CN107189604A - A kind of environment-friendly type building construction finishing paint and preparation method thereof - Google Patents
A kind of environment-friendly type building construction finishing paint and preparation method thereof Download PDFInfo
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- CN107189604A CN107189604A CN201710566518.5A CN201710566518A CN107189604A CN 107189604 A CN107189604 A CN 107189604A CN 201710566518 A CN201710566518 A CN 201710566518A CN 107189604 A CN107189604 A CN 107189604A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment-friendly type building construction finishing paint, belong to technical field of coatings, include the raw material of following parts by weight：35 parts of 30 40 parts of silicone acrylic emulsion, 10 14 parts of waterglass, 58 parts of cocounut oil, 10 12 parts of palm oil, 15 17 parts of aerosil, 46 parts of vermiculite power, 57 parts of titanium dioxide, 46 parts of calcium carbonate, 13 15 parts of brominated epoxy resin, resorcinol double (diphenyl phosphoesters), 13 parts of carboxymethyl cellulose, 9 13 parts of ethylene glycol, 24 parts of water reducer, 12 parts of defoamer, 0.5 1 parts of light stabilizer, 12 parts of coalescents, 26 30 parts of water；The invention also discloses a kind of preparation method of environment-friendly type building construction finishing paint；Environmental pollution of the present invention is small, and adhesive ability is strong, with preferably fire retardancy.
Description
Technical field
The present invention relates to technical field of coatings, specifically, relate to a kind of environment-friendly type building construction finishing paint and its
Preparation method.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating is to be coated in the body surface protected or decorated, and
The continuous film of firm attachment can be formed with coated article, is typically based on resin or oil or emulsion, to add or without face
Material, filler, add corresponding additive, the thick liquid being formulated with organic solvent or water.
Chinese coating circle is more authoritative《Coating process》What one book was defined as：Coating is a kind of material, this material
Material can be coated in object surface with different construction technologies, form adhesion firm, thin with some strength, continuous solid-state
Film.The film common name film so formed, also known as paint film or coating.
At present, the decorative paint used in construction finishing, either water paint or oil paint, are all present
, poor durability relatively low with cement basic layer bonding force, easily cracking, peeling come off；Price is higher to wait not enough.Especially apply
Above-mentioned drawback can be more obvious during the spraying of clear-water concrete basic unit, and fitting dispute also happens occasionally.
In Publication No. CN104628328A patent document, disclose a kind of environment-friendly type building construction finishing paint and
Its preparation method, it constitutes (parts by weight)：30-40% white cements, 20-35% silica flours, 5-10% mucilage of starch, 3-4% silicon
Hydrochlorate, 0.2-1.0% defoamers, 2-3.5% pigment, 3-5% polyurethane；Component is uniformly mixed in proportion, by dry powder
Packaging.During construction, dry powder paint is added water, sprayed after stirring.The invention and cement basal plane energy good bond, coating are not opened
Split, it is difficult for drop-off, waterproof, anti-corrosion, alkaline-resisting, resistance to scrub, fire resisting, nontoxic, tasteless, ornamental strong；But the fire resisting of the invention, resistance to height
Warm ability remains to further raising.
The content of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art to be applied there is provided a kind of environment-friendly type building construction finishing
Material and preparation method thereof, is prepared simply, environmental pollution is small, and adhesive ability is strong, with preferably fire retardancy.
A kind of environment-friendly type building construction finishing paint that the present invention is provided, includes the raw material of following parts by weight：
30-40 parts of silicone acrylic emulsion, 10-14 parts of waterglass, 5-8 parts of cocounut oil, 10-12 parts of palm oil, aerosil 15-
17 parts, 4-6 parts of vermiculite power, 5-7 parts of titanium dioxide, 4-6 parts of calcium carbonate, 13-15 parts of brominated epoxy resin, the double (hexichol of resorcinol
Base phosphate) 3-5 parts, 1-3 parts of carboxymethyl cellulose, 9-13 parts of ethylene glycol, 2-4 parts of water reducer, 1-2 parts of defoamer, light it is stable
0.5-1 parts of agent, 1-2 parts of coalescents, 26-30 parts of water.
Preferably, the mesh number of vermiculite power and titanium dioxide is 300 mesh, calcium carbonate is the precipitated calcium carbonate of the mesh of mesh number 600.
Preferably, water reducer is naphthalenesulfonate formaldehyde condensation compound, condensate of melamine sulfonate and formaldehyde, sulfamic acid
One or two or more kinds of mixtures of salt, aliphatic hydroxyl sulphonate condensation product.
