CN107142552A - A kind of waterproof composite textile materials and preparation method thereof - Google Patents
A kind of waterproof composite textile materials and preparation method thereof Download PDFInfo
- Publication number
- CN107142552A CN107142552A CN201710531346.8A CN201710531346A CN107142552A CN 107142552 A CN107142552 A CN 107142552A CN 201710531346 A CN201710531346 A CN 201710531346A CN 107142552 A CN107142552 A CN 107142552A
- Authority
- CN
- China
- Prior art keywords
- parts
- ball
- poly
- temperature
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
Abstract
The invention discloses a kind of waterproof composite textile materials and preparation method thereof, it is with Fypro, acrylic fiber, the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate is main component, by adding polyurethanes, triisopropyl phosphite, polyoxylethylene abietate, the different tridecane ester of mono phosphoric acid ester, poly- methyl silicon resin, lauryl sodium sulfate, benzoin ethyl ether, eucalyptus oil, potassium chloride, silane coupler, adhesive, deionized water, it is aided with magnetic agitation, heat up water-bath, ball-milling treatment, it is high-pressure homogeneous, the techniques such as Screw Extrusion, so that the textile material water resistance being prepared from is excellent, waterproof continuation is strong, it disclosure satisfy that the requirement of industry, with preferable application prospect.
Description
Technical field
The present invention relates to textile material technical field, more particularly to a kind of waterproof composite textile materials and preparation method thereof.
Background technology
Textile material refers to fiber and fibre, is embodied in fiber, yarn, fabric and its compound.Modern times are spun
In knitting, the exploitation of the research and development of new textile material, particularly nanofiber and use, breach traditional textile material general
Read.Textile material turns into the important component of soft material, is that study subject is material of weaving using " shape " and its complex form
One of essential characteristic of material.
Traditional textile material is primarily referred to as fiber, and fiber is the elementary cell of textile material.The source of fiber, composition,
Preparation, form, performance are extremely enriched and complexity.In simple terms, fiber is divided into natural fiber and the major class of chemical fibre two.According to fibre
Natural fiber is divided into plant fiber, animal fiber and mineral fiber by the material source attribute of dimension.By raw material, processing side
The difference of method and constituent, can be divided into regenerated fiber, synthetic fibers and the class of inorfil three again.Current chemical fibre is excellent because of its
Different performance occupies the leading of market.But every kind of chemical fibre, while possessing advantage, there is also many deficiencies.
The characteristics of several main chemical fibres are listed below：
Acrylic fibers：Acrylic fiber has the title of artificial wool.With soft, bulk, easy dye, bright in colour, fast light, antibacterial, worm is not afraid of it
The advantages of moth.But it has the disadvantage easy balling-up, electrostatic is easily played, dust is easily adsorbed, wrinkle resistance is poor, and elastic force difference.
Spandex, is the abbreviation of polyurethane fibre, is a kind of elastomer.Spandex can be used for will to meet comfortableness
The clothes for asking needs to stretch, elasticity preferably, there is preferable fast light, acidproof, alkaline-resisting, wearability.It is soft and do not rise
Wrinkle, can remain original profile.But its intensity difference, moisture absorption is poor.
Polyamide fibre, also known as " polyamides fiber ", there are titles such as " nylon " in foreign countries.No matter fiber is in dry state or hygrometric state, all unsuitable
Break, strength is big, it is soft without silk.Great advantage is solid wear-resisting, is optimal one kind.Density is small, and fabric is light, elasticity
Good, endurance destruction, chemical stability is also fine, alkaline-resisting not acidproof.Disadvantage is that sunlight resistance is bad, and fabric shines long will
Turn yellow, intensity declines, and moisture absorption is also bad, but than acrylic fibers, terylene is good.Poor heat resistance, sun-resistant property is poor, there is electrostatic.Terylene, is called
Polyester fiber, knitted polyester fabric is divided into Grade A, goods of inferior quality, third grade product and off standard by its quality good or not.Advantage is bullet
Property it is good and smooth；Wrinkle resistance and good heat preservation performance；Intensity is high, quick-drying washable；It is heat-resist；Light resistance is stable；Wearability is strong；Chemistry
Performance is stable；Have the disadvantage that water imbibition is poor；It is also easy to produce electrostatic.
