CN107118398A - Degradable asepsis environment-protecting toy material and preparation method thereof - Google Patents
Degradable asepsis environment-protecting toy material and preparation method thereof Download PDFInfo
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- CN107118398A CN107118398A CN201710262228.1A CN201710262228A CN107118398A CN 107118398 A CN107118398 A CN 107118398A CN 201710262228 A CN201710262228 A CN 201710262228A CN 107118398 A CN107118398 A CN 107118398A
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- parts
- degradable
- asepsis environment
- protecting
- calcium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Biological Depolymerization Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of degradable asepsis environment-protecting toy material and preparation method thereof, and degradable asepsis environment-protecting toy material includes following raw material：0.4 0.8 parts of 20 30 parts of rice husk, 18 26 parts of cellulose, 30 40 parts of natural resin, 10 16 parts of starch, 12 20 parts of Sodium Polyacrylate, 39 parts of polyvinyl alcohol, 12 parts of talcum powder, 0.3 0.8 parts of food coloring, 20 26 parts of calcium carbonate, 20 26 parts of polyethylene and photodegradable aid.Degradable asepsis environment-protecting toy material is made by using inventive formulation and method, the characteristics of it has asepsis environment-protecting, biodegradable and light degradation can be carried out, organic fertilizer can be turned into after degraded, back to nature, and this product hardness and medium density, nondiscolouring, it is not mouldy, shrink-proof, not crisp, do not split, it is indeformable, be highly suitable for make toy.
Description
Technical field
The present invention relates to toy art technology, a kind of degradable asepsis environment-protecting toy material and its preparation side are referred in particular to
Method.
Background technology
The world today, with the improvement of people's living standards, it is continuous to improve adaptable new material with living standards of the people
Arise at the historic moment.With people's lives relation it is maximum be plastic material, plastic material is also commonly used for manufacturing the material of toy, but modeling
Material is expected due to using stabilizer, plasticizer, crosslinking agent etc. in process of production, and environmental pollution is very big, and product can not degrade,
Ecological environment is easily damaged after use.At present, not yet find can be degradable have common plasticses mechanical property and
The non-toxic environment-friendlymaterial material of performance.
The content of the invention
In view of this, in view of the existing deficiencies of the prior art, its main purpose is to provide a kind of degradable nothing to the present invention
Poison ring protects toy material and preparation method thereof, and it can be degradable and has common plasticses mechanical property and performance.
To achieve the above object, the present invention is using following technical scheme：
A kind of degradable asepsis environment-protecting toy material, includes following raw material：20-30 parts of rice husk, cellulose 18-
26 parts, 30-40 parts of natural resin, 10-16 parts of starch, 12-20 parts of Sodium Polyacrylate, 3-9 parts of polyvinyl alcohol, talcum powder
0.4-0.8 parts of 1-2 parts, 0.3-0.8 parts of food coloring, 20-26 parts of calcium carbonate, 20-26 parts of polyethylene and photodegradable aid.
As a kind of preferred scheme, the calcium carbonate is at least one of powdered whiting, precipitated calcium carbonate.
As a kind of preferred scheme, the photodegradable aid is at least one in ferric stearate, cerium stearate, calcium stearate
Kind.
As a kind of preferred scheme, the natural resin uses one kind or several in gummi arabicum pulveratum, gelatin, hydrogenated rosin
Kind.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 400-450 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 50-80 mass parts water is injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 120-130 DEG C of extrusion temperature.
The present invention has clear advantage and beneficial effect compared with prior art, specifically, by above-mentioned technical proposal
Understand：
Degradable asepsis environment-protecting toy material is made by using inventive formulation and method, it has the spy of asepsis environment-protecting
Point, can carry out biodegradable and light degradation, can turn into organic fertilizer, back to nature, and this product hardness and density after degraded
It is moderate, nondiscolouring, it is not mouldy, shrink-proof, not crisp, do not split, it is indeformable, be highly suitable for make toy.
Embodiment
Present invention is disclosed a kind of degradable asepsis environment-protecting toy material, include following raw material：Rice husk
20-30 parts, 18-26 parts of cellulose, 30-40 parts of natural resin, 10-16 parts of starch, 12-20 parts of Sodium Polyacrylate, poly- second
3-9 parts of enol, 1-2 parts of talcum powder, 0.3-0.8 parts of food coloring, 20-26 parts of calcium carbonate, 20-26 parts of polyethylene and
0.4-0.8 parts of photodegradable aid.The calcium carbonate is at least one of powdered whiting, precipitated calcium carbonate.The photodegradable aid
For at least one of ferric stearate, cerium stearate, calcium stearate.The natural resin uses gummi arabicum pulveratum, gelatin, hydrogenation
One or more in rosin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 400-450 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 50-80 mass parts water is injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 120-130 DEG C of extrusion temperature.
