CN107118835A - A kind of water base bentonite lubricant and preparation method thereof - Google Patents

A kind of water base bentonite lubricant and preparation method thereof Download PDF

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Publication number
CN107118835A
CN107118835A CN201710363446.4A CN201710363446A CN107118835A CN 107118835 A CN107118835 A CN 107118835A CN 201710363446 A CN201710363446 A CN 201710363446A CN 107118835 A CN107118835 A CN 107118835A
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China
Prior art keywords
parts
water base
bentonite
lubricant
base bentonite
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Pending
Application number
CN201710363446.4A
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Chinese (zh)
Inventor
刘新兵
刘长淼
刘玉林
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Jurong Kangtai Bentonite Co Ltd
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Jurong Kangtai Bentonite Co Ltd
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Priority to CN201710363446.4A priority Critical patent/CN107118835A/en
Publication of CN107118835A publication Critical patent/CN107118835A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06—Mixtures of thickeners and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C10M2209/126—Polysaccharides, e.g. cellulose, biopolymers used as thickening agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Abstract

The invention discloses a kind of water base bentonite lubricant and preparation method thereof, it is related to lubricant preparation field.The water base bentonite lubricant is prepared from by following parts by weight raw material：40 60 parts of bentonite, 5 30 parts of phosphate, 5 30 parts of boron salt, 5 20 parts of kollag, 0.2 1 parts of methyl acrylate, 0.1 5 parts of dispersant, 0.1 5 parts of thickener, surplus is water.The present invention is without using base oil, the problem of solving the cleaning of traditional infrastructure oil lubricant hardly possible, pollution weight.The water base bentonite lubricant prepared by the present invention, which has, to be uniformly dispersed, high temperature resistant, the advantage of high lubricating effect, and easy cleaning is pollution-free.

