CN107164003A - Improve the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation - Google Patents

Improve the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation Download PDF

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CN107164003A
CN107164003A CN201710264797.XA CN201710264797A CN107164003A CN 107164003 A CN107164003 A CN 107164003A CN 201710264797 A CN201710264797 A CN 201710264797A CN 107164003 A CN107164003 A CN 107164003A
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sludge
coal
slurry
water
ultrasonic wave
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王睿坤
赵争辉
刘志坚
尹倩倩
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North China Electric Power University
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North China Electric Power University
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2462Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention discloses improve the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation, this method is modified using ultrasonic wave to sludge first, microorganism wall in the shear action produced and high temperature and high pressure environment destruction sludge flocculation structure and sludge is acted on using ultrasonic cavitation, reduce mud granule granularity, discharge portion gap water, then the blending such as modified sludge and coal, slurrying additive, water are prepared into sludge water-coal-slurry, or modified sludge is mixed into finished product water-coal-slurry, stir and sludge water-coal-slurry is made.Compared with prior art, the present invention can substantially reduce sludge water-coal-slurry into slurry viscosity, improve its slurry concentration, obtain the excellent sludge water-coal-slurry of paste-forming properties, at the same have processing time it is short, it is easy to operate the features such as, it is adaptable to large-scale promotion application.

Description

Improve the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation
Technical field
The present invention relates to a kind of method for improving sludge water-coal-slurry paste-forming properties, and in particular to sludge is carried out using ultrasonic wave It is modified, and the blending such as modified sludge, coal, slurrying additive, water are prepared into sludge water-coal-slurry, or modified sewage sludge is direct Sludge water-coal-slurry is formed in incorporation finished product water-coal-slurry, breaking sludge Floe structure is acted on using ultrasonic cavitation and then improves slurry Paste-forming properties technical method.
Background technology
With society and economic fast development, China is continuously increased to the demand of the energy, high-grade energy such as oil, naturally It is in accelerated growth situation that the demand of gas, which is even more,.2016, China's oil whole year accumulative 381,010,000 tons of import volume added up same Than rise 13.56%.In following one period, China's economy will high speed development, oil demand amount will keep strong growth to become Gesture, insufficiency of supply-demand will continue to increase.Reliable oil replacement fuel is found, is pacified for China's energy supply is stable with energy strategy It is of great immediate significance entirely.
At the same time, with the fast development and the continuous improvement of living standard of industry, industry and sanitary sewage yield It is significantly increased, thus the output sludge of substantial amounts.Contain more salinity, nutriment, heavy metal, cause of disease in sludge Thing, organic pollution etc., the sludge without rationally disposing, which is discharged into environment, will necessarily produce serious environmental hazard.It is how efficient Cleaning handles these sludge at low cost, it has also become urban sustainable development urgent problem to be solved.Usually, sewage treatment plant The sludge that dispatches from the factory be sludge after biochemical treatment and mechanical dehydration, moisture content still reaches more than 80%, it is difficult to further straight Connect utilization.As burned or blending coal combustion, it is necessary to which moisture removal is arrived 40-50% or so, so also need to consume substantial amounts of heat Energy.
Water-coal-slurry is a kind of coal base fuel slurry of technology maturation, with the mobility for being similar to oil, can pass through pipeline Conveying, it is ensured that coal derived fuel convey and storage clean environment, can efficient spray burning in the boiler, can also It is a kind of more satisfactory oil-substituted fuel as vaporising fuel output combustible gas.Sludge water-coal-slurry technology is to contain sludge effect Carbon material containing energy is mixed water-coal-slurry processed or directly mixed in water-coal-slurry with coal, is utilized being burnt or being gasified to water-coal-slurry Cheng Zhong, realizes the synchronous of sludge and utilizes and handle.Sludge water-coal-slurry technology mainly shows following advantage:Need not be to sludge Processing is dried, can be solved in the case where inheriting the advantage of sludge and coal mixed combustion or gasification by sludge high-moisture Caused application problem;After the moisture of high content is by reasonably handling in sludge, the water of free-flowing, Ke Yijie can be converted into Save the clear water needed for slurrying;Sludge water-coal-slurry can realize the recycling of energy in sludge, and sludge by burning or gasification Volume reduction effect is notable.In addition, in sludge and coal mixed combustion and when gasifying, by distributing rationally and reasonable operation, can effectively it control The discharge of smoke-discharging pollution thing and heavy metal processed.In view of above-mentioned advantage, sludge water-coal-slurry technology is increasingly becoming sludge high efficient resourcing One of main path utilized.
