CN107164268A - It is a kind of to be used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin - Google Patents

It is a kind of to be used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin Download PDF

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Publication number
CN107164268A
CN107164268A CN201710417863.2A CN201710417863A CN107164268A CN 107164268 A CN107164268 A CN 107164268A CN 201710417863 A CN201710417863 A CN 201710417863A CN 107164268 A CN107164268 A CN 107164268A
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CN
China
Prior art keywords
medium
scale
cgmcc
mix bacterium
preserving number
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Pending
Application number
CN201710417863.2A
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Chinese (zh)
Inventor
肖兵
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Wuhu Huaying Automation Equipment Co Ltd
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Wuhu Huaying Automation Equipment Co Ltd
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Priority to CN201710417863.2A priority Critical patent/CN107164268A/en
Publication of CN107164268A publication Critical patent/CN107164268A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/20Bacteria; Culture media therefor
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/02Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by biological methods, i.e. processes using enzymes or microorganisms
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14Fungi; Culture media therefor
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/08Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances
    • A62D2101/28Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

Abstract

It is used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin the invention discloses a kind of, mixed bacteria scale-up medium and water are 1 by volume:50 100 are mixed to get.Mixed bacteria is made up of streptomyces cinereogriseus, geotrichum candidum, trichodermaharzianum, halobacterium halobium and sulphur amycolatosis.The preserving number of streptomyces cinereogriseus is CGMCC 4.342, the preserving number of geotrichum candidum is CGMCC 2.1135, the preserving number of trichodermaharzianum is CGMCC 3.2064, and the preserving number of halobacterium halobium is CGMCC 1.1952, and the preserving number of sulphur amycolatosis is CGMCC 1.1144.

