CN107189714A - A kind of preparation method of cigarette overlapping glue - Google Patents
A kind of preparation method of cigarette overlapping glue Download PDFInfo
- Publication number
- CN107189714A CN107189714A CN201710511609.9A CN201710511609A CN107189714A CN 107189714 A CN107189714 A CN 107189714A CN 201710511609 A CN201710511609 A CN 201710511609A CN 107189714 A CN107189714 A CN 107189714A
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- Prior art keywords
- overlapping glue
- cigarette
- preparation
- cigarette overlapping
- solution
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/10—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2275—Ferroso-ferric oxide (Fe3O4)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of preparation method of cigarette overlapping glue, first cmc soln and copperas solution are blended, carboxymethyl cellulose is set fully to be coordinated with ferrous ion, obtain carboxymethyl cellulose Complexing Iron, then it is well mixed to form composite solution system with sodium alginate soln, and uniformly generate ferriferrous oxide nano-particle by adjusting the oxidation of oxygen in pH and air in composite solution system situ, composite solution system is formed into drop into carrying out gelation reaction in coagulation bath in high-pressure electrostatic off field again and obtains composite gel microsphere, cigarette overlapping glue is obtained after being well mixed with oxidized starch.Cigarette overlapping glue produced by the present invention both has excellent adhesive property, has the auxiliary effect for improving flavor quality of cigarette again, practical.
Description
Technical field
The present invention relates to cigarette field of adhesive technology, more particularly to a kind of preparation method of cigarette overlapping glue.
Background technology
Adhesive is essential supplementary material in cigarette making process, mainly including overlapping glue, connect mouth glue, packaging glue,
Wherein overlapping glue directly participates in cigarette burning, and its quality also produces large effect to cigarette product quality and smoke components.With
The raising of quality of life, environmental requirement of the people not only to cigarette overlapping glue is more and more stricter, also to cigarette overlapping glue to volume
The improvement ability of tobacco quality proposes higher expectation.Current cigarette product generally existing flue gas intensity is big, thorn of choking sense is relatively strong, inhale
Taste owes comfortable defect, is on the one hand due to contain a large amount of harmful components in flue gas, excitant is strong, another aspect pipe tobacco humectation
Difference, moisture are not enough, cause flue gas drying, and taste comfort level is inhaled in reduction.Existing environment-friendly type cigarette overlapping glue main component is
Starch, although its smell of burning is similar to paper, the negative effect to cigarette odor-absorbing is small, but can not reach and cigarette odor-absorbing is changed
Kind effect, therefore, the single starch cigarette overlapping glue of composition have been difficult to meet the market demand.
The content of the invention
The object of the invention is exactly that can improve the cigarette of flavor quality of cigarette there is provided a kind of to make up the defect of prior art
The preparation method of overlapping glue.
The present invention is achieved by the following technical solutions：
A kind of preparation method of cigarette overlapping glue, comprises the following steps：
（1）Carboxymethyl cellulose is first added to the water stirring and dissolving and obtains cmc soln completely, then to the carboxylic
Copperas solution, and the stirring reaction 0.5-1h under logical nitrogen protective condition are slowly added dropwise in methocel solution, obtains
Carboxymethyl cellulose is complexed ferrous solution, and the volume ratio of the cmc soln and copperas solution is 2：（0.5-1）；
（2）By sodium alginate soln and step（1）Obtained carboxymethyl cellulose complexing ferrous solution by volume 1：（0.1-
0.15）It is well mixed, pH is then adjusted to 10-11 with sodium hydroxide and 0.5-1h is stirred, pH is then adjusted to neutrality, in high pressure
Drop is formed under electrostatic field to enter in coagulation bath, will obtain composite gel microsphere after the product washing of gelation reaction；
（3）20-30 weight starch, 5-10 parts by weight hydrogen peroxide and 50-60 parts by weight water are well mixed and stirred after 60-80 DEG C
Reaction 2-4h is mixed, 3-5 parts by weight steps are added after cooling（2）Obtained composite gel microsphere mixing is uniformly dispersed, and obtains cigarette
Overlapping glue.
The mass fraction of the cmc soln is 1-2%.
The mass fraction of the copperas solution is 3-5%.
The mass fraction of the sodium alginate soln is 2-3%.
The coagulation bath is mass fraction 0.5-1% calcium chloride solution.
One or more of the starch in cornstarch, farina, tapioca.
The mass fraction of the hydrogen peroxide is 20-30%.
It is an advantage of the invention that：
First cmc soln and copperas solution are blended by the present invention, carboxymethyl cellulose is filled with ferrous ion
Position is distributed, carboxymethyl cellulose Complexing Iron is obtained, then is well mixed to form composite solution system with sodium alginate soln, and lead to
The oxidation for overregulating oxygen in pH and air uniformly generates ferriferrous oxide nano grain in composite solution system situ
Son, then composite solution system is formed into drop into gelation reaction is carried out in coagulation bath in high-pressure electrostatic off field obtain compound solidifying
Glue microballoon, cigarette overlapping glue is obtained after being well mixed with oxidized starch.On the one hand cigarette overlapping glue produced by the present invention is loaded with
Ferriferrous oxide nano-particle, can effectively adsorb a variety of harmful components in flue gas, on the other hand with extremely strong water suction, water conservation
Ability, can increase the moisture in flue gas, reduce gas drying sense and excitant, improve flue gas mouthfeel and comfort level, both
With excellent adhesive property, there is the auxiliary effect for improving flavor quality of cigarette again, it is practical.
