CN107189148A - Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof - Google Patents
Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof Download PDFInfo
- Publication number
- CN107189148A CN107189148A CN201710584633.5A CN201710584633A CN107189148A CN 107189148 A CN107189148 A CN 107189148A CN 201710584633 A CN201710584633 A CN 201710584633A CN 107189148 A CN107189148 A CN 107189148A
- Authority
- CN
- China
- Prior art keywords
- hydrogenated nitrile
- temperature resistant
- butadiene rubber
- high temperature
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/262—Alkali metal carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof, belong to field of rubber technology.The colored hydrogenated nitrile-butadiene rubber material of the high temperature resistant of the present invention includes the component of following parts by weight：80~90 parts of hydrogenated nitrile-butadiene rubber rubber, 55~65 parts of reinforcing filler, 2~3.5 parts of silane coupler softens 5~10 parts of plasticizer, 5 parts of zinc oxide, Li2CO310~20 parts of 50GN, 4 parts of age resistor flows 0.8~1.2 part of 1~2 part of dispersant, 9~12 parts of vulcanizing agent, 5~7 parts of crosslinking coagent and dark green.The colored hydrogenated nitrile-butadiene rubber material of the present invention has splendid high temperature resistant, oil resistance, while the characteristics of having low temperature resistant, low compression set.
Description
Technical field
The present invention relates to field of rubber technology, there is splendid high temperature resistant, oil resistance more specifically to a kind of,
The characteristics of having low temperature resistant, low compression set simultaneously hydrogenated nitrile-butadiene rubber material, further relates to a kind of hydrogenated nitrile-butadiene rubber
The preparation method of material.
Background technology
As the innovation that continues to develop of technology manufacturing technology, and energy-conserving and environment-protective consciousness volume constantly strengthen, automobile engine combustion
The effective rate of utilization of material is being improved constantly, and the temperature of engine bin is constantly being lifted, and Long-term service temperature is almost close to 150 DEG C
High temperature.This requires the heat resistance of the part of engine environment also to improve therewith, the rubber zero especially sealed
Part.
Due to the continuous lifting of engine temperature, the heat resistance requirement of inlet manifold seal is consequently increased, by
The hot air aging of 150 DEG C × 168h originally is lifted to 150 DEG C × 1008h and 150 DEG C × 1512h, and this is to hydrogenated butyronitrile rubber
For glue, it is desirable to extremely harsh.
The key characteristic of inlet manifold seal has：1), resistance to elevated temperatures 150 DEG C × 1008h hot air agings and 150
DEG C × 1512h hot air agings after technical requirement it is almost identical, i.e.,：After 1008h agings, 0~+15S of firmness change hore
After A, strength change≤25%, the aging of elongation change≤40%, 1512h, 0~+25S of firmness change horeA, strength change
≤ 30%, elongation change≤50%；2), in SAE.5W30 oil after 150 DEG C × 504h immersions, firmness change -5~+5S
Hore A, strength change≤25%, elongation change≤30%, Volume Changes ± 10%；3), the aging in 150 DEG C of hot-air
Compression set≤25% after 72h；4), low temperature resistant Tg glass transition temperature >=-30 DEG C；This technical standard is for resistance to height
For the fluorubber that temperature, resistance to liquid can be best, all it is not easy to meet, and for hydrogenated nitrile-butadiene rubber, because in molecular chain structure
More or less there are residual double bonds, easily decomposed after long-time aging at high temperature, it is high temperature resistant to hydrogenated nitrile-butadiene rubber material, resistance to
Compression set performance impact is very big, more hardly possible to meet.
Additionally, it is also well known that in addition to fluorubber, other colorful rubber materials are (such as the rubber filled using white filler
Glue material), the heat resistance heat endurance of the elastomeric material carbon black filled compared with black is poor, and property retention is poor, and of the invention
It is required that meeting above-mentioned harsh technical requirements using colored hydrogenated nitrile-butadiene rubber material, its complexity is self-evident.
The content of the invention
1. the invention technical problem to be solved
Heat resistance heat endurance difference and property retention for colored hydrogenated nitrile-butadiene rubber material in the prior art compared with
Poor the problem of, the invention provides colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof, elastomeric material tool
There are splendid high temperature resistant, oil resistance, while having low temperature resistant, low compression set performance characteristics.
2. technical scheme
To reach above-mentioned purpose, the technical scheme that the present invention is provided is：
A kind of colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present invention, includes the component of following parts by weight：
As a further improvement on the present invention, described Li2CO3When -50GN parts by weight are 15 parts, hydrogenated butyronitrile rubber
The parts by weight of glue rubber are 80 parts.
