CN107142793A - Environment-friendly antibacterial wallpaper - Google Patents
Environment-friendly antibacterial wallpaper Download PDFInfo
- Publication number
- CN107142793A CN107142793A CN201710540751.6A CN201710540751A CN107142793A CN 107142793 A CN107142793 A CN 107142793A CN 201710540751 A CN201710540751 A CN 201710540751A CN 107142793 A CN107142793 A CN 107142793A
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- Prior art keywords
- parts
- environment
- bamboo fibre
- pvc
- friendly type
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- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 39
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 39
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 39
- 239000011425 bamboo Substances 0.000 claims abstract description 39
- 239000000835 fiber Substances 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims abstract description 37
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 229960000892 attapulgite Drugs 0.000 claims abstract description 17
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 17
- 239000003063 flame retardant Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000006260 foam Substances 0.000 claims abstract description 13
- 239000004088 foaming agent Substances 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 11
- 239000003549 soybean oil Substances 0.000 claims abstract description 11
- 229920002907 Guar gum Polymers 0.000 claims abstract description 9
- 239000000665 guar gum Substances 0.000 claims abstract description 9
- 229960002154 guar gum Drugs 0.000 claims abstract description 9
- 235000010417 guar gum Nutrition 0.000 claims abstract description 9
- 238000004049 embossing Methods 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 52
- 241001330002 Bambuseae Species 0.000 claims description 38
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 230000003115 biocidal effect Effects 0.000 claims description 19
- 125000006487 butyl benzyl group Chemical group 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 12
- 241000894006 Bacteria Species 0.000 claims description 11
- 238000000855 fermentation Methods 0.000 claims description 10
- 230000004151 fermentation Effects 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 239000000084 colloidal system Substances 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- 239000001069 triethyl citrate Substances 0.000 claims description 5
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000013769 triethyl citrate Nutrition 0.000 claims description 5
- 235000010290 biphenyl Nutrition 0.000 claims description 4
- 239000004305 biphenyl Substances 0.000 claims description 4
- 125000006267 biphenyl group Chemical group 0.000 claims description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- IGEXLRPUBMSKGX-UHFFFAOYSA-N [O]C(O)(O)O Chemical group [O]C(O)(O)O IGEXLRPUBMSKGX-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical group [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 244000082204 Phyllostachys viridis Species 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- UCVPKAZCQPRWAY-UHFFFAOYSA-N dibenzyl benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC=2C=CC=CC=2)C=1C(=O)OCC1=CC=CC=C1 UCVPKAZCQPRWAY-UHFFFAOYSA-N 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000007639 printing Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 244000303965 Cyamopsis psoralioides Species 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000013016 damping Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- -1 trihydroxy methyl phosphorous Chemical compound 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
- D21H19/68—Coatings characterised by a special visual effect, e.g. patterned, textured uneven, broken, discontinuous
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environment-friendly antibacterial wallpaper which is prepared by coating PVC paste on base paper and the base paper, heating, embossing and printing patterns, wherein the PVC paste comprises the following raw materials: PVC 450 resin powder, modified attapulgite powder, modified bamboo fiber, nano titanium dioxide, nano barium sulfate, guar gum, polyacrylate, epoxidized soybean oil, benzyl phthalate, a dispersing agent, a foaming agent, a foam stabilizer and a flame retardant. The preparation method comprises adding water into the raw materials, stirring, mixing, and grinding. The PVC paste on the antibacterial wallpaper is simple to prepare and low in production cost, and finished wallpaper using the PVC paste has good flame retardance, heat insulation and sound absorption properties, humidity adjustment and antibacterial properties, and is suitable for popularization and application.
Description
Technical field
The present invention relates to New Building Materials metal field, and in particular to a kind of environment-friendly type antibiotic wallpaper.
Background technology
Wallpaper, also known as wallpaper, with color and figure line design combine be characterized, expressive force infinitely enrich, can convenient satisfaction it is many
The indoor wall ornament materials of sample individual character esthetic requirement and fashion demand, is current international and domestic most popular indoor wall dress
Exterior material.Wallpaper is the same with other ornament materials, is constantly sent out with the development of World Economics culture and the demand of human lives
Exhibition varies, and the PVC paste material that basic unit's paper overlying is applied in wallpaper plays the function affect of key.