The paste-forming properties of slurry be both related to the preparation benefit of slurry, and its pumping, atomization are directly influenced again and is burnt(Or Gasification)Effect, is the key index for assessing water-coal-slurry quality.The paste-forming properties of slurry are especially by slurry concentration, into slurry viscosity etc. Parameter measure, good paste-forming properties require that slurry slurry concentration is high and low into slurry viscosity.However, because sludge has higher water Point content and toughness, prepare water-coal-slurry by itself and coal blending or are directly mixed in water-coal-slurry, can all cause sludge water Viscosity of coal slurry greatly increases, and slurry concentration is also decreased obviously.This necessarily causes water-coal-slurry utilization benefit to decline, and is unfavorable for sludge Extensive efficient process.
Therefore, exploitation is a kind of can improve the technical method of sludge water-coal-slurry paste-forming properties, reduce sludge water-coal-slurry into slurry viscosity, Increase its slurry concentration, to reducing the application cost of sludge water-coal-slurry, accelerating the development and popularization and application of sludge water-coal-slurry technology It is significant.
The content of the invention
There is provided improve sludge water-coal-slurry into slurry using ultrasonic wave breaking sludge floc sedimentation for existing technical problem by the present invention Property method, it is therefore an objective to overcome in existing sludge water-coal-slurry technology the problem of slurry paste-forming properties are poor.
To achieve the above object, the present invention provides following technical scheme:Improve sludge using ultrasonic wave breaking sludge floc sedimentation The method of water-coal-slurry paste-forming properties, it comprises the following steps:
(1) sludge initially enters ultrasonic generator and pre-processed, the shear action produced using ultrasonic cavitation effect Microorganism wall in sludge flocculation structure and sludge is destroyed with high temperature and high pressure environment, mud granule granularity is reduced, part is discharged Interstitial Water, obtains modified sewage sludge;
(2) raw coal is crushed successively, ground, screening process, obtain particle diameter and be less than 150 μm of coal dust;
(3) slurrying additive is completely dissolved in water, obtains additive solution, afterwards by the modified sewage sludge in step (1) with Coal dust in step (2) is added in additive solution, is sufficiently stirred for by slurrying agitating device, obtains uniform sludge water coal Slurry;Or the modified sewage sludge in step (1) is directly incorporated into finished product water-coal-slurry, it is sufficiently stirred for by agitating device, obtains equal Even sludge water-coal-slurry.
Further, preferably, in the present invention, the service condition of processor for ultrasonic wave is:Working frequency be 15kHz~ 35kHz, power is 114W~325W, and ultrasonic wave input specific energy is 0~75kJ/g dewatered sludges (DS);Wherein ultrasonic wave is inputted The calculation formula of specific energy is:
In formula:ESpec--- ultrasonic wave inputs specific energy, kJ/g DS;
P --- the ultrasonic power of input sludge, kW;
T --- the ultrasonic wave duration, s;
V --- the volume of dilution mud sample, L;
S --- the concentration of dry matter sludge, g/L.
Further, preferably, the service condition of processor for ultrasonic wave is:Working frequency is 15kHz-35kHz, and power is 114W-325 W, ultrasonic wave input specific energy is 0-75kJ/g dewatered sludges;.