Preferably, defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene Ji Wusi
Alcohol ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, polydimethylsiloxanes
One or two or more kinds of mixtures of alkane.
Preferably, light stabilizer is the mixture of photomask agent and ultra-violet absorber, weight ratio between the two is
1:2, photomask agent is carbon black, titanium oxide, phthalocyanine blue, one or two or more kinds of mixtures of phthalocyanine green.
Preferably, coalescents are alcohol ester 12.
Present invention also offers a kind of preparation method of environment-friendly type building construction finishing paint, comprise the following steps：
(1) various raw materials, are weighed by above-mentioned parts by weight；
(2), by waterglass, cocounut oil, palm oil, brominated epoxy resin, resorcinol double (diphenyl phosphoester), carboxymethyls
Cellulose and water add stirring 8-10min in mixer, stand and silicone acrylic emulsion, ethylene glycol, water reducer, froth breaking are added after 2-4min
After agent, light stabilizer, coalescents stirring 20-30min, aerosil, vermiculite power, titanium dioxide and calcium carbonate are added, is stirred
Mix uniform.
Wherein,
Mixer mixing speed is 400-500r/min in step (2).
A kind of environment-friendly type building construction finishing paint of the present invention and preparation method thereof, is prepared simply, environmental pollution is small, attached
Ability strong, with preferably fire retardancy, specifically have the beneficial effect that：
(1), silicone acrylic emulsion is a kind of high durable, high water-fast, resistant to pollution environment-friendly type building emulsion, waterglass cohesive force
By force, intensity is higher, acid resistance, heat-resist；The addition of cocounut oil and palm oil can make the smell of coating pure and fresh simple and elegant, improve coating
Weatherability, while having the effect of good purification air；
(2), brominated epoxy resin and resorcinol double (diphenyl phosphoesters) have preferably fire retardancy, while very
Environmental protection；Carboxymethyl cellulose have the effects such as thickening, film forming, gluing, water tariff collection, colloid protection, emulsification and suspension；Add second two
Alcohol has antifreeze effect；
(3), water reducer, defoamer, light stabilizer, coalescents can improve the physical property and processing stability of coating,
Improve the service life of coating；Aerosil can improve heat-resisting ability, and vermiculite power and calcium carbonate can improve the resistance to of coating
Mill ability and physical strength；
(4), the mixing of various raw material correspondence ratios of the invention, is effective to ensure that physical property, the insulation of coating
Ability and heat-resisting ability；Preparation method will effectively can be sufficiently mixed between each raw material.
Embodiment
Invention is described in further detail below in conjunction with specific embodiment.
Embodiment 1
A kind of environment-friendly type building construction finishing paint of the present embodiment, includes the raw material of following parts by weight：
30 parts of silicone acrylic emulsion, 10 parts of waterglass, 5 parts of cocounut oil, 10 parts of palm oil, 15 parts of aerosil, vermiculite power 4
Part, 3 parts of 5 parts of titanium dioxide, 4 parts of calcium carbonate, 13 parts of brominated epoxy resin, resorcinol double (diphenyl phosphoesters), carboxymethyl are fine
1 part of dimension element, 9 parts of ethylene glycol, 2 parts of water reducer, 1 part of defoamer, 0.5 part of light stabilizer, 1 part of coalescents, 26 parts of water.
In the present embodiment, the mesh number of vermiculite power and titanium dioxide is 300 mesh, and calcium carbonate is the precipitated calcium carbonate of the mesh of mesh number 600.
In the present embodiment, water reducer is naphthalenesulfonate formaldehyde condensation compound, condensate of melamine sulfonate and formaldehyde, amino sulphur
The mixture of hydrochlorate, aliphatic hydroxyl sulphonate condensation product.
In the present embodiment, defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene season penta
Four alcohol ethers, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, poly dimethyl silicon
The mixture of oxygen alkane.
In the present embodiment, light stabilizer is the mixture of photomask agent and ultra-violet absorber, weight ratio between the two
For 1:2, photomask agent is carbon black, titanium oxide, phthalocyanine blue, the mixture of phthalocyanine green.
In the present embodiment, coalescents are alcohol ester 12.
The present embodiment additionally provides a kind of preparation method of environment-friendly type building construction finishing paint, comprises the following steps：
(1) various raw materials, are weighed by above-mentioned parts by weight；
(2), by waterglass, cocounut oil, palm oil, brominated epoxy resin, resorcinol double (diphenyl phosphoester), carboxymethyls
Cellulose and water add stirring 8min in mixer, stand and silicone acrylic emulsion, ethylene glycol, water reducer, defoamer, light are added after 2min
After stabilizer, coalescents stirring 20min, aerosil, vermiculite power, titanium dioxide and calcium carbonate are added, is stirred i.e.
