CN107098677A - Black matrix erythema droplet temmoku glaze ceramics and its preparation technology - Google Patents
Black matrix erythema droplet temmoku glaze ceramics and its preparation technology Download PDFInfo
- Publication number
- CN107098677A CN107098677A CN201710397617.5A CN201710397617A CN107098677A CN 107098677 A CN107098677 A CN 107098677A CN 201710397617 A CN201710397617 A CN 201710397617A CN 107098677 A CN107098677 A CN 107098677A
- Authority
- CN
- China
- Prior art keywords
- parts
- erythema
- glaze
- droplet
- black matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6583—Oxygen containing atmosphere, e.g. with changing oxygen pressures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/66—Specific sintering techniques, e.g. centrifugal sintering
- C04B2235/661—Multi-step sintering
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Adornments (AREA)
Abstract
The invention belongs to ceramic field, specifically, the present invention relates to a kind of black matrix erythema droplet temmoku glaze ceramics and preparation technology.This kind of black matrix erythema droplet temmoku glaze ceramics, including iron tire base substrate and erythema oil droplet glaze.Above-mentioned black matrix erythema droplet temmoku glaze ceramics and preparation method thereof, the ceramics burnt out have the carcass of atropurpureus, its erythema oil droplet glaze reflects the speckle of kermesinus from inside to outside, and crystalline particle is remained with glaze layer, seen with magnifying glass, will be obvious sense of movement when glaze is molded at high temperature；When burning till, using reducing atmosphere and nitrogen is filled with when burning till to be reacted, erythema oil droplet glaze is extracted combustion-supporting with the element in iron tire base substrate, glaze raw material is set to change and recombinate, this kind of black matrix erythema droplet temmoku glaze ceramic color is exquisite, texture is gentle, with very high enjoying value and artistic value.
Description
Technical field
The invention belongs to ceramic field, specifically, the present invention relates to a kind of black matrix erythema droplet temmoku glaze ceramics
And preparation technology.
Background technology
Temmoku glaze, its wound was burnt in the Song Dynasty, was one of special kinds of black glaze, and feature is to form one in the black glaze layer of bowl
The round point shape crystallization of each and every one metallic luster not of uniform size, several millimeters of big diameter, small only needle point size has golden yellow,
There is the dot of silvery white metallic luster, i.e., as night sky shining star, like the oil droplet that drop drop is sparkling and crystal-clear, therefore named " oil-spot glaze ".
The kind of oil droplet has countless crystallization spots not of uniform size are uneven to show especially in putting up a kiln on black glaze, color such as gold
Person claims " polishes drop ", and for example silver grey person of color claims " silver-colored oil droplet ", and more rare in oil droplet temmoku is red temmoku.And red temmoku
Firing skill it is also lost already, the application for a patent for invention of Application No. 2005100349032 discloses a kind of red sunlight change of weather
Mesh process for preparing ceramic, this kind red sunlight becomes temmoku and adds the change such as di-iron trioxide, magnesia, phosphorus pentoxide by parent glaze
Work raw material is formed by a firing as colour former, and under the atmosphere of oxidizing flame.From glaze proportioning, although the colour former of chemical industry is just
Preferably, it is easy to get, but the effect of produced temmoku glaze differs greatly compared with raw ore glaze, is not had using the porcelain glaze of chemical industry glaze
Sense of movement when being molded at high temperature；From firing process, this kind red sunlight becomes temmoku ceramics and uses di-iron trioxide conduct
Main colour former, it is therefore necessary to fire, otherwise when kiln temperature degree reaches more than 1000 DEG C, begin under the atmosphere of oxidizing flame
Resolve into iron oxide and be dissolved in glaze, it is impossible to reflect the spot of red, and a traditional temmoku glaze of founding a capital is to use reducing glaze
Burn till, glaze does not have gorgeous color, but with containing comfortable texture.In terms of glaze composition and burning process two, though
Though right this kind of method, which can produce red sunlight, becomes temmoku ceramics, its effect has a long way to go with traditional red temmoku, need into
One step is improved.
So if the limitation in traditional handicraft can be overcome, a kind of erythema high using safety, firing success rate is developed
Temmoku glaze ceramics, the need for can not only meeting consumer, also all have positive meaning to the development for promoting temmoku glaze ceramics
Justice.
The content of the invention
In order to solve the above problems, the invention provides a kind of black matrix erythema droplet temmoku glaze ceramics and preparation technology.
