CN107151920A - The manufacture method of high-visibility waterproof cladding - Google Patents

The manufacture method of high-visibility waterproof cladding Download PDF

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Publication number
CN107151920A
CN107151920A CN201610117779.4A CN201610117779A CN107151920A CN 107151920 A CN107151920 A CN 107151920A CN 201610117779 A CN201610117779 A CN 201610117779A CN 107151920 A CN107151920 A CN 107151920A
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CN
China
Prior art keywords
visibility
manufacture method
waterproof cladding
waterproof
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610117779.4A
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Chinese (zh)
Inventor
许秉叡
徐正己
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FORMOSAN RUBBER GROUP Inc
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FORMOSAN RUBBER GROUP Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FORMOSAN RUBBER GROUP Inc filed Critical FORMOSAN RUBBER GROUP Inc
Priority to CN201610117779.4A priority Critical patent/CN107151920A/en
Publication of CN107151920A publication Critical patent/CN107151920A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

A kind of manufacture method of high-visibility waterproof cladding, utilize the mode of transfer coated, surface prior to release liners forms surface layer, the main composition of surface layer is a liquid type polycarbonate resin and is added with fluorescent color, the following layer using two-liquid type polycarbonate resin as main composition is formed on surface layer, afterwards, base fabric is fitted in after following layer, release liners are stripped, you can waterproof, moisture-inhibiting and water-fastness high-visibility waterproof cladding is made.High-visibility waterproof cladding obtained by the present invention directly makees face in glue and imports fluorescent color, visibility effect is set to be easier presentation, simultaneously, because transfer coated make use of the surface smooth property of release liners in itself, facing surface is allowed to remain smooth, so as to improve the phenomenon that glue surface is bad, the outward appearance and use value of high-visibility waterproof cladding can be substantially improved.

Description

The manufacture method of high-visibility waterproof cladding
Technical field
The present invention relates to a kind of waterproof cladding, particularly relate to a kind of improve glue surface smoothness and the height of visibility The manufacture method of visibility waterproof cladding.
Background technology
Polyurethane (Polyurethane, PU) can generally be divided into the resin of polyesters, polyethers and poly- carbonic acid, In terms of polyurethane such as is applied into fabric processing, the resins of polyesters and polyethers in after processing on fabric, because It can produce the phenomenon of splitting after high temperature washing, then the effect can not with high temperature resistant water washing.
And the heat resistance of polycarbonate resin is preferably, it can improve the temperature of washing after being processed on fabric, Yu Gao Phenomenon without splitting after warm water is washed, with water-fastness effect, can increase the validity period of waterproof cladding Limit.Fabric and its manufacture method as disclosed in TaiWan, China patent the I472662nd, are in scrim surfaces Following layer and surface layer containing polycarbonate resin are sequentially coated with, makes fabric that there is high temperature resistant water washing, wash durable Degree, moisture permeable and watertight function;However, because polycarbonate resin in the processing on fabric is with direct Coating method is for it, it is impossible to carry out the action of froth breaking so that glue surface easily forms hole, causes the table of fabric Face is presented uneven, and its smoothness is to be improved.
In addition, in terms of high-visibility waterproof cladding, for example:Wind coat, snow clothing, anorak, gym suit etc. Purposes, is usually directly coated at fabric using luminous or fluorescent coating, fabric is had more high-visibility, To reach the effect for being available for recognizing and producing safety;But only apply there is provided the coating of such a fabric visibility Make face in the cloth of fabric, may be covered by the waterproof glued membrane of following process, and reduce visibility;Furthermore, Even if the influence not being shielded from, after fabric is in high temperature washing or more washing times, also easily The effect of its visibility is caused to decline.
Therefore, except investigating the high temperature water washing effect and durability degree of waterproof cladding, for surface flatness and can The lifting of degree of opinion also turns into particularly important problem.In view of this, applicant of the present invention is particularly developed for this A kind of manufacture method of high-visibility waterproof cladding, enables a fabric to possess waterproof, moisture-inhibiting, water-fastness and height The various functions such as visibility fluorescent, while having splendid surface flatness, are adapted to make high-visibility demand Waterproof work clothes and other aspect, it is sufficient to overcome foregoing variety of problems and missing.