In the past, wallpaper came into the life of people as just a kind of decorative material, and people require it many in dicoration
Above aesthetic property, as the improvement of people's living standards, people need to want the wallpaper of high-quality to decorate the life of oneself, people
It is also more and more to other Functional Requirements of wallpaper.With the progress of society and the development of science and technology, people are to living environment
The continuous improvement of comfortableness requirement, in the prior art, it is existing a small amount of on family expenses interior room wallpaper is fire-retardant, heat insulation sound absorbent, damping resist
The features such as bacterium are reported, still, many deficiencies are still there is, accordingly, it would be desirable to improve.
Recessed native powder is a kind of powder of zeopan containing Shuifu County for having chain layer structure, and pH value is in neutral, nontoxic, adsorptivity
Can be strong, unit weight is light, has excellent extensibility, thickening property, thixotropy, levelability, weather resisteant, thermal insulation and environment-friendly type, also has
The characteristics such as higher impact strength, tensile strength, tearing strength, and its sun protection strong, soft constitution is gently a kind of filling out for high-quality
Material, can be applied to various fields, it is modified by particular step, and the various aspects of performance showed is improved, and is applied to ring
Protect in wallpaper material, with product extremely favourable meaning.
The content of the invention
For problems of the prior art, the invention provides a kind of environment-friendly type antibiotic wallpaper, this kind of antibacterial wallpaper
On PVC paste material prepare simple, production cost is low, has good anti-flammability, heat-insulated suction using the finished product wallpaper of the PVC paste material
Sound and damping antibiotic property, suitable popularization and application.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of environment-friendly type antibiotic wallpaper, the wallpaper be by basic unit's paper and basic unit paper overlying apply heated PVC paste material, embossing,
Impressing pattern is made, and the PVC paste material is made including following raw material by weight：70-90 parts of 450 resin-oatmeals of PVC, change
Property recessed native powder 25-35 parts, modified 20-30 parts of bamboo fibre, 10-20 parts of nanometer titanium dioxide, 5-15 parts of nano barium sulfate, guar gum 6-
12 parts, 8-12 parts of polyacrylate, 4-8 parts of epoxidized soybean oil, 4-8 parts of O-phthalic butyl benzyl, 1-5 parts of dispersant, foaming agent
1-5 parts of 1-3 parts, 1-3 parts of foam stabilizer and fire retardant；
The modified attapulgite powder is made by following steps：First recessed native powder is dried in 110-130 DEG C of baking oven, then will
Recessed native powder after drying is put into high-speed kneading machine, adds aluminate coupling agent, 2-4% equivalent to recessed native powder weight 3-5%
Wooden sodium sulfonate, 2-4% triethyl citrate, 1-2% atoleine and 2-4% talcum powder, after mixed at high speed, dry
Dry, attrition grinding is crossed 100-200 mesh sieves and produced.
Further, the PVC paste material is made including following raw material by weight：80 parts of 450 resin-oatmeals of PVC, change
Property recessed native 30 parts of powder, modified 25 parts of bamboo fibre, 15 parts of nanometer titanium dioxide, 10 parts of nano barium sulfate, 9 parts of guar gum, polyacrylic acid
10 parts of ester, 6 parts of epoxidized soybean oil, 6 parts of O-phthalic butyl benzyl, 3 parts of dispersant, 2 parts of foaming agent, 2 parts of foam stabilizer and fire retardant 3
Part.
Preferably, the dispersant is one kind in sodium tripolyphosphate, sodium pyrophosphate or lauryl sodium sulfate.
Preferably, the foaming agent be sodium metasilicate, calcium carbonate, magnesium carbonate or sodium acid carbonate in it is a kind of or a kind of with
On.
Preferably, the foam stabilizer is one kind in silicones polyethers emulsion, polyacrylamide or polyvinyl alcohol.
Preferably, the fire retardant is one or more than one kinds of in trihydroxy methyl phosphorous oxide or diphenyl phosphoester.