Further, preferably, the quality proportioning relation of each raw material components of sludge water-coal-slurry is:Using by moisture content 90% The sludge of conversion:Dry pulverized coal=30:100, additive:Dry pulverized coal=0.8:100.
Further, preferably, described sludge is the excess sludge or its mechanical dehydration of municipal sewage plant's output Product, its moisture content is 90%-98%.
Further, preferably, described slurrying additive uses naphthalenesulfonate formaldehyde condensation compound or lignin sulfonic acid Salt.
Further, preferably, described finished product water-coal-slurry is the water coal being configured to using coal dust, water, slurrying additive Slurry.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention is modified using ultrasonic wave to sludge, the shear action and HTHP produced using ultrasonic cavitation effect Microorganism wall in environmental disruption sludge flocculation structure and sludge, reduces mud granule granularity, discharges portion gap water, then The material blending such as modified sludge and coal, slurrying additive, water are prepared into sludge water-coal-slurry, or modified sewage sludge is directly mixed Enter in finished product water-coal-slurry and form sludge water-coal-slurry, can substantially reduce sludge water-coal-slurry into slurry viscosity, improve its slurry concentration, obtain Obtain the excellent sludge water-coal-slurry of paste-forming properties.
Compared with prior art, advantage of the invention is:
1st, the present invention carries out pretreatment modification using low-frequency ultrasonic waves to sludge, and pretreatment time is short, and energy consumption is relatively low, method Easily realize, be easy to operation;
2nd, slurry viscosity more than 41%, more than 3 percentage points of increase slurry concentration can be reduced into.Compared with prior art, reduce Cost is pumped, sludge water-coal-slurry heat utilization economy is added.
3rd, improve the paste-forming properties of sludge water-coal-slurry, improve its slurry concentration, realize the recycling profit of sludge higher efficiency With reducing the environmental pollution of sludge.
Brief description of the drawings
Fig. 1 mixes the technological process of sludge water-coal-slurry processed for ultrasonically-modified sludge in the present invention with coal dust, additive and water Schematic diagram.
Technological processes of the Fig. 2 to prepare sludge water-coal-slurry in ultrasonically-modified sludge incorporation water-coal-slurry in the present invention is illustrated Figure.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Fig. 1-2 is referred to, the present invention provides a kind of technical scheme:Improve sludge water coal using ultrasonic wave breaking sludge floc sedimentation The method for starching paste-forming properties, it is to be modified processing to sludge using ultrasonic cavitation effect, and using modified sewage sludge and coal, add Plus the blending such as agent, water prepares sludge water-coal-slurry(As shown in Figure 1)Or modified sewage sludge is blended into finished product water-coal-slurry forms sludge Water-coal-slurry(As shown in Figure 2).During ultrasonically-modified, sludge floc sedimentation is substantially cracked, and grain graininess is substantially reduced, simultaneously Ultrasonic wave can open microbial cell structure in sludge floc sedimentation inner space and sludge, and Interstitial Water therein is released to be formed certainly By water.The slurry that slurry viscosity is low, slurry concentration is high can be obtained into using modified sewage sludge sludge water-coal-slurry.
Embodiment 1:
(1) implementation
Sludge is derived from the excess sludge of certain sewage treatment plant's output, after different degrees of mechanical dehydration, forms moisture content point Not Wei 90%, 95% and 98% mud sample, for sludge water-coal-slurry ultrasonically-modified and subsequently processed.
Using probe type ultrasonic chemical processing system, the equipment is by generator, transducer and the part group of ultrasonic probe three Into.Ultrasonic frequency is 20 kHz, and ultrasonic power is respectively set to 190W, and ultrasonic wave input specific energy is chosen to be 0(I.e. without Ultrasonication)、3.8、7.5、15、30、75 kJ/g DS.
During modified sewage sludge water-coal-slurry, the quality proportioning relation of each raw material components is:The sludge converted by moisture content 90%: Dry pulverized coal=30:100, additive:Dry pulverized coal=0.8:100.Additive selects naphthalenesulfonate formaldehyde condensation compound.The water being made The solid masses concentration of coal slurry is 60%.
