CN107101951B - A kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring - Google Patents

A kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring Download PDF

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CN107101951B
CN107101951B CN201710314811.2A CN201710314811A CN107101951B CN 107101951 B CN107101951 B CN 107101951B CN 201710314811 A CN201710314811 A CN 201710314811A CN 107101951 B CN107101951 B CN 107101951B
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hydrogen
photonic crystal
fiber
optical fiber
crystal fiber
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CN107101951A (en
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张亚男
彭慧杰
周添敏
张乐宾
赵勇
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Northeastern University China
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K11/00Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00
    • G01K11/32Measuring temperature based upon physical or chemical changes not covered by groups G01K3/00, G01K5/00, G01K7/00 or G01K9/00 using changes in transmittance, scattering or luminescence in optical fibres
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/08Optical fibres; light guides
    • G01N2201/088Using a sensor fibre

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Abstract

The invention proposes a kind of fibre optical sensors for density of hydrogen and temperature simultaneously measuring, including light source part, pass light part, transducing part, gas supply part and optical detector part, transducing part includes optic fibre environment and photonic crystal fiber, and wherein optic fibre environment includes three-dB coupler and high birefringence optical fiber;The transducing part is set to gas supply partial interior, and the output end of wide spectrum light source and the input terminal of spectroanalysis instrument pass through single mode optical fiber respectively and connect with three-dB coupler one end;High birefringence optical fiber both ends pass through single mode optical fiber respectively and connect with three-dB coupler both ends;One section of photonic crystal fiber is connected on the single mode optical fiber that spectroanalysis instrument is connect with three-dB coupler, coats hydrogen sensitive film in the periphery of photonic crystal fiber, subsidence area is respectively set in photonic crystal fiber both ends.Highly sensitive, the long-range real-time detection to gas concentration and temperature can be achieved in the combination of optic fibre environment and photonic crystal fiber, and increases the safety of monitoring hydrogen.

Description

A kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring
Technical field
The invention belongs to technical field of optical fiber sensing, it is related to a kind of combining based on photonic crystal fiber and fiber loop mirror Fibre optical sensor for density of hydrogen and temperature simultaneously measuring.
Background technique
Hydrogen is a kind of cleaning and the reusable energy, is widely used in auto industry, aerospace, chemistry and adds The every field such as work.Due to the high diffusivity (0.16cm of hydrogen2/ s), low burning point (0.018mJ) and very wide explosive range (4%-75%), hydrogen are easily revealed and are set off an explosion.It can be seen that the hydrogen sensing technology of research and development hypostazation is to grind Study carefully Hydrogen Energy, utilize Hydrogen Energy and the most important condition for preventing hydrogen from endangering.The transducing signal of traditional electrochemical transducer[sensor is telecommunications Number, there is the potential danger for the hydrogen that ignites and is difficult to realize the single selective of hydrogen.Compared to traditional electrochemical hydrogen Sensor, Optical Fider Hybrogen Sensor with high security, not by electromagnetic interference, the advantages such as telemeasurement, be suitable for hydrogen this The detection of kind hazardous gas, receives significant attention.Most gas sensor is easy to be caused to measure by the interference of environment temperature Inaccurate (document 1.Yu J, Li J, and Dai Q.Temperature compensation and data fusion based on a multifunctional gas detector[J].IEEE Transactions on Instrumentation and Measurement,2015,64(1):204-211.).Therefore, research can monitor hydrogen simultaneously The fibre optical sensor of gas concentration and temperature is necessary.
