CN107151133A - A kind of blue bricks in building in the style of the ancients and preparation method thereof - Google Patents

A kind of blue bricks in building in the style of the ancients and preparation method thereof Download PDF

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CN107151133A
CN107151133A CN201710418937.4A CN201710418937A CN107151133A CN 107151133 A CN107151133 A CN 107151133A CN 201710418937 A CN201710418937 A CN 201710418937A CN 107151133 A CN107151133 A CN 107151133A
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parts
water
building
style
blue bricks
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刘东升
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Hefei Moon New Decorative Material Co Ltd
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Hefei Moon New Decorative Material Co Ltd
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    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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    • C03C13/06Mineral fibres, e.g. slag wool, mineral wool, rock wool
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Abstract

The invention discloses blue bricks in a kind of building in the style of the ancients and preparation method thereof, it is related to blue bricks technical field, includes the raw material of following part meter:200 ~ 300 parts of 80 ~ 90 parts of cement, 60 ~ 70 parts of flyash, 50 ~ 60 parts of riverway sludge, 45 ~ 55 parts of solid waste fibre stuff, 10 ~ 25 parts of sand, 10 ~ 15 parts of iron oxide black, 10 ~ 15 parts of iron oxide green, 2 ~ 10 parts of chicken girt, 2 ~ 10 parts of Calcium Carbide Ash, 1 ~ 8 part of reinforcing agent, 1 ~ 6 part of water proof anticorrusion agent, 2 ~ 7 parts of sintering aid and water.Of the invention rationally to utilize resource, preparation method is simple, reduces cost, the blue bricks compression strength prepared is good, freezing and thawing performance is excellent.