As a further improvement on the present invention, described Li2CO3- 50GN is 50 DEG C of Mooney viscosities 40 of ML (1+4), density
1.41g/cm3, Li2CO3Effective mass degree is 49%~51%.
As a further improvement on the present invention, the reinforcing filler is light reinforcing filler VM56.
As a further improvement on the present invention, the silane coupler is silane coupling A 172.
As a further improvement on the present invention, the softening plasticizer is softening plasticizer TOTM.
As a further improvement on the present invention, the age resistor is the mixture of age resistor ZMMBI and age resistor 445, its
Part by weight relation：Age resistor ZMMBI：Age resistor 445 is 1: 1.
As a further improvement on the present invention, the flowing dispersant is flowing dispersant WB222；Vulcanizing agent is vulcanizing agent
Perkadox 14-40B-GR。
As a further improvement on the present invention, the crosslinking coagent is crosslinking coagent Ricon153D.
A kind of preparation method of the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present invention, comprises the following steps：
(1) masterbatching rubber A preparation：Got the raw materials ready according to above-mentioned formula, by hydrogenated nitrile-butadiene rubber rubber, Li2CO3-50GN、
Age resistor 445 and age resistor ZMMBI are put into banbury simultaneously, and the dumping when temperature reaches 145 DEG C~150 DEG C obtains mother
Refine rubber A；
(2) masterbatching rubber B preparation：The masterbatching rubber A after 24h and sulphur removal agent Perkadox 14-40B-GR will be parked
Outer all raw materials are sent in banbury, obtain masterbatching rubber B；
(3) two sections of masterbatch plus sulphur：Masterbatch B, vulcanizing agent Perkadox 14-40B-GR are put into banbury together
Carry out banburying and add sulphur, the dumping when temperature reaches 105~110 DEG C；
(4) vulcanize：Mould will be inserted after mixing gum forming after two sections plus sulphur, (180~190 DEG C) are carried out on vulcanizer
After-treatment is carried out after × 8min once vulcanization and under the conditions of (180~185 DEG C) × 3h, vulcanizate finished product is obtained.
3. beneficial effect
The technical scheme provided using the present invention, compared with existing known technology, with following remarkable result：
(1) the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the invention, the particular type of used raw material and specific
Collaboration anti-aging effect, age resistor and the Li reached between chemical reaction and age resistor that ratio combination number is produced2CO3-50GN
And the equivalent fruit of the raising heat resistance reached between other components so that obtained colored hydrogenated nitrile-butadiene rubber material tool
For high temperature resistant, resistance to cooling fluidity energy, while having the advantages that low temperature resistant, low compression set；
(2) the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the invention, using 50 DEG C of Mooney viscosities 40 of ML (1+4), density
1.41g/cm3, Li2CO3Effective mass degree is 49%~51% Li2CO3- 50GN, and light reinforcing filler
VM56 and other components interaction, and colored hydrogenated nitrile-butadiene rubber material after vulcanization is improved by the preparation method of the present invention
Expect the Van der Waals force between molecule so that the long-term heat resistance of colored hydrogenated nitrile-butadiene rubber material can obtain larger carry
Height, can almost match in excellence or beauty with the fluorubber under being applied at equal temperature；
(3) preparation method of the invention, preparation method is easy, can cause Li2CO3- 50GN reaches in hydrogenated butyronitrile rubber
Disperse to maximum, and just interacted in mixing with age resistor 445 and age resistor ZMMBI initial stage, improve of the invention make
The heat resistance of the colored hydrogenated nitrile-butadiene rubber material obtained；
(4) vulcanization process that the present invention is used, can effectively volatilize the chemical small molecule structured product remained in vulcanization,
So that obtained colored hydrogenated nitrile-butadiene rubber material just has the performance of superior resistance thermo-oxidative ageing, while having low temperature resistant, low
The advantage of compression set.
Embodiment
To further appreciate that present disclosure, with reference to embodiment, the invention will be further described.