Description

A kind of water base bentonite lubricant and preparation method thereof
Technical field
The present invention relates to lubricant preparation field, more particularly to a kind of water base bentonite lubricant and preparation method thereof.
Background technology
Lubricant is that a kind of grease-like with certain viscosity is semi-solid, mainly by mineral oil (or synthetic lubricant fluid) Formed with thickening agent modulation, it can be divided into soap grease and the class of non-soap base fat two, bentonite lubricant category according to the difference of thickening agent Viscosity or high viscosity Dormant oils are made in non-soap base lubricating agent, the organobentonite thickening after being handled through surfactant, It is widely used in the heavy duty equipment of the industries such as mine, metallurgy, casting and steel rolling, and heavy-load automobile, papermaking equipment, water Mud production equipment, high temp tunnel kiln car, airplane wheel bearing, the lubricant housings of the equipment such as railway diesel locomotive.
Bentonite is one kind of clay, and its main component is montmorillonite, belongs to the aqueous aluminosilicate mineral of layer structure Thing.Because itself has the commutative feature of cation, therefore the organobentonite of different series can be made by required purposes. Organobentonite is often made the thickening agent of lubricant, the auxiliary agent of coating, the sagging inhibitor of paint and thickener, the solution of oil drilling Card agent etc..
In process of metal working, kollag, which is adsorbed onto metal surface in its mutual motion process and formed, lubricates thin Film, the friction between lubricating film and the transfer membrane for being transferred to material surface is changed into by the dry friction between contact material, so that significantly Degree reduction fretting wear.Bentonitic thixotropy has the effect of rheology modifier in the lubricant, with excellent lubrication Property, heat resistance, not drip, is the outstanding lubriation material of essential high-temperature high-load at high temperature.But it is existing using swollen The lubricant high temperature resistant of profit soil preparation, high load capacity are poor.
The content of the invention
Embodiments of the invention provide a kind of water base bentonite lubricant and preparation method thereof, and the present invention is without using basis Oil, the problem of solving the cleaning of traditional infrastructure oil lubricant hardly possible, pollution weight.The water base bentonite lubricant prepared by the present invention With being uniformly dispersed, high temperature resistant, the advantage of high lubricating effect, and easy cleaning is pollution-free.
To reach above-mentioned purpose, embodiments of the invention are adopted the following technical scheme that：
Embodiments of the invention provide a kind of water base bentonite lubricant, including the raw material of following parts by weight is prepared from： 40-60 parts of bentonite, 5-30 parts of phosphate, 5-30 parts of boron salt, 5-20 parts of kollag, 0.2-1 parts of methyl acrylate disperses 0.1-5 parts of agent, 0.1-5 parts of thickener, surplus is water.
Further, described water base bentonite lubricant is that the raw materials of following parts by weight is prepared from：Bentonite 45- 55 parts, 10-20 parts of phosphate, 10-20 parts of boron salt, 8-12 parts of kollag, 0.6-0.8 parts of methyl acrylate, dispersant 1-2 Part, 0.5-2 parts of thickener, surplus is water.
Further, the bentonite is one kind in sodium bentonite, lithium bentonite.
Further, the phosphate is disodium hydrogen phosphate, tertiary sodium phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, hexa metaphosphoric acid One or more mixtures in sodium, sodium pyrophosphate, sodium polyphosphate.
Further, the boron salt is potassium fluoborate, sodium fluoborate, calcium metaborate, Boratex, Firebrake ZB, in lithium borate One or more mixtures.
Further, the kollag is graphite microparticles, talcum powder, nano-calcium carbonate, in cyanurate melamine One or more mixtures.
Further, the dispersant is glyceryl monostearate, oleic acid acyl, one or more mixing in polyethylene glycol Thing.
Further, the thickener is sodium carboxymethylcellulose, carboxyethyl cellulose, polyvinyl alcohol, polyacrylamide, One or more mixtures in Sodium Polyacrylate..
Present invention also offers a kind of preparation method of water base bentonite lubricant, including：
S1, by thickener, phosphate, boron salt dissolves in water, is heated to 40-80 DEG C, stirs 15-30 minutes, obtains viscous fluid Body；