Description

A kind of blue bricks in building in the style of the ancients and preparation method thereof
Technical field
The present invention relates to blue bricks technical field, and in particular to blue bricks in a kind of building in the style of the ancients and preparation method thereof.
Background technology
Blue bricks is the building ceramics that China's Gu has, and is also the embodiment of China's architectural culture, building materials are used as with blue bricks Building has traditional Chinese culture characteristic;At present, have in the prior art and make brick by adding industrial chemicals using white china clay Base, is fired using high-temperature oxydation flame and obtains ancient blue bricks, but white china clay is non-renewable resources, and mineral resources distributional region compared with By force, cost of winning is higher, most of when using and trans-regional transport, adds cost of transportation;Another method is to utilize iron content Matter clay base, is fired using reducing flame kiln, but because clay loss is more, national policy, which has limited to exploit it, to be made With this method is faced without the desirable present situation of soil.
The content of the invention
It is an object of the invention to provide blue bricks in a kind of building in the style of the ancients and preparation method thereof, rationally using resource, prepare Method is simple, reduces cost, the blue bricks compression strength prepared is good, freezing and thawing performance is excellent.
The invention provides following technical scheme:A kind of blue bricks in building in the style of the ancients, includes the raw material of following part meter:Water 80 ~ 90 parts of mud, 60 ~ 70 parts of flyash, 50 ~ 60 parts of riverway sludge, 45 ~ 55 parts of solid waste fibre stuff, 10 ~ 25 parts of sand, 10 ~ 15 parts of iron oxide black, 10 ~ 15 parts of iron oxide green, 2 ~ 10 parts of chicken girt, 2 ~ 10 parts of Calcium Carbide Ash, 1 ~ 8 part of reinforcing agent, water-tight corrosion-proof 200 ~ 300 parts of 1 ~ 6 part of agent, 2 ~ 7 parts of sintering aid and water;
The solid waste fibre stuff includes the raw material that following part is counted:10 ~ 25 parts of organic fiber, industrial solid castoff 8 ~ 10 ~ 20 parts of 15 parts, 1 ~ 3 part of sodium hydrate aqueous solution, 1 ~ 3 part of the modified starch aqueous solution and water.
Preferably, the raw material of following part meter is included:85 parts of cement, 65 parts of flyash, 55 parts of riverway sludge, solid waste 50 parts of fibre stuff, 18 parts of sand, 12.5 parts of iron oxide black, 12.5 parts of iron oxide green, 6 parts of chicken girt, 6 parts of Calcium Carbide Ash, reinforcing agent 4.5 Part, 3.5 parts of water proof anticorrusion agent, 4.5 parts of sintering aid and 250 parts of water;
The solid waste fibre stuff includes the raw material that following part is counted:18 parts of organic fiber, 11 parts of industrial solid castoff, 15 parts of 2 parts of sodium hydrate aqueous solution, 2 parts of the modified starch aqueous solution and water.
Preferably, the cement is any in Portland cement, alumina cement, alumina cement and aluminate cement Kind.
Preferably, the riverway sludge is the sticky mud after sludge dewatering equipment carries out removal of impurities dewater treatment, and is contained The control of water rate is 20 ~ 30%.
Preferably, the reinforcing agent is calcium chloride or sodium metasilicate.
Preferably, the water proof anticorrusion agent includes the raw material of following parts by weight:2 ~ 3 parts of oleic acid, polyvinyl alcohol 0.2 ~ 1.2 0.1 ~ 0.3 part of part, 0.6 ~ 0.8 part of surfactant and corrosion inhibitor, the corrosion inhibitor are phosphate, and the surface is lived Property agent be monoglyceride.
Preferably, the sintering aid is TiO2Micro mist, MgO micro mists, Cr2O3Micro mist, MgF2Micro mist and AlF3Appointing in micro mist It is a kind of.
Preferably, the industrial solid castoff is any of Iron-ore Slag, slag, industrial and mineral flue dust and waste mining rock Or it is several, the organic fiber is any of wood-fibred slurry, grass fiber slurry, mixed plant fiber pulp and secondary stock or several Kind.
The present invention also provides a kind of preparation method of the blue bricks in building in the style of the ancients, comprises the following steps:
(1), prepare solid waste fibre stuff
Weigh in industrial solid castoff, input melting furnace, it is 800 ~ 1200 DEG C to control ignition temperature, is melt into slurry, will be into slurry Raw material afterwards is imported in fiberizer, generates preliminary inorfil and the preliminary inorfil is imported into fine room and screen;
Inorfil after screening is delivered to dispersion machine, under the momentum effect of water inlet, the length formed needed for inorfil, takes Mix, be added to the water with organic fiber, sodium hydrate aqueous solution and the modified starch aqueous solution after going out, obtain described after being uniformly dispersed Solid waste fibre stuff, it is standby;
(2), raw material mixing
Weigh surplus stock and step(1)Obtained solid waste fibre stuff is well mixed and obtains mixed material;
(3), it is compressing
Using forcing press to step(2)Mixed material it is compressing, the press time be 5~10s, obtain semi-finished product;
(4), maintenance
By step(3)Semi-finished product after compacting are placed in water vapour maintenance of equipment, use water vapor pressure under 0.8 ~ 1.1MPa, Maintenance processing 1~3 day;
(5), high-temperature calcination
By step(4)Semi-finished product after maintenance carry out high-temperature calcination processing, and calcining heat is 800~1200 DEG C, during high-temperature calcination Between be 10 ~ 20h, the blue bricks in the building in the style of the ancients is obtained after calcining.
Beneficial effects of the present invention:Resource is rationally utilized, preparation method is simple, reduces cost, the blue bricks resistance to compression prepared Intensity is good, freezing and thawing performance is excellent, specific as follows:
(1), the present invention blue bricks compare traditional blue bricks, surface is brighter and cleaner, more resistant to soda acid, freeze-thawing resistant, and growth over time, Brick body is colour-fast, and more aobvious glossy further as season drying and watering cycle alternating action, darker, ancient charm is full;
(2), the riverway sludge that adds in the present invention, substitute clay resource and white china clay, solve blue bricks in the prior art former The problem of expecting to cause resource scarcity and high Mining Transport cost for non-renewable resources, also achieves solid waste silt in addition The added value of mud is utilized, and is solved and is largely banked up the problem of occupying cultivated land after solid waste sludge pollution environment and desilting;
(3), add industrial solid castoff in the present invention, not only solve this kind of solid waste process problem, and save log Expend, reduce cost, protect the forest reserves, obtained solid waste fibre stuff has water resistance, corrosion resistance and resistance Combustion property;
(4), the present invention using the material such as cement, flyash, riverway sludge and solid waste fibre stuff, not only fundamentally Pollution is prevented, and can effectively utilize waste resource, turns waste into wealth, meets low-carbon economy requirement;
(5), the present invention pass through proportioning combination and the control of each technological parameter to raw material, fragment of brick exquisite in texture, exquisite appearance are raw The environmental protection of production process, energy consumption are low, and traditional blue bricks is conveniently superior in intensity, flatness, color and luster, frost resistance etc..
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.
Embodiment 1
A kind of blue bricks in building in the style of the ancients, includes the raw material of following part meter:80 parts of cement, 60 parts of flyash, 50 parts of riverway sludge, 45 parts of solid waste fibre stuff, 10 parts of sand, 10 parts of iron oxide black, 10 parts of iron oxide green, 2 parts of chicken girt, 2 parts of Calcium Carbide Ash, increasing Strong 200 parts of 1 part of agent, 1 part of water proof anticorrusion agent, 2 parts of sintering aid and water;
The solid waste fibre stuff includes the raw material that following part is counted:10 parts of organic fiber, 8 parts of industrial solid castoff, 10 parts of 1 part of sodium hydrate aqueous solution, 1 part of the modified starch aqueous solution and water.
Wherein, the cement is Portland cement, and the riverway sludge is to carry out removal of impurities by sludge dewatering equipment to take off Sticky mud after water process, and moisture control is 20%.
Wherein, the reinforcing agent is calcium chloride, and the water proof anticorrusion agent includes the raw material of following parts by weight:It is 2 parts of oleic acid, poly- 0.1 part of 0.2 part of vinyl alcohol, 0.6 part of surfactant and corrosion inhibitor, the corrosion inhibitor are phosphate, the surface Activating agent is monoglyceride.
Wherein, the sintering aid is TiO2Micro mist, the industrial solid castoff is Iron-ore Slag, and the organic fiber is wood Fiber pulp.
A kind of preparation method of blue bricks in building in the style of the ancients is also provided in the present embodiment, comprised the following steps:
(1), prepare solid waste fibre stuff
Weigh industrial solid castoff, in input melting furnace, control ignition temperature for 800 DEG C, be melt into slurry, by into the original after slurry Material is imported in fiberizer, generates preliminary inorfil and the preliminary inorfil is imported into fine room and screen;
Inorfil after screening is delivered to dispersion machine, under the momentum effect of water inlet, the length formed needed for inorfil, takes Mix, be added to the water with organic fiber, sodium hydrate aqueous solution and the modified starch aqueous solution after going out, obtain described after being uniformly dispersed Solid waste fibre stuff, it is standby;
(2), raw material mixing
Weigh surplus stock and step(1)Obtained solid waste fibre stuff is well mixed and obtains mixed material;
(3), it is compressing
Using forcing press to step(2)Mixed material it is compressing, the press time is 5s, obtains semi-finished product;
(4), maintenance
By step(3)Semi-finished product after compacting are placed in water vapour maintenance of equipment, use water vapor pressure under 0.8MPa, to conserve Processing 1 day;
(5), high-temperature calcination
By step(4)Semi-finished product after maintenance carry out high-temperature calcination processing, and calcining heat is 800 DEG C, and the high-temperature calcination time is The blue bricks in the building in the style of the ancients is obtained after 10h, calcining.
Embodiment 2
A kind of blue bricks in building in the style of the ancients, includes the raw material of following part meter:90 parts of cement, 70 parts of flyash, 60 parts of riverway sludge, 55 parts of solid waste fibre stuff, 25 parts of sand, 15 parts of iron oxide black, 15 parts of iron oxide green, 10 parts of chicken girt, 10 parts of Calcium Carbide Ash, 300 parts of 8 parts of reinforcing agent, 6 parts of water proof anticorrusion agent, 7 parts of sintering aid and water;
The solid waste fibre stuff includes the raw material that following part is counted:25 parts of organic fiber, 15 parts of industrial solid castoff, 20 parts of 3 parts of sodium hydrate aqueous solution, 3 parts of the modified starch aqueous solution and water.
Wherein, the cement is alumina cement, and the riverway sludge is to carry out removal of impurities dewater treatment by sludge dewatering equipment Sticky mud afterwards, and moisture control is 30%.
Wherein, the reinforcing agent is calcium chloride or sodium metasilicate.
