CN107141936A - 一种超疏水耐沾污多彩涂料及其制备方法 - Google Patents
一种超疏水耐沾污多彩涂料及其制备方法 Download PDFInfo
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- CN107141936A CN107141936A CN201710416193.2A CN201710416193A CN107141936A CN 107141936 A CN107141936 A CN 107141936A CN 201710416193 A CN201710416193 A CN 201710416193A CN 107141936 A CN107141936 A CN 107141936A
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- stain resistant
- multicolor finish
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- hydrophobic
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- 230000003075 superhydrophobic effect Effects 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002966 varnish Substances 0.000 claims abstract description 22
- 239000003973 paint Substances 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000002585 base Substances 0.000 claims description 21
- 239000008279 sol Substances 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 239000000084 colloidal system Substances 0.000 claims description 15
- 239000013530 defoamer Substances 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- 239000002562 thickening agent Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- 239000003755 preservative agent Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 6
- -1 coalescents Substances 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- ARFDIYMUJAUTDK-UHFFFAOYSA-N 1-hydroxypentyl 2-methylpropanoate Chemical compound CCCCC(O)OC(=O)C(C)C ARFDIYMUJAUTDK-UHFFFAOYSA-N 0.000 claims description 4
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical class [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000007798 antifreeze agent Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 230000008719 thickening Effects 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 14
- 239000011248 coating agent Substances 0.000 abstract description 13
- 238000004140 cleaning Methods 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 7
- 240000002853 Nelumbo nucifera Species 0.000 abstract description 5
- 235000006508 Nelumbo nucifera Nutrition 0.000 abstract description 5
- 235000006510 Nelumbo pentapetala Nutrition 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 4
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000004575 stone Substances 0.000 description 3
- 239000010438 granite Substances 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- VPJOGDPLXNTKAZ-UHFFFAOYSA-N 2-methylpropanoic acid;2,2,4-trimethylpentane-1,3-diol Chemical class CC(C)C(O)=O.CC(C)C(O)C(C)(C)CO VPJOGDPLXNTKAZ-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009500 colour coating Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
Description
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Priority Applications (1)
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CN201710416193.2A CN107141936B (zh) | 2017-06-06 | 2017-06-06 | 一种超疏水耐沾污多彩涂料及其制备方法 |
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CN201710416193.2A CN107141936B (zh) | 2017-06-06 | 2017-06-06 | 一种超疏水耐沾污多彩涂料及其制备方法 |
Publications (2)
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CN107141936A true CN107141936A (zh) | 2017-09-08 |
CN107141936B CN107141936B (zh) | 2019-07-30 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117483A (zh) * | 2019-12-24 | 2020-05-08 | 苏州多彩铝业有限责任公司 | 一种纳米自洁涂料和自洁型铝板 |
CN111171614A (zh) * | 2020-01-21 | 2020-05-19 | 南京双善节能科技有限公司 | 一种批刮型仿大理石漆及其制备方法与应用 |
CN111454629A (zh) * | 2020-04-29 | 2020-07-28 | 湖北中科博策新材料科技有限公司 | 一种超疏水水漆及其生产工艺 |
CN112480763A (zh) * | 2020-11-27 | 2021-03-12 | 四川三棵树涂料有限公司 | 免罩面水包水多彩仿大理石涂料及其制备方法 |
CN112680079A (zh) * | 2020-12-16 | 2021-04-20 | 北京三棵树新材料科技有限公司 | 一种可外露高强高韧水包水多彩涂料 |
CN112724760A (zh) * | 2020-12-29 | 2021-04-30 | 富思特新材料科技发展股份有限公司 | 一种耐沾污涂料及其制备方法和应用 |
Citations (5)
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US20090253832A1 (en) * | 2004-01-08 | 2009-10-08 | Bakeev Kirill N | Colorant compatible hydrophobically modified polyurethane thickener for paint |
CN103013258A (zh) * | 2012-12-26 | 2013-04-03 | 黎卓 | 抗紫外线超自洁花岗岩建筑涂料及其制备方法 |
CN103224741A (zh) * | 2013-04-03 | 2013-07-31 | 广东电网公司电力科学研究院 | 一种应用于绝缘子防污闪的新型纳米TiO2/PTFE杂化氟碳涂料及其制备方法 |
CN106256859A (zh) * | 2016-08-25 | 2016-12-28 | 上海磐彩环保科技股份有限公司 | 一种纳米高耐候多彩环保涂料及其制备方法 |
CN106566350A (zh) * | 2016-11-15 | 2017-04-19 | 厦门富思特新材料科技有限公司 | 一种多彩反射隔热涂层及多彩彩粒体系层制造工艺 |
-
2017
- 2017-06-06 CN CN201710416193.2A patent/CN107141936B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090253832A1 (en) * | 2004-01-08 | 2009-10-08 | Bakeev Kirill N | Colorant compatible hydrophobically modified polyurethane thickener for paint |
CN103013258A (zh) * | 2012-12-26 | 2013-04-03 | 黎卓 | 抗紫外线超自洁花岗岩建筑涂料及其制备方法 |
CN103224741A (zh) * | 2013-04-03 | 2013-07-31 | 广东电网公司电力科学研究院 | 一种应用于绝缘子防污闪的新型纳米TiO2/PTFE杂化氟碳涂料及其制备方法 |
CN106256859A (zh) * | 2016-08-25 | 2016-12-28 | 上海磐彩环保科技股份有限公司 | 一种纳米高耐候多彩环保涂料及其制备方法 |
CN106566350A (zh) * | 2016-11-15 | 2017-04-19 | 厦门富思特新材料科技有限公司 | 一种多彩反射隔热涂层及多彩彩粒体系层制造工艺 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111117483A (zh) * | 2019-12-24 | 2020-05-08 | 苏州多彩铝业有限责任公司 | 一种纳米自洁涂料和自洁型铝板 |
CN111171614A (zh) * | 2020-01-21 | 2020-05-19 | 南京双善节能科技有限公司 | 一种批刮型仿大理石漆及其制备方法与应用 |
CN111454629A (zh) * | 2020-04-29 | 2020-07-28 | 湖北中科博策新材料科技有限公司 | 一种超疏水水漆及其生产工艺 |
CN112480763A (zh) * | 2020-11-27 | 2021-03-12 | 四川三棵树涂料有限公司 | 免罩面水包水多彩仿大理石涂料及其制备方法 |
CN112680079A (zh) * | 2020-12-16 | 2021-04-20 | 北京三棵树新材料科技有限公司 | 一种可外露高强高韧水包水多彩涂料 |
CN112724760A (zh) * | 2020-12-29 | 2021-04-30 | 富思特新材料科技发展股份有限公司 | 一种耐沾污涂料及其制备方法和应用 |
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Denomination of invention: A super hydrophobic stain resistant multicolor coating and its preparation method Effective date of registration: 20210319 Granted publication date: 20190730 Pledgee: Bank of China Limited Xiamen Convention and Exhibition Center sub branch Pledgor: XIAMEN FIRST NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2021980001824 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20190730 Pledgee: Bank of China Limited Xiamen Convention and Exhibition Center sub branch Pledgor: XIAMEN FIRST NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: Y2021980001824 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right |