S2, surplus stock added in the thick liquid, stir 1-2 hours, obtain the water base bentonite lubricant.
A kind of water base bentonite lubricant provided in an embodiment of the present invention and preparation method thereof, with advantages below：
（1）Preparation technology simple possible, method is simple and easy to control, prepares cost low；（2）Using methyl acrylate, lubrication is improved The suspension of agent；（3）Resistance to elevated temperatures of the present invention is good, and with suitable viscosity and oil film thickness；（4）Bentonite is substituted Base oil, easy cleaning is pollution-free；（5）There is good antirust, antiseptic property simultaneously.
Embodiment
To make those skilled in the art more fully understand technical scheme, with reference to embodiment to this Invention is described in further detail.
Embodiment 1
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：40-45 parts of lithium bentonite, six is inclined 5-10 parts of sodium phosphate, 5-10 parts of calcium metaborate, 5-8 parts of talcum powder, 0.2-0.6 parts of methyl acrylate, 0.1-1 parts of polyethylene glycol, 0.1-0.5 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 40 DEG C, stirs 30 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 1 hour, obtain the water base bentonite lubricant.
Embodiment 2
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：40-45 parts of lithium bentonite, six is inclined 5-10 parts of sodium phosphate, 5-10 parts of calcium metaborate, 5-8 parts of talcum powder, 0.2-0.6 parts of methyl acrylate, 0.1-1 parts of polyethylene glycol, 0.1-0.5 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 80 DEG C, stirs 15 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 2 hours, obtain the water base bentonite lubricant.
Embodiment 3
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：45-55 parts of lithium bentonite, six is inclined 10-20 parts of sodium phosphate, 10-20 parts of calcium metaborate, 8-12 parts of talcum powder, 0.6-0.8 parts of methyl acrylate, 1-2 parts of polyethylene glycol, 0.5-2 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 40 DEG C, stirs 30 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 1 hour, obtain the water base bentonite lubricant.
Embodiment 4
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：45-55 parts of lithium bentonite, six is inclined 10-20 parts of sodium phosphate, 10-20 parts of calcium metaborate, 8-12 parts of talcum powder, 0.6-0.8 parts of methyl acrylate, 1-2 parts of polyethylene glycol, 0.5-2 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 80 DEG C, stirs 15 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 2 hours, obtain the water base bentonite lubricant.
Embodiment 5
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：55-60 parts of lithium bentonite, six is inclined 20-30 parts of sodium phosphate, 20-30 parts of calcium metaborate, 12-20 parts of talcum powder, 0.8-1 parts of methyl acrylate, 2-5 parts of polyethylene glycol, 2-5 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 40 DEG C, stirs 30 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 1 hour, obtain the water base bentonite lubricant.
Embodiment 6
A kind of water base bentonite lubricant, is prepared from by the raw material of following parts by weight：55-60 parts of lithium bentonite, six is inclined 20-30 parts of sodium phosphate, 20-30 parts of calcium metaborate, 12-20 parts of talcum powder, 0.8-1 parts of methyl acrylate, 2-5 parts of polyethylene glycol, 2-5 parts of sodium carboxymethylcellulose, surplus is water.
A kind of water base bentonite method for preparing lubricant, including：
S1, by sodium carboxymethylcellulose, calgon, calcium metaborate dissolves in water, is heated to 80 DEG C, stirs 15 minutes, Obtain thick liquid；
S2, surplus stock added in the thick liquid, stir 2 hours, obtain the water base bentonite lubricant.
Each embodiment in this specification is described by the way of progressive, identical similar portion between each embodiment Divide mutually referring to what each embodiment was stressed is the difference with other embodiment.It is real especially for equipment Apply for example, because it is substantially similar to embodiment of the method, so describing fairly simple, related part is referring to embodiment of the method Part explanation.The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited to This, any one skilled in the art the invention discloses technical scope in, the change that can readily occur in or replace Change, should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claim Enclose and be defined.