Wherein, the water proof anticorrusion agent includes the raw material of following parts by weight:3 parts of oleic acid, 1.2 parts of polyvinyl alcohol, surface are lived Property 0.8 part of agent and 0.3 part of corrosion inhibitor, the corrosion inhibitor is phosphate, and the surfactant is monoglyceride.
Wherein, the sintering aid is MgO micro mists, and the industrial solid castoff is slag, and the organic fiber is fine for grass Dimension slurry.
The present embodiment also provides a kind of preparation method of the blue bricks in building in the style of the ancients, comprises the following steps:
(1), prepare solid waste fibre stuff
Weigh industrial solid castoff, in input melting furnace, control ignition temperature for 1200 DEG C, be melt into slurry, by into after slurry Raw material is imported in fiberizer, generates preliminary inorfil and the preliminary inorfil is imported into fine room and screen;
Inorfil after screening is delivered to dispersion machine, under the momentum effect of water inlet, the length formed needed for inorfil, takes Mix, be added to the water with organic fiber, sodium hydrate aqueous solution and the modified starch aqueous solution after going out, obtain described after being uniformly dispersed Solid waste fibre stuff, it is standby;
(2), raw material mixing
Weigh surplus stock and step(1)Obtained solid waste fibre stuff is well mixed and obtains mixed material;
(3), it is compressing
Using forcing press to step(2)Mixed material it is compressing, the press time is 10s, obtains semi-finished product;
(4), maintenance
By step(3)Semi-finished product after compacting are placed in water vapour maintenance of equipment, use water vapor pressure under 1.1MPa, to conserve Processing 3 days;
(5), high-temperature calcination
By step(4)Semi-finished product after maintenance carry out high-temperature calcination processing, and calcining heat is 1200 DEG C, and the high-temperature calcination time is The blue bricks in the building in the style of the ancients is obtained after 20h, calcining.
Embodiment 3
A kind of blue bricks in building in the style of the ancients, includes the raw material of following part meter:85 parts of cement, 65 parts of flyash, 55 parts of riverway sludge, 50 parts of solid waste fibre stuff, 18 parts of sand, 12.5 parts of iron oxide black, 12.5 parts of iron oxide green, 6 parts of chicken girt, Calcium Carbide Ash 6 Part, 4.5 parts of reinforcing agent, 3.5 parts of water proof anticorrusion agent, 4.5 parts of sintering aid and 250 parts of water;
The solid waste fibre stuff includes the raw material that following part is counted:18 parts of organic fiber, 11 parts of industrial solid castoff, 15 parts of 2 parts of sodium hydrate aqueous solution, 2 parts of the modified starch aqueous solution and water.
Wherein, the cement is alumina cement, and the riverway sludge is to carry out removal of impurities dewater treatment by sludge dewatering equipment Sticky mud afterwards, and moisture control is 25%.
Wherein, the reinforcing agent is sodium metasilicate, and the water proof anticorrusion agent includes the raw material of following parts by weight:2.5 parts of oleic acid, 0.2 part of 1 part of polyvinyl alcohol, 0.7 part of surfactant and corrosion inhibitor, the corrosion inhibitor are phosphate, the surface Activating agent is monoglyceride.
Wherein, the sintering aid is Cr2O3Micro mist.
Wherein, the industrial solid castoff is industrial and mineral flue dust, and the organic fiber is mixed plant fiber pulp.
The present embodiment also provides a kind of preparation method of the blue bricks in building in the style of the ancients, comprises the following steps:
(1), prepare solid waste fibre stuff
Weigh industrial solid castoff, in input melting furnace, control ignition temperature for 1000 DEG C, be melt into slurry, by into after slurry Raw material is imported in fiberizer, generates preliminary inorfil and the preliminary inorfil is imported into fine room and screen;
Inorfil after screening is delivered to dispersion machine, under the momentum effect of water inlet, the length formed needed for inorfil, takes Mix, be added to the water with organic fiber, sodium hydrate aqueous solution and the modified starch aqueous solution after going out, obtain described after being uniformly dispersed Solid waste fibre stuff, it is standby;
(2), raw material mixing
Weigh surplus stock and step(1)Obtained solid waste fibre stuff is well mixed and obtains mixed material;
(3), it is compressing
Using forcing press to step(2)Mixed material it is compressing, the press time is 7s, obtains semi-finished product;
(4), maintenance
By step(3)Semi-finished product after compacting are placed in water vapour maintenance of equipment, use water vapor pressure under 1.0MPa, to conserve Processing 2 days;
(5), high-temperature calcination
By step(4)Semi-finished product after maintenance carry out high-temperature calcination processing, and calcining heat is 1000 DEG C, and the high-temperature calcination time is The blue bricks in the building in the style of the ancients is obtained after 15h, calcining
The preparation method of the modified starch aqueous solution is in embodiment 1 ~ 3:According to 80:10:5 ratio weighs starch, sodium citrate And sodium ethylene diamine tetracetate, it is added to the water and heats, heating and temperature control is 55 ~ 60 DEG C, dissolving 50 ~ 60min of stirring is cooled to 10 ~ 25 DEG C obtain starch milk;Then, weigh aqueous slkali to be slowly added in foregoing obtained starch milk, the pH of regulation starch milk is 12.0 ~ 12.2, sodium trimetaphosphate is then added, 20 ~ 50min of reaction under the conditions of 30 ~ 50 DEG C is well mixed, acetic acid is then added dropwise Acid anhydride, the pH value of starch milk is adjusted to after 8.2 ~ 8.3, completion of dropping, and 10 ~ 20min of stirring reaction adds water and obtains modified starch water Solution.
The present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention Protection domain within.

