CN107177429A - It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology - Google Patents

It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology Download PDF

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Publication number
CN107177429A
CN107177429A CN201610138389.5A CN201610138389A CN107177429A CN 107177429 A CN107177429 A CN 107177429A CN 201610138389 A CN201610138389 A CN 201610138389A CN 107177429 A CN107177429 A CN 107177429A
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China
Prior art keywords
parts
easy
carry
laundry sheet
surfactant
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Pending
Application number
CN201610138389.5A
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Chinese (zh)
Inventor
王志良
杨燕峰
韩军涛
徐永刚
苏华
杨坤
吕嘉
张振华
平晓鹏
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North China Pharmaceutical Qinhuangdao Co Ltd
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Priority to CN201610138389.5A priority Critical patent/CN107177429A/en
Publication of CN107177429A publication Critical patent/CN107177429A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609Protease or amylase in solid compositions only

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention provides it is a kind of be easy to carry, laundry sheet easy to use and its preparation technology, be composed of the following components in parts by weight:0.5-18 parts of nonionic surfactant, 0.1-18 parts of anion surfactant, 0.1-0.5 parts of caustic soda, 0.1-15 parts of effervescent agent, 0.1-2 parts of sodium citrate, 0.01-0.03 parts of defoamer, 0.1-0.3 parts of brightening agent .1-0.3 parts of proteinase-10,0.01-0.1 parts of softener, 0.001-0.2 parts of essence, 5-50 parts of purified water, raw material is measured by step S1, according to following parts by weight;S2, by spray drying process and the attached polymer molding method granulate mixture is made in filler, gas-producing disintegrant and highly enriched liquid detergent;S3, by the particle being made send tabletting machine;S4, the tabletting finished product being made send to quality inspection is examined, qualified rear packaging and storage is made, carry easy to use, preparation technology simple possible.