The present invention is described in further detail with multiple embodiments below：
Embodiment 1
A kind of degradable asepsis environment-protecting toy material, includes following raw material：25 parts of rice husk, 24 parts of cellulose,
40 parts of natural resin, 14 parts of starch, 18 parts of Sodium Polyacrylate, 6 parts of polyvinyl alcohol, 1.4 parts of talcum powder, food coloring
0.5 part of 0.8 part, 25 parts of calcium carbonate, 26 parts of polyethylene and photodegradable aid.The calcium carbonate is powdered whiting.The light
Degradation agent is ferric stearate.The natural resin uses gummi arabicum pulveratum.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 400 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 60 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 125 DEG C of extrusion temperature.
Embodiment 2
A kind of degradable asepsis environment-protecting toy material, includes following raw material：20 parts of rice husk, 25 parts of cellulose,
30 parts of natural resin, 13 parts of starch, 12 parts of Sodium Polyacrylate, 5 parts of polyvinyl alcohol, 1 part of talcum powder, food coloring 0.5
Part, 20 parts of calcium carbonate, 23 parts of polyethylene and 0.4 part of photodegradable aid.The calcium carbonate is precipitated calcium carbonate.The light drop
Solution agent is cerium stearate.The natural resin uses gelatin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 430 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 50 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 130 DEG C of extrusion temperature.
Embodiment 3
A kind of degradable asepsis environment-protecting toy material, includes following raw material：30 parts of rice husk, 26 parts of cellulose,
35 parts of natural resin, 12 parts of starch, 15 parts of Sodium Polyacrylate, 4 parts of polyvinyl alcohol, 1.6 parts of talcum powder, food coloring
0.6 part of 0.6 part, 26 parts of calcium carbonate, 24 parts of polyethylene and photodegradable aid.The calcium carbonate is powdered whiting and lightweight
The mixture of calcium carbonate.The photodegradable aid is calcium stearate.The natural resin uses hydrogenated rosin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 450 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 80 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 120 DEG C of extrusion temperature.
Embodiment 4
A kind of degradable asepsis environment-protecting toy material, includes following raw material：23 parts of rice husk, 18 parts of cellulose,
37 parts of natural resin, 10 parts of starch, 16 parts of Sodium Polyacrylate, 3 parts of polyvinyl alcohol, 1.8 parts of talcum powder, food coloring
0.7 part of 0.7 part, 23 parts of calcium carbonate, 25 parts of polyethylene and photodegradable aid.The calcium carbonate is powdered whiting.The light
Degradation agent is the mixture of ferric stearate and cerium stearate.The natural resin is using gummi arabicum pulveratum and the mixture of gelatin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 420 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 55 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 122 DEG C of extrusion temperature.
Embodiment 5
A kind of degradable asepsis environment-protecting toy material, includes following raw material：28 parts of rice husk, 20 parts of cellulose,
38 parts of natural resin, 11 parts of starch, 19 parts of Sodium Polyacrylate, 8 parts of polyvinyl alcohol, 2 parts of talcum powder, food coloring 0.3
Part, 24 parts of calcium carbonate, 20 parts of polyethylene and 0.8 part of photodegradable aid.The calcium carbonate is powdered whiting and lightweight carbonic acid
The mixture of calcium.The photodegradable aid is the mixture of cerium stearate and calcium stearate.The natural resin uses gelatin and hydrogen
Change the mixture of rosin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 410 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 65 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 128 DEG C of extrusion temperature.
Embodiment 6
A kind of degradable asepsis environment-protecting toy material, includes following raw material：26 parts of rice husk, 22 parts of cellulose,
34 parts of natural resin, 16 parts of starch, 20 parts of Sodium Polyacrylate, 9 parts of polyvinyl alcohol, 1.2 parts of talcum powder, food coloring
0.4 part of 0.4 part, 22 parts of calcium carbonate, 21 parts of polyethylene and photodegradable aid.The calcium carbonate is powdered whiting and lightweight
The mixture of calcium carbonate.The photodegradable aid is the mixture of ferric stearate, cerium stearate and calcium stearate.The natural resin
Using the mixture of gummi arabicum pulveratum, gelatin and hydrogenated rosin.
A kind of preparation method of degradable asepsis environment-protecting toy material, includes following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 425 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 70 mass parts water are injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 127 DEG C of extrusion temperature.
Asepsis environment-protecting toy material degradable made from each above-mentioned embodiment is tested, assay is shown：
It is nontoxic, biodegradable and light degradation can be carried out.
The design focal point of the present invention is：Degradable asepsis environment-protecting toy is made by using inventive formulation and method
Material, the characteristics of it has asepsis environment-protecting can carry out biodegradable and light degradation, can turn into organic fertilizer after degraded, return certainly
So, and this product hardness and medium density, nondiscolouring, it is not mouldy, shrink-proof, not crisp, do not split, it is indeformable, be especially suitable for using
In making toy.