Claims (9)

1. a kind of blue bricks in building in the style of the ancients, it is characterised in that the raw material counted including following part:80 ~ 90 parts of cement, flyash 60 ~ 70 parts, 50 ~ 60 parts of riverway sludge, 45 ~ 55 parts of solid waste fibre stuff, 10 ~ 25 parts of sand, 10 ~ 15 parts of iron oxide black, oxygen Change green 10 ~ 15 parts of iron, 2 ~ 10 parts of chicken girt, 2 ~ 10 parts of Calcium Carbide Ash, 1 ~ 8 part of reinforcing agent, 1 ~ 6 part of water proof anticorrusion agent, 2 ~ 7 parts of sintering aid With 200 ~ 300 parts of water;
The solid waste fibre stuff includes the raw material that following part is counted:10 ~ 25 parts of organic fiber, industrial solid castoff 8 ~ 10 ~ 20 parts of 15 parts, 1 ~ 3 part of sodium hydrate aqueous solution, 1 ~ 3 part of the modified starch aqueous solution and water.
2. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the raw material counted including following part:Cement 85 parts, 65 parts of flyash, 55 parts of riverway sludge, 50 parts of solid waste fibre stuff, 18 parts of sand, 12.5 parts of iron oxide black, oxygen Change green 12.5 parts of iron, 6 parts of chicken girt, 6 parts of Calcium Carbide Ash, 4.5 parts of reinforcing agent, 3.5 parts of water proof anticorrusion agent, 4.5 parts of sintering aid and water 250 Part;
The solid waste fibre stuff includes the raw material that following part is counted:18 parts of organic fiber, 11 parts of industrial solid castoff, 15 parts of 2 parts of sodium hydrate aqueous solution, 2 parts of the modified starch aqueous solution and water.
3. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the cement is normal silicate water Any of mud, alumina cement, alumina cement and aluminate cement.
4. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the riverway sludge is to be taken off by sludge Water dispenser carries out the sticky mud after removal of impurities dewater treatment, and moisture control is 20 ~ 30%.
5. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the reinforcing agent is calcium chloride or silicon Sour sodium.
6. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the water proof anticorrusion agent includes following heavy Measure the raw material of part:2 ~ 3 parts of oleic acid, 0.2 ~ 1.2 part of polyvinyl alcohol, 0.6 ~ 0.8 part of surfactant and corrosion inhibitor 0.1 ~ 0.3 Part, the corrosion inhibitor is phosphate, and the surfactant is monoglyceride.
7. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the sintering aid is TiO2Micro mist, MgO Micro mist, Cr2O3Micro mist, MgF2Micro mist and AlF3Any of micro mist.
8. the blue bricks in building in the style of the ancients according to claim 1, it is characterised in that the industrial solid castoff is iron ore Any of slag, slag, industrial and mineral flue dust and waste mining rock are several, the organic fiber is starched for wood-fibred, grass fiber is starched, Any of mixed plant fiber pulp and secondary stock are several.
9. a kind of preparation method of the blue bricks in building in the style of the ancients according to any one of claim 1 ~ 8, it is characterised in that bag Include following steps:
(1), prepare solid waste fibre stuff
Weigh in industrial solid castoff, input melting furnace, it is 800 ~ 1200 DEG C to control ignition temperature, is melt into slurry, will be into slurry Raw material afterwards is imported in fiberizer, generates preliminary inorfil and the preliminary inorfil is imported into fine room and screen;
Inorfil after screening is delivered to dispersion machine, under the momentum effect of water inlet, the length formed needed for inorfil, takes Mix, be added to the water with organic fiber, sodium hydrate aqueous solution and the modified starch aqueous solution after going out, obtain described after being uniformly dispersed Solid waste fibre stuff, it is standby;
(2), raw material mixing
Weigh surplus stock and step(1)Obtained solid waste fibre stuff is well mixed and obtains mixed material;
(3), it is compressing
Using forcing press to step(2)Mixed material it is compressing, the press time be 5~10s, obtain semi-finished product;
(4), maintenance
By step(3)Semi-finished product after compacting are placed in water vapour maintenance of equipment, use water vapor pressure under 0.8 ~ 1.1MPa, Maintenance processing 1~3 day;
(5), high-temperature calcination
By step(4)Semi-finished product after maintenance carry out high-temperature calcination processing, and calcining heat is 800~1200 DEG C, during high-temperature calcination Between be 10 ~ 20h, the blue bricks in the building in the style of the ancients is obtained after calcining.
CN201710418937.4A 2017-06-06 2017-06-06 A kind of blue bricks in building in the style of the ancients and preparation method thereof Withdrawn CN107151133A (en)