Can.
Wherein,
Mixer mixing speed is 400r/min in step (2).
Embodiment 2
A kind of environment-friendly type building construction finishing paint of the present embodiment, includes the raw material of following parts by weight：
35 parts of silicone acrylic emulsion, 12 parts of waterglass, 7 parts of cocounut oil, 11 parts of palm oil, 16 parts of aerosil, vermiculite power 5
Part, 4 parts of 6 parts of titanium dioxide, 5 parts of calcium carbonate, 14 parts of brominated epoxy resin, resorcinol double (diphenyl phosphoesters), carboxymethyl are fine
2 parts of dimension element, 11 parts of ethylene glycol, 3 parts of water reducer, 1.5 parts of defoamer, 0.8 part of light stabilizer, 1.5 parts of coalescents, 28 parts of water.
In the present embodiment, the mesh number of vermiculite power and titanium dioxide is 300 mesh, and calcium carbonate is the precipitated calcium carbonate of the mesh of mesh number 600.
In the present embodiment, water reducer is naphthalenesulfonate formaldehyde condensation compound, condensate of melamine sulfonate and formaldehyde, amino sulphur
The mixture of hydrochlorate, aliphatic hydroxyl sulphonate condensation product.
In the present embodiment, defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene season penta
Four alcohol ethers, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, poly dimethyl silicon
The mixture of oxygen alkane.
In the present embodiment, light stabilizer is the mixture of photomask agent and ultra-violet absorber, weight ratio between the two
For 1:2, photomask agent is carbon black, titanium oxide, phthalocyanine blue, the mixture of phthalocyanine green.
In the present embodiment, coalescents are alcohol ester 12.
The present embodiment additionally provides a kind of preparation method of environment-friendly type building construction finishing paint, comprises the following steps：
(1) various raw materials, are weighed by above-mentioned parts by weight；
(2), by waterglass, cocounut oil, palm oil, brominated epoxy resin, resorcinol double (diphenyl phosphoester), carboxymethyls
Cellulose and water add stirring 9min in mixer, stand and silicone acrylic emulsion, ethylene glycol, water reducer, defoamer, light are added after 3min
After stabilizer, coalescents stirring 25min, aerosil, vermiculite power, titanium dioxide and calcium carbonate are added, is stirred i.e.
Can.
Wherein,
Mixer mixing speed is 450r/min in step (2).
Embodiment 3
A kind of environment-friendly type building construction finishing paint of the present embodiment, includes the raw material of following parts by weight：
40 parts of silicone acrylic emulsion, 14 parts of waterglass, 8 parts of cocounut oil, 12 parts of palm oil, 17 parts of aerosil, vermiculite power 6
Part, 5 parts of 7 parts of titanium dioxide, 6 parts of calcium carbonate, 15 parts of brominated epoxy resin, resorcinol double (diphenyl phosphoesters), carboxymethyl are fine
3 parts of dimension element, 13 parts of ethylene glycol, 4 parts of water reducer, 2 parts of defoamer, 1 part of light stabilizer, 2 parts of coalescents, 30 parts of water.
In the present embodiment, the mesh number of vermiculite power and titanium dioxide is 300 mesh, and calcium carbonate is the precipitated calcium carbonate of the mesh of mesh number 600.
In the present embodiment, water reducer is naphthalenesulfonate formaldehyde condensation compound, condensate of melamine sulfonate and formaldehyde, amino sulphur
The mixture of hydrochlorate, aliphatic hydroxyl sulphonate condensation product.
In the present embodiment, defoamer is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene season penta
Four alcohol ethers, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, poly dimethyl silicon
The mixture of oxygen alkane.
In the present embodiment, light stabilizer is the mixture of photomask agent and ultra-violet absorber, weight ratio between the two
For 1:2, photomask agent is carbon black, titanium oxide, phthalocyanine blue, the mixture of phthalocyanine green.
In the present embodiment, coalescents are alcohol ester 12.
The present embodiment additionally provides a kind of preparation method of environment-friendly type building construction finishing paint, comprises the following steps：
(1) various raw materials, are weighed by above-mentioned parts by weight；
(2), by waterglass, cocounut oil, palm oil, brominated epoxy resin, resorcinol double (diphenyl phosphoester), carboxymethyls
Cellulose and water add stirring 10min in mixer, stand added after 4min silicone acrylic emulsion, ethylene glycol, water reducer, defoamer,
After light stabilizer, coalescents stirring 30min, aerosil, vermiculite power, titanium dioxide and calcium carbonate are added, is stirred
.