Polypropylene fibre, is with the China that the accessory substance propylene of petroleum refining is synthetic fibers isotactic polypropylene fibre made from raw material
Trade name.Also known as polypropylene fibre.The hygroscopicity very little of polypropylene fibre, almost non-hygroscopic, the regain under the conditions of general atmosphere is approached
In zero.But it has core sucting action, vapor can be transmitted by the capillary in fabric, but itself does not play any absorption.Lack
Point is that polypropylene fibre light resistance is poor, and heat endurance is also poor, easy aging, intolerant to flatiron.
Viscose rayon, is made of the various strings such as timber, cotton linter and bamboo, reed, bagasse, straw.12
In kind main textile fabric, the moisture percentage of viscose rayon best suits the physiological requirement of human body skin, with it is smooth it is nice and cool, ventilative,
It is antistatic, dye the characteristic such as gorgeous.But it is yielding simultaneously there is also lacking flexibility, crumple and produce the defects such as sagging.
Therefore, from the perspective of material science development, simple chemical fibre or natural fiber can not meet the modern times
The social growing requirement for preventing material property, how on the basis of existing fibrous material, by adding other
Organic or electrodeless class chemical composition, and coordinate corresponding production technology, prepare a kind of Compound spinning better than general fibre material
Knit material and just seem particularly necessary.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of waterproof composite textile materials, by using specific raw material
It is combined, coordinates specific production technology so that the textile material water resistance being prepared from is excellent, waterproof continuation is strong,
The requirement of industry is disclosure satisfy that, with preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of waterproof composite textile materials, are made from the following raw materials in parts by weight：50-55 parts of Fypro, acrylic fiber
45-50 parts, sub- 30-40 parts of the propyl ester of poly- carbonic acid succinic acid, 28-32 parts of polyethylene terephthalate, polyurethanes 18-
22 parts, it is 15-19 parts of triisopropyl phosphite, 12-16 parts of polyoxylethylene abietate, 8-10 parts of mono phosphoric acid ester different tridecane ester, poly-
6-8 parts of methyl silicon resin, 6-8 parts of lauryl sodium sulfate, 4-6 parts of benzoin ethyl ether, 3-5 parts of eucalyptus oil, 3-5 parts of potassium chloride,
2-4 parts of silane coupler, 2-4 parts of adhesive, 160 parts of deionized water.
Preferably, the silane coupler is selected from silane coupler KH-590, silane resin acceptor kh-550, silane coupler
Any one in KH-560.
Preferably, any one of described adhesive in sulfenamide, epoxy resin, polyvinyl alcohol.
The preparation method of described waterproof composite textile materials, comprises the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with rotating speed 650-750
R/min stirs 35-45 min, then raises temperature to 80-90 DEG C, water-bath 15-25 min obtain initial mixture；
（3）By Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride be collectively disposed at ball
Ball-milling treatment is carried out in grinding machine, the rotating speed of ball mill is 220-280 r/min, and Ball-milling Time is 1-2 h, makes each group in mixture
It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler, adhesive, are well mixed, are then melted at 350-360 DEG C, obtain intermediate product；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, then in an oven in
Dry, pelletizing, obtains finished product textile material under the conditions of 40-50 DEG C.
Preferably, the step（4）The pressure of mesohigh homogenizer is 16-18Mpa.
Preferably, the step（5）In, the screw speed of double screw extruder is 250-280 r/min, twin-screw extrusion
The temperature of each section of machine is：One 170-190 DEG C of area's temperature, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four area's temperature
175-185 DEG C of degree.
Compared with prior art, its advantage is the present invention：
（1）The waterproof composite textile materials of the present invention are with Fypro, acrylic fiber, the sub- propyl ester of poly- carbonic acid succinic acid, poly-
Ethylene glycol terephthalate is main component, by adding polyurethanes, triisopropyl phosphite, rosin acid polyoxy second
The different tridecane ester of alkene ester, mono phosphoric acid ester, poly- methyl silicon resin, lauryl sodium sulfate, benzoin ethyl ether, eucalyptus oil, potassium chloride, silicon
Alkane coupling agent, adhesive, deionized water, are aided with the works such as magnetic agitation, heating water-bath, ball-milling treatment, high-pressure homogeneous, Screw Extrusion
Skill so that the textile material water resistance being prepared from is excellent, waterproof continuation is strong, disclosure satisfy that the requirement of industry, with compared with
Good application prospect.