The content of the invention
In view of the above problems, it is a primary object of the present invention to provide a kind of system of high-visibility waterproof cladding Method is made, by two-liquid type polycarbonate resin and a liquid type polycarbonate resin for the processing mode of fabric, is made The temperature tolerance of fabric is lifted with water-wash resistance, and as face be introduced directly into fluorescent sizing material in the glue of fabric Visibility effect, effectively improves and maintain the high-visibility of cladding, in addition, being more directed to prior art institute The glue surface bad phenomenon of experience, using transfer coated mode, the surface that waterproof cladding can be substantially improved is smooth Degree, thus, allows product to be able to more diversified, and application is more extensive.
To achieve the above object, the present invention provides a kind of manufacture method of high-visibility waterproof cladding, its step It is that a release liners are first provided, and uses a liquid type polycarbonate resin, the lubrication prescription of 3~4 parts by weight of 100 parts by weight And 10~15 the fluorescent colors of parts by weight be prepared into the first coating fluid, use the poly- carbonic acid of the two-liquid type of 100 parts by weight The white cream of resin, the isocyanates bridging agent of 5~10 parts by weight and 30~40 parts by weight is prepared into the second coating Liquid.Then, by the first coating solution on the surface of release liners, to form surface layer, then by the second coating Liquid is coated on surface layer, to form following layer, and then, base fabric is fitted on following layer, finally, will be from Type paper is removed, you can high-visibility waterproof cladding is made.
Specifically, base fabric therein may be selected from group's combination of looped fabric, flat fabric, adhesive-bonded fabric and epithelium; Second coating fluid with can further include 15~30 parts by weight fire retardant and 0.5~1 parts by weight antibacterial and mouldproof Agent, and the antibacterial for matching somebody with somebody the fire retardant that can further include 10~15 parts by weight and 0.5~1 parts by weight of the first coating fluid Mould inhibitor.In more detail, the viscosity of a liquid type polycarbonate resin is preferably 1800~2200cps, two-liquid type The viscosity of polycarbonate resin is preferably 3000~5000cps, in addition, containing fluorescent color in fluorescent color is optional Heat curing-type polyamide (polyamide) resin fine powder of material, white cream can be titanium dioxide or polyurethane, slide Agent can be silica flour, and fire retardant can be antimony oxide or decabromodiphenyl ethane, and antibacterial mildew inhibitor can be Nano Silver Ion.
It is using transfer in processing procedure according to the manufacture method of high-visibility waterproof cladding provided by the present invention The processing mode of coating, because the flatness on release liners surface is high, roughness is low, makes the coating of coating thereon Uniform and smooth effect can be reached.That is, the present invention is the processing being directly coated with of being different from over Mode, the fabric face after processing will not be presented uneven, and the outer of visibility waterproof cladding can be substantially improved See and use value.
Therefore, manufacture method of the invention can produce a kind of high-visibility waterproof cladding, except with resistance to High temperature washing, washing durability degree, moisture permeable and watertight function, and surface flatness is splendid, more can The effect of high-visibility fluorescent is provided, can be widely applied to make wind coat, snow clothing, waterproof work clothes, skin Bag, soft bag, handbag, medical mattress or camp canvas etc., so as to improve the surcharge of those products.
Brief description of the drawings
The flow chart of the manufacture method for the high-visibility waterproof cladding that Fig. 1 is provided by embodiments of the invention.
Correspondence in the manufacture method for the high-visibility waterproof cladding that Fig. 2A -2E are provided by embodiments of the invention The sectional structure chart of each step.
Description of reference numerals:10- high-visibility waterproof claddings;20- release liners;30- surface layers;40- following layers; 50- base fabrics.
Embodiment
Fig. 1 is refer to, the stream of the manufacture method of the high-visibility waterproof cladding provided by embodiments of the invention Cheng Tu;Meanwhile, Fig. 2A -2E are refer to, the high-visibility waterproof cladding 10 provided by embodiments of the invention Manufacture method in each step of correspondence sectional structure chart.