Further, the modified bamboo fibre is made by following steps：Bamboo fibre is added water and adjusts water content to 65-
75%, then uniform sprinkling EM bacterium solutions are sprayed on bamboo fibre, EM bacterium solutions consumption is the 3-5% of bamboo fibre weight, builds heap fermentation,
Under the environment temperature of 24-28 DEG C of temperature, ferment 3-5 days, the bamboo fibre after fermentation, which is put to dry to moisture at 75-85 DEG C, to exist
Less than 3%, ground 100-200 mesh sieves are produced.
The preparation method of above-mentioned PVC paste material comprises the following steps：
(1) raw material is weighed by the weight；
(2) first by the resin-oatmeals of PVC 450, modified attapulgite powder, modified bamboo fibre, nanometer titanium dioxide, nano barium sulfate, Guar
Glue, polyacrylate, epoxidized soybean oil and O-phthalic butyl benzyl, which are delivered in electrical heating stirring tank, adds its gross weight 8-
12% deionized water is stirred mixing processing, and whipping temp is 42-48 DEG C, and speed of agitator is 200-400r/min, stirring
Time is 25-35min, obtains material A；
(3) surplus stock is delivered in electrical heating stirring tank again and handled with material mixing, whipping temp is 45-55
DEG C, speed of agitator is 300-500r/min, and mixing time is 15-25min, obtains material B；
(4) material B is delivered in Multifunction colloid mill and is ground processing, finally cross 180-220 mesh sieves.
The present invention has following beneficial effect：
(1) wallpaper environmental protection of the invention, safety non-toxic, free from extraneous odour, its internal PVC paste material prepare it is simple and convenient, into
This low, suitable popularization and application；
(2) wallpaper PVC paste material of the invention is made in it by adding modified attapulgite powder and modified bamboo fibre in the feed
Portion's structure sheaf is in a large amount of stable and firm closure micropores, and then finished product wallpaper has good heat insulation sound absorbent and the work(of damping
Can, with excellent adsorptivity, the entomogenous fungi of wallpaper surface can be effectively absorbed, indoor environmental quality is improved；
(3) wallpaper PVC paste material shear bond strength of the invention is high, and service life is long, can with excellent flame retardant effect
It is not on fire for a long time with naked light calcination to reach B1 flame retardant standards, naked light is disconnected remove after can stop burning in 5 seconds, raising is known clearly
The security of indoor electric fire.
Embodiment
The embodiment of the present invention is further described with reference to embodiment, following examples are only used for more
Technical scheme is clearly demonstrated, and can not be limited the scope of the invention with this.
Embodiment 1
A kind of environment-friendly type antibiotic wallpaper, the wallpaper be by basic unit's paper and basic unit paper overlying apply heated PVC paste material, embossing,
Impressing pattern is made, and the PVC paste material is made including following raw material：The resin-oatmeal 70kg of PVC 450, modified attapulgite powder 25kg, change
Property bamboo fibre 20kg, nanometer titanium dioxide 10kg, nano barium sulfate 5kg, guar gum 6kg, polyacrylate 8kg, epoxidized soybean oil
4kg, O-phthalic butyl benzyl 4kg, dispersant 1kg, foaming agent 1kg, foam stabilizer 1kg and fire retardant 1kg；
The modified attapulgite powder is made by following steps：First recessed native powder is dried in 110 DEG C of baking ovens, then will drying
Recessed native powder afterwards is put into high-speed kneading machine, adds aluminate coupling agent, 2% wooden sulphur equivalent to recessed native powder weight 3%
After sour sodium, 2% triethyl citrate, 1% atoleine and 2% talcum powder, mixed at high speed, drying, attrition grinding mistake
100 mesh sieves are produced.
Wherein, above-mentioned dispersant uses sodium tripolyphosphate；Foaming agent uses sodium metasilicate；Foam stabilizer uses silicones polyethers
Emulsion；Fire retardant uses trihydroxy methyl phosphorous oxide.
Above-mentioned modification bamboo fibre is made by following steps：Bamboo fibre is added water into regulation water content to 65%, then in bamboo
Uniform sprinkling EM bacterium solutions are sprayed on fiber, EM bacterium solutions consumption is the 3% of bamboo fibre weight, heap fermentation is built, in 24 DEG C of ring of temperature
At a temperature of border, ferment 3 days, the bamboo fibre after fermentation, which is put, to be dried at 75 DEG C to moisture below 3%, ground 100 mesh sieve,
Produce.