Grating type hydrogen gas sensor makes it not based on wavelength modulation to be influenced by light source fluctuation, and fiber bragg grating Have the advantages that relatively easy structure, distributed measurement and small in size, many hydrogen gas sensors based on fiber bragg grating It rapidly develops.However need by carrying out some special treatment process such as Side polishing fibers and corrosion to optical fiber, to realize pair The quick response of nm grades of sensitive thin films, this can reduce the mechanical performance of sensor, influence the reliability monitored for a long time, and in this The sensitivity of sensor after treatment it is not high compared to for other kinds of hydrogen gas sensor (document 2.Z.P.Yu, L.Jin,L.J.Chen,J.Li,Y.Ran,B.O.Guan.Microfiber Bragg grating hydrogen sensors [J].IEEE Photonics Technology Letters,2015,27(24):2575-2578.).Most of optical fiber hydrogen Sensor is all the measurement for considering only density of hydrogen, though measurement hydrogen sensitivity it is higher, but in environment temperature change Changing can be sensitive to the sensing arrangement generation Temperature cross-over for coating hydrogen sensitive film, so as to cause the inaccurate of density of hydrogen measurement (document 3.Xu B, Zhao C L, Yang F, Gong H P, Wang D N, Dai J X, Yang M H.Sagnac interferometer hydrogen sensor based on panda fiber with Pt-loaded WO3/ SiO2coating[J].Optics Letters,2016,41(7):1594-1597.).In addition, some hydrogen gas sensors are benefits Chemical reaction releasing heat occurs with sensitive membrane and hydrogen to change the temperature around sensor to realize the survey of density of hydrogen Measure (document 4.Hu T Y, Wang D N, Wang M, Li Z, and Yang M H.Miniature hydrogen sensor based on fiber inner cavity and Pt-doped WO3coating[J].IEEE Photonics Technology Letters, 2014,26 (14): 1458-1461.), although which realizes the survey of higher sensitivity Amount, equally increases the risk of hydrogen explosion.
In order to realize density of hydrogen and temperature simultaneously measuring, 2014 Nian Wangmin et al. propose using Mach-Zehnder interferometer and Fiber bragg grating carries out density of hydrogen and temperature simultaneously measuring (document 5.Wang M, Wang D N, Yang M H, Cheng J,and Li J Y.In-line Mach-Zehnderinterferometer and FBG with Pd film for simultaneous hydrogen and temperature detection[J].Sensors and Actuators B: Chemical,2014,202:893-896.).The Mach-Zehnder interferometer of coating palladium film measures density of hydrogen sensitive It spends up to 70pm/%, while being 6pm/ DEG C to the sensitivity of temperature, and fiber bragg grating is insensitive to density of hydrogen, it is right The sensitivity of temperature only reaches 4pm/%.The sensitivity of measurement hydrogen in article is lower, and the optical fiber as temperature-compensating The temperature sensitivity of Bragg grating is relatively low, can not eliminate the influence of Temperature cross-over sensitivity well.In order to improve hydrogen The safety that gas uses not only needs to consider to improve the sensitivity of density of hydrogen measurement, it is also necessary to consider the influence of temperature change, It therefore, is very necessary to the double monitoring of density of hydrogen and temperature.
Summary of the invention
It is an object of the invention to propose that a kind of structure is simple, be easily achieved, highly-safe, high sensitivity and right simultaneously The novel optical fiber sensor that density of hydrogen and temperature measure.
In order to achieve the above object, the present invention proposes
A kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring, including light source part, biography light part, sensing Partially, gas supply part and optical detector part, wherein light source part is wide spectrum light source, and passing light part includes single mode optical fiber, gas supply Part is the space of the density of hydrogen environment of setting, and optical detector part is spectroanalysis instrument, and transducing part includes optic fibre environment And photonic crystal fiber, wherein optic fibre environment includes three-dB coupler and high birefringence optical fiber;The transducing part is set to confession Gas partial interior, the output end of wide spectrum light source and the input terminal of spectroanalysis instrument pass through single mode optical fiber and three-dB coupler one respectively End connection;High birefringence optical fiber both ends pass through single mode optical fiber respectively and connect with three-dB coupler both ends;Spectroanalysis instrument and 3dB coupling One section of photonic crystal fiber is connected on the single mode optical fiber of clutch connection, coating hydrogen sensitive is thin in the periphery of photonic crystal fiber Film, length is consistent with photonic crystal fiber length, and subsidence area is respectively set in photonic crystal fiber both ends.
Further, described to pass through photonic crystal fiber and the interference spectrum resonance wavelength position by optic fibre environment generation Difference, to distinguish the sensitive variation to density of hydrogen and temperature.Since two kinds of interference spectrum resonance wavelength positions are different, so The interference spectrum generated after two interference superpositions can generate two kinds of easily distinguishable resonance paddy, both resonance paddy are respectively to hydrogen Concentration and temperature are sensitive, and the amount of movement by monitoring them respectively obtains the variable quantity of density of hydrogen and temperature.
