CN107189150A - A kind of AMOLED display screens transparent conductive composite films material - Google Patents

A kind of AMOLED display screens transparent conductive composite films material Download PDF

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Publication number
CN107189150A
CN107189150A CN201710446006.5A CN201710446006A CN107189150A CN 107189150 A CN107189150 A CN 107189150A CN 201710446006 A CN201710446006 A CN 201710446006A CN 107189150 A CN107189150 A CN 107189150A
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parts
transparent conductive
conductive composite
composite films
display screens
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CN201710446006.5A
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Chinese (zh)
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白航空
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Hefei Huike Precision Mould Co Ltd
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Hefei Huike Precision Mould Co Ltd
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Priority to CN201710446006.5A priority Critical patent/CN107189150A/en
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    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/14—Homopolymers or copolymers of vinyl fluoride
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    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
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    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/14—Homopolymers or copolymers of vinyl fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/14—Homopolymers or copolymers of vinyl fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/10—Transparent films; Clear coatings; Transparent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of AMOLED display screens transparent conductive composite films material, it is made up of the raw material of following parts by weight：18 22 parts of polyethylene terephthalate, 25 32 parts of microporous polymer matrix, 7 11 parts of graphene powder, 5 12 parts of dispersant, 7 16 parts of ethylenediamine tetra-acetic acid, 10 14 parts of polyaniline, 8 13 parts of isopropanol, 69 parts of plasticizer, 14 18 parts of carboxymethyl cellulose, 7 10 parts of light trigger.The surface film uniformity of transparent conductive composite films material of the present invention is good, and itself and impedance are consistent, improve environmental stability, transparent conductive material before the etch after reflection differences be less than 1.5%, then it is as electrode, and its etched pattern is not obvious, will not influence its display effect, and, its resistance is low, with excellent electrode characteristic, the structure of transparent conductive material, relatively conventional film has anti-reflection effect, can improve transmitance.

Description

A kind of AMOLED display screens transparent conductive composite films material
Technical field
The present invention relates to AMOLED technical fields, and in particular to a kind of AMOLED display screens transparent conductive composite films material.
Background technology
Nesa coating is the important component of many commonly-used photoelectric instrument, in solar cell, touch-screen, You Jifa Extensive use in the devices such as optical diode, liquid crystal display, so that the object as people's extensive concern and research.Existing commercialization Transparent conductive material has significant limitation, does not apply to the development trend of existing photoelectric device, thus research cost is cheap, property Can the excellent and transparent conductive membrane material that can largely prepare as the substitute of ito film there is important meaning for photoelectric field Justice.
The content of the invention
The present invention is intended to provide a kind of AMOLED display screens transparent conductive composite films material.
The present invention provides following technical scheme：
A kind of AMOLED display screens transparent conductive composite films material, it is made up of the raw material of following parts by weight：Gather to benzene 18-22 parts of naphthalate, 25-32 parts of microporous polymer matrix, 7-11 parts of graphene powder, 5-12 parts of dispersant, second 7-16 parts of ethylenediamine tetraacetic acid (EDTA), 10-14 parts of polyaniline, 8-13 parts of isopropanol, 6-9 parts of plasticizer, 14-18 parts of carboxymethyl cellulose, 7-10 parts of light trigger.
The polyethylene terephthalate is the complex of double-deck polyethylene terephthalate.
The microporous polymer matrix is by the one or more in polyolefin, polyamide, polyvinyl fluoride, polytetrafluoroethylene (PTFE) Mix.
The dispersant is selected from polyvinyl pyrrolidone or dodecyl ether sulfate.
The plasticizer uses tributyl 2-acetylcitrate.
The light trigger selects 2,4,6- front three benzoyloxy phenyl phosphinic acid ethyl esters.
The conductive composite film material is prepared using low temperature magnetic sputtering technology.
Compared with prior art, the beneficial effects of the invention are as follows：The surface film of transparent conductive composite films material of the present invention Uniformity is good, and itself and impedance are consistent, improves environmental stability, transparent conductive material before the etch after reflection differences be less than 1.5%, then it is as electrode, and its etched pattern is not obvious, will not influence its display effect, moreover, its resistance is low, with excellent Electrode characteristic, the structure of transparent conductive material, relatively conventional film has anti-reflection effect, can improve transmitance.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
A kind of AMOLED display screens transparent conductive composite films material of embodiment 1, it is made up of the raw material of following parts by weight： 18 parts of polyethylene terephthalate, 25 parts of microporous polymer matrix, 7 parts of graphene powder, 5 parts of dispersant, ethylenediamine tetraacetic 7 parts of acetic acid, 10 parts of polyaniline, 8 parts of isopropanol, 6 parts of plasticizer, 14 parts of carboxymethyl cellulose, 7 parts of light trigger.
The polyethylene terephthalate is the complex of double-deck polyethylene terephthalate.
The microporous polymer matrix is by the one or more in polyolefin, polyamide, polyvinyl fluoride, polytetrafluoroethylene (PTFE) Mix.
The dispersant is selected from polyvinyl pyrrolidone or dodecyl ether sulfate.
The plasticizer uses tributyl 2-acetylcitrate.
The light trigger selects 2,4,6- front three benzoyloxy phenyl phosphinic acid ethyl esters.
The conductive composite film material is prepared using low temperature magnetic sputtering technology.
A kind of AMOLED display screens transparent conductive composite films material of embodiment 2, it is made up of the raw material of following parts by weight： 22 parts of polyethylene terephthalate, 32 parts of microporous polymer matrix, 11 parts of graphene powder, 12 parts of dispersant, ethylenediamine 16 parts of tetraacethyl, 14 parts of polyaniline, 13 parts of isopropanol, 9 parts of plasticizer, 18 parts of carboxymethyl cellulose, 10 parts of light trigger.
The polyethylene terephthalate is the complex of double-deck polyethylene terephthalate.
The microporous polymer matrix is by the one or more in polyolefin, polyamide, polyvinyl fluoride, polytetrafluoroethylene (PTFE) Mix.
The dispersant is selected from polyvinyl pyrrolidone or dodecyl ether sulfate.
The plasticizer uses tributyl 2-acetylcitrate.
The light trigger selects 2,4,6- front three benzoyloxy phenyl phosphinic acid ethyl esters.
The conductive composite film material is prepared using low temperature magnetic sputtering technology.
A kind of AMOLED display screens transparent conductive composite films material of embodiment 3, it is made up of the raw material of following parts by weight： 20 parts of polyethylene terephthalate, 28 parts of microporous polymer matrix, 9 parts of graphene powder, 8 parts of dispersant, ethylenediamine tetraacetic 12 parts of acetic acid, 12 parts of polyaniline, 11 parts of isopropanol, 8 parts of plasticizer, 16 parts of carboxymethyl cellulose, 9 parts of light trigger.
The polyethylene terephthalate is the complex of double-deck polyethylene terephthalate.
The microporous polymer matrix is by the one or more in polyolefin, polyamide, polyvinyl fluoride, polytetrafluoroethylene (PTFE) Mix.
The dispersant is selected from polyvinyl pyrrolidone or dodecyl ether sulfate.
The plasticizer uses tributyl 2-acetylcitrate.
The light trigger selects 2,4,6- front three benzoyloxy phenyl phosphinic acid ethyl esters.
The conductive composite film material is prepared using low temperature magnetic sputtering technology.
It is obvious to a person skilled in the art that the invention is not restricted to the details of the one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than the explanation is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Although not each moreover, it will be appreciated that the present specification is described in terms of embodiments Embodiment is only comprising an independent technical scheme, and this narrating mode of specification is only this area for clarity Technical staff should be using specification as an entirety, and the technical solutions in the various embodiments may also be suitably combined, forms this Art personnel may be appreciated other embodiment.