The preparation method of above-mentioned PVC paste material, is followed the steps below：
(1) first by the resin-oatmeals of PVC 450, modified attapulgite powder, modified bamboo fibre, nanometer titanium dioxide, nano barium sulfate, Guar
Glue, polyacrylate, epoxidized soybean oil and O-phthalic butyl benzyl, which are delivered to, adds its gross weight 8% in electrical heating stirring tank
Deionized water is stirred mixing processing, and whipping temp is 42 DEG C, and speed of agitator is controlled in 200r/min, and mixing time is set as
25min, obtains material A；
(2) surplus stock is delivered in electrical heating stirring tank again and handled with material mixing, whipping temp is 45 DEG C,
Speed of agitator is controlled in 300r/min, and mixing time is set as 15min, obtains material B；
(3) material B is delivered in Multifunction colloid mill and is ground processing, it is that the present invention is made finally to cross 180 mesh sieves
Environment-friendly type antibiotic wallpaper needed for PVC paste material.
Embodiment 2
A kind of environment-friendly type antibiotic wallpaper, the wallpaper be by basic unit's paper and basic unit paper overlying apply heated PVC paste material, embossing,
Impressing pattern is made, and the PVC paste material is made including following raw material：The resin-oatmeal 80kg of PVC 450, modified attapulgite powder 30kg, change
Property bamboo fibre 25kg, nanometer titanium dioxide 15kg, nano barium sulfate 10kg, guar gum 9kg, polyacrylate 10kg, epoxy soybean
Oily 6kg, O-phthalic butyl benzyl 6kg, dispersant 3kg, foaming agent 2kg, foam stabilizer 2kg and fire retardant 3kg；
The modified attapulgite powder is made by following steps：First recessed native powder is dried in 120 DEG C of baking ovens, then will drying
Recessed native powder afterwards is put into high-speed kneading machine, adds aluminate coupling agent, 3% wooden sulphur equivalent to recessed native powder weight 4%
After sour sodium, 3% triethyl citrate, 1.5% atoleine and 3% talcum powder, mixed at high speed, drying, attrition grinding
Cross 150 mesh sieves.
Wherein, above-mentioned dispersant uses sodium pyrophosphate；The foaming agent uses two kinds of mixtures of calcium carbonate and magnesium carbonate,
And mass ratio between the two is 1:1；Foam stabilizer uses polyacrylamide；Fire retardant uses diphenyl phosphoester.
Above-mentioned modification bamboo fibre is made by following steps：Bamboo fibre is added water into regulation water content to 70%, then in bamboo
Uniform sprinkling EM bacterium solutions are sprayed on fiber, EM bacterium solutions consumption is the 4% of bamboo fibre weight, heap fermentation is built, in 26 DEG C of ring of temperature
At a temperature of border, ferment 4 days, the bamboo fibre after fermentation, which is put, to be dried at 80 DEG C to moisture below 3%, ground 150 mesh sieve,
Produce.
The preparation method of above-mentioned PVC paste material, is followed the steps below：
(1) first by the resin-oatmeals of PVC 450, modified attapulgite powder, modified bamboo fibre, nanometer titanium dioxide, nano barium sulfate, Guar
Glue, polyacrylate, epoxidized soybean oil and O-phthalic butyl benzyl, which are delivered in electrical heating stirring tank, adds its gross weight 10%
Deionized water be stirred mixing processing, whipping temp is 45 DEG C, and speed of agitator control is in 300r/min, mixing time setting
For 30min, material A is obtained；
(2) surplus stock is delivered in electrical heating stirring tank again and handled with material mixing, whipping temp is 50 DEG C,
Speed of agitator is controlled in 400r/min, and mixing time is set as 20min, obtains material B；
(3) material B is delivered in Multifunction colloid mill and is ground processing, it is that the present invention is made finally to cross 200 mesh sieves
Environment-friendly type antibiotic wallpaper needed for PVC paste material.