The above described is only a preferred embodiment of the present invention, be not intended to limit the scope of the present invention,
Therefore any subtle modifications, equivalent variations and modifications that every technical spirit according to the present invention is made to above example, still
Belong in the range of technical solution of the present invention.
Claims (5)
1. a kind of degradable asepsis environment-protecting toy material, it is characterised in that：Include following raw material：Rice husk 20-30
Part, 18-26 parts of cellulose, 30-40 parts of natural resin, 10-16 parts of starch, 12-20 parts of Sodium Polyacrylate, polyvinyl alcohol
3-9 parts, 1-2 parts of talcum powder, 0.3-0.8 parts of food coloring, 20-26 parts of calcium carbonate, 20-26 parts of polyethylene and light degradation
0.4-0.8 parts of agent.
2. degradable asepsis environment-protecting toy material according to claim 1, it is characterised in that：The calcium carbonate is heavy
At least one of calcium carbonate, precipitated calcium carbonate.
3. degradable asepsis environment-protecting toy material according to claim 1, it is characterised in that：The photodegradable aid is hard
At least one of resin acid iron, cerium stearate, calcium stearate.
4. degradable asepsis environment-protecting toy material according to claim 1, it is characterised in that：The natural resin is used
One or more in gummi arabicum pulveratum, gelatin, hydrogenated rosin.
5. a kind of preparation method of degradable asepsis environment-protecting toy material as described in any one of Claims 1-4, its feature
It is：Include following steps：
（1）Rice husk is ground to form to the molecule powdered rice hulls of 400-450 mesh using grinder；
（2）Powdered rice hulls are added in high temperature and high speed mixer, cellulose, starch, talcum powder and calcium carbonate are then sequentially added mixed
Close uniform, 50-80 mass parts water is injected in mixed process, cooling is then taken out；
（3）By step（2）In material, natural resin, Sodium Polyacrylate, polyvinyl alcohol, food coloring, polyethylene and light degradation
Agent is uniformly mixed at normal temperatures, is then extruded 3 minutes at 120-130 DEG C of extrusion temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710262228.1A CN107118398A (en) | 2017-04-20 | 2017-04-20 | Degradable asepsis environment-protecting toy material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710262228.1A CN107118398A (en) | 2017-04-20 | 2017-04-20 | Degradable asepsis environment-protecting toy material and preparation method thereof |
Publications (1)
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| CN107118398A true CN107118398A (en) | 2017-09-01 |
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| CN201710262228.1A Pending CN107118398A (en) | 2017-04-20 | 2017-04-20 | Degradable asepsis environment-protecting toy material and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641254A (en) * | 2017-11-23 | 2018-01-30 | 马鞍山松鹤信息科技有限公司 | A kind of environment-protecting and non-poisonous toy material and its preparation technology |
| CN108294411A (en) * | 2018-03-23 | 2018-07-20 | 嘉善奇美服饰辅料厂 | A kind of environmentally protective button and preparation method thereof |
| CN109181336A (en) * | 2018-08-15 | 2019-01-11 | 厦门壳氏新材料科技有限公司 | A kind of degradable plant fibre composite article, and preparation method thereof |
| CN109575437A (en) * | 2018-11-20 | 2019-04-05 | 曹峰 | A kind of preparation method of high tenacity modified polypropene pellet |
| CN112225951A (en) * | 2020-10-22 | 2021-01-15 | 吕立军 | Environment-friendly toy plastic and preparation method thereof |
| CN112409684A (en) * | 2020-11-03 | 2021-02-26 | 临沂利方塑胶制品有限公司 | Processing method of high-strength toy plastic |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107641254A (en) * | 2017-11-23 | 2018-01-30 | 马鞍山松鹤信息科技有限公司 | A kind of environment-protecting and non-poisonous toy material and its preparation technology |
| CN108294411A (en) * | 2018-03-23 | 2018-07-20 | 嘉善奇美服饰辅料厂 | A kind of environmentally protective button and preparation method thereof |
| CN109181336A (en) * | 2018-08-15 | 2019-01-11 | 厦门壳氏新材料科技有限公司 | A kind of degradable plant fibre composite article, and preparation method thereof |
| CN109575437A (en) * | 2018-11-20 | 2019-04-05 | 曹峰 | A kind of preparation method of high tenacity modified polypropene pellet |
| CN112225951A (en) * | 2020-10-22 | 2021-01-15 | 吕立军 | Environment-friendly toy plastic and preparation method thereof |
| CN112409684A (en) * | 2020-11-03 | 2021-02-26 | 临沂利方塑胶制品有限公司 | Processing method of high-strength toy plastic |
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