CN107141934A - A kind of silicone modified acrylic resin protective paint - Google Patents
A kind of silicone modified acrylic resin protective paint Download PDFInfo
- Publication number
- CN107141934A CN107141934A CN201710354603.5A CN201710354603A CN107141934A CN 107141934 A CN107141934 A CN 107141934A CN 201710354603 A CN201710354603 A CN 201710354603A CN 107141934 A CN107141934 A CN 107141934A
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- silicone modified
- modified acrylic
- resin protective
- protective paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of silicone modified acrylic resin protective paint, the invention belongs to chemical technology field, its formula is characterized in：It is made up of silicone modified acrylic resin, zinc powder, toluene, bentonite, zinc oxide ultra_fine powderses, ultra-fine palm wax micro mist, coalescents AH 12, oleic acid acyl, dispersant 5040.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, be the coating that its work is protected.The present invention has micron order and the dual coarse structure of nanoscale simultaneously, so just having the super-hydrophobic self-cleaning function of lotus leaf effect, after product using the present invention, the surface long term of object need not manually be cleaned and returned newly from overcoating brush, save substantial amounts of manpower and materials, also do not corroded simultaneously by wind and rain, the service life of 3 times of conventional acrylic resin protective paints, strictly a kind of service life is permanent and silicone modified acrylic resin protective paint of excellent performance.
Description
Technical field
The invention belongs to chemical field, the present invention relates to a kind of organosilicon acrylic fat protective paint, and in particular to be one
Plant silicone modified acrylic resin protective paint.
Background technology
Acrylic resin protective paint is that one kind can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing, hull bottom
The protective coating for the structure such as anti-planktonic organism, deck be anti-wear.But acrylic resin protection lacquer coat does not have hydrophobic self-cleaning
Function, will manually clean and be returned newly from overcoating brush in short term, service life is not long, wastes manpower and materials.
The content of invention
The purpose of the present invention is：There is provided a kind of have hydrophobic self-cleaning function, need not manually clean for a long time and from overcoating brush
Return it is new, can save a large amount of manpower and materials, not by erosion by wind and rain, service life for a long time and excellent performance super-hydrophobic acrylic resin
Protective paint.
To achieve the above object, the technical solution adopted in the present invention is a kind of silicone modified acrylic resin protective paint, its
It is formulated and is characterized in：By silicone modified acrylic resin, zinc powder, toluene, bentonite, zinc oxide ultra_fine powderses (0.5um~0.8um
Footpath), ultra-fine palm wax micro mist (25nm~90nm particle diameters), coalescents AH-12, oleic acid acyl, dispersant 5040 constitute.
The percentage by weight of its component is：
Beneficial effects of the present invention：The present invention is that zinc oxide ultra_fine powderses (0.5um~0.8um particle diameters), ultra-fine palm wax is micro-
The peptizaiton that powder (25nm~90nm particle diameters) is risen by dispersant 5040 and oleic acid acyl, is highly dispersed in acid-organosilicon crylic acid
In resin protective paint, distributive law more than 97%, using the present invention finished product after, paint film formation tool lotus leaf effect it is super-hydrophobic from
Clean surface, the contact angle of multiple silicone modified acrylic resins protection paint film samples and water is determined with half ball, 150 ° with
On；Moreover, the observation that sample is carried out by using electron microscope, finds its surface while having micron order and nanoscale dual thick
Rough structure.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, each
The surface of the outdoor indoor hardware equipment of class, makes the surface of object have the super-hydrophobic self-cleaning function of lotus leaf effect, can be not required to for a long time
Manually to clean and be returned newly from overcoating brush, save substantial amounts of manpower and materials, and not corroded by wind and rain, 3 times common third
The service life of olefin(e) acid resin protective paint, is that a kind of service life is permanent and super-hydrophobic silicone modified acrylic resin of excellent performance
Protective paint.
Embodiment
The following examples are that the present invention is made further to prove, the invention is not restricted to this.
Embodiment one
A kind of silicone modified acrylic resin protective paint, its component and weight proportion are as follows：
Embodiment two
A kind of silicone modified acrylic resin protective paint, its component and weight proportion are as follows：
Embodiment three
A kind of silicone modified acrylic resin protective paint, its component and weight proportion are as follows：
Finished product obtained by the three above embodiment of the present invention is respectively coated on three pieces of slides, surveyed with half ball
The contact angle of fixed these three samples and water：
1st, the contact angle of the slide sample of embodiment one and water is 153.4 °
2nd, the contact angle of the slide sample of embodiment two and water is 151.2 °
3rd, the contact angle of the slide sample of embodiment three and water is 152.5 °
The sample of three above embodiment is determined with half ball, finished product its surface wettability of the present invention is all showed
For superhydrophobic characteristic.
A kind of silicone modified acrylic resin protective paint of the present invention, applies in western district of Guangdong, has supplied Duo Jia advertising companies,
Used on the surface of its outdoor large advertisement metal structure skeleton；Made comparisons with common acrylic resin protective paint, this hair
Bright product has the super-hydrophobic self-cleaning function of lotus leaf effect, the surface of metal structure is not corroded by wind and rain, permanent light
It is bright such as new, substantial amounts of manpower and materials are saved, product of the invention has the use longevity of 3 times of conventional acrylic resin protective paints
Life, strictly a kind of service life is permanent and silicone modified acrylic resin protective paint of excellent performance.
Claims (2)
1. a kind of silicone modified acrylic resin protective paint, it is characterised in that：The percentage by weight of the formula each component is：Organosilicon
Acrylic resin 49%--79%, zinc powder 1%--22%, toluene 4%--24%, bentonite 5%--23%, zinc oxide ultra_fine powderses
3%--25%, ultra-fine palm wax micro mist 2%--26%, coalescents AH-12 3%--22%, oleic acid acyl 2%--24%, point
The 1%--23% of powder 5040.
2. a kind of silicone modified acrylic resin protective paint according to claim 1, it is characterized in that：Zinc oxide ultra_fine powderses
0.5um~0.8um particle diameters, ultra-fine palm wax micro mist 25nm~90nm particle diameters, point risen by dispersant 5040 and oleic acid acyl
Effect is dissipated, is highly dispersed in silicone modified acrylic resin protective paint, distributive law is more than 97%, using after this finished product, paint film
The super-hydrophobic self-cleaning surface of tool lotus leaf effect is formed, multiple silicone modified acrylic resin protection paint film samples are determined with half ball
With the contact angle of water, more than 150 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354603.5A CN107141934A (en) | 2017-05-11 | 2017-05-11 | A kind of silicone modified acrylic resin protective paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354603.5A CN107141934A (en) | 2017-05-11 | 2017-05-11 | A kind of silicone modified acrylic resin protective paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107141934A true CN107141934A (en) | 2017-09-08 |
Family
ID=59778680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710354603.5A Pending CN107141934A (en) | 2017-05-11 | 2017-05-11 | A kind of silicone modified acrylic resin protective paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141934A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652879A (en) * | 2017-10-22 | 2018-02-02 | 惠州市阿斯顿涂料有限公司 | A kind of long-acting cold galvanizing fire-resistant anticorrosion paint |
| CN110211732A (en) * | 2019-05-14 | 2019-09-06 | 许对兴 | A kind of enameled wire with cleaning function with winding structure |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102321415A (en) * | 2011-08-11 | 2012-01-18 | 天津大学 | Fluorine-silicon acrylic resin nano composite anti-icing coating and preparation method thereof |
| CN103666173A (en) * | 2012-09-04 | 2014-03-26 | 中国石油天然气股份有限公司 | Super hydrophobic anticorrosive paint and preparation method thereof |
| CN105462413A (en) * | 2015-12-28 | 2016-04-06 | 杭州名匠建筑装饰工程有限公司 | High-strength low-covering-thickness high-grade nano finish paint for vehicles and preparation method thereof |
| CN106566354A (en) * | 2016-11-11 | 2017-04-19 | 浙江大学 | Nano composite anti-fouling paint co-used with anticorrosion intermediate paint and preparation method thereof |
-
2017
- 2017-05-11 CN CN201710354603.5A patent/CN107141934A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102321415A (en) * | 2011-08-11 | 2012-01-18 | 天津大学 | Fluorine-silicon acrylic resin nano composite anti-icing coating and preparation method thereof |
| CN103666173A (en) * | 2012-09-04 | 2014-03-26 | 中国石油天然气股份有限公司 | Super hydrophobic anticorrosive paint and preparation method thereof |
| CN105462413A (en) * | 2015-12-28 | 2016-04-06 | 杭州名匠建筑装饰工程有限公司 | High-strength low-covering-thickness high-grade nano finish paint for vehicles and preparation method thereof |
| CN106566354A (en) * | 2016-11-11 | 2017-04-19 | 浙江大学 | Nano composite anti-fouling paint co-used with anticorrosion intermediate paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652879A (en) * | 2017-10-22 | 2018-02-02 | 惠州市阿斯顿涂料有限公司 | A kind of long-acting cold galvanizing fire-resistant anticorrosion paint |
| CN110211732A (en) * | 2019-05-14 | 2019-09-06 | 许对兴 | A kind of enameled wire with cleaning function with winding structure |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170908 |
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| WD01 | Invention patent application deemed withdrawn after publication |