Embodiment 3
A kind of environment-friendly type antibiotic wallpaper, the wallpaper be by basic unit's paper and basic unit paper overlying apply heated PVC paste material, embossing,
Impressing pattern is made, and the PVC paste material is made including following raw material：The resin-oatmeal 90kg of PVC 450, modified attapulgite powder 35kg, change
Property bamboo fibre 30kg, nanometer titanium dioxide 20kg, nano barium sulfate 15kg, guar gum 12kg, polyacrylate 12kg, epoxy soybean
Oily 8kg, O-phthalic butyl benzyl 8kg, dispersant 5kg, foaming agent 3kg, foam stabilizer 3kg and fire retardant 5kg；
The modified attapulgite powder is made by following steps：First recessed native powder is dried in 130 DEG C of baking ovens, then will drying
Recessed native powder afterwards is put into high-speed kneading machine, adds aluminate coupling agent, 4% wooden sulphur equivalent to recessed native powder weight 5%
After sour sodium, 4% triethyl citrate, 2% atoleine and 4% talcum powder, mixed at high speed, drying, attrition grinding mistake
200 mesh sieves.
Wherein, above-mentioned dispersant uses lauryl sodium sulfate；The foaming agent uses sodium acid carbonate；Foam stabilizer is used
Polyvinyl alcohol；Fire retardant uses two kinds of mixtures of trihydroxy methyl phosphorous oxide and diphenyl phosphoester, and mass ratio between the two
For 1:2.
Above-mentioned modification bamboo fibre is made by following steps：Bamboo fibre is added water into regulation water content to 75%, then in bamboo
Uniform sprinkling EM bacterium solutions are sprayed on fiber, EM bacterium solutions consumption is the 5% of bamboo fibre weight, heap fermentation is built, in 28 DEG C of ring of temperature
At a temperature of border, ferment 5 days, the bamboo fibre after fermentation, which is put, to be dried at 85 DEG C to moisture below 3%, ground 200 mesh sieve,
Produce.
The preparation method of above-mentioned PVC paste material, is followed the steps below：
(1) first by the resin-oatmeals of PVC 450, modified attapulgite powder, modified bamboo fibre, nanometer titanium dioxide, nano barium sulfate, Guar
Glue, polyacrylate, epoxidized soybean oil and O-phthalic butyl benzyl, which are delivered in electrical heating stirring tank, adds its gross weight 12%
Deionized water be stirred mixing processing, whipping temp is 48 DEG C, and speed of agitator control is in 400r/min, mixing time setting
For 35min, material A is obtained；
(2) surplus stock is delivered in electrical heating stirring tank again and handled with material mixing, whipping temp is 55 DEG C,
Speed of agitator is controlled in 500r/min, and mixing time is set as 25min, obtains material B；
(3) material B is delivered in Multifunction colloid mill and is ground processing, it is that the present invention is made finally to cross 220 mesh sieves
Environment-friendly type antibiotic wallpaper needed for PVC paste material.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of environment-friendly type antibiotic wallpaper, the wallpaper is to apply heated PVC paste material, embossing, print by basic unit's paper and basic unit's paper overlying
Pattern is made, it is characterised in that the PVC paste material is made including following raw material by weight：The resin-oatmeals of PVC 450
70-90 parts, 25-35 parts of modified attapulgite powder, modified 20-30 parts of bamboo fibre, 10-20 parts of nanometer titanium dioxide, nano barium sulfate 5-15
Part, 6-12 parts of guar gum, 8-12 parts of polyacrylate, 4-8 parts of epoxidized soybean oil, 4-8 parts of O-phthalic butyl benzyl, dispersant 1-
1-5 parts of 5 parts, 1-3 parts of foaming agent, 1-3 parts of foam stabilizer and fire retardant；
The modified attapulgite powder is made by following steps：First recessed native powder is dried in 110-130 DEG C of baking oven, then will drying
Recessed native powder afterwards is put into high-speed kneading machine, adds aluminate coupling agent, 2-4% wood equivalent to recessed native powder weight 3-5%
After matter sodium sulfonate, 2-4% triethyl citrate, 1-2% atoleine and 2-4% talcum powder, mixed at high speed, drying,
Attrition grinding is crossed 100-200 mesh sieves and produced.
2. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the PVC paste material includes pressing below
The raw material of parts by weight meter is made：80 parts of 450 resin-oatmeals of PVC, 30 parts of modified attapulgite powder, modified 25 parts of bamboo fibre, nanometer titanium dioxide
15 parts, 10 parts of nano barium sulfate, 9 parts of guar gum, 10 parts of polyacrylate, 6 parts of epoxidized soybean oil, 6 parts of O-phthalic butyl benzyl,
3 parts of 3 parts of dispersant, 2 parts of foaming agent, 2 parts of foam stabilizer and fire retardant.
3. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the dispersant is tripolyphosphate
One kind in sodium, sodium pyrophosphate or lauryl sodium sulfate.
4. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the foaming agent is sodium metasilicate, carbon
It is one or more than one kinds of in sour calcium, magnesium carbonate or sodium acid carbonate.
5. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the foam stabilizer is silicones polyethers
One kind in emulsion, polyacrylamide or polyvinyl alcohol.
6. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the fire retardant is trihydroxy methyl oxygen
It is one or more than one kinds of in change phosphorus or diphenyl phosphoester.
7. a kind of environment-friendly type antibiotic wallpaper according to claim 1, it is characterised in that the modified bamboo fibre passes through following
Step is made：Bamboo fibre is added water into regulation water content to 65-75%, then the uniform sprinkling EM bacterium solutions of sprinkling, EM bacterium on bamboo fibre
Liquid consumption is the 3-5% of bamboo fibre weight, builds heap fermentation, under the environment temperature of 24-28 DEG C of temperature, is fermented 3-5 days, after fermentation
Bamboo fibre put at 75-85 DEG C dry to moisture below 3%, ground 100-200 mesh sieves are produced.
8. a kind of environment-friendly type antibiotic wallpaper according to claim 1-7 any one, it is characterised in that the PVC paste material
Preparation method comprise the following steps：
(1) raw material is weighed by the weight；
(2) first by the resin-oatmeals of PVC 450, modified attapulgite powder, modified bamboo fibre, nanometer titanium dioxide, nano barium sulfate, guar gum,
Polyacrylate, epoxidized soybean oil and O-phthalic butyl benzyl, which are delivered to, adds its gross weight 8-12%'s in electrical heating stirring tank
Deionized water is stirred mixing processing, and whipping temp is 42-48 DEG C, and speed of agitator is 200-400r/min, and mixing time is
25-35min, obtains material A；
(3) surplus stock is delivered in electrical heating stirring tank again and handled with material mixing, whipping temp is 45-55 DEG C,
Speed of agitator is 300-500r/min, and mixing time is 15-25min, obtains material B；
(4) material B is delivered in Multifunction colloid mill and is ground processing, finally cross 180-220 mesh sieves.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710540751.6A CN107142793A (en) | 2017-07-05 | 2017-07-05 | Environment-friendly antibacterial wallpaper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710540751.6A CN107142793A (en) | 2017-07-05 | 2017-07-05 | Environment-friendly antibacterial wallpaper |
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| CN107142793A true CN107142793A (en) | 2017-09-08 |
Family
ID=59785117
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| Application Number | Title | Priority Date | Filing Date |
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| CN107761453A (en) * | 2017-11-17 | 2018-03-06 | 安徽银兔装饰材料有限公司 | Waterproof foam wallpaper and preparation method thereof |
| CN107938393A (en) * | 2017-11-01 | 2018-04-20 | 浙江圣山科纺有限公司 | A kind of Non-water washing pigment printing umbrella cloth |
| CN108384145A (en) * | 2018-02-27 | 2018-08-10 | 合肥尚涵装饰工程有限公司 | A kind of wallpaper PVC paste material and preparation method thereof |
| CN109021455A (en) * | 2018-08-19 | 2018-12-18 | 柳州市家富连装饰有限公司 | A kind of moistureproof and mildewproof PVC wallpaper and preparation method thereof |
| CN110747676A (en) * | 2019-10-31 | 2020-02-04 | 广宁县正达特种纸业有限公司 | Preparation method and application of high-strength adhesive tape |
| CN112095348A (en) * | 2020-08-20 | 2020-12-18 | 安徽紫荆花墙饰材料股份有限公司 | Environment-friendly composite wallpaper with antibacterial and antibacterial properties |
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Application publication date: 20170908 |