（2）Waterproof composite textile materials raw material of the invention is cheap, technique is simple, is used suitable for heavy industrialization, real
It is strong with property.
Embodiment
The technical scheme of invention is described in detail with reference to specific embodiment.
Embodiment 1
（1）Sub- 30 parts of the propyl ester of 50 parts of Fypro, 45 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
28 parts of ethylene glycol terephthalate, 18 parts of polyurethanes, 15 parts of triisopropyl phosphite, polyoxylethylene abietate 12
Part, 8 parts of the different tridecane ester of mono phosphoric acid ester, 6 parts of poly- methyl silicon resin, 6 parts of lauryl sodium sulfate, 4 parts of benzoin ethyl ether, eucalyptus oil
3 parts, 3 parts of potassium chloride, 2 parts of silane coupler KH-590,2 parts of sulfenamide, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with the r/ of rotating speed 650
Min stirs 35 min, then raises temperature to 80 DEG C, the min of water-bath 15 obtains initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 220 r/min, and Ball-milling Time is 1 h, make each component in mixture scattered equal
It is even, obtain ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler KH-590, sulfenamide, are well mixed, are then melted at 350 DEG C, obtain middle production
The pressure of thing, wherein high pressure homogenizer is 16Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 170 DEG C of area's temperature, two 200 DEG C of area's temperature,
Three 235 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 40 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Embodiment 2
（1）Sub- 35 parts of the propyl ester of 52 parts of Fypro, 47 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
30 parts of ethylene glycol terephthalate, 20 parts of polyurethanes, 17 parts of triisopropyl phosphite, polyoxylethylene abietate 14
Part, 9 parts of the different tridecane ester of mono phosphoric acid ester, 7 parts of poly- methyl silicon resin, 7 parts of lauryl sodium sulfate, 5 parts of benzoin ethyl ether, eucalyptus oil
4 parts, 4 parts of potassium chloride, 3 parts of silane resin acceptor kh-550,3 parts of epoxy resin, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with the r/ of rotating speed 700
Min stirs 40 min, then raises temperature to 85 DEG C, the min of water-bath 20 obtains initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 250 r/min, and Ball-milling Time is 1.5 h, disperses each component in mixture
Uniformly, ball-milled mixtures are obtained；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane resin acceptor kh-550, epoxy resin, are well mixed, are then melted at 355 DEG C, obtain middle production
The pressure of thing, wherein high pressure homogenizer is 17Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 265 r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two 205 DEG C of area's temperature,
Three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, the then dry, pelletizing under the conditions of 45 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Embodiment 3
（1）Sub- 40 parts of the propyl ester of 55 parts of Fypro, 50 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
32 parts of ethylene glycol terephthalate, 22 parts of polyurethanes, 19 parts of triisopropyl phosphite, polyoxylethylene abietate 16
Part, 10 parts of the different tridecane ester of mono phosphoric acid ester, 8 parts of poly- methyl silicon resin, 8 parts of lauryl sodium sulfate, 6 parts of benzoin ethyl ether, folium eucalypti
5 parts of oil, 5 parts of potassium chloride, 4 parts of silane coupler KH-560,4 parts of polyvinyl alcohol, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with the r/ of rotating speed 750
Min stirs 45 min, then raises temperature to 90 DEG C, the min of water-bath 25 obtains initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 280 r/min, and Ball-milling Time is 2 h, make each component in mixture scattered equal
It is even, obtain ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler KH-560, polyvinyl alcohol, are well mixed, are then melted at 360 DEG C, obtain middle production
The pressure of thing, wherein high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 280 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 210 DEG C of area's temperature,
Three 250 DEG C of area's temperature, four 185 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Embodiment 4
（1）Sub- 40 parts of the propyl ester of 55 parts of Fypro, 45 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
28 parts of ethylene glycol terephthalate, 22 parts of polyurethanes, 15 parts of triisopropyl phosphite, polyoxylethylene abietate 16
Part, 8 parts of the different tridecane ester of mono phosphoric acid ester, 8 parts of poly- methyl silicon resin, 6 parts of lauryl sodium sulfate, 6 parts of benzoin ethyl ether, eucalyptus oil
3 parts, 5 parts of potassium chloride, 2 parts of silane coupler KH-590,4 parts of epoxy resin, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with the r/ of rotating speed 650
Min stirs 45 min, then raises temperature to 80 DEG C, the min of water-bath 25 obtains initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 220 r/min, and Ball-milling Time is 2 h, make each component in mixture scattered equal
It is even, obtain ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler KH-590, epoxy resin, are well mixed, are then melted at 350 DEG C, obtain middle production
The pressure of thing, wherein high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 200 DEG C of area's temperature,
Three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Comparative example 1
（1）Sub- 35 parts of the propyl ester of 52 parts of Fypro, 47 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
30 parts of ethylene glycol terephthalate, 20 parts of polyurethanes, 17 parts of triisopropyl phosphite, polyoxylethylene abietate 14
Part, 7 parts of poly- methyl silicon resin, 7 parts of lauryl sodium sulfate, 5 parts of benzoin ethyl ether, 4 parts of potassium chloride, silane resin acceptor kh-550
3 parts, 3 parts of epoxy resin, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
Polyoxylethylene abietate and deionized water mixing, are placed on magnetic stirrer and stir 40 min with the r/min of rotating speed 700, then
85 DEG C are warming up to, the min of water-bath 20 obtains initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 250 r/min, and Ball-milling Time is 1.5 h, disperses each component in mixture
Uniformly, ball-milled mixtures are obtained；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, silane resin acceptor kh-550, epoxy resin, are well mixed, are then melted at 355 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 17Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 265 r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two 205 DEG C of area's temperature,
Three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, the then dry, pelletizing under the conditions of 45 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Comparative example 2
（1）Sub- 40 parts of the propyl ester of 55 parts of Fypro, 45 parts of acrylic fiber, poly- carbonic acid succinic acid is weighed according to parts by weight, gathered
28 parts of ethylene glycol terephthalate, 22 parts of polyurethanes, 15 parts of triisopropyl phosphite, polyoxylethylene abietate 16
Part, 8 parts of the different tridecane ester of mono phosphoric acid ester, 6 parts of lauryl sodium sulfate, 6 parts of benzoin ethyl ether, 3 parts of eucalyptus oil, silane coupler
2 parts of KH-590,4 parts of epoxy resin, 160 parts of deionized water；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with the r/ of rotating speed 650
Min stirs 45 min, then raises temperature to 80 DEG C, the min of water-bath 25 obtains initial mixture；
（3）Fypro, acrylic fiber, lauryl sodium sulfate are collectively disposed in ball mill and carry out ball-milling treatment, ball
The rotating speed of grinding machine is 220 r/min, and Ball-milling Time is 2 h, each component in mixture is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler KH-590, epoxy resin, are well mixed, are then melted at 350 DEG C, obtain middle production
The pressure of thing, wherein high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder
Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 200 DEG C of area's temperature,
Three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving material
Material.
The performance test results of obtained waterproof composite textile materials are as shown in table 1.
Embodiment 1-4 and comparative example 1-2 waterproof composite textile materials are subjected to water resistance test respectively, used
Method is AATCC-22 water repellency methods of testing, wherein according to the water droplet on textile material or water shape, the water resistance of textile
It is divided into 0,50,70,80,90,100 several grades.
Table 1
| Water proofing property after washing 10 times | Water proofing property after washing 50 times | Water proofing property after washing 80 times | |
| Embodiment 1 | 100 | 100 | 90 |
| Embodiment 2 | 100 | 100 | 90 |
| Embodiment 3 | 100 | 100 | 90 |
| Embodiment 4 | 100 | 100 | 90 |
| Comparative example 1 | 100 | 90 | 80 |
| Comparative example 2 | 100 | 90 | 70 |
The waterproof composite textile materials of the present invention are with Fypro, acrylic fiber, the sub- propyl ester of poly- carbonic acid succinic acid, poly- to benzene
Naphthalate is main component, by adding polyurethanes, triisopropyl phosphite, rosin acid polyoxyethylene
The different tridecane ester of ester, mono phosphoric acid ester, poly- methyl silicon resin, lauryl sodium sulfate, benzoin ethyl ether, eucalyptus oil, potassium chloride, silane
Coupling agent, adhesive, deionized water, are aided with the works such as magnetic agitation, heating water-bath, ball-milling treatment, high-pressure homogeneous, Screw Extrusion
Skill so that the textile material water resistance being prepared from is excellent, waterproof continuation is strong, disclosure satisfy that the requirement of industry, with compared with
Good application prospect.Waterproof composite textile materials raw material of the invention is cheap, technique is simple, is used suitable for heavy industrialization,
It is practical.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (6)
1. a kind of waterproof composite textile materials, it is characterised in that：It is made from the following raw materials in parts by weight：Fypro 50-55
Part, sub- 30-40 part of the propyl ester of 45-50 parts of acrylic fiber, poly- carbonic acid succinic acid, 28-32 parts of polyethylene terephthalate, gather
18-22 parts of carbamate, 15-19 parts of triisopropyl phosphite, 12-16 parts of polyoxylethylene abietate, mono phosphoric acid ester different 13
8-10 parts of alkyl ester, poly- methyl silicon resin 6-8 parts, 6-8 parts of lauryl sodium sulfate, 4-6 parts of benzoin ethyl ether, 3-5 parts of eucalyptus oil,
3-5 parts of potassium chloride, 2-4 parts of silane coupler, 2-4 parts of adhesive, 160 parts of deionized water.
2. waterproof composite textile materials according to claim 1, it is characterised in that：It is even that the silane coupler is selected from silane
Join any one in agent KH-590, silane resin acceptor kh-550, silane coupler KH-560.
3. waterproof composite textile materials according to claim 1, it is characterised in that：Described adhesive be selected from sulfenamide,
Any one in epoxy resin, polyvinyl alcohol.
4. according to the preparation method of any described waterproof composite textile materials of claims 1 to 3, it is characterised in that including with
Lower step：
（1）Each raw material is weighed according to parts by weight；
（2）By the sub- propyl ester of poly- carbonic acid succinic acid, polyethylene terephthalate, polyurethanes, triisopropyl phosphite,
The different tridecane ester of polyoxylethylene abietate, mono phosphoric acid ester and deionized water mixing, are placed on magnetic stirrer with rotating speed 650-750
R/min stirs 35-45 min, then raises temperature to 80-90 DEG C, water-bath 15-25 min obtain initial mixture；
（3）Fypro, acrylic fiber, poly- methyl silicon resin, lauryl sodium sulfate, potassium chloride are collectively disposed at ball milling
Ball-milling treatment is carried out in machine, the rotating speed of ball mill is 220-280 r/min, and Ball-milling Time is 1-2 h, makes each component in mixture
It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add peace
The fragrant ether of breath, eucalyptus oil, silane coupler, adhesive, are well mixed, are then melted at 350-360 DEG C, obtain intermediate product；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, then in an oven in
Dry, pelletizing, obtains finished product textile material under the conditions of 40-50 DEG C.
5. the preparation method of waterproof composite textile materials according to claim 4, it is characterised in that the step（4）In
The pressure of high pressure homogenizer is 16-18Mpa.
6. the preparation method of waterproof composite textile materials according to claim 4, it is characterised in that the step（5）In,
The screw speed of double screw extruder is 250-280 r/min, and the temperature of each section of double screw extruder is：One area temperature 170-
190 DEG C, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four 175-185 DEG C of area's temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710531346.8A CN107142552A (en) | 2017-07-03 | 2017-07-03 | A kind of waterproof composite textile materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710531346.8A CN107142552A (en) | 2017-07-03 | 2017-07-03 | A kind of waterproof composite textile materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107142552A true CN107142552A (en) | 2017-09-08 |
Family
ID=59784761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710531346.8A Pending CN107142552A (en) | 2017-07-03 | 2017-07-03 | A kind of waterproof composite textile materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107142552A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108060470A (en) * | 2017-12-29 | 2018-05-22 | 付主枝 | A kind of preparation method and applications of hard special type textile material |
| CN110528118A (en) * | 2019-08-23 | 2019-12-03 | 张媛婷 | It is a kind of fire prevention, sound-insulating and heat-insulating fabric |
| CN110983484A (en) * | 2019-12-06 | 2020-04-10 | 浙江升丽纺织有限公司 | High-wear-resistance flame-retardant fabric and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1334363A (en) * | 2000-07-18 | 2002-02-06 | 上海杰事杰新材料股份有限公司 | Silk-like material and its preparing process |
| CN105220265A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of new type natural fiber textile material and preparation method thereof |
| CN105696325A (en) * | 2016-04-20 | 2016-06-22 | 吴江市林旺纺织厂 | Antifungal anti-mite textile material and preparation method thereof |
| CN105802198A (en) * | 2016-04-05 | 2016-07-27 | 吴江市林旺纺织厂 | Waterproof textile material and preparation method thereof |
-
2017
- 2017-07-03 CN CN201710531346.8A patent/CN107142552A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1334363A (en) * | 2000-07-18 | 2002-02-06 | 上海杰事杰新材料股份有限公司 | Silk-like material and its preparing process |
| CN105220265A (en) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | A kind of new type natural fiber textile material and preparation method thereof |
| CN105802198A (en) * | 2016-04-05 | 2016-07-27 | 吴江市林旺纺织厂 | Waterproof textile material and preparation method thereof |
| CN105696325A (en) * | 2016-04-20 | 2016-06-22 | 吴江市林旺纺织厂 | Antifungal anti-mite textile material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108060470A (en) * | 2017-12-29 | 2018-05-22 | 付主枝 | A kind of preparation method and applications of hard special type textile material |
| CN110528118A (en) * | 2019-08-23 | 2019-12-03 | 张媛婷 | It is a kind of fire prevention, sound-insulating and heat-insulating fabric |
| CN110983484A (en) * | 2019-12-06 | 2020-04-10 | 浙江升丽纺织有限公司 | High-wear-resistance flame-retardant fabric and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103361997B (en) | Pupa albumen, cotton and blend polyester fabric | |
| CN102071539B (en) | Double-layer water-adsorption and moisture-transfer non-woven fabric and preparation method thereof | |
| CN104757724B (en) | A kind of knitting fabric of absorbing fast-drying shitosan | |
| CN102772081A (en) | Cool fiber/ hemp composite summer sleeping mat and manufacture method thereof | |
| CN106883459A (en) | A kind of textile material of ventilation wear-resistance and preparation method thereof | |
| CN107142552A (en) | A kind of waterproof composite textile materials and preparation method thereof | |
| CN109706546B (en) | Graphene sea-island fiber and manufacturing method thereof | |
| CN105177739A (en) | Two-component round hollow cross-shaped special-shaped high-absorbent complex fiber and production method thereof | |
| CN103628180A (en) | Ultra-extinction memory fiber and preparation method | |
| CN106757504A (en) | A kind of composite elastic fiber and preparation method thereof | |
| CN102733024A (en) | Preparation method and application for pineapple fiber yarns | |
| CN109706545B (en) | Microporous hollow graphene sea-island fiber and manufacturing method thereof | |
| CN107034546A (en) | A kind of composite fibre textile material and preparation method thereof | |
| CN106977772A (en) | Fire-type textile material for fire-fighting operation and preparation method thereof | |
| CN111519276A (en) | High-shrinkage polyamide fiber and preparation method and application thereof | |
| CN1240887C (en) | Process for making synthetic fiber colored cloth with high color stability | |
| CN104805531A (en) | Magnetic composite fiber | |
| CN103088662A (en) | Rapid water absorption bamboo fiber cloth | |
| CN102839472A (en) | Nylon-viscose fiber-collagen fiber blended yarn | |
| CN101608364A (en) | A kind of milk protein fiber modification preparation and the application in home textile product thereof | |
| CN201263406Y (en) | Natural anti-ultraviolet dress | |
| CN108866829A (en) | A kind of preparation process of tri- component acoustical cotton of high resiliency PP/PET/PTT | |
| CN106617364A (en) | Sunblocking breathable cheongsam | |
| CN107337921A (en) | A kind of textile material added with crushed crude pearlite and preparation method thereof | |
| CN104328575A (en) | Bamboo fiber, wool and vinylon blended fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170908 |