The invention has the benefit that
1) this density of hydrogen combined based on photonic crystal fiber and fiber loop mirror proposed by the present invention and temperature are same When the fibre optical sensor that measures, the photonic crystal fiber that will coat sensitive thin film pops one's head in as hydrogen sensitive, fiber loop mirror conduct Temperature measurement unit, highly sensitive, the long-range real-time detection to gas concentration and temperature can be achieved in the combination of the two, and increases The safety of monitoring hydrogen.
2) it using photonic crystal fiber as hydrogen sensing unit, is easy to collapse generation higher order mode by simple welding Into photonic crystal fiber covering, and it can use photonic band gap effects constraint cladding mode and stablize transmission.With non-structure of film It compares, the cladding mode of photonic crystal fiber is more limited in internal layer, between this sensitive membrane and covering with high refractive index It influences each other related.The loss decline of core mode simultaneously, and transmission intensity stability is preferable.Finally with inside cladding mode Coupling produces a stronger interference effect.The above result shows that having plated the hydrogen sensitive of high refractive index in photonic crystal fiber Film can be improved the quality of intermode interference.
Detailed description of the invention
Fig. 1 is that the density of hydrogen provided by the invention combined based on photonic crystal fiber and fiber loop mirror and temperature are surveyed simultaneously Measure overall system architecture schematic diagram;
Fig. 2 is spectroscopic studying figure of the Optical Fider Hybrogen Sensor provided by the invention under different hydrogen concentration;
Fig. 3 is that the curve of Optical Fider Hybrogen Sensor provided by the invention two kinds of resonance troughs under different hydrogen concentration is quasi- It closes;
Fig. 4 is the spectroscopic studying figure of Optical Fider Hybrogen Sensor provided by the invention at different temperatures;
Fig. 5 be Optical Fider Hybrogen Sensor provided by the invention at different temperatures two kinds resonance trough curve matching;
In figure: 1 wide spectrum light source;2 single mode optical fibers;33dB coupler;4 high birefringence optical fibers;5 hydrogen sensitive films;6 photons Crystal optical fibre;7 subsidence areas;8 spectrometers;9 gas chambers.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, and reference Attached drawing is described in further detail specific structure of the invention, principle and experimentation.
Embodiment 1
A kind of optical fiber biography of the density of hydrogen combined based on photonic crystal fiber and fiber loop mirror and temperature simultaneously measuring Sensor, including light source part, biography light part, transducing part, gas supply part, optical detector part.Light source part uses laboratory In spontaneous radiation wide spectrum light source, output power 5.0-10mW/dBm, operation wavelength meets and uses in 1520-1640nm It is required that.It passes light part and uses single mode optical fiber, optical fiber tie jumper head is then needed to carry out turning for optical signal when biography light part is longer It connects.YOKOGAWA Yokogawa AQ6370 spectroanalysis instrument (OSA), wave-length coverage 600- are used in optical detection part Experiment 1700nm completely covers transmitting light source light spectrum signal.Gas supply part is that detection system tests the important component built, real The air distribution system for testing design detaches residual gas in pipeline first with vacuum pump.Next gas supply gas source is opened from gas tank Gas out first controls the flow of every road gas through flowmeter, enters back into mixing chamber and is uniformly mixed.Finally it is passed through measurement gas chamber In, stable density of hydrogen atmosphere is formed, is sensed by the sensitive structure perception concentration variation of transducing part.
In the structure, the refractive index of the sensitive membrane of photonic crystal fiber coating can reduce with the increase of density of hydrogen, Simultaneously in view of the chemical reaction that sensitive membrane and hydrogen occur can release heat so as to cause sensitive membrane expanded by heating, in this process Middle photonic crystal fiber will receive stress.When temperature transmitting variation in environment, the photonic crystal fiber of sensitive membrane is coated It will receive influence, the Temperature cross-over sensitivity of generation results in the inaccurate of measurement.In addition, the easy increase hydrogen of the variation of temperature is quick-fried Fried danger.Fiber loop mirror temperature sensitivity with higher and unique spectrum, the knot of photonic crystal fiber and fiber loop mirror Conjunction can be realized two-parameter measurement.