The apparent viscosity of slurry utilizes rotary viscosity design determining.
(2) implementation result
Table 1 give ultrasonically-modified sludge sludge water-coal-slurry into slurry viscosity(ηc, shear rate is flat under 100 s 1 Equal apparent viscosity).It can be seen in table 1 that being reduced rapidly with the increase of ultrasonic wave specific energy into slurry viscosity for sludge water-coal-slurry, says The paste-forming properties that bright sludge blends preparation water-coal-slurry after ultrasonication with coal improve.For the sludge of 95% moisture content, without The raw sewage of processing blends the higher into slurry viscosity of the sludge water-coal-slurry prepared with coal, is 1663.60 mPa s, sludge passes through 30 After kJ/g DS ultrasonication, sludge water-coal-slurry into slurry viscosity is reduced to 1205.43 mPa s.By 75 kJ/g DS Ultrasonication after, sludge water-coal-slurry into slurry viscosity is reduced to 980.85 mPa s, into slurry viscosity compared to raw sewage water Coal slurry reduces 41%.Undressed raw sewage flco is loose, and with abundant inner space and space, constraint outlet capacity is very By force, and in raw sewage contain substantial amounts of cell tissue, undressed raw sewage is mixed in water-coal-slurry, the Free water in slurry A part turns into Interstitial Water by loose sludge flco constraint, and another part, which is infiltrated through, turns into cellular water in cell tissue, therefore The viscosity of raw sewage water-coal-slurry is higher.After sludge is ultrasonically treated, sludge flco is acted on by ultrasonic wave empty verbiage and produced Raw powerful shearing force and crack, the ability that the organic relic of flco is mutually wound declines, and sludge flco inner space is due to flco Crack and become open, the ability of sludge flco irreducible water declines, when ultrasonic wave specific energy is higher, the groups of cells in sludge Knit and also destroyed, sludge irreducible water is released.Therefore the sludge through ultrasonication is compared with raw sewage, obtained sludge The viscosity of water-coal-slurry declines.On the other hand, mud granule is after ultrasonication, and granularity diminishes, and is conducive to improving consolidating for slurry Body inserts, this can also reduce the viscosity of slurry to a certain extent.
The ultrasonically-modified sludge sludge water-coal-slurry of table 1. into slurry viscosity
It is 100 s that the maximum slurry concentration of sludge water-coal-slurry, which is defined as in shear rate,−1Under conditions of apparent viscosity reach 1000 The mass fraction of solid contained by sludge water-coal-slurry during mPa s, available for the slurry performance for weighing slurry.With the dirt of 95% moisture content For mud, raw sewage water-coal-slurry and ultrasonication(Ultrasonic wave input specific energy is 75 kJ/g DS)Dirt prepared by sludge afterwards The maximum slurry concentration of muddy water coal slurry is respectively 57.39% and 60.47%, i.e., the sludge water being made by ultrasonically-modified sludge Coal slurry adds more than 3 percentage points on maximum slurry concentration.Maximum slurry concentration increase, shows under identical viscosity, Slurry concentration can reach higher level, and slurry paste-forming properties are also better.That is, after being ultrasonically treated, sludge is into slurry Performance is greatly improved, and economic benefit can also be improved.
Embodiment 2:
(1)Implementation
Sludge is derived from the excess sludge of certain sewage treatment plant's output, after a certain degree of mechanical dehydration, forms moisture content point Not Wei 95% mud sample, for sludge water-coal-slurry ultrasonically-modified and subsequently processed.
Same as Example 1, using probe type ultrasonic chemical processing system, the equipment is by generator, transducer and surpasses The part of sonic probe three is constituted.Ultrasonic frequency is 20 kHz, and ultrasonic power is respectively set to 114W, 190W and 266 W, ultrasound Ripple input specific energy is 75 kJ/g DS.