Claims (7)

1. a kind of AMOLED display screens transparent conductive composite films material, it is characterised in that its by following parts by weight raw material group Into：18-22 parts of polyethylene terephthalate, 25-32 parts of microporous polymer matrix, 7-11 parts of graphene powder, dispersant 5-12 parts, 7-16 parts of ethylenediamine tetra-acetic acid, 10-14 parts of polyaniline, 8-13 parts of isopropanol, 6-9 parts of plasticizer, carboxymethyl cellulose 14-18 parts, 7-10 parts of light trigger.
2. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：It is described poly- Ethylene glycol terephthalate is the complex of double-deck polyethylene terephthalate.
3. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：It is described micro- Pore polymer matrix is mixed by the one or more in polyolefin, polyamide, polyvinyl fluoride, polytetrafluoroethylene (PTFE).
4. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：Described point Powder is selected from polyvinyl pyrrolidone or dodecyl ether sulfate.
5. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：It is described to increase Modeling agent uses tributyl 2-acetylcitrate.
6. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：The light Initiator selects 2,4,6- front three benzoyloxy phenyl phosphinic acid ethyl esters.
7. a kind of AMOLED display screens transparent conductive composite films material according to claim 1, it is characterised in that：It is described to lead Electric composite film material is prepared using low temperature magnetic sputtering technology.
CN201710446006.5A 2017-06-14 2017-06-14 A kind of AMOLED display screens transparent conductive composite films material Pending CN107189150A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466603A (en) * 2013-08-09 2013-12-25 中国科学院苏州纳米技术与纳米仿生研究所 Preparation method of graphene dispersion liquid, and preparation method of graphene film
CN104217788A (en) * 2014-08-26 2014-12-17 南京邮电大学 Silver nanowire based transparent conductive film and production method thereof
CN106046709A (en) * 2016-06-30 2016-10-26 嘉兴市高正高分子材料有限公司 Carbon nanotube modified PET antistatic thin film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466603A (en) * 2013-08-09 2013-12-25 中国科学院苏州纳米技术与纳米仿生研究所 Preparation method of graphene dispersion liquid, and preparation method of graphene film
CN104217788A (en) * 2014-08-26 2014-12-17 南京邮电大学 Silver nanowire based transparent conductive film and production method thereof
CN106046709A (en) * 2016-06-30 2016-10-26 嘉兴市高正高分子材料有限公司 Carbon nanotube modified PET antistatic thin film

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Application publication date: 20170922