Claims (9)

1. a kind of water base bentonite lubricant, it is characterised in that the raw material including following parts by weight is prepared from：Bentonite 40-60 parts, 5-30 parts of phosphate, 5-30 parts of boron salt, 5-20 parts of kollag, 0.2-1 parts of methyl acrylate, dispersant 0.1- 5 parts, 0.1-5 parts of thickener, surplus is water.
2. a kind of water base bentonite lubricant according to claim 1, it is characterised in that include the original of following parts by weight Material is prepared from：45-55 parts of bentonite, 10-20 parts of phosphate, 10-20 parts of boron salt, 8-12 parts of kollag, acrylic acid first 0.6-0.8 parts of ester, 1-2 parts of dispersant, 0.5-2 parts of thickener, surplus is water.
3. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the bentonite is Na-bentonite One kind in soil, lithium bentonite.
4. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the phosphate is di(2-ethylhexyl)phosphate One kind or many in sodium, tertiary sodium phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, calgon, sodium pyrophosphate, sodium polyphosphate Plant mixture.
5. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the boron salt is potassium fluoborate, One or more mixtures in sodium fluoborate, calcium metaborate, Boratex, Firebrake ZB, lithium borate.
6. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the kollag is graphite One or more mixtures in micro mist, talcum powder, nano-calcium carbonate, cyanurate melamine.
7. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the dispersant is stearic acid list One or more mixtures in glyceride, oleic acid acyl, polyethylene glycol.
8. a kind of water base bentonite lubricant according to claim 1, it is characterised in that the thickener is that carboxymethyl is fine One or more mixtures in the plain sodium of dimension, carboxyethyl cellulose, polyvinyl alcohol, polyacrylamide, Sodium Polyacrylate.
9. a kind of water base bentonite method for preparing lubricant, it is characterised in that comprise the following steps：
S1, by thickener, phosphate, boron salt dissolves in water, is heated to 40-80 DEG C, stirs 15-30 minutes, obtains viscous fluid Body；
S2, surplus stock added in the thick liquid, stir 1-2 hours, obtain the water base bentonite lubricant.
CN201710363446.4A 2017-05-22 2017-05-22 A kind of water base bentonite lubricant and preparation method thereof Pending CN107118835A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723067A (en) * 2017-10-26 2018-02-23 湖南金化科技集团有限公司 A kind of water-based low temperature resistant graphitic lubricant and its preparation method and application
CN107723068A (en) * 2017-10-26 2018-02-23 湖南金化科技集团有限公司 A kind of water-soluble forging lubricant compositions
CN108865349A (en) * 2018-06-15 2018-11-23 安徽森米诺农业科技有限公司 For safeguarding the lubricant of roller dryer shaft
CN108913278A (en) * 2018-08-27 2018-11-30 安徽江杰实业有限公司 A kind of water base mechanical lubrication agent preparation method
CN109137120A (en) * 2018-08-22 2019-01-04 安徽利通达纤维新材料有限公司 A kind of preparation method of insect prevention woven bag
CN112680270A (en) * 2019-10-18 2021-04-20 中国石油化工股份有限公司 Oil-water type lubricating grease composition and preparation method thereof
CN112680264A (en) * 2019-10-18 2021-04-20 中国石油化工股份有限公司 Oil-water type bentonite-lithium-based composite lubricating grease composition and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101270317A (en) * 2008-04-17 2008-09-24 启东尤希路化学工业有限公司 High-lubricity environment-friendly water-based core rod lubricant agent
CN104498165A (en) * 2014-11-28 2015-04-08 衡阳市金化科技有限公司 Water-based graphite lubricant for hot-rolling seamless tube and preparation method for water-based graphite lubricant for hot-rolling seamless tube
CN104694240A (en) * 2015-02-13 2015-06-10 衡阳市金化科技有限公司 Water-based clay lubricant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101270317A (en) * 2008-04-17 2008-09-24 启东尤希路化学工业有限公司 High-lubricity environment-friendly water-based core rod lubricant agent
CN104498165A (en) * 2014-11-28 2015-04-08 衡阳市金化科技有限公司 Water-based graphite lubricant for hot-rolling seamless tube and preparation method for water-based graphite lubricant for hot-rolling seamless tube
CN104694240A (en) * 2015-02-13 2015-06-10 衡阳市金化科技有限公司 Water-based clay lubricant

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107723067A (en) * 2017-10-26 2018-02-23 湖南金化科技集团有限公司 A kind of water-based low temperature resistant graphitic lubricant and its preparation method and application
CN107723068A (en) * 2017-10-26 2018-02-23 湖南金化科技集团有限公司 A kind of water-soluble forging lubricant compositions
CN108865349A (en) * 2018-06-15 2018-11-23 安徽森米诺农业科技有限公司 For safeguarding the lubricant of roller dryer shaft
CN109137120A (en) * 2018-08-22 2019-01-04 安徽利通达纤维新材料有限公司 A kind of preparation method of insect prevention woven bag
CN108913278A (en) * 2018-08-27 2018-11-30 安徽江杰实业有限公司 A kind of water base mechanical lubrication agent preparation method
CN112680270A (en) * 2019-10-18 2021-04-20 中国石油化工股份有限公司 Oil-water type lubricating grease composition and preparation method thereof
CN112680264A (en) * 2019-10-18 2021-04-20 中国石油化工股份有限公司 Oil-water type bentonite-lithium-based composite lubricating grease composition and preparation method thereof
CN112680264B (en) * 2019-10-18 2022-06-28 中国石油化工股份有限公司 Oil-water type bentonite-lithium-based composite lubricating grease composition and preparation method thereof

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