</mo> <mrow> <mi>j</mi> <mo>=</mo> <mn>0</mn> </mrow> <mi>k</mi> </munderover> <msub> <mi>e</mi> <mi>j</mi> </msub> <mo>+</mo> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <mrow> <mo>(</mo> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>-</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>)</mo> </mrow> <mo>&amp;rsqb;</mo> <mo>+</mo> <msub> <mi>u</mi> <mn>0</mn> </msub> <mo>-</mo> <mo>-</mo> <mo>-</mo> <mrow> <mo>(</mo> <mn>1</mn> <mo>)</mo> </mrow> </mrow>
In formula, K is sampling sequence number, K=0,1,2,3 ...;ukFor the input deviation value of kth sampling instant;ek-1For K- The input deviation value of 1 sampling instant;K1=KPT/T1;KDPosition derivative constant;KD=KPTD/T;u0To control constant, when sampling week Phase, T was sufficiently small, and above-mentioned result of calculation can reach that enough accurately discrete control process can be regarded as approximately as continuous control Journey;Said process employs whole controlled quentity controlled variables, therefore is referred to as full dose formula or positional PID control calculation, because being that full dose is defeated Go out, so output result is relevant with past state every time, calculating formula is to ekAdded up, workload is big and controller output ukThe physical location of corresponding executing agency, when controller breaks down, if output is widely varied, can cause and hold Row mechanism is widely varied, and is likely to result in serious production accident;Increment type PID refers to that the output of digitial controller is control The increment △ u of amount processedk, when the controlled quentity controlled variable that actuator needs is increment rather than position, increment type PID algorithm can be used to enter Row control;Can obtain controller by (1) formula is in the output valve of the K-1 sampling instant:
<mrow> <msub> <mi>u</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mo>&amp;lsqb;</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>+</mo> <mfrac> <mi>T</mi> <msub> <mi>T</mi> <mi>I</mi> </msub> </mfrac> <munderover> <mo>&amp;Sigma;</mo> <mrow> <mi>j</mi> <mo>=</mo> <mn>0</mn> </mrow> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </munderover> <msub> <mi>e</mi> <mi>j</mi> </msub> <mo>+</mo> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <mrow> <mo>(</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>-</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>2</mn> </mrow> </msub> <mo>)</mo> </mrow> <mo>&amp;rsqb;</mo> <mo>+</mo> <msub> <mi>u</mi> <mn>0</mn> </msub> <mo>-</mo> <mo>-</mo> <mo>-</mo> <mrow> <mo>(</mo> <mn>2</mn> <mo>)</mo> </mrow> </mrow>
Subtracted each other and arranged by two formulas, can obtain incremental timestamp algorithmic formula is:
<mfenced open = "" close = ""> <mtable> <mtr> <mtd> <mrow> <msub> <mi>&amp;Delta;u</mi> <mi>k</mi> </msub> <mo>=</mo> <msub> <mi>u</mi> <mi>k</mi> </msub> <mo>-</mo> <msub> <mi>u</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mo>&amp;lsqb;</mo> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>-</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>+</mo> <mfrac> <mi>T</mi> <msub> <mi>T</mi> <mi>I</mi> </msub> </mfrac> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>+</mo> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <mrow> <mo>(</mo> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>-</mo> <mn>2</mn> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>+</mo> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>2</mn> </mrow> </msub> <mo>)</mo> </mrow> <mo>&