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CN108046760A (en) * 2018-01-29 2018-05-18 大连民族大学 A kind of preparation method of environment-friendly imitation ancient building heat preservation and decoration of outer wall blue bricks
CN108249840A (en) * 2018-01-25 2018-07-06 广西亿品投资有限公司 Pavior brick modelled after an antique and preparation method thereof
CN108560806A (en) * 2018-05-22 2018-09-21 深圳市绿志新型建材研究院有限公司 A kind of baking-free imitation of ancient blue bricks and preparation method thereof
CN109020460A (en) * 2018-08-31 2018-12-18 陈毅忠 A kind of preparation method of compound grass-planting brick raw material
CN110723961A (en) * 2019-09-23 2020-01-24 广东莞绿环保工程有限公司 Environment-friendly microporous brick prepared by comprehensively utilizing solid wastes and preparation method thereof
CN111943655A (en) * 2020-08-25 2020-11-17 自贡新雄风陶瓷制造有限公司 Formula and preparation method of black brick
CN114620993A (en) * 2022-03-14 2022-06-14 浙江广厦建设职业技术大学 Preparation method of high-strength grey brick for ancient building restoration

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CN102587195A (en) * 2012-03-08 2012-07-18 厦门市特纤机械设备有限公司 Industrial solid waste fiber paper slurry as well as making method and application thereof
CN104016629A (en) * 2014-06-23 2014-09-03 黎思俊 Antique black brick and manufacturing method thereof
CN104230201A (en) * 2013-06-09 2014-12-24 王广茂 Waterproof anticorrosion agent for cement mortar and concrete and preparation thereof

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CN102503264A (en) * 2011-10-20 2012-06-20 上海交通大学 Composition taking silt as raw material as well as construction material prepared by utilizing composition and method thereof
CN102587195A (en) * 2012-03-08 2012-07-18 厦门市特纤机械设备有限公司 Industrial solid waste fiber paper slurry as well as making method and application thereof
CN104230201A (en) * 2013-06-09 2014-12-24 王广茂 Waterproof anticorrosion agent for cement mortar and concrete and preparation thereof
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Publication number Priority date Publication date Assignee Title
CN108249840A (en) * 2018-01-25 2018-07-06 广西亿品投资有限公司 Pavior brick modelled after an antique and preparation method thereof
CN108046760A (en) * 2018-01-29 2018-05-18 大连民族大学 A kind of preparation method of environment-friendly imitation ancient building heat preservation and decoration of outer wall blue bricks
CN108560806A (en) * 2018-05-22 2018-09-21 深圳市绿志新型建材研究院有限公司 A kind of baking-free imitation of ancient blue bricks and preparation method thereof
CN109020460A (en) * 2018-08-31 2018-12-18 陈毅忠 A kind of preparation method of compound grass-planting brick raw material
CN109020460B (en) * 2018-08-31 2021-09-24 陈毅忠 Preparation method of composite grass planting brick raw material
CN110723961A (en) * 2019-09-23 2020-01-24 广东莞绿环保工程有限公司 Environment-friendly microporous brick prepared by comprehensively utilizing solid wastes and preparation method thereof
CN111943655A (en) * 2020-08-25 2020-11-17 自贡新雄风陶瓷制造有限公司 Formula and preparation method of black brick
CN114620993A (en) * 2022-03-14 2022-06-14 浙江广厦建设职业技术大学 Preparation method of high-strength grey brick for ancient building restoration

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Application publication date: 20170912