Fig. 1 is that the density of hydrogen provided by the invention combined based on photonic crystal fiber and fiber loop mirror and temperature are surveyed simultaneously Measure overall system architecture schematic diagram.The light that light source issues enters three-dB coupler from single mode optical fiber, and it is equal by force to be then divided into two-beam Light, respectively along transmitting clockwise and counterclockwise in ring, due to the birefringence effect of high birefringence optical fiber so that The two-beam transmitted in opposite direction in fiber loop mirror generates optical path difference, interferes when two-beam meets in coupler again. For whole system, the input of photonic crystal fiber is the output spectrum of fiber loop mirror, coats the light of hydrogen sensitive film For photonic crystal fiber since the presence of both ends subsidence area forms another interference spectrum, the output of last whole system is two kinds of sensings The variable quantity of density of hydrogen and temperature can be obtained in the superposition interference spectrum of unit, the amount of movement by monitoring different resonance paddy.
The output spectrum of fiber loop mirror indicates are as follows:
In formula, θ1And θ2It is the rotation angle of incident light fast (slow) axis when outputting and inputting high birefringence optical fiber, B is Gao Shuan The birefringent of optical fiber is reflected, L is the length of high birefringence optical fiber.The period of High-Birefringence Fiber Loop Mirror transmission spectrum are as follows:
The amount of movement Δ λ of change in temperature Δ T and resonance trough wavelengthdipRelationship may be expressed as:
In formula, Δ B is influenced by thermo-optic effect, CtIt is thermo-optical coeffecient.It is birefringent to send out when external environment variation Changing, therefore, resonant wavelength can move.
By the present invention in that preparing hydrogen sensitive film with sol-gal process, and sensitivity is coated on photonic crystal fiber Film, so that the sensing arrangement is to hydrogen sensitive.Light enters from input terminal single mode optical fiber, behind first subsidence area, one Light splitting is coupled in the fibre core of photonic crystal fiber to be transmitted with core mode;Another part is optically coupled to the packet of photonic crystal fiber Continue to transmit with cladding mode in layer.During this, the propagation of core mode and cladding mode in photonic crystal fiber is normal Number is different, after transmitting a certain distance length, can there is phase delay between both of which.Finally, when two parts optical transport When to second subsidence area, the cladding mode of sensitive zones is being exported with the core mode transmitted in photonic crystal fiber fibre core It is interfered in single mode optical fiber, forms interference effect.Interference spectrum may be expressed as:
Wherein, I is the output intensity of interference signal, I1And I2It is the light intensity of two beam interferometer light in photonic crystal fiber,It is The phase difference of both of which, δ are initial phases.Phase difference and central wavelength may be expressed as:
Wherein, neff1And neff2It is the effective refractive index of core mode and cladding mode, L is the length of interference region, Δ neffIt is two specific refractivities, λ is free optical wavelength, λmIt is m-th of interference wavelength.
When density of hydrogen increases, sensitive membrane and hydrogen react, and the refractive index of film reduces therewith, photonic crystal fiber Interfere wavelength mobile to shortwave length direction.During this, due to the chemical reaction be it is exothermic, cause sensitive membrane to be heated swollen It is swollen, certain stress can be applied to photonic crystal fiber, interference spectrum is equally as shortwave length direction is mobile.Therefore, hydrogen is dense Degree can pass through the mobile acquisition of monitoring interference spectrum.However, the variation of temperature can generate centainly the measurement of density of hydrogen It influences, and increases the danger of hydrogen explosion.Fiber loop mirror temperature sensitivity with higher, and its spectrum and photon are brilliant The interference spectrum of body optical fiber, which combines, to be easy to differentiate, the not phase of the sensitivity and photonic crystal fiber to temperature and density of hydrogen Together, thus using fiber loop mirror and photonic crystal fiber measurement while being implemented in combination with two-parameter.