Description

It is a kind of to be used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin
Technical field
It is used to reduce consumer waste incineration Wei gas Zhong bis- Evil the present invention relates to environment-friendly materials technical field, more particularly to one kind The mix bacterium agent of English content.
Background technology
Over nearly 10 years, as Development of China's Urbanization is accelerated, China's Municipal Domestic Garbage Output is increased considerably.According to China The data that urban environmental hygiene association provides, house refuse year yield is 440kg, National urban rubbish year per capita for current China Yield is increased up to 1.5 hundred million t, and every year with 8~10% speed, and whole nation garbage amount over the years there are about 2/3 more than 6,000,000,000 t City be absorbed in the predicament of garbage-surrounded city.At present, house refuse mainly has sanitary landfills, During High-Temperature Composting and burns three kinds of processing sides Formula, although wherein central incineration one-time investment is higher, incineration tail gas secondary pollution complex treatment process, technical requirements Height, but a kind of effective technology of minimizing of still can yet be regarded as, innoxious, stabilisation and recycling.And managed in this place Journey produces the title bioxin for being also easy to produce " poison in century ", has investigation to claim, bioxin is produced in waste incineration and accounts for air The 90% of Zhong content of dioxin, and be difficult in flue gas to decompose.
Bioxin is a kind of chloride strong toxic organic material, be there's almost no in nature, only by changing Learning synthesis could produce.Quilt in 2001《Convention of Stockholm on persistence organic pollutant》It is appointed as 12 kinds of persistence One kind in organic pollution.Bioxin is through everybody most laggard body of food chain richness product, because its is fat-soluble, be difficult removing property, from And long-term hazards are produced to health, countries in the world government and the highest attention of the public have been caused at present.
Dioxin chemical toxicity is big, property stable, and difficult degradation causes significant damage to environmental and human health impacts. And microbial degradation bioxin is used, cost is low, and environmental pollution is small, can make resource regeneration, has a good application prospect.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of for reducing in consumer waste incineration tail gas The mix bacterium agent of content of dioxin, produced by being handled using mix bacterium agent obtained by the present invention during consumer waste incineration tail gas Flying dust, makes the degradation rate of bioxin in flying dust reach 93-97%, greatly reduces the discharge of bioxin, realizes environment Protection.
It is proposed by the present invention a kind of for reducing the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin, by mixing Strain scale-up medium and water are 1 by volume:50-100 is mixed to get.
Preferably, mixed bacteria is intended without branch acid by streptomyces cinereogriseus, geotrichum candidum, trichodermaharzianum, halobacterium halobium and sulphur Bacterium constitutes.
Preferably, mixed bacteria scale-up medium is by streptomyces cinereogriseus scale-up medium, geotrichum candidum scale-up medium, healthy and free from worry Trichoderma scale-up medium, halobacterium halobium scale-up medium, sulphur amycolatosis scale-up medium are 1 by volume:0.5- 1:0.5-1:0.5-1:0.5-1 is mixed to get.
Preferably, viable count is all higher than 2 × 10 in above-mentioned scale-up medium7Individual/mL.
Preferably, the preserving number of streptomyces cinereogriseus (Streptomyces cinereogriseus) is CGMCC 4.342.
Preferably, the preserving number of geotrichum candidum (Geotrichum candidum) is CGMCC 2.1135.
Preferably, the preserving number of trichodermaharzianum (Trichoderma koningii) is CGMCC 3.2064.
Preferably, the preserving number of halobacterium halobium (Halobacterium halobium) is CGMCC 1.1952.
Preferably, the CGMCC 1.1144 of sulphur amycolatosis (Amycolatopsis sulphurea).
The present invention compared with prior art, during handling consumer waste incineration tail gas using mix bacterium agent obtained by the present invention Produced flying dust, makes the degradation rate of bioxin in flying dust reach 93-97%, greatly reduces the discharge of bioxin, realizes The protection of environment.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
It is proposed by the present invention a kind of for reducing the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin, by mixing Strain scale-up medium and water are 1 by volume:50 are mixed to get;And mixed bacteria scale-up medium is CGMCC by preserving number 4.342 streptomyces cinereogriseus scale-up medium, the geotrichum candidum scale-up medium that preserving number is CGMCC 2.1135, preserving number are CGMCC 3.2064 trichodermaharzianum scale-up medium, preserving number for CGMCC 1.1952 halobacterium halobium scale-up medium, The sulphur amycolatosis scale-up medium that preserving number is CGMCC 1.1144 is 1 by volume:0.5:0.5:0.5:0.5 mixing Obtain, wherein viable count is all higher than 2 × 10 in scale-up medium7Individual/mL.
It is mixed with water into the bag-type dust step of consumer waste incineration vent gas treatment in collected flying dust, flying dust Weight ratio with water is 1:0.3, flying dust Zhong bioxin concentration is 3400ng I-TEQ/kg;Add mix bacterium agent, mix bacterium agent Envelope-bulk to weight ratio (mL/g) with flying dust is 0.5:100, aerobic fermentation 14 days, aerobic fermentation temperature is 50 DEG C, and 100 DEG C of drying are extremely Moisture content is 0-1wt%, then landfill or melting.
Embodiment 2
It is proposed by the present invention a kind of for reducing the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin, by mixing Strain scale-up medium and water are 1 by volume:75 are mixed to get;And mixed bacteria scale-up medium is CGMCC by preserving number 4.342 streptomyces cinereogriseus scale-up medium, the geotrichum candidum scale-up medium that preserving number is CGMCC 2.1135, preserving number are CGMCC 3.2064 trichodermaharzianum scale-up medium, preserving number for CGMCC 1.1952 halobacterium halobium scale-up medium, The sulphur amycolatosis scale-up medium that preserving number is CGMCC 1.1144 is 1 by volume:0.6:0.7:0.6:0.9 mixing Obtain, wherein viable count is all higher than 2 × 10 in scale-up medium7Individual/mL.
It is mixed with water into the bag-type dust step of consumer waste incineration vent gas treatment in collected flying dust, flying dust Weight ratio with water is 1:0.4, flying dust Zhong bioxin concentration is 1200ng I-TEQ/kg;Add mix bacterium agent, mix bacterium agent Envelope-bulk to weight ratio (mL/g) with flying dust is 1:100, aerobic fermentation 12 days, aerobic fermentation temperature is 40 DEG C, and 150 DEG C of drying are to containing Water rate is 0-1wt%, then landfill or melting.
Embodiment 3
It is proposed by the present invention a kind of for reducing the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin, by mixing Strain scale-up medium and water are 1 by volume:100 are mixed to get;And mixed bacteria scale-up medium is CGMCC by preserving number 4.342 streptomyces cinereogriseus scale-up medium, the geotrichum candidum scale-up medium that preserving number is CGMCC 2.1135, preserving number are CGMCC 3.2064 trichodermaharzianum scale-up medium, preserving number for CGMCC 1.1952 halobacterium halobium scale-up medium, The sulphur amycolatosis scale-up medium that preserving number is CGMCC 1.1144 is 1 by volume:1:1:1:1 is mixed to get, its Viable count is all higher than 2 × 10 in middle scale-up medium7Individual/mL.
It is mixed with water into the bag-type dust step of consumer waste incineration vent gas treatment in collected flying dust, flying dust Weight ratio with water is 1:0.5, flying dust Zhong bioxin concentration is 850ng I-TEQ/kg;Add mix bacterium agent, mix bacterium agent Envelope-bulk to weight ratio (mL/g) with flying dust is 0.5:100, aerobic fermentation 10 days, aerobic fermentation temperature is 30 DEG C, and 100 DEG C of drying are extremely Moisture content is 0-1wt%, then landfill or melting.
Embodiment 1-3 Zhong content of dioxin is detected by US EPA 1613 and 1668A methods.In embodiment 1,2,3 The degradation rate of bioxin is respectively 94.2%, 94.7%, 96.5%.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (9)