amp;rsqb;</mo> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mrow> <mo>(</mo> <mn>1</mn> <mo>+</mo> <mfrac> <mi>T</mi> <msub> <mi>T</mi> <mi>I</mi> </msub> </mfrac> <mo>+</mo> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <mo>)</mo> </mrow> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>-</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mrow> <mo>(</mo> <mn>1</mn> <mo>+</mo> <mfrac> <mrow> <mn>2</mn> <msub> <mi>T</mi> <mi>D</mi> </msub> </mrow> <mi>T</mi> </mfrac> <mo>)</mo> </mrow> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>+</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <msub> <mi>e</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>2</mn> </mrow> </msub> </mrow> </mtd> </mtr> <mtr> <mtd> <mrow> <mo>=</mo> <msub> <mi>Ae</mi> <mi>k</mi> </msub> <mo>+</mo> <msub> <mi>Be</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>1</mn> </mrow> </msub> <mo>+</mo> <msub> <mi>Ce</mi> <mrow> <mi>k</mi> <mo>-</mo> <mn>2</mn> </mrow> </msub> </mrow> </mtd> </mtr> </mtable> </mfenced>
In formula,
In above formula, △ ukIt can also be write as following form:
<mrow> <msub> <mi>&amp;Delta;u</mi> <mi>k</mi> </msub> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mrow> <mo>(</mo> <msub> <mi>&amp;Delta;e</mi> <mi>k</mi> </msub> <mo>+</mo> <mfrac> <mi>T</mi> <msub> <mi>T</mi> <mi>I</mi> </msub> </mfrac> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>+</mo> <mfrac> <msub> <mi>T</mi> <mi>D</mi> </msub> <mi>T</mi> </mfrac> <msup> <mi>&amp;Delta;</mi> <mn>2</mn> </msup> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>)</mo> </mrow> <mo>=</mo> <msub> <mi>K</mi> <mi>P</mi> </msub> <mrow> <mo>(</mo> <msub> <mi>&amp;Delta;e</mi> <mi>k</mi> </msub> <mo>+</mo> <msub> <mi>Ie</mi> <mi>k</mi> </msub> <mo>+</mo> <msup> <mi>D&amp;Delta;</mi> <mn>2</mn> </msup> <msub> <mi>e</mi> <mi>k</mi> </msub> <mo>)</mo> </mrow> </mrow>
In formula, △ ek=ek-ek-1;I=ek-2ek-1+ek-2=△ ek-△ek-2;I=T/TI;D=TD/T。
10. a kind of electrolyte automatic vacuum charging method, it is characterised in that comprise the following steps:
1) automatic detection device power supply, is opened, from screen display self-detection result is touched, enters next step after self-inspection success, if from Inspection is unsuccessful, then is overhauled according to self-inspection error message;
If 2), during the alarm of electrolyte hopper residue, need to add electrolyte, equipment can then automatically terminate alarm;
3), battery pack to be filled is loaded manually;
4) the dimensional parameters information of battery pack to be filled, is selected:Battery size, appearance and size, cell size and arrangement;Such as Fruit is the information for continuing to use last filling battery, then numbers automatic plus " 1 ", remaining selection default value;
5) filling process, is started;
6) after filling is finished, device systems automatically save the every terms of information of filling battery pack:Battery pack information, filling starting and knot The beam time;It can be consulted by touch-screen;If continuing to fill next battery pack, return 2), otherwise can select to treat Machine and shutdown.
CN201710471479.0A 2017-06-20 2017-06-20 Automatic vacuum filling device of electrolyte Active CN107195850B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710471479.0A CN107195850B (en) 2017-06-20 2017-06-20 Automatic vacuum filling device of electrolyte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710471479.0A CN107195850B (en) 2017-06-20 2017-06-20 Automatic vacuum filling device of electrolyte

Publications (2)

Publication Number Publication Date
CN107195850A true CN107195850A (en) 2017-09-22
CN107195850B CN107195850B (en) 2023-02-07

Family

ID=59878142

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710471479.0A Active CN107195850B (en) 2017-06-20 2017-06-20 Automatic vacuum filling device of electrolyte

Country Status (1)

Country Link
CN (1) CN107195850B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109921096A (en) * 2019-03-07 2019-06-21 广东鸿宝科技有限公司 A kind of band protects the battery sealing machine and its control method of liquid measure closed-loop control
CN113491028A (en) * 2018-12-26 2021-10-08 Tm普拉萨株式会社 Vacuum hopper pre-charger
CN114597608A (en) * 2022-05-09 2022-06-07 张家港博华新能源机械有限公司 Automatic acid filling machine for filling acid into storage battery
CN115377626A (en) * 2022-08-24 2022-11-22 上海地铁维护保障有限公司 Supplementary liquid feeding device of subway train battery
CN115841127A (en) * 2022-10-31 2023-03-24 宁德时代新能源科技股份有限公司 Electrolyte filling control method and device and storage medium

Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0752996A (en) * 1993-08-10 1995-02-28 Mitsubishi Heavy Ind Ltd Filling apparatus
JP2006130574A (en) * 2004-11-02 2006-05-25 Disco Abrasive Syst Ltd High-pressure liquid injection type cutting device
CN201263982Y (en) * 2008-09-28 2009-07-01 王学东 Piston type quantitative liquid injection washing head
CN101697371A (en) * 2009-10-28 2010-04-21 东莞市鸿宝锂电科技有限公司 Method and device for injecting electrolyte into lithium battery
JP2011119088A (en) * 2009-12-02 2011-06-16 Iwashita Engineering Inc Electrolyte injection device
CN102148349A (en) * 2011-03-04 2011-08-10 深圳市吉阳自动化科技有限公司 Automatic filling machine for battery and battery filling method
US20110201050A1 (en) * 2011-04-26 2011-08-18 Therapeutic Proteins Inc. Gas Scrubbed Perfusion Filter
JP2012038685A (en) * 2010-08-11 2012-02-23 Iwashita Engineering Inc Electrolyte solution injection device using weight management in vacuum
CN202231092U (en) * 2011-09-21 2012-05-23 广东五洲龙电源科技有限公司 Volume type full-automatic vacuum liquid-injecting machine
CN202605328U (en) * 2012-05-21 2012-12-19 冯有为 Novel medicine feeding device for critically ill patient
CN202957322U (en) * 2012-11-23 2013-05-29 凯迈(江苏)机电有限公司 Battery liquid injection system
CN103208607A (en) * 2013-03-12 2013-07-17 深圳市恒瑞兴自动化设备有限公司 Extensively-adjustable precision liquid injection equipment
CN103236514A (en) * 2013-04-24 2013-08-07 深圳市沃特玛电池有限公司 Battery fluid filling device and method
CN103515570A (en) * 2012-06-21 2014-01-15 深圳拓邦股份有限公司 Square battery liquid injection machine
CN104518196A (en) * 2013-09-27 2015-04-15 上海空间电源研究所 Vacuum automatic charging system of silver-zinc secondary battery electrolyte and method thereof
CN204303906U (en) * 2014-11-12 2015-04-29 东莞新能源科技有限公司 A kind of electrolytic solution priming device of lithium ion battery
US20150130872A1 (en) * 2013-11-13 2015-05-14 Seiko Epson Corporation Liquid ejecting apparatus and maintenance method
CN205283961U (en) * 2015-11-23 2016-06-01 西安建筑科技大学 Utilize BGA welding set of small -size numerical control platform
CN106099028A (en) * 2016-08-19 2016-11-09 重庆市中欣维动力科技有限公司 Lithium battery electrolytes liquid injection system with automatic delivering mechanism
CN206849941U (en) * 2017-06-20 2018-01-05 三峡大学 A kind of electrolyte automatic vacuum filling apparatus

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0752996A (en) * 1993-08-10 1995-02-28 Mitsubishi Heavy Ind Ltd Filling apparatus
JP2006130574A (en) * 2004-11-02 2006-05-25 Disco Abrasive Syst Ltd High-pressure liquid injection type cutting device
CN201263982Y (en) * 2008-09-28 2009-07-01 王学东 Piston type quantitative liquid injection washing head
CN101697371A (en) * 2009-10-28 2010-04-21 东莞市鸿宝锂电科技有限公司 Method and device for injecting electrolyte into lithium battery
JP2011119088A (en) * 2009-12-02 2011-06-16 Iwashita Engineering Inc Electrolyte injection device
JP2012038685A (en) * 2010-08-11 2012-02-23 Iwashita Engineering Inc Electrolyte solution injection device using weight management in vacuum
CN102148349A (en) * 2011-03-04 2011-08-10 深圳市吉阳自动化科技有限公司 Automatic filling machine for battery and battery filling method
US20110201050A1 (en) * 2011-04-26 2011-08-18 Therapeutic Proteins Inc. Gas Scrubbed Perfusion Filter
CN202231092U (en) * 2011-09-21 2012-05-23 广东五洲龙电源科技有限公司 Volume type full-automatic vacuum liquid-injecting machine
CN202605328U (en) * 2012-05-21 2012-12-19 冯有为 Novel medicine feeding device for critically ill patient
CN103515570A (en) * 2012-06-21 2014-01-15 深圳拓邦股份有限公司 Square battery liquid injection machine
CN202957322U (en) * 2012-11-23 2013-05-29 凯迈(江苏)机电有限公司 Battery liquid injection system
CN103208607A (en) * 2013-03-12 2013-07-17 深圳市恒瑞兴自动化设备有限公司 Extensively-adjustable precision liquid injection equipment
CN103236514A (en) * 2013-04-24 2013-08-07 深圳市沃特玛电池有限公司 Battery fluid filling device and method
CN104518196A (en) * 2013-09-27 2015-04-15 上海空间电源研究所 Vacuum automatic charging system of silver-zinc secondary battery electrolyte and method thereof
US20150130872A1 (en) * 2013-11-13 2015-05-14 Seiko Epson Corporation Liquid ejecting apparatus and maintenance method
CN204303906U (en) * 2014-11-12 2015-04-29 东莞新能源科技有限公司 A kind of electrolytic solution priming device of lithium ion battery
CN205283961U (en) * 2015-11-23 2016-06-01 西安建筑科技大学 Utilize BGA welding set of small -size numerical control platform
CN106099028A (en) * 2016-08-19 2016-11-09 重庆市中欣维动力科技有限公司 Lithium battery electrolytes liquid injection system with automatic delivering mechanism
CN206849941U (en) * 2017-06-20 2018-01-05 三峡大学 A kind of electrolyte automatic vacuum filling apparatus