The photonic crystal fiber for the use of length being 19.5mm in the present invention forms 120 μm at the both ends of photonic crystal fiber Subsidence area, make its generate resonance wavelength 1551.5nm spectrum;Use the optical fiber for the high birefringence optical fiber that length is 72mm Ring mirror makes it generate the spectrum of resonance wavelength 1595.39nm, passes in conjunction with above-mentioned spectrum, to form integrated optical fiber Sensor carries out the experiment measured while density of hydrogen and temperature.It is as shown in Figure 2 experimental system when density of hydrogen changes Spectrogram.With the increase of density of hydrogen, the interference spectrum of photonic crystal fiber is mobile to shortwave length direction, with theory analysis It is consistent.Be fitted respectively as shown in Figure 3 two in Fig. 2 resonance troughs with density of hydrogen variable quantity.It can be seen that the sensing The hydrogen sensitivity of device can reach -1.12nm/%, simultaneously as fiber loop mirror is by the disturbance in environment, the trough that resonates has can The fluctuation ignored.In the measurement process of temperature, as shown in figure 4, movement all has occurred in two resonance troughs, it is carried out respectively As shown in figure 5, photonic crystal fiber has been actually subjected to the influence of temperature in environment, movement is had occurred in interference spectrum for fitting.The same time Fine ring mirror realizes higher temperature sensitivity.Therefore, the mobile Δ λ of the interference wavelength of photonic crystal fiber1And fiber loop mirror The mobile Δ λ of resonant wavelength2It may be expressed as:
Wherein, Δ C indicates the variation of density of hydrogen, and Δ T indicates the variation of temperature in environment.The variation and temperature of density of hydrogen The variation of degree has resulted in the resonant wavelength Δ λ of two kinds of interferometers1With Δ λ2Movement.In addition, Δ λ1With Δ λ2To Δ C and Δ T There is different sensitivity.Therefore, using the dual wavelength means of proof, monitoring the movements of two kinds of resonant wavelengths, can to obtain simultaneously hydrogen dense The variation of degree and temperature:
Density of hydrogen and temperature change can be respectively obtained by above formula.Therefore, an optical fiber hydrogen with temperature-compensating Sensor is accomplished.It can be seen that photonic crystal fiber interferes to obtain the sensitivity point of density of hydrogen and temperature from the experimental result Not -1.12nm/% and -0.078nm/ DEG C, similarly, the density of hydrogen and temperature sensitivity of fiber loop mirror be respectively - 0.07nm/% and -1.84nm/ DEG C.Currently, the lowest detection of spectrometer is limited to 1pm, density of hydrogen and temperature can theoretically be obtained The lowest detection obtained respectively reaches 8.93ppm and 5.4 × 10-4℃.It is demonstrated experimentally that compared to other Optical Fider Hybrogen Sensors, The density of hydrogen and temperature that the integral optical fiber sensing device designed in the present invention can measure simultaneously, and have relatively high sensitive Degree.

Claims (3)

1. a kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring, which is characterized in that including light source part, pass light Partially, transducing part, gas supply part and optical detector part, wherein light source part is wide spectrum light source, and passing light part includes single mode Optical fiber, gas supply part are divided into the space of the density of hydrogen environment of setting, and optical detector part is spectroanalysis instrument, and transducing part includes Optic fibre environment and photonic crystal fiber, wherein optic fibre environment includes three-dB coupler and high birefringence optical fiber;The transducing part It is set to gas supply partial interior, the output end of wide spectrum light source and the input terminal of spectroanalysis instrument pass through single mode optical fiber and 3dB respectively The connection of coupler one end, the both ends of high birefringence optical fiber pass through single mode optical fiber respectively and connect with three-dB coupler both ends;Spectrum analysis One section of photonic crystal fiber is connected on the single mode optical fiber that instrument is connect with three-dB coupler, which coats hydrogen Sensitive thin film, length are consistent with photonic crystal fiber length;Subsidence area is respectively set in photonic crystal fiber both ends.
2. a kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring according to claim 1, feature exist In, it is different from the interference spectrum resonance wavelength position generated by optic fibre environment by photonic crystal fiber, to distinguish to hydrogen The sensitive variation of gas concentration and temperature.
3. a kind of fibre optical sensor for density of hydrogen and temperature simultaneously measuring according to claim 1 or 2, feature It is, the length of photonic crystal fiber is 19.5mm, and the both ends of photonic crystal fiber form 120 μm of subsidence area, make its generation Resonance wavelength is the spectrum of 1551.5nm;The length of high birefringence optical fiber is 72mm, it is made to generate resonance wavelength 1595.39nm Spectrum.
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