Description

It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology
Technical field
The present invention relates to daily living article preparing technical field, more particularly to a kind of it be easy to carry, easy to use wash Garment piece and its preparation technology.
Background technology
The liquid detergent of main flow is usually liquid washing products currently on the market.One is that liquid washing products mostly have carrying Inconvenience, a variety of shortcomings that usage amount is bad to be calculated, dissolution velocity is slow, freight is high etc., to packaging, storage and transport and Consumer is using bringing a variety of inconvenience.Two be as the improvement of people's living standards, the requirement to cleaning product is not only limited to In common function of washing clothes, and need special purpose detergent various in style this just promotes it is sought that consuming low, small investment, using The cleaning product and technique of many advantages such as convenient.
Therefore a kind of carrying instant effervesce laundry sheet easy to use is just produced, and this method, which is used for reference, absorbs spray drying process production The features such as less " hollow " the type particle of product density, good fluidity, prevented from caking, outward appearance and good solubility and the attached polymer molding method Equipment volume is small, operating flexibility big, low power consumption and other advantages.Using brand-new medicine preparation tablet forming technique tabletting and make May.
The content of the invention
The invention provides it is a kind of be easy to carry, laundry sheet easy to use and its preparation technology, the technology of preparing can make Liquid detergent not only makes various chemical substances mutually promote, and mutually makes up, and makes washing clean effect even more ideal, can also substantially reduce Production cost, solve transport and bring trouble, make consumer more facilitate and save pay.
In order to solve the above technical problems, the invention provides it is a kind of be easy to carry, laundry sheet easy to use, by following heavy Measure the composition composition of part:0.5-18 parts of nonionic surfactant, 0.1-18 parts of anion surfactant, caustic soda 0.1-0.5 Part, 0.1-15 parts of effervescent agent, 0.1-2 parts of sodium citrate, 0.01-0.03 parts of defoamer, 0.1-0.3 parts of brightening agent, protease 0.1-0.3 parts, 0.01-0.1 parts of softener, 0.001-0.2 parts of essence, 5-50 parts of purified water, 0.1-10 parts of filler, effervesce collapse Solve 0.1-15 parts of agent.
As the preferred technical scheme of the present invention, it is composed of the following components in parts by weight:Non-ionic surface is lived Property 12 parts of agent, 12 parts of anion surfactant, 0.5 part of caustic soda, 12 parts of effervescent agent, 1.5 parts of sodium citrate, defoamer 0.03 Part, 0.2 part of brightening agent .2 parts of proteinase-10,0.07 part of softener, 1.5 parts of essence, 40 parts of purified water, 9 parts of filler, effervesce collapse Solve 11 parts of agent.
As the preferred technical scheme of the present invention, described nonionic surfactant includes following component:Alkyl phenol It is APEO, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, the ethylene oxide adduct of polypropylene glycol, poly- Any one in the ionic surfactant of oxyethylation, sorbitan ester, sucrose ester, alkylolamides type or one Plant the combination of the above.
As the preferred technical scheme of the present invention, described anion surfactant includes following component:Alkane Base benzene sulfonate, alpha-alkene sulfonate, alkylsulfonate, alpha-sulfo monocarboxylate, aliphatic acid sulfoalkyl ester, succinate sulfonic acid Any one in salt, alkylnaphthalene sulfonate, petroleum sulfonate, lignosulfonates, alkyl glyceryl ether sulfonate etc. or one kind Combination above.
It is of the present invention it is a kind of be easy to carry, laundry sheet preparation technology easy to use, comprise the following steps:S1, press Raw material is measured according to following parts by weight:12 parts of nonionic surfactant, 12 parts of anion surfactant, 0.5 part of caustic soda, bubble Rise 12 parts of agent, 1.5 parts of sodium citrate, 0.03 part of defoamer, 0.2 part of brightening agent .2 parts of proteinase-10,0.07 part of softener, essence 1.5 parts, 40 parts of purified water, 9 parts of filler, 11 parts of gas-producing disintegrant;
S2, by spray drying process and the attached polymer molding method particle is made in filler, disintegrant and highly enriched liquid detergent Mixture, its detailed process is as follows:
Be involved in after highly enriched liquid detergent is measured by metering device it is strong it is ring-like breathe heavily in stream, liquid can by mounted in The nozzle on comminutor top spray into the filler being well mixed in fluid bed, fluid bed, the solid particle of disintegrant surface because The dispersion of the liquid of atomization or the liquid of diffusion and bedewed by uniformity, with incorporation liquid increasing number, wet granular Flocked together in stream is breathed heavily, its size gradually increases, when bottom discharge is passed through in path of the condensate along a spatially spiral line Drying ageing system is dried in the way of mouth, and the particle of certain particle size is obtained finally by the screen cloth of certain amount;
S3, by the step S2 particles being made send tabletting machine;
S4, the tabletting finished product that step S3 is made sent quality inspection examine, qualified rear packaging and storage.
The one or more technical schemes provided in the embodiment of the present application, have at least the following technical effects or advantages:
The technology of preparing can make liquid detergent various chemical substances is mutually promoted, and mutually make up, and make washing clean effect more For ideal, it can also substantially reduce production cost, solution transport and the trouble brought, consumer is more facilitated and save branch Go out.
Embodiment
Embodiment one
The invention provides it is a kind of be easy to carry, laundry sheet easy to use and its preparation technology, the technology of preparing can make laundry Liquid not only makes various chemical substances mutually promote, and mutually makes up, and makes washing clean effect even more ideal, can also substantially reduce production Cost, solve transport and bring trouble, make consumer more facilitate and save pay.
A kind of described in the present embodiment is easy to carry, laundry sheet easy to use, is composed of the following components in parts by weight:It is non- 0.5-18 parts of ionic surface active agent, 0.1-18 parts of anion surfactant, 0.1-0.5 parts of caustic soda, 0.1-15 parts of effervescent agent, 0.1-2 parts of sodium citrate, 0.01-0.03 parts of defoamer, 0.1-0.3 parts of brightening agent .1-0.3 parts of proteinase-10, softener 0.01- 0.1 part, 0.001-0.2 parts of essence, 5-50 parts of purified water, 0.1-10 parts of filler, 0.1-15 parts of gas-producing disintegrant.
Wherein, in the present embodiment, it is composed of the following components in parts by weight:12 parts of nonionic surfactant, it is cloudy from Sub- 12 parts of surfactant, 0.5 part of caustic soda, 12 parts of effervescent agent, 1.5 parts of sodium citrate, 0.03 part of defoamer, 0.2 part of brightening agent, .2 parts of proteinase-10,0.07 part of softener, 1.5 parts of essence, 40 parts of purified water, 9 parts of filler, 11 parts of gas-producing disintegrant.
Wherein, in the present embodiment, described nonionic surfactant includes following component:APES, height Carbon fatty alcohol APEO, polyoxyethylene carboxylate, the ethylene oxide adduct of polypropylene glycol, polyoxyethylated ion Any one in type surfactant, sorbitan ester, sucrose ester, alkylolamides type or more than one combination.
Wherein, in the present embodiment, described anion surfactant includes following component:Alkylbenzenesulfonate, α- Alkene sulfonate, alkylsulfonate, alpha-sulfo monocarboxylate, aliphatic acid sulfoalkyl ester, sulphosuccinates, alkyl naphthalene sulfonic acid Any one in salt, petroleum sulfonate, lignosulfonates, alkyl glyceryl ether sulfonate etc. or more than one combination.
A kind of described in the present embodiment is easy to carry, laundry sheet preparation technology easy to use, comprises the following steps:S1、 Raw material is measured according to following parts by weight:12 parts of nonionic surfactant, 12 parts of anion surfactant, 0.5 part of caustic soda, 12 parts of effervescent agent, 1.5 parts of sodium citrate, 0.03 part of defoamer, 0.2 part of brightening agent .2 parts of proteinase-10,0.07 part of softener, perfume 1.5 parts of essence, 40 parts of purified water, 9 parts of filler, 11 parts of gas-producing disintegrant;
S2, by spray drying process and the attached polymer molding method particle is made in filler, disintegrant and highly enriched liquid detergent Mixture, its detailed process is as follows:
Be involved in after highly enriched liquid detergent is measured by metering device it is strong it is ring-like breathe heavily in stream, liquid can by mounted in The nozzle on comminutor top spray into the filler being well mixed in fluid bed, fluid bed, the solid particle of disintegrant surface because The dispersion of the liquid of atomization or the liquid of diffusion and bedewed by uniformity, with incorporation liquid increasing number, wet granular Flocked together in stream is breathed heavily, its size gradually increases, when bottom discharge is passed through in path of the condensate along a spatially spiral line Drying ageing system is dried in the way of mouth, and the particle of certain particle size is obtained finally by the screen cloth of certain amount;
S3, by the step S2 particles being made send tabletting machine;
S4, the tabletting finished product that step S3 is made sent quality inspection examine, qualified rear packaging and storage.
The mechanism of action of each composition is as follows in the present embodiment:
Nonionic surfactant:Because nonionic surfactant has the non-ionizing feature in water, determine it in water Neutralizing in organic solvent has preferable dissolubility, and stability is high in the solution, is difficult by strong electrolyte inorganic salts and sour, alkali Influence.And it is good with other types surfactant compatibility, nonionic surfactant has good resistance to hard water ability, there is low The characteristics of bubble property.Also there is the multiple performances such as scattered, emulsification, foam, wetting, solubilising;
Anion surfactant:It is divided into carboxylate, sulfuric acid, sulfonate and the major class of phosphate ester salt four, with preferably going The characteristic such as dirty, foaming, scattered, emulsification, wetting.It is widely used as detergent, foaming agent, wetting agent, emulsifying agent and dispersant;
Caustic soda:Adjust pH value;
Sodium citrate:Sodium tripolyphosphate can form soluble complexing in weakly alkaline substitute with the metal ion such as calcium, magnesium, iron Thing;
Defoamer:Defoam;
Protease:Remove bloodstain.
Filler:Excipients during tabletting;
Gas-producing disintegrant:Quick dissolution;
The above described is only a preferred embodiment of the present invention, not making any formal limitation to the present invention, although this Invention is disclosed above with preferred embodiment, but is not limited to the present invention, any those skilled in the art, Do not depart from the range of technical solution of the present invention, when the technology contents using the disclosure above make a little change or are modified to equivalent The equivalent embodiment of change, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention is to the above Any simple modification, equivalent variations and modification that embodiment is made, in the range of still falling within technical solution of the present invention.
The invention provides it is a kind of be easy to carry, laundry sheet easy to use and its preparation technology, by the composition of following parts by weight Composition:0.5-18 parts of nonionic surfactant, 0.1-18 parts of anion surfactant, 0.1-0.5 parts of caustic soda, effervescent agent 0.1-15 parts, it is 0.1-2 parts of sodium citrate, 0.01-0.03 parts of defoamer, 0.1-0.3 parts of brightening agent .1-0.3 parts of proteinase-10, soft Along 0.01-0.1 parts of agent, 0.001-0.2 parts of essence, 5-50 parts of purified water, original is measured by step S1, according to following parts by weight Material;S2, filler, gas-producing disintegrant and highly enriched liquid detergent be made up of spray drying process and the attached polymer molding method Grain mixture;S3, by the particle being made send tabletting machine;S4, the tabletting finished product being made sent quality inspection examine, it is qualified after pack Storage is made, and carries easy to use, preparation technology simple possible.

Claims (7)

1. it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that:It is composed of the following components in parts by weight:Nonionic 0.5-18 parts of surfactant, 0.1-18 parts of anion surfactant, 0.1-0.5 parts of caustic soda, 0.1-2 parts of sodium citrate, disappears 0.01-0.03 parts of infusion, 0.1-0.3 parts of brightening agent .1-0.3 parts of proteinase-10,0.01-0.1 parts of softener, essence 0.001- 0.2 part, 5-50 parts of purified water, 0.1-10 parts of filler, 0.1-15 parts of gas-producing disintegrant.
2. it is according to claim 1 it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that by following weight The composition composition of part:12 parts of nonionic surfactant, 12 parts of anion surfactant, 0.5 part of caustic soda, 12 parts of effervescent agent, It is 1.5 parts of sodium citrate, 0.03 part of defoamer, 0.2 part of brightening agent .2 parts of proteinase-10,0.07 part of softener, 1.5 parts of essence, pure Change 40 parts of water, 9 parts of filler, 11 parts of gas-producing disintegrant.
3. it is according to claim 1 it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that it is described it is non-from Sub- surfactant includes following component:APES, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid polyethenoxy Ester, the ethylene oxide adduct of polypropylene glycol, polyoxyethylated ionic surfactant, sorbitan ester, sucrose ester, Any one in alkylolamides type or more than one combination.
4. it is according to claim 1 it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that it is described it is cloudy from Sub- surfactant includes following component:Alkylbenzenesulfonate, alpha-alkene sulfonate, alkylsulfonate, alpha-sulfo monocarboxylate, Aliphatic acid sulfoalkyl ester, sulphosuccinates, alkylnaphthalene sulfonate, petroleum sulfonate, lignosulfonates, alkyl glycerylether Any one in sulfonate etc. or more than one combination.
5. it is according to claim 1 it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that described filling Agent includes following component:Any one in microcrystalline cellulose (MCC), starch, dextrin, amylum pregelatinisatum, inorganic salts or one kind Combination above.
6. it is according to claim 1 it is a kind of be easy to carry, laundry sheet easy to use, it is characterised in that described effervesce Disintegrant includes following component:Sodium acid carbonate and citric acid, carboxyrnethyl starch sodium, low-substituted hydroxypropyl cellulose, cross-linked carboxymethyl Any one in sodium cellulosate or more than one combination.
7. it is a kind of be easy to carry, laundry sheet preparation technology easy to use, it is characterised in that comprise the following steps:
S1, according to following parts by weight measure raw material:12 parts of nonionic surfactant, 12 parts of anion surfactant, burning 0.5 part of alkali, 12 parts of effervescent agent, 1.5 parts of sodium citrate, 0.03 part of defoamer, 0.2 part of brightening agent .2 parts of proteinase-10, softener 0.07 part, 1.5 parts of essence, 40 parts of purified water, 9 parts of filler, 11 parts of gas-producing disintegrant;
S2, the filler of corresponding amount, disintegrant in corresponding ratio passed through into spray drying side after mixing with highly enriched liquid detergent Granulate mixture is made in method and the attached polymer molding method, and its detailed process is as follows:
Be involved in after highly enriched liquid detergent is measured by metering device it is strong it is ring-like breathe heavily in stream, liquid can by mounted in The nozzle on comminutor top spray into the filler being well mixed in fluid bed, fluid bed, the solid particle of disintegrant surface because The dispersion of the liquid of atomization or the liquid of diffusion and bedewed by uniformity, with incorporation liquid increasing number, wet granular Flocked together in stream is breathed heavily, its size gradually increases, when bottom discharge is passed through in path of the condensate along a spatially spiral line Drying ageing system is dried in the way of mouth, and the particle of certain particle size is obtained finally by the screen cloth of certain amount;
S3, by the step S2 particles being made send tabletting machine;
S4, the tabletting finished product that step S3 is made sent quality inspection examine, qualified rear packaging and storage.
CN201610138389.5A 2016-03-11 2016-03-11 It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology Pending CN107177429A (en)

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CN201610138389.5A CN107177429A (en) 2016-03-11 2016-03-11 It is a kind of be easy to carry, laundry sheet easy to use and its preparation technology

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285834A (en) * 2017-12-28 2018-07-17 广州立白企业集团有限公司 Detergent composition
CN108865483A (en) * 2018-06-11 2018-11-23 广州市欣婷生物科技有限公司 A kind of laundry sheet and preparation method thereof

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Publication number Priority date Publication date Assignee Title
WO1999006524A1 (en) * 1997-07-30 1999-02-11 Basf Aktiengesellschaft Solid textile detergent formulation based on glycin-n and n-diacetic acid derivatives
WO1999038948A1 (en) * 1998-01-28 1999-08-05 Henkel Kommanditgesellschaft Auf Aktien Multiphase detergent tablets
CA2300017A1 (en) * 1999-02-25 2000-08-25 Henkel Kommanditgesellschaft Auf Aktien A process for the production of rapidly disintegrating detergent tablets
CN1276828A (en) * 1997-10-22 2000-12-13 尤尼利弗公司 Detergent compositions in tablet form
CN1399672A (en) * 1999-11-26 2003-02-26 荷兰联合利华有限公司 Detergent compositions
CN1428410A (en) * 2001-12-25 2003-07-09 上海白猫有限公司 Sheet detergent for washing clothes and its preparation method
CN101243169A (en) * 2005-08-19 2008-08-13 宝洁公司 A process for preparing a solid laundry detergent composition, comprising at least two drying steps
CN101892133A (en) * 2010-07-22 2010-11-24 兰州泰坦电子科技有限责任公司 Effervescent tablet for removing pesticide residue on fruits and vegetables and preparation method and use method thereof
CN107001984A (en) * 2014-09-08 2017-08-01 宝洁公司 Detergent composition comprising branched surfactants

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999006524A1 (en) * 1997-07-30 1999-02-11 Basf Aktiengesellschaft Solid textile detergent formulation based on glycin-n and n-diacetic acid derivatives
CN1276828A (en) * 1997-10-22 2000-12-13 尤尼利弗公司 Detergent compositions in tablet form
WO1999038948A1 (en) * 1998-01-28 1999-08-05 Henkel Kommanditgesellschaft Auf Aktien Multiphase detergent tablets
CA2300017A1 (en) * 1999-02-25 2000-08-25 Henkel Kommanditgesellschaft Auf Aktien A process for the production of rapidly disintegrating detergent tablets
CN1399672A (en) * 1999-11-26 2003-02-26 荷兰联合利华有限公司 Detergent compositions
CN1428410A (en) * 2001-12-25 2003-07-09 上海白猫有限公司 Sheet detergent for washing clothes and its preparation method
CN101243169A (en) * 2005-08-19 2008-08-13 宝洁公司 A process for preparing a solid laundry detergent composition, comprising at least two drying steps
CN101892133A (en) * 2010-07-22 2010-11-24 兰州泰坦电子科技有限责任公司 Effervescent tablet for removing pesticide residue on fruits and vegetables and preparation method and use method thereof
CN107001984A (en) * 2014-09-08 2017-08-01 宝洁公司 Detergent composition comprising branched surfactants

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285834A (en) * 2017-12-28 2018-07-17 广州立白企业集团有限公司 Detergent composition
CN108285834B (en) * 2017-12-28 2020-04-10 广州立白企业集团有限公司 Detergent composition
CN108865483A (en) * 2018-06-11 2018-11-23 广州市欣婷生物科技有限公司 A kind of laundry sheet and preparation method thereof

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