First, step S01 is seen, as shown in Figure 2 A there is provided a release liners 20, the surface of this release liners 20 is light Sliding cloudy surface.Specifically, the characteristic of release liners 20 is that flatness is good and roughness is low, that is to say, that release The surface of paper 20 typically appears as shiny surface, when being coated processing, can obtain preferably coating layer thickness point Cloth, can also allow coating surface to obtain quite good planarization.
Step S02 is seen, as shown in Figure 2 B, using coating machine, by the first coating solution in the table of release liners 20 On face, and surface layer 30 is formed, then by the heating, drying of surface layer 30.
In the present embodiment, the formula of the first coating fluid includes a liquid type polycarbonate resin of 100 parts by weight (Polycarbonate), the lubrication prescription of 3~4 parts by weight and the fluorescent color of 10~15 parts by weight, while can add The antibacterial mildew inhibitor of the fire retardant of 10~15 parts by weight and 0.5~1 parts by weight.More specifically, the poly- carbon of liquid type The viscosity of acid resin is preferably 1800~2200cps;Viscosity is too high to cause the bubble in thickener to be easily wrapped by In thickener, the appearance for causing thickener to there is serious bubble impression and glue surface to have pin hole when coating, so most preferably Control be this scope, when viscosity be higher than 4000cps, pin hole can be produced during paste, causes finished product not have There is watertight effect;Lubrication prescription can be silica flour (silica powder);Fluorescent color contains fluorescent in can select It is with can be by Unite States Standard in heat curing-type polyamide (polyamide) resin fine powder of colorant, practice ANSI-107 fluorescent color is preferable;Fire retardant can be antimony oxide or decabromodiphenyl ethane;And antibacterial Mould inhibitor can be nano-silver ionic.
In addition, the preparation method of the first coating fluid is to be thoroughly mixed above-mentioned be formulated in butter-mixing machine, make Its mixture is dispersed;In mixed process, incorporation time control is within 20 minutes preferably 5~20 Minute mixing temperature is that can not be stirred vigorously in 20~50 DEG C, its whipping process, in order to avoid produce bubble and cause Sizing material is damaged;Also, need to first pass through the strainer filtering of 200 mesh before upper machine, to eliminate bubble in thickener Produce, it is possible to decrease it is bad that bubble is produced.
And the coating method of the first coating fluid utilizes roller scraper (knife on roll) or the scraper that swims (knife on Air on the surface for) being coated on release liners 20, then after baking oven heating, drying, batched, oven temperature For 100~170 DEG C, the heat time is 30~120 seconds.
It must be noted that as used in this specification, the usage amount of various materials is with " parts by weight " The unit of counting, according to the present embodiment content, wherein it is 100 that the main formula of the first coating fluid, which includes ratio,: 3~4:One liquid type polycarbonate resin of 10~15 (parts by weight/parts by weight/parts by weight):Lubrication prescription:Fluorescent color, One liquid type polycarbonate resin of namely every 100 parts by weight, the usage amount of lubrication prescription is 3~4 parts by weight, fluorescent color The usage amount of cream is 10~15 parts by weight, is such as converted to parts by weight with kilogram for digit, then equivalent to 100 kilograms of a liquid type polycarbonate resin is often used, the usage amount of lubrication prescription is 3~4 kilograms, fluorescent color makes Consumption is 10~15 kilograms.Describe also to be these situations below, therefore repeat no more.
Then, see step S03, as shown in Figure 2 C, reuse coating machine, by the second coating solution in surface layer On 30, and following layer 40 is formed, then by the heating, drying of following layer 40.
In the present embodiment, the second coating fluid formula includes the two-liquid type polycarbonate resin of 100 parts by weight (Polycarbonate), the isocyanates bridging agent of 5~10 parts by weight and the white cream of 30~40 parts by weight, together When can add the fire retardant of 15~30 parts by weight and the antibacterial mildew inhibitor of 0.5~1 parts by weight.More specifically, two The viscosity of liquid type polycarbonate resin is preferably 3000~5000cps;White cream can select titanium dioxide or poly- ammonia Ester, wherein preferable with the screening rate of titanium dioxide;Fire retardant can be antimony oxide or decabromodiphenyl ethane; Antibacterial mildew inhibitor can be nano-silver ionic.