1. a kind of be used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin, it is characterised in that by Mixed Microbes It is 1 by volume to plant scale-up medium and water:50-100 is mixed to get.
2. mix bacterium agent according to claim 1, it is characterised in that mixed bacteria is by streptomyces cinereogriseus, geotrichum candidum, healthy and free from worry wood Mould, halobacterium halobium and sulphur amycolatosis composition.
3. mix bacterium agent according to claim 1 or claim 2, it is characterised in that mixed bacteria scale-up medium is by streptomyces cinereogriseus Scale-up medium, geotrichum candidum scale-up medium, trichodermaharzianum scale-up medium, halobacterium halobium scale-up medium, sulphur intend nothing The sour bacterium scale-up medium of branch is 1 by volume:0.5-1:0.5-1:0.5-1:0.5-1 is mixed to get.
4. mix bacterium agent according to claim 3, it is characterised in that viable count is all higher than 2 × 10 in above-mentioned scale-up medium7 Individual/mL.
5. according to any one of the claim 1-4 mix bacterium agents, it is characterised in that the preserving number of streptomyces cinereogriseus is CGMCC 4.342。
6. according to any one of the claim 1-5 mix bacterium agents, it is characterised in that the preserving number of geotrichum candidum is CGMCC 2.1135。
7. according to any one of the claim 1-6 mix bacterium agents, it is characterised in that the preserving number of trichodermaharzianum is CGMCC 3.2064。
8. according to any one of the claim 1-7 mix bacterium agents, it is characterised in that the preserving number of halobacterium halobium is CGMCC 1.1952。
9. according to any one of the claim 1-8 mix bacterium agents, it is characterised in that the preserving number of sulphur amycolatosis is CGMCC 1.1144。
CN201710417863.2A 2017-06-06 2017-06-06 It is a kind of to be used to reduce the mix bacterium agent of consumer waste incineration Wei gas Zhong content of dioxin Pending CN107164268A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112122309A (en) * 2020-09-09 2020-12-25 杭州灰弘环保科技有限公司 Novel method for detoxifying municipal solid waste incineration fly ash by using dioxin

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850093A (en) * 2012-10-08 2013-01-02 熊汉夫 Method for preparing fertilizer by mineralized fermentation through rejecting heavy metal in kitchen waste and decomposing dioxin

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850093A (en) * 2012-10-08 2013-01-02 熊汉夫 Method for preparing fertilizer by mineralized fermentation through rejecting heavy metal in kitchen waste and decomposing dioxin

Non-Patent Citations (2)

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Title
NAM 等: ""Biological removal of polychlorinated dibenzo-p-dioxins from incineratory ash by Sphingomonas wittichii RW1"", 《WATER RESEARCH》 *
弓爱君 等: ""二恶英降解菌及其降解机理的研究进展"", 《沧州师范学院学报》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112122309A (en) * 2020-09-09 2020-12-25 杭州灰弘环保科技有限公司 Novel method for detoxifying municipal solid waste incineration fly ash by using dioxin
CN112122309B (en) * 2020-09-09 2021-08-17 杭州灰弘环保科技有限公司 Novel method for detoxifying municipal solid waste incineration fly ash by using dioxin

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Application publication date: 20170915

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