To achieve the above object, the present invention provides black matrix erythema droplet temmoku glaze ceramics, it is characterised in that including iron tire base
Body and erythema oil droplet glaze, the iron tire base substrate, its raw material and parts by weight are as follows：Water Ji 40-50 parts of clay, 20-30 parts of black mud,
10-20 parts of laterite, 10-20 parts of sericite, 1-5 parts of calcite, 1-3 parts of feldspar, the wherein iron oxide in iron tire blank raw material are total
Measure as 5-8%；The erythema oil droplet glaze, its parts by weight of raw materials is as follows：20-30 parts of clay of water Ji, 20-30 parts of quartz, feldspar
20-30 parts, 5-10 parts of talcum, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of bloodstone, 1-5 parts of kaolin, and erythema oil
It is 10-13% to drip the iron oxide total amount in glaze raw material.
Optimization, iron tire base substrate, its raw material and parts by weight are as follows：43 parts of clay of water Ji, 23 parts of black mud, 18 parts of laterite, thin,tough silk
11 parts of mica, 3 parts of calcite, 2 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material are 7%.
Optimization, erythema oil droplet glaze, its parts by weight of raw materials is as follows：Water Ji 28 parts of clay, quartz 24 parts, 27 parts of feldspar,
Iron oxide total amount in 6 parts of talcum, 7 parts of andalusite, 4 parts of wollastonite, bloodstone 2, kaolin 2, and erythema oil droplet glaze raw material
For 12%.
Optimization, iron tire base substrate, its raw material and parts by weight are as follows：48 parts of clay of water Ji, black mud 21, laterite 14, sericite
12 parts, calcite 2,3 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material be 6%.
Optimization, erythema oil droplet glaze, its parts by weight of raw materials is as follows：Water Ji 24 parts of clay, quartz 29 parts, 23 parts of feldspar,
Iron oxide total amount in 8 parts of talcum, 6 parts of andalusite, 2 parts of wollastonite, bloodstone 5, kaolin 3, and erythema oil droplet glaze raw material
For 11%.
The preparation technology of black matrix erythema droplet temmoku glaze ceramics, it is characterised in that prepare above-mentioned black matrix erythema oil droplet day
Mesh glaze ceramics, are comprised the following steps that：
Step 1, by the composition of raw materials composition difference dispensing of iron tire base substrate, iron is made in raw material wet grinding in ball mill
Tire base substrate slurry；
Step 2, the sieving of iron tire base substrate slurry, the dehydration after grinding, dry, iron tire base substrate are made；
Step 3, by erythema oil droplet glaze composition of raw materials composition dispensing, raw material mistake after wet grinding in ball mill respectively
Sieve, is made erythema oil droplet glaze；
Step 4, iron tire biscuit is made through biscuiting in the iron tire base substrate in step 2, applies red made from step 3 on iron tire biscuit
Spot oil droplet glaze；
Step 5, the ceramic body after step 4 glazing is put into kiln, kiln rose under oxidation atmosphere through 1-2 hours
900 DEG C, turn reducing atmosphere, when being warming up to 1000 DEG C through 1-2 hours, be incubated 1-2 hours, be passed through nitrogen, under reducing atmosphere after
Continue and reach firing temperature when rising to 1280-1310 DEG C through 20-30 minutes, remove nitrogen, natural cooling after being incubated 50-60 minutes,
Obtain black matrix erythema droplet temmoku glaze ceramics.
Further, the iron tire base substrate slurry in step 2 crosses 150 mesh sieves.
Further, erythema oil droplet glaze crosses 180 mesh sieves in step 3.
Further, the temperature of step 4 iron biscuiting I 600-630 DEG C, the moisture content of iron tire biscuit is 1.5-2%.
Further, the glazing thickness of the erythema oil-spot glaze of step 4 is 2-4mm, and the B concentration of erythema oil-spot glaze
For 55-60 degree.
From the above-mentioned description of this invention, black matrix erythema droplet temmoku glaze ceramics and its making side that the present invention is provided
Method, iron tire base substrate and erythema oil droplet glaze are configured using raw ore raw material, and the ceramics burnt out have the carcass of atropurpureus, and its is red
Spot oil droplet glaze reflects the speckle of kermesinus from inside to outside, and crystalline particle is remained with glaze layer, is seen with magnifying glass, can be obvious
The sense of movement found out when glaze is molded at high temperature；When burning till, nitrogen progress is filled with using reducing atmosphere and when burning till
Reaction, erythema oil droplet glaze is extracted combustion-supporting with the element in iron tire base substrate, glaze raw material is changed and is recombinated,
Iron reflects the speckle of kermesinus compared with the place of enrichment, and forms crystallization, this kind of black matrix in the place of other Biosorption of Metal Elements
Erythema droplet temmoku glaze ceramic color is exquisite, texture is gentle, with very high enjoying value and artistic value.
Embodiment
Below by way of embodiment, the invention will be further described.