During modified sewage sludge water-coal-slurry, the quality proportioning relation of each raw material components is:The sludge converted by moisture content 90%: Dry pulverized coal=30:100, additive:Dry pulverized coal=0.8:100.Additive selects naphthalenesulfonate formaldehyde condensation compound.The water coal being made The solid masses concentration of slurry is 60%.
The apparent viscosity of slurry utilizes rotary viscosity design determining.
(2) implementation result
Table 2 gives dense into slurry viscosity and most great achievement slurry through sludge sludge water-coal-slurry modified under different ultrasonic powers Degree.As seen from Table 2, compared with undressed raw sewage, the sludge water-coal-slurry being made by ultrasonically-modified sludge has Have relatively low into slurry viscosity and higher slurry concentration, show the paste-forming properties enhancing of ultrasonically-modified sludge.Ultrasonic power is got over Greatly, lower into slurry viscosity, maximum slurry concentration is higher.Because ultrasonic power is big, cavitation is just stronger, to sludge Disintegration effect just becomes apparent from.In addition, cavitation supervenes fuel factor, and during ultrasonication, sludge local temperature Rise.During ultrasonic power increase, reach that the time that identical ultrasonic intensity needs is short, radiating is few, sludge local temperature water It is flat higher, therefore sludge disintegration effect can be higher.
Table 2. is through sludge sludge water-coal-slurry modified under different ultrasonic powers into slurry viscosity and maximum slurry concentration
Embodiment 3:
(1) implementation
Sludge is derived from the excess sludge of certain sewage treatment plant's output, after a certain degree of mechanical dehydration, forms moisture content point Not Wei 95% mud sample, for sludge water-coal-slurry ultrasonically-modified and subsequently processed.
Sludge is modified using multi-frequency ultrasonic cell disruption instrument.Ultrasonic frequency is respectively 15 kHz, 25 KHz and 35 kHz, ultrasonic power is respectively set to 325W, and ultrasonic wave input specific energy is respectively 4 kJ/g DS and 30 kJ/ g DS。
Water-coal-slurry is using the finished product made in advance, and additive is lignosulfonates, additive and dry coal during water-coal-slurry processed The quality proportioning relation of powder is 0.8:100.
It is sufficiently stirred in modified sewage sludge incorporation water-coal-slurry, forms uniform sludge water-coal-slurry sample, the quality of sludge incorporation Ratio is:The sludge converted by moisture content 90%:Dry pulverized coal=30 in water-coal-slurry:100.The solid masses for the water-coal-slurry being made Concentration is 60%.
The apparent viscosity of slurry utilizes rotary viscosity design determining.
(2) implementation result
The water-coal-slurry that raw sewage is made is 1656.8 mPa s into slurry viscosity, and sludge during repulping, glues after ultrasonication Degree reduction, paste-forming properties improve.When ultrasonic wave input specific energy is 4 kJ/g DS, sludge passes through 15 kHz, 25 kHz and 35 kHz Ultrasonication after slurrying be reduced to 1210.4 mPa s, 1421.5 mPa s and 1557.5 mPa respectively into slurry viscosity s;When ultrasonic wave input specific energy is 30kJ/g DS, sludge is made after 15 kHz, 25 kHz and 35 kHz ultrasonication That starches reduces by 1127.0 mPa s, 1186.2 mPa s and 1230.6 mPa s into slurry viscosity respectively.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. improving the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation, it comprises the following steps:
(1) sludge initially enters ultrasonic generator and pre-processed, the shear action produced using ultrasonic cavitation effect Microorganism wall in sludge flocculation structure and sludge is destroyed with high temperature and high pressure environment, mud granule granularity is reduced, part is discharged Interstitial Water, obtains modified sewage sludge;
(2) raw coal is crushed successively, ground, screening process, obtain particle diameter and be less than 150 μm of coal dust;
(3) slurrying additive is completely dissolved in water, obtains additive solution, afterwards by the modified sewage sludge in step (1) with Coal dust in step (2) is added in additive solution, is sufficiently stirred for by slurrying agitating device, obtains uniform sludge water coal Slurry;Or the modified sewage sludge in step (1) is directly incorporated into finished product water-coal-slurry, it is sufficiently stirred for by agitating device, obtains equal Even sludge water-coal-slurry.