Embodiment
A kind of preparation method of cigarette overlapping glue, comprises the following steps：
（1）Carboxymethyl cellulose is first added to the water stirring and dissolving and obtains cmc soln completely, then to the carboxylic
Copperas solution, and the stirring reaction 0.5h under logical nitrogen protective condition are slowly added dropwise in methocel solution, carboxylic is obtained
Methylcellulose is complexed ferrous solution, and the volume ratio of the cmc soln and copperas solution is 2：0.5；
（2）By sodium alginate soln and step（1）Obtained carboxymethyl cellulose complexing ferrous solution by volume 1：0.1 mixing is equal
It is even, pH is then adjusted to 10 with sodium hydroxide and 0.5h is stirred, pH is then adjusted to neutrality, drop is formed off field in high-pressure electrostatic
Into in coagulation bath, composite gel microsphere will be obtained after the product washing of gelation reaction；
（3）20 weight starch, 5 parts by weight hydrogen peroxide and 50 parts by weight water are well mixed after 60 DEG C of stirring reaction 2h, it is cold
But 3 parts by weight steps are added afterwards（2）Obtained composite gel microsphere mixing is uniformly dispersed, and obtains cigarette overlapping glue.
The mass fraction of the cmc soln is 1%.
The mass fraction of the copperas solution is 3%.
The mass fraction of the sodium alginate soln is 2%.
The coagulation bath is the calcium chloride solution of mass fraction 0.5%.
The starch is cornstarch.
The mass fraction of the hydrogen peroxide is 20%.
Claims (7)
1. a kind of preparation method of cigarette overlapping glue, it is characterised in that comprise the following steps：
（1）Carboxymethyl cellulose is first added to the water stirring and dissolving and obtains cmc soln completely, then to the carboxylic
Copperas solution, and the stirring reaction 0.5-1h under logical nitrogen protective condition are slowly added dropwise in methocel solution, obtains
Carboxymethyl cellulose is complexed ferrous solution, and the volume ratio of the cmc soln and copperas solution is 2：（0.5-1）；
（2）By sodium alginate soln and step（1）Obtained carboxymethyl cellulose complexing ferrous solution by volume 1：（0.1-
0.15）It is well mixed, pH is then adjusted to 10-11 with sodium hydroxide and 0.5-1h is stirred, pH is then adjusted to neutrality, in high pressure
Drop is formed under electrostatic field to enter in coagulation bath, will obtain composite gel microsphere after the product washing of gelation reaction；
（3）20-30 weight starch, 5-10 parts by weight hydrogen peroxide and 50-60 parts by weight water are well mixed and stirred after 60-80 DEG C
Reaction 2-4h is mixed, 3-5 parts by weight steps are added after cooling（2）Obtained composite gel microsphere mixing is uniformly dispersed, and obtains cigarette
Overlapping glue.
2. a kind of preparation method of cigarette overlapping glue according to claim 1, it is characterised in that the carboxymethyl cellulose
The mass fraction of solution is 1-2%.
3. a kind of preparation method of cigarette overlapping glue according to claim 1, it is characterised in that the copperas solution
Mass fraction be 3-5%.
4. a kind of preparation method of cigarette overlapping glue according to claim 1, it is characterised in that the sodium alginate soln
Mass fraction be 2-3%.
5. the preparation method of a kind of cigarette overlapping glue according to claim 1, it is characterised in that the coagulation bath is quality
Fraction 0.5-1% calcium chloride solution.
6. the preparation method of a kind of cigarette overlapping glue according to claim 1, it is characterised in that the starch is selected from corn
One or more in starch, farina, tapioca.
7. a kind of preparation method of cigarette overlapping glue according to claim 1, it is characterised in that the quality of the hydrogen peroxide
Fraction is 20-30%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710511609.9A CN107189714A (en) | 2017-06-29 | 2017-06-29 | A kind of preparation method of cigarette overlapping glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710511609.9A CN107189714A (en) | 2017-06-29 | 2017-06-29 | A kind of preparation method of cigarette overlapping glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189714A true CN107189714A (en) | 2017-09-22 |
Family
ID=59880202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710511609.9A Pending CN107189714A (en) | 2017-06-29 | 2017-06-29 | A kind of preparation method of cigarette overlapping glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107189714A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3914556A1 (en) * | 1988-07-11 | 1990-02-01 | Chemiewerke Agrotex Pirna Veb | Aqueous adhesive mixture for gluing cigarette-paper seams |
| CN103242776A (en) * | 2013-04-27 | 2013-08-14 | 海南必凯水性涂料有限公司 | Modified starch lap adhesive used for high-speed cigarette making machine and preparation method thereof |
| CN103265909A (en) * | 2013-04-28 | 2013-08-28 | 海南必凯水性涂料有限公司 | High-solid content quick-drying modified starch lap adhesive and preparation method thereof |
| CN104941610A (en) * | 2015-06-09 | 2015-09-30 | 西安交通大学 | Preparation and application of magnetic hydrogel loaded with one-dimensional Fe3O4 nanocrystals |
-
2017
- 2017-06-29 CN CN201710511609.9A patent/CN107189714A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3914556A1 (en) * | 1988-07-11 | 1990-02-01 | Chemiewerke Agrotex Pirna Veb | Aqueous adhesive mixture for gluing cigarette-paper seams |
| CN103242776A (en) * | 2013-04-27 | 2013-08-14 | 海南必凯水性涂料有限公司 | Modified starch lap adhesive used for high-speed cigarette making machine and preparation method thereof |
| CN103265909A (en) * | 2013-04-28 | 2013-08-28 | 海南必凯水性涂料有限公司 | High-solid content quick-drying modified starch lap adhesive and preparation method thereof |
| CN104941610A (en) * | 2015-06-09 | 2015-09-30 | 西安交通大学 | Preparation and application of magnetic hydrogel loaded with one-dimensional Fe3O4 nanocrystals |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170922 |
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| RJ01 | Rejection of invention patent application after publication |