Wherein,
Mixer mixing speed is 500r/min in step (2).
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (8)
- The finishing paint 1. a kind of environment-friendly type building is constructed, it is characterised in that：Include the raw material of following parts by weight：30-40 parts of silicone acrylic emulsion, 10-14 parts of waterglass, 5-8 parts of cocounut oil, 10-12 parts of palm oil, aerosil 15-17 Part, the double (diphenyl of 4-6 parts of vermiculite power, 5-7 parts of titanium dioxide, 4-6 parts of calcium carbonate, 13-15 parts of brominated epoxy resin, resorcinol Phosphate) 3-5 parts, 1-3 parts of carboxymethyl cellulose, 9-13 parts of ethylene glycol, 2-4 parts of water reducer, 1-2 parts of defoamer, light stabilizer 0.5-1 parts, 1-2 parts of coalescents, 26-30 parts of water.
- The finishing paint 2. environment-friendly type building according to claim 1 is constructed, it is characterised in that：The mesh of vermiculite power and titanium dioxide Number is 300 mesh, and calcium carbonate is the precipitated calcium carbonate of the mesh of mesh number 600.
- The finishing paint 3. environment-friendly type building according to claim 1 is constructed, it is characterised in that：Water reducer is naphthalene sulfonate first Aldehyde condensate, condensate of melamine sulfonate and formaldehyde, sulfamate, one kind of aliphatic hydroxyl sulphonate condensation product or two Plant the mixture of the above.
- The finishing paint 4. environment-friendly type building according to claim 1 is constructed, it is characterised in that：Defoamer be silicone emulsion, The fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxypropylene Glycerin ether and polyoxyethylene polyoxypropylene glycerin ether, one or two or more kinds of mixtures of dimethyl silicone polymer.
- The finishing paint 5. environment-friendly type building according to claim 1 is constructed, it is characterised in that：Light stabilizer is photomask agent With the mixture of ultra-violet absorber, weight ratio between the two is 1:2, photomask agent is carbon black, titanium oxide, phthalocyanine blue, phthalein The green one or two or more kinds of mixtures of cyanines.
- The finishing paint 6. environment-friendly type building according to claim 1 is constructed, it is characterised in that：Coalescents are alcohol ester ten Two.
- The preparation method of finishing paint 7. a kind of environment-friendly type building according to claim 1-6 any one is constructed, it is special Levy and be：Comprise the following steps：(1) various raw materials, are weighed by above-mentioned parts by weight；(2), by waterglass, cocounut oil, palm oil, brominated epoxy resin, resorcinol double (diphenyl phosphoester), carboxymethyl celluloses Element and water add mixer in stirring 8-10min, stand 2-4min after add silicone acrylic emulsion, ethylene glycol, water reducer, defoamer, After light stabilizer, coalescents stirring 20-30min, aerosil, vermiculite power, titanium dioxide and calcium carbonate are added, stirring is equal It is even.
- The preparation method of finishing paint 8. environment-friendly type building according to claim 7 is constructed, it is characterised in that：Step (2) Middle mixer mixing speed is 400-500r/min.
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| CN201710566518.5A CN107189604A (en) | 2017-07-12 | 2017-07-12 | A kind of environment-friendly type building construction finishing paint and preparation method thereof |
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| CN201710566518.5A CN107189604A (en) | 2017-07-12 | 2017-07-12 | A kind of environment-friendly type building construction finishing paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107760137A (en) * | 2017-11-21 | 2018-03-06 | 江苏艾科赛特新材料有限公司 | It is a kind of to improve long-term water-fast and weather resistance roofing waterproof paint |
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| CN111019479A (en) * | 2019-12-20 | 2020-04-17 | 佛山科学技术学院 | Coating and preparation method thereof |
| CN111961376A (en) * | 2020-08-26 | 2020-11-20 | 南京工程学院 | Manufacturing process of weather-resistant environment-friendly water-based paint |
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Cited By (5)
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| CN108299877A (en) * | 2017-09-28 | 2018-07-20 | 马鞍山松鹤信息科技有限公司 | A kind of finishing special environment protection coating and its preparation process |
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| CN111019479A (en) * | 2019-12-20 | 2020-04-17 | 佛山科学技术学院 | Coating and preparation method thereof |
| CN111961376A (en) * | 2020-08-26 | 2020-11-20 | 南京工程学院 | Manufacturing process of weather-resistant environment-friendly water-based paint |
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Application publication date: 20170922 |