Black matrix erythema droplet temmoku glaze ceramics, including iron tire base substrate and erythema oil droplet glaze,
The iron tire base substrate, its raw material and parts by weight are as follows：40-50 parts of clay of water Ji, 20-30 parts of black mud, laterite 10-20
Part, 10-20 parts of sericite, 1-5 parts of calcite, 1-3 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material are 5-8%；
The erythema oil droplet glaze, its parts by weight of raw materials is as follows：20-30 parts of clay of water Ji, 20-30 parts of quartz, feldspar 20-
30 parts, 5-10 parts of talcum, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of bloodstone, 1-5 parts of kaolin, and erythema oil-spot glaze
It is 10-13% to expect the iron oxide total amount in raw material.
Specific embodiment one：
Black matrix erythema droplet temmoku glaze ceramics, including iron tire base substrate and erythema oil droplet glaze,
Its iron tire blank raw material and parts by weight are as follows：Water Ji 43 parts of clay, 23 parts of black mud, 18 parts of laterite, 11 parts of sericite,
3 parts of calcite, 2 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material are 7%；
Erythema oil droplet glaze, its parts by weight of raw materials is as follows：Water Ji 28 parts of clay, quartz 24 parts, 27 parts of feldspar, 6 parts of talcum,
Iron oxide total amount in 7 parts of andalusite, 4 parts of wollastonite, bloodstone 2, kaolin 2, and erythema oil droplet glaze raw material is 12%.
Specific embodiment two：
Black matrix erythema droplet temmoku glaze ceramics, including iron tire base substrate and erythema oil droplet glaze, its raw material and parts by weight are as follows：
The iron tire base substrate, its raw material and parts by weight are as follows：48 parts of clay of water Ji, black mud 21, laterite 14, sericite 12
Part, calcite 2,3 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material are 6%；
The erythema oil droplet glaze, its parts by weight of raw materials is as follows：24 parts of clay of water Ji, 29 parts of quartz, 23 parts of feldspar, talcum
8 parts, 6 parts of andalusite, 2 parts of wollastonite, bloodstone 5, the iron oxide total amount in kaolin 3, and erythema oil droplet glaze raw material be
11%.
The preparation technology of black matrix erythema droplet temmoku glaze ceramics, prepares above-mentioned black matrix erythema droplet temmoku glaze ceramics, tool
Body step is as follows：
Step 1, by the composition of raw materials composition difference dispensing of iron tire base substrate, iron is made in raw material wet grinding in ball mill
Tire base substrate slurry；
Step 2, the iron tire base substrate slurry after grinding crosses 150 mesh sieves, dehydration, dries, iron tire base substrate is made；
Step 3, by erythema oil droplet glaze composition of raw materials composition dispensing, raw material mistake after wet grinding in ball mill respectively
180 mesh sieves, are made erythema oil droplet glaze；
Step 4, iron tire biscuit is made through 600-630 DEG C of biscuiting in the iron tire base substrate in step 2, and the moisture content of iron tire biscuit is
1.5-2%, applies erythema oil droplet glaze made from step 3 on iron tire biscuit, and the B concentration of erythema oil-spot glaze is during glazing
55-60 degree, glazing thickness are 2-4mm；
Step 5, the ceramic body after step 4 glazing is put into kiln, kiln rose under oxidation atmosphere through 1-2 hours
900 DEG C, turn reducing atmosphere, when being warming up to 1000 DEG C through 1-2 hours, be incubated 1-2 hours, be passed through nitrogen, under reducing atmosphere after
Continue and reach firing temperature when rising to 1280-1310 DEG C through 20-30 minutes, remove nitrogen, natural cooling after being incubated 50-60 minutes,
Obtain black matrix erythema droplet temmoku glaze ceramics.
Embodiment：
The preparation technology of black matrix erythema droplet temmoku glaze ceramics, prepares above-mentioned black matrix erythema droplet temmoku glaze ceramics, tool
Body step is as follows：
Step 1, by the composition of raw materials composition difference dispensing of iron tire base substrate, iron is made in raw material wet grinding in ball mill
Tire base substrate slurry；
Step 2, the iron tire base substrate slurry after grinding crosses 150 mesh sieves, dehydration, dries, iron tire base substrate is made；
Step 3, by erythema oil droplet glaze composition of raw materials composition dispensing, raw material mistake after wet grinding in ball mill respectively
180 mesh sieves, are made erythema oil droplet glaze；
Step 4, iron tire biscuit is made through 620 DEG C of biscuitings in the iron tire base substrate in step 2, and the moisture content of iron tire biscuit is
1.5%, erythema oil droplet glaze made from step 3 is applied on iron tire biscuit, the B concentration of erythema oil-spot glaze is 58 during glazing
Degree, glazing thickness are 3mm；
Step 5, the ceramic body after step 4 glazing is put into kiln, kiln rose under oxidation atmosphere through 1.6 hours
900 DEG C, turn reducing atmosphere, when being warming up to 1000 DEG C through 1.5 hours, be incubated 2 hours, be passed through nitrogen, continue under reducing atmosphere
Firing temperature is reached when rising to 1300 DEