CN107123741B - 一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 - Google Patents
一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 Download PDFInfo
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- CN107123741B CN107123741B CN201710365485.8A CN201710365485A CN107123741B CN 107123741 B CN107123741 B CN 107123741B CN 201710365485 A CN201710365485 A CN 201710365485A CN 107123741 B CN107123741 B CN 107123741B
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- cspbbr3
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- sensitized
- transport layer
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 title claims description 18
- 239000001007 phthalocyanine dye Substances 0.000 claims abstract description 37
- 230000005525 hole transport Effects 0.000 claims abstract description 35
- 239000000758 substrate Substances 0.000 claims abstract description 33
- 239000010409 thin film Substances 0.000 claims abstract description 28
- 239000000975 dye Substances 0.000 claims abstract description 23
- 238000012986 modification Methods 0.000 claims abstract description 22
- 230000004048 modification Effects 0.000 claims abstract description 22
- 239000010408 film Substances 0.000 claims description 32
- 206010070834 Sensitisation Diseases 0.000 claims description 18
- 239000002243 precursor Substances 0.000 claims description 18
- 230000008313 sensitization Effects 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 16
- 238000000137 annealing Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- 238000011068 loading method Methods 0.000 claims description 10
- 238000002207 thermal evaporation Methods 0.000 claims description 10
- 238000001771 vacuum deposition Methods 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- LYQFWZFBNBDLEO-UHFFFAOYSA-M caesium bromide Chemical compound [Br-].[Cs+] LYQFWZFBNBDLEO-UHFFFAOYSA-M 0.000 claims description 8
- 230000005540 biological transmission Effects 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 7
- 238000004528 spin coating Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- MCEWYIDBDVPMES-UHFFFAOYSA-N [60]pcbm Chemical compound C123C(C4=C5C6=C7C8=C9C%10=C%11C%12=C%13C%14=C%15C%16=C%17C%18=C(C=%19C=%20C%18=C%18C%16=C%13C%13=C%11C9=C9C7=C(C=%20C9=C%13%18)C(C7=%19)=C96)C6=C%11C%17=C%15C%13=C%15C%14=C%12C%12=C%10C%10=C85)=C9C7=C6C2=C%11C%13=C2C%15=C%12C%10=C4C23C1(CCCC(=O)OC)C1=CC=CC=C1 MCEWYIDBDVPMES-UHFFFAOYSA-N 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 238000002834 transmittance Methods 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- ZASWJUOMEGBQCQ-UHFFFAOYSA-L dibromolead Chemical compound Br[Pb]Br ZASWJUOMEGBQCQ-UHFFFAOYSA-L 0.000 claims description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- GEQBRULPNIVQPP-UHFFFAOYSA-N 2-[3,5-bis(1-phenylbenzimidazol-2-yl)phenyl]-1-phenylbenzimidazole Chemical compound C1=CC=CC=C1N1C2=CC=CC=C2N=C1C1=CC(C=2N(C3=CC=CC=C3N=2)C=2C=CC=CC=2)=CC(C=2N(C3=CC=CC=C3N=2)C=2C=CC=CC=2)=C1 GEQBRULPNIVQPP-UHFFFAOYSA-N 0.000 claims description 3
- XDXWNHPWWKGTKO-UHFFFAOYSA-N 207739-72-8 Chemical compound C1=CC(OC)=CC=C1N(C=1C=C2C3(C4=CC(=CC=C4C2=CC=1)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)C1=CC(=CC=C1C1=CC=C(C=C13)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)N(C=1C=CC(OC)=CC=1)C=1C=CC(OC)=CC=1)C1=CC=C(OC)C=C1 XDXWNHPWWKGTKO-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910015711 MoOx Inorganic materials 0.000 claims description 3
- 229920001167 Poly(triaryl amine) Polymers 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- 239000005368 silicate glass Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000005361 soda-lime glass Substances 0.000 claims description 3
- TVIVIEFSHFOWTE-UHFFFAOYSA-K tri(quinolin-8-yloxy)alumane Chemical compound [Al+3].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 TVIVIEFSHFOWTE-UHFFFAOYSA-K 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 238000000151 deposition Methods 0.000 description 9
- 230000001235 sensitizing effect Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 238000011049 filling Methods 0.000 description 5
- 230000031700 light absorption Effects 0.000 description 5
- 230000002194 synthesizing effect Effects 0.000 description 5
- 230000006798 recombination Effects 0.000 description 4
- 238000005215 recombination Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/311—Phthalocyanine
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Manufacturing & Machinery (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
Claims (7)
Priority Applications (2)
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CN201710365485.8A CN107123741B (zh) | 2017-05-22 | 2017-05-22 | 一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 |
CN201910975662.3A CN110676389A (zh) | 2017-05-22 | 2017-05-22 | 一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 |
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CN201710365485.8A CN107123741B (zh) | 2017-05-22 | 2017-05-22 | 一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 |
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CN107123741A CN107123741A (zh) | 2017-09-01 |
CN107123741B true CN107123741B (zh) | 2019-12-10 |
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CN201910975662.3A Withdrawn CN110676389A (zh) | 2017-05-22 | 2017-05-22 | 一种酞菁染料敏化的CsPbBr3光伏电池及其制造方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108258126B (zh) * | 2018-01-29 | 2019-07-16 | 芜湖乐知智能科技有限公司 | 一种基于无机钙钛矿的光电探测器及其制备方法 |
EP3547339A1 (en) * | 2018-03-30 | 2019-10-02 | Ricoh Company, Ltd. | Photoelectric conversion element, photoelectric conversion element module, electronic device, and power supply module |
CN109516496B (zh) * | 2018-12-18 | 2020-11-03 | 江南大学 | 一种稳定分散的全无机钙钛矿CsPbBr3纳米晶的制备方法 |
CN114864829B (zh) * | 2022-07-07 | 2022-09-20 | 中国长江三峡集团有限公司 | 一种钙钛矿太阳能电池及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015189551A1 (en) * | 2014-06-12 | 2015-12-17 | Isis Innovation Limited | Heterojunction device |
CN105514282A (zh) * | 2016-02-05 | 2016-04-20 | 南方科技大学 | 太阳能电池以及制备太阳能电池的方法 |
CN105742508A (zh) * | 2016-04-12 | 2016-07-06 | 上海大学 | 四氨基锌酞菁有机空穴传输层钙钛矿太阳能电池的制备方法 |
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2017
- 2017-05-22 CN CN201710365485.8A patent/CN107123741B/zh active Active
- 2017-05-22 CN CN201910975662.3A patent/CN110676389A/zh not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015189551A1 (en) * | 2014-06-12 | 2015-12-17 | Isis Innovation Limited | Heterojunction device |
CN105514282A (zh) * | 2016-02-05 | 2016-04-20 | 南方科技大学 | 太阳能电池以及制备太阳能电池的方法 |
CN105742508A (zh) * | 2016-04-12 | 2016-07-06 | 上海大学 | 四氨基锌酞菁有机空穴传输层钙钛矿太阳能电池的制备方法 |
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CN110676389A (zh) | 2020-01-10 |
CN107123741A (zh) | 2017-09-01 |
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Effective date of registration: 20191016 Address after: 317205 Taizhou, Tiantai County, Zhejiang Province Street Town Creek Zhoucun No. 2 Applicant after: Zhou Xiaoyin Address before: 241008 Anhui city of Wuhu Province Silver Lake Economic and Technological Development Zone Polka International Garden 78-5-301 Applicant before: WUHU LEZHI INTELLIGENT TECHNOLOGY CO.,LTD. |
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Denomination of invention: A CsPbBr3 photovoltaic cell sensitized with phthalocyanine dye and its manufacturing method Effective date of registration: 20231211 Granted publication date: 20191210 Pledgee: Agricultural Bank of China Limited by Share Ltd. Tiantai County branch Pledgor: Zhou Xiaoyin Registration number: Y2023330002995 |