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113491028A (en) * 2018-12-26 2021-10-08 Tm普拉萨株式会社 Vacuum hopper pre-charger
CN113491028B (en) * 2018-12-26 2024-02-06 Tm普拉萨株式会社 Vacuum hopper pre-charger
CN109921096A (en) * 2019-03-07 2019-06-21 广东鸿宝科技有限公司 A kind of band protects the battery sealing machine and its control method of liquid measure closed-loop control
CN109921096B (en) * 2019-03-07 2024-02-23 广东鸿宝科技有限公司 Electrolyte liquid-retaining amount closed-loop control method of battery sealing machine
CN114597608A (en) * 2022-05-09 2022-06-07 张家港博华新能源机械有限公司 Automatic acid filling machine for filling acid into storage battery
CN114597608B (en) * 2022-05-09 2022-07-22 张家港博华新能源机械有限公司 Automatic acid filling machine for acid filling of storage battery
CN115377626A (en) * 2022-08-24 2022-11-22 上海地铁维护保障有限公司 Supplementary liquid feeding device of subway train battery
CN115377626B (en) * 2022-08-24 2024-03-15 上海地铁维护保障有限公司 Auxiliary liquid adding device for storage battery of subway train
CN115841127A (en) * 2022-10-31 2023-03-24 宁德时代新能源科技股份有限公司 Electrolyte filling control method and device and storage medium

Also Published As

Publication number Publication date
CN107195850B (en) 2023-02-07

Similar Documents

Publication Publication Date Title
CN107195850A (en) A kind of electrolyte automatic vacuum filling apparatus
CN102173055B (en) Liquid level detection and oil liquid automatic compensation device
CN204214881U (en) A kind of automatic quantitative liquid feeder
CN103940496B (en) Small liquid flow standard device special for hemodialysis machine calibrator
CN203440658U (en) Intelligent automatic dyestuff dissolving device
CN100546706C (en) Automatic control method for hydrochloric acid solution dilution technique
CN102252473A (en) Fully-automatic refrigerant weight-measuring type filling machine
CN206849941U (en) A kind of electrolyte automatic vacuum filling apparatus
CN202575947U (en) Double-station barrel extracting and cleaning device
CN106066198B (en) Simple device and method for measuring volume of methane in gas collecting bag
CN209038288U (en) It is a kind of can automatic feeding fluid reservoir
CN104787715A (en) Injection meter
CN103257172B (en) Limestone activity determination and detection apparatus
CN101607687B (en) Self-calibration linear displacement type filling machine for liquid
CN103387201A (en) Automatic filling system and method for single-component polyurethane sealing gum
CN203464984U (en) Self-lifting container combination applying oblique support springs
CN206847739U (en) Two-way self-circulation type liquid level meter detecting device
CN105919149A (en) Automatic grease adding device on basis of PLC (programmable logic control) system
CN203486883U (en) Filling amount adjusting device of filling machine
CN205644786U (en) Liquid measurement system of machine is sold to liquid
CN205396608U (en) Liquid quantitative filling controlling means based on weightometer volume
CN203083666U (en) Water meter verification device
CN104999050B (en) A kind of quantitative molten metal vacuum pumping device
CN217600356U (en) Automatic liquid device that divides of solution
CN218359135U (en) Pharmaceutical adding equipment for circulating water

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Zhang Jinwei

Inventor before: Chen Li

CB03 Change of inventor or designer information
GR01 Patent grant
GR01 Patent grant