Firstly the need of explanation, the hydrogenated nitrile-butadiene rubber rubber used in embodiment is German Lanxess Corporation's production
Therban2007；VM56 is the light reinforcing filler VM56 that HOFFMANN companies of Germany produce；A172 is Qingdao rising sun sunrise chemical industry
The silane coupling A 172 of Co., Ltd's production；TOTM is the softening softening plasticizer of Guangzhou Zheng Tong Chemical Co., Ltd.s generation
TOTM；Zinc oxide is the indirect process zinc oxide of Zhenjiang plain boiled water Chemical Co., Ltd. production；Age resistor 445 is that Jiangsu China reaches chemical industry collection
The age resistor 445 (No. CAS of Co., Ltd of group production：10081-67-1)；Flowing dispersant is WB222, and supplier opens up to be good
Extra large chemical industry；Age resistor ZMMBI, vulcanizing agent Perkadox 14-40B-GR supplier are upper seascape favour Chemical Co., Ltd.s；
Ricon153D is the crosslinking coagent Ricon153D of Sa Duoma companies production；Li2CO3(graininess, content are 50% carbon to -50GN
Sour lithium) manufacturer be Zhuhai Special Economic Zone Ke Mao rubber-plastics materials Co., Ltd.
Wherein, Li2CO3- 50GN is 50 DEG C of Mooney viscosities 40 of ML (1+4), density 1.41g/cm3, Li2CO3Effective mass hundred
It is 49%~51% to divide than content.
Embodiment 1
A kind of colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment, includes the component of following parts by weight：Hydrogenate fourth
80 parts of nitrile rubber rubber, light 55 parts of reinforcing filler VM56,172 2 parts of silane coupling A, 5 parts of softening plasticizer TOTM,
5 parts of zinc oxide, Li2CO315 parts of -50GN, 4452 parts of age resistor, 2 parts of age resistor ZMMBI, 1.5 parts of flowing dispersant WB222,
5 parts of 12 parts of vulcanizing agent Perkadox 14-40B-GR, crosslinking coagent Ricon153D, 0.8 part of dark green.
A kind of preparation process of the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment is：
(1) masterbatching rubber A preparation：Formula according to the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant is got the raw materials ready, and will hydrogenate fourth
Nitrile rubber rubber, Li2CO3- 50GN, age resistor 445 and age resistor ZMMBI are put into banbury simultaneously, when temperature reaches 145
DEG C when dumping, obtain masterbatching rubber A；
(2) masterbatching rubber B preparation：The masterbatching rubber A after 24h and sulphur removal agent Perkadox 14-40B-GR will be parked
Outer all raw materials are sent in banbury, obtain masterbatching rubber B；
(3) two sections of masterbatch plus sulphur：Masterbatch B, vulcanizing agent Perkadox 14-40B-GR are put into banbury together
Carry out banburying and add sulphur, the dumping when temperature reaches 110 DEG C；
(4) vulcanize：Mould will be inserted after mixing gum forming after two sections plus sulphur, 180 DEG C × 8min is carried out on vulcanizer
Once vulcanization after and carry out after-treatment under the conditions of 183 DEG C × 3h, obtain vulcanizate finished product.
Comparative example 1
As different from Example 1, it is added without Li in the comparative example2CO3- 50GN, finally gives high temperature resistant colour hydrogenation fourth
Nitrile rubber material.
The performance of high temperature resistant colour hydrogenated nitrile-butadiene rubber material is as shown in table 1 made from embodiment 1 and comparative example 1：
The embodiment 1 of table 1 and the colored hydrogenated nitrile-butadiene rubber testing of materials performance of the high temperature resistant of comparative example 1
Embodiments of the invention 1 add Li it can be seen from the test result of table 12CO3After -50GN, colored hydrogenated butyronitrile
The heat resistance of elastomeric material is significantly improved, and every test result meets the requirement of technical indicator, and technical requirement it
On.This be inventor by testing and groping for a long time, obtained the technical scheme of the embodiment of the present invention 1, wherein ML (1+4)
50 DEG C of Mooney viscosities 40, density 1.41g/cm3, Li2CO3Effective mass degree is 49%~51% Li2CO3- 50GN,
Improve the Van der Waals force between colored hydrogenated nitrile-butadiene rubber material molecule after vulcanization so that colored hydrogenated nitrile-butadiene rubber material
Long-term heat resistance can be greatly improved.
Embodiment 2
A kind of colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment, includes the component of following parts by weight：Hydrogenate fourth
90 parts of nitrile rubber rubber, light 65 parts of reinforcing filler VM56,172 3.5 parts of silane coupling A, 10 parts of TOTM, zinc oxide 5
Part, Li2CO320 parts of -50GN, 445 2 parts of age resistor, 2 parts of age resistor ZMMBI, 2 parts of flowing dispersant WB222, vulcanizing agent
7 parts of 9 parts of Perkadox 14-40B-GR, crosslinking coagent Ricon153D, 1 part of dark green.
A kind of preparation process of the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment is：
(1) masterbatching rubber A preparation：Formula according to the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant is got the raw materials ready, by rubber,
Li2CO3- 50GN, age resistor 445 and age resistor ZMMBI are put into banbury simultaneously, and the dumping when temperature reaches 148 DEG C is obtained
To masterbatching rubber A；
(2) masterbatching rubber B preparation：The masterbatching rubber A after 24h and sulphur removal agent Perkadox 14-40B-GR will be parked
Outer all raw materials are sent in banbury, obtain masterbatching rubber B；
(3) two sections of masterbatch plus sulphur：Masterbatch B, vulcanizing agent Perkadox 14-40B-GR are put into banbury together
Carry out banburying and add sulphur, the dumping when temperature reaches 105 DEG C；
(4) vulcanize：Mould will be inserted after mixing gum forming after two sections plus sulphur, 185 DEG C × 8min is carried out on vulcanizer
Once vulcanization after and carry out after-treatment under the conditions of 180 DEG C × 3h, obtain vulcanizate finished product.
The property that the performance of high temperature resistant colour hydrogenated nitrile-butadiene rubber material made from the present embodiment and the table 1 of embodiment 1 are listed
Energy parameter similar, is entirely capable of meeting the requirement of technical indicator.
Embodiment 3
A kind of colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment, includes the component of following parts by weight：Hydrogenate fourth
85 parts of nitrile rubber rubber, light 60 parts of reinforcing filler VM56,172 3 parts of silane coupling A, 8 parts of softening plasticizer TOTM,
5 parts of zinc oxide, Li2CO310 parts of -50GN, 445 2 parts of age resistor, 2 parts of age resistor ZMMBI, 1 part of flowing dispersant WB222,
6 parts of 10 parts of vulcanizing agent Perkadox 14-40B-GR, Ricon153D, 1.2 parts of dark green.
A kind of preparation process of the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant of the present embodiment is：
(1) masterbatching rubber A preparation：Formula according to the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant is got the raw materials ready, and will hydrogenate fourth
Nitrile rubber rubber, Li2CO3- 50GN, age resistor 445 and age resistor ZMMBI are put into banbury simultaneously, when temperature reaches 150
DEG C when dumping, obtain masterbatching rubber A；
(2) masterbatching rubber B preparation：The masterbatching rubber A after 24h and sulphur removal agent Perkadox 14-40B-GR will be parked
Outer all raw materials are sent in banbury, obtain masterbatching rubber B；
(3) two sections of masterbatch plus sulphur：Masterbatch B, vulcanizing agent Perkadox 14-40B-GR are put into banbury together
Carry out banburying and add sulphur, the dumping when temperature reaches 107 DEG C；
(4) vulcanize：Mould will be inserted after mixing gum forming after two sections plus sulphur, 190 DEG C × 8min is carried out on vulcanizer
Once vulcanization after and carry out after-treatment under the conditions of 185 DEG C × 3h, obtain vulcanizate finished product.
The property that the performance of high temperature resistant colour hydrogenated nitrile-butadiene rubber material made from the present embodiment and the table 1 of embodiment 1 are listed
Energy parameter similar, is entirely capable of meeting the requirement of technical indicator.
Claims (10)
1. the colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant, it is characterised in that include the component of following parts by weight：
2. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 1, it is characterised in that described Li2CO3-
When 50GN parts by weight are 15 parts, the parts by weight of hydrogenated nitrile-butadiene rubber rubber are 80 parts.
3. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 2, it is characterised in that described Li2CO3-
50GN is 50 DEG C of Mooney viscosities 40 of ML (1+4), density 1.41g/cm3, Li2CO3Effective mass degree be 49%~
51%.
4. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 3, it is characterised in that the reinforcing filler
For light reinforcing filler VM56.
5. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 4, it is characterised in that the silane coupler
For silane coupling A 172.
6. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 5, it is characterised in that the softening plasticizer
For softening plasticizer TOTM.
7. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 6, it is characterised in that the age resistor is anti-
Old agent ZMMBI and age resistor 445 mixture, its part by weight relation：Age resistor ZMMBI: age resistor 445 is 1: 1.
8. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 7, it is characterised in that the flowing dispersant
For flowing dispersant WB222；Vulcanizing agent is vulcanizing agent Perkadox 14-40B-GR.