2. the method that utilization ultrasonic wave breaking sludge floc sedimentation according to claim 1 improves sludge water-coal-slurry paste-forming properties, its It is characterised by:The service condition of processor for ultrasonic wave is:Working frequency is 15kHz-35kHz, and power is 114W-325 W, ultrasound Ripple input specific energy is 0-75kJ/g dewatered sludges;.
3. the method that utilization ultrasonic wave breaking sludge floc sedimentation according to claim 1 improves sludge water-coal-slurry paste-forming properties, its It is characterised by:The quality proportioning relation of each raw material components of sludge water-coal-slurry is:Using the sludge converted by moisture content 90%:Dry coal Powder=30:100, additive:Dry pulverized coal=0.8:100.
4. the utilization ultrasonic wave breaking sludge floc sedimentation according to claim 1-3 any one improves sludge water-coal-slurry paste-forming properties Method, it is characterised in that:Described sludge is the excess sludge or its mechanical dehydration product of municipal sewage plant's output, its Moisture content is 90%-98%.
5. the utilization ultrasonic wave breaking sludge floc sedimentation according to claim 1-3 any one improves sludge water-coal-slurry paste-forming properties Method, it is characterised in that:Described slurrying additive uses naphthalenesulfonate formaldehyde condensation compound or lignosulfonates.
6. the method that utilization ultrasonic wave breaking sludge floc sedimentation according to claim 1 improves sludge water-coal-slurry paste-forming properties, its It is characterised by:Described finished product water-coal-slurry is the water-coal-slurry being configured to using coal dust, water, slurrying additive.
CN201710264797.XA 2017-04-21 2017-04-21 Improve the method for sludge water-coal-slurry paste-forming properties using ultrasonic wave breaking sludge floc sedimentation Pending CN107164003A (en)

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CN108046550A (en) * 2017-11-28 2018-05-18 四川理工学院 A kind of excess sludge ultrasound rotational flow, which is combined, cracks technique
CN109796111A (en) * 2019-01-03 2019-05-24 天津生态城水务投资建设有限公司 A kind of ultrasonic sludge cracks preprocess method
CN113029981A (en) * 2021-03-08 2021-06-25 长春工程学院 Method for detecting sludge total phosphorus of urban sewage plant
CN113355141A (en) * 2021-07-09 2021-09-07 中煤陕西榆林能源化工有限公司 Method and device for preparing high-concentration sludge gasification coal water slurry by sludge modification
CN115093888A (en) * 2022-07-20 2022-09-23 西安科技大学 Method for preparing water coke slurry by ultrasonically modifying sludge mixed with blue carbon powder

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CN103979768A (en) * 2014-05-27 2014-08-13 陕西延长石油(集团)有限责任公司 Method for tempering oily sludge blended with coal water slurry

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046550A (en) * 2017-11-28 2018-05-18 四川理工学院 A kind of excess sludge ultrasound rotational flow, which is combined, cracks technique
CN109796111A (en) * 2019-01-03 2019-05-24 天津生态城水务投资建设有限公司 A kind of ultrasonic sludge cracks preprocess method
CN113029981A (en) * 2021-03-08 2021-06-25 长春工程学院 Method for detecting sludge total phosphorus of urban sewage plant
CN113355141A (en) * 2021-07-09 2021-09-07 中煤陕西榆林能源化工有限公司 Method and device for preparing high-concentration sludge gasification coal water slurry by sludge modification
CN115093888A (en) * 2022-07-20 2022-09-23 西安科技大学 Method for preparing water coke slurry by ultrasonically modifying sludge mixed with blue carbon powder

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