In addition, the preparation method of the second coating fluid is to be thoroughly mixed above-mentioned be formulated in butter-mixing machine, make Its mixture is dispersed;In mixed process, incorporation time control is 5~10 minutes, in its whipping process It can not be stirred vigorously, in order to avoid produce bubble and cause sizing material to be damaged, and mixing temperature is controlled at 20 to 50 DEG C, Temperature is too high to allow thickener to do sth. in advance hardening, cause thickener not process.
And the coating method of the second coating fluid is to utilize roller scraper (knife on roll) or the scraper (knife that swims On air) it is coated on surface layer 30, then by baking oven heating, drying, oven temperature is 100~170 DEG C, heating Time is 80~120 seconds.
See step S04, as shown in Figure 2 D, base fabric 50 is first, with high temperature hot pressing, to make the surfacing of base fabric 50;Base The fabric of cloth 50 can widely be selected from group's combination of looped fabric, flat fabric, adhesive-bonded fabric and epithelium.Then, In the way of half wet combining, base fabric 50 is fitted on the following layer 40 dried in baking oven outlet, placed into ripe Into room, completed via maturation in 24 hours;Ripening chamber is the confined space that temperature is 40 DEG C, humidity is 50%, and The maturation time is too short to cause glue surface out-of-flatness.
Finally, see step S05, as shown in Figure 2 E, release liners 20 are peeled off from base fabric 50, you can To the final finished of high-visibility waterproof cladding 10.
The manufacture method of high-visibility waterproof cladding disclosed in embodiments in accordance with the present invention, is further included following Advantage:First, the present invention be high-visibility waterproof cladding glue make that face (i.e. surface layer) has been introduced directly into can The fluorescent color of degree of opinion fluorescent effect, when ultraviolet light or blue light illumination, i.e., can send fluorescent;And arrange in pairs or groups in Following layer can be covered the background color of base fabric using white paste composition, then when by ultraviolet light or blue light photograph When penetrating, the glue of high-visibility waterproof cladding makees the fluorescent color that the color that face shown is fluorescent color, uses Realize the purpose of high-visibility.
Furthermore, the present invention passes through the processing of two-liquid type polycarbonate resin and a liquid type polycarbonate resin for fabric Mode, not only make it that the temperature tolerance of fabric is lifted with water-wash resistance, and processing mode is obtained according to this Visibility and antibacterial effect can be increased its durability.
Meanwhile, the processing method that the polycarbonate resin of being different from over is directly coated at fabric, the present invention is by turning The mode of coating is moved, by the surface characteristic of release liners in itself, the coating of coating thereon is reached uniformly And smooth effect.Therefore, the present invention can effectively overcome asking for the easy surface irregularity of fabric after processing Topic, can be substantially improved the outward appearance and use value of visibility waterproof cladding.
Therefore, manufacturing method according to the invention can provide a kind of high-visibility waterproof cladding, except with resistance to height (95 DEG C) washings of temperature, washing durability degree, moisture permeable, watertight function, can make the surface of waterproof cladding Reach smooth, can more increase antibacterial and the ability and durability degree of high-visibility fluorescent.Then, it is of the invention The various product of high-visibility demand, particularly wind coat, snow clothing, waterproofer will be can be widely applied to make Take, suitcase, soft bag, handbag, medical mattress or camp canvas etc., so as to improve the attached of those products Price markup value.
The above embodiment is only exemplary, does not constitute any limitation to the scope of the present invention.Ability Field technique personnel should be understood that without departing from the spirit and scope of the invention can be to the technology of the present invention The details and form of scheme are modified or replaced, but these modifications and replacement each fall within the protection model of the present invention In enclosing.

Claims (13)

1. a kind of manufacture method of high-visibility waterproof cladding, includes the following steps:
One release liners are provided;
One first coating fluid is coated with the surface of the release liners, to form a surface layer, and is added Heat drying, wherein first coating fluid includes a liquid type polycarbonate resin, 3~4 weights of 100 parts by weight Measure the lubrication prescription of part and the fluorescent color of 10~15 parts by weight;
One second coating fluid is coated with the surface layer, to form a following layer, and with heating, drying, Wherein second coating fluid includes the two-liquid type polycarbonate resins of 100 parts by weight, 5~10 parts by weight The white cream of isocyanates bridging agent and 30~40 parts by weight;
A base fabric fit on the following layer;And
The release liners are separated, to form the high-visibility waterproof cladding.
2. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, the wherein base fabric be selected from looped fabric, Group's combination of flat fabric, adhesive-bonded fabric and epithelium.
3. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, the surface of the wherein release liners is Smooth cloudy surface.
4. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, the wherein base fabric are first with high warm Pressure, makes the scrim surfaces smooth.
5. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein second coating fluid are more wrapped The antibacterial mildew inhibitor of fire retardant and 0.5~1 parts by weight containing 15~30 parts by weight, and first coating fluid is more The antibacterial mildew inhibitor of fire retardant comprising 10~15 parts by weight and 0.5~1 parts by weight.
6. the manufacture method of high-visibility waterproof cladding as claimed in claim 5, the wherein poly- carbonic acid tree of liquid type The viscosity of fat is 1800~2200cps, and the viscosity of the two-liquid type polycarbonate resin is 3000~5000cps, , should and the fluorescent color is interior heat curing-type polyamide (polyamide) resin fine powder containing fluorescent colorant White cream is titanium dioxide or polyurethane, and the lubrication prescription is silica flour, and the fire retardant is antimony oxide or ten bromines Diphenyl oxide, the antibacterial mildew inhibitor is nano-silver ionic.
7. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein first coating fluid is by this One liquid type polycarbonate resin, the lubrication prescription and fluorescent color stirring are mixed to form, and incorporation time is 5~20 Minute, mixing temperature is 20 to 50 DEG C.
8. the painting of the manufacture method, wherein first coating fluid of high-visibility waterproof cladding as claimed in claim 1 Mode for cloth is to utilize roller scraper or the scraper that swims.
9. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein the surface layer is heated In the step of drying, heating-up temperature is 100~170 DEG C, and the heat time is 30~120 seconds.
10. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein second coating fluid is by this Two-liquid type polycarbonate resin, the isocyanates bridging agent and the white cream stirring are mixed to form, incorporation time For 5~10 minutes, mixing temperature was 20 to 50 DEG C.
11. the painting of the manufacture method, wherein second coating fluid of high-visibility waterproof cladding as claimed in claim 1 Mode for cloth is to utilize roller scraper or the scraper that swims.
12. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein the following layer is added In the step of heat drying, heating-up temperature is 100~170 DEG C, and the heat time is 80~120 seconds.
13. the manufacture method of high-visibility waterproof cladding as claimed in claim 1, wherein the base fabric is fitted in into this After the step of following layer, further include that 24 are carried out in the ripening chamber that temperature is 40 DEG C, humidity is 50% is small When maturation.
CN201610117779.4A 2016-03-02 2016-03-02 The manufacture method of high-visibility waterproof cladding Pending CN107151920A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110116520A (en) * 2019-05-14 2019-08-13 东莞顺裕纸业有限公司 A kind of manufacture craft of the composite corrugated paper of waterproof antimildew and antibacterial
CN111519441A (en) * 2020-04-23 2020-08-11 罗莱生活科技股份有限公司 Skin-care coating and preparation method and application thereof
WO2022039607A1 (en) * 2020-08-19 2022-02-24 SANWIL POLSKA Sp. z o.o. A method for manufacturing coated fabrics using water-based or solvent-free, voc-free polyurethanes and a fabric obtained using this method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110116520A (en) * 2019-05-14 2019-08-13 东莞顺裕纸业有限公司 A kind of manufacture craft of the composite corrugated paper of waterproof antimildew and antibacterial
CN111519441A (en) * 2020-04-23 2020-08-11 罗莱生活科技股份有限公司 Skin-care coating and preparation method and application thereof
WO2022039607A1 (en) * 2020-08-19 2022-02-24 SANWIL POLSKA Sp. z o.o. A method for manufacturing coated fabrics using water-based or solvent-free, voc-free polyurethanes and a fabric obtained using this method

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Application publication date: 20170912