9. the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant according to claim 8, it is characterised in that the crosslinking coagent is
Crosslinking coagent Ricon153D.
10. a kind of preparation method of the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant described in claim 9, its step includes：
(1) masterbatching rubber A preparation：Formula according to the colored hydrogenated nitrile-butadiene rubber material of high temperature resistant is got the raw materials ready, by hydrogenated butyronitrile rubber
Glue rubber, Li2CO3- 50GN, age resistor 445 and age resistor ZMMBI are put into banbury simultaneously, when temperature reaches 145~150
DEG C when dumping, obtain masterbatching rubber A；
(2) masterbatching rubber B preparation：It will park outside the masterbatching rubber A after 24h and sulphur removal agent Perkadox 14-40B-GR
All raw materials are sent in banbury, obtain masterbatching rubber B；
(3) two sections of masterbatch plus sulphur：Masterbatch B, vulcanizing agent Perkadox 14-40B-GR are put into banbury together and carried out
Banburying adds sulphur, the dumping when temperature reaches 105~110 DEG C；
(4) vulcanize：Mould will be inserted after mixing gum forming after two sections plus sulphur, carried out on vulcanizer (180~190 DEG C) ×
After-treatment is carried out after 8min once vulcanization and under the conditions of (180~185 DEG C) × 3h, vulcanizate finished product is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584633.5A CN107189148A (en) | 2017-07-17 | 2017-07-17 | Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584633.5A CN107189148A (en) | 2017-07-17 | 2017-07-17 | Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189148A true CN107189148A (en) | 2017-09-22 |
Family
ID=59882267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710584633.5A Pending CN107189148A (en) | 2017-07-17 | 2017-07-17 | Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107189148A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359152A (en) * | 2018-02-11 | 2018-08-03 | 南京金三力高分子科技有限公司 | A kind of cooling system high temperature resistant hydrogenated nitrile-butadiene rubber material and preparation method thereof |
| CN108641151A (en) * | 2018-05-07 | 2018-10-12 | 广东贝洛新材料科技有限公司 | A kind of low temperature resistant hydraulic pressure resistant oil hydrogenated nitrile-butadiene rubber sizing material of high abrasion and preparation method thereof |
| CN110591191A (en) * | 2019-10-17 | 2019-12-20 | 宁波市北仑优联特橡塑制品有限公司 | Hydrogenated nitrile rubber for automobile sealing ring and preparation method thereof |
| CN110862594A (en) * | 2019-11-29 | 2020-03-06 | 南京金三力高分子科技有限公司 | High-temperature CH4 diesel engine oil medium-low pressure variable hydrogenated nitrile rubber material and preparation method thereof |
| CN114015133A (en) * | 2021-11-15 | 2022-02-08 | 启东市亿方密封科技有限公司 | Ultrahigh-performance environment-friendly hydrogenated nitrile-butadiene rubber and preparation method thereof |
| CN115322464A (en) * | 2022-06-29 | 2022-11-11 | 安徽亚新科密封技术有限公司 | Low-temperature-resistant low-compression-set rubber material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2581407A1 (en) * | 2011-10-11 | 2013-04-17 | Lanxess Deutschland GmbH | Vulcanisable compounds on the basis of nitrile rubbers containing epoxy groups |
| CN104194100A (en) * | 2014-08-26 | 2014-12-10 | 安徽蓝德集团股份有限公司 | High-performance rubber material for cable sheaths |
| CN105602056A (en) * | 2016-01-15 | 2016-05-25 | 广东杜巴新材料科技有限公司 | Heat-resistant agent containing pre-dispersed masterbatch for hydrogenated nitrile butadiene rubber and preparation method of heat-resistant agent containing pre-dispersed masterbatch |
-
2017
- 2017-07-17 CN CN201710584633.5A patent/CN107189148A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2581407A1 (en) * | 2011-10-11 | 2013-04-17 | Lanxess Deutschland GmbH | Vulcanisable compounds on the basis of nitrile rubbers containing epoxy groups |
| CN104194100A (en) * | 2014-08-26 | 2014-12-10 | 安徽蓝德集团股份有限公司 | High-performance rubber material for cable sheaths |
| CN105602056A (en) * | 2016-01-15 | 2016-05-25 | 广东杜巴新材料科技有限公司 | Heat-resistant agent containing pre-dispersed masterbatch for hydrogenated nitrile butadiene rubber and preparation method of heat-resistant agent containing pre-dispersed masterbatch |
Non-Patent Citations (1)
| Title |
|---|
| 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108359152A (en) * | 2018-02-11 | 2018-08-03 | 南京金三力高分子科技有限公司 | A kind of cooling system high temperature resistant hydrogenated nitrile-butadiene rubber material and preparation method thereof |
| CN108641151A (en) * | 2018-05-07 | 2018-10-12 | 广东贝洛新材料科技有限公司 | A kind of low temperature resistant hydraulic pressure resistant oil hydrogenated nitrile-butadiene rubber sizing material of high abrasion and preparation method thereof |
| CN110591191A (en) * | 2019-10-17 | 2019-12-20 | 宁波市北仑优联特橡塑制品有限公司 | Hydrogenated nitrile rubber for automobile sealing ring and preparation method thereof |
| CN110862594A (en) * | 2019-11-29 | 2020-03-06 | 南京金三力高分子科技有限公司 | High-temperature CH4 diesel engine oil medium-low pressure variable hydrogenated nitrile rubber material and preparation method thereof |
| CN110862594B (en) * | 2019-11-29 | 2022-04-15 | 南京金三力高分子科技有限公司 | High-temperature CH4 diesel engine oil medium-low pressure variable hydrogenated nitrile rubber material and preparation method thereof |
| CN114015133A (en) * | 2021-11-15 | 2022-02-08 | 启东市亿方密封科技有限公司 | Ultrahigh-performance environment-friendly hydrogenated nitrile-butadiene rubber and preparation method thereof |
| CN115322464A (en) * | 2022-06-29 | 2022-11-11 | 安徽亚新科密封技术有限公司 | Low-temperature-resistant low-compression-set rubber material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107189148A (en) | Colored hydrogenated nitrile-butadiene rubber material of a kind of high temperature resistant and preparation method thereof | |
| CN105111598A (en) | Automobile rubber sealing strip and preparation method thereof | |
| CN103087432B (en) | Flame-retardant and oil-resistant marine rubber material and molding preparation method thereof | |
| CN103408948B (en) | A kind of rubber combination and application thereof | |
| CN104672624B (en) | Rubber composition, V belt wrapper glue with adoption of rubber composition and preparation method of V belt wrapper glue | |
| CN105400088B (en) | A kind of ethylene propylene diene rubber and neoprene co-vulcanization material and preparation method thereof | |
| CN108178892B (en) | High-strength low-pressure variable fluororubber material and preparation method thereof | |
| CN106589963A (en) | High-temperature-resistant silicone rubber gasket and preparation process thereof | |
| CN103435917A (en) | High-hardness color ethylene-propylene-diene monomer (EPDM) suitable for microwave vulcanizing and preparation method thereof | |
| CN111057317A (en) | Oil-resistant radiator water pipe material vulcanized by peroxide system and preparation method thereof | |
| CN102702628B (en) | Method for producing rubber sealing plug composition for aluminum electrolytic capacitor by using butyl rubber as main material | |
| CN105729971A (en) | Preparation method of foaming rubber metal composite sealing plate | |
| CN105778174A (en) | Cold resistant rubber for vehicles | |
| CN104710693B (en) | Low-temperature-resistant door/window sealing strip and preparation method thereof | |
| CN102532910B (en) | Double-component room-temperature vulcanized silicon rubber having adhesiveness and acidosis resistance and preparation method | |
| CN105670146B (en) | A kind of transmission belt high-performance curing bag | |
| CN104910532B (en) | A kind of high rigidity ethylene propylene diene monomer (EPDM) material and preparation method thereof | |
| CN101332681A (en) | Preparation method of heat-proof, abrasion-proof cementing plug | |
| CN115490969A (en) | Production and manufacturing method of ultrahigh-voltage insulation ethylene propylene diene monomer | |
| CN108641127A (en) | A kind of silicon substrate heat resistant rubber and preparation method thereof for gear box suspension | |
| CN113604055B (en) | Oil-resistant rubber material for engine sealing gasket and preparation method thereof | |
| CN104927114A (en) | Automobile chassis bushing rubber material and preparing method thereof | |
| CN104829939A (en) | FAM-B-methanol-gasoline-resistant low-temperature-resistant low-compressive-deformation ethylene-acrylate rubber material and preparation method thereof | |
| CN104072822A (en) | Elastic rubber part for chair back connection and processing technology | |
| CN102399527A (en) | Room temperature curing lamp adhesive and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170922 |
|
| RJ01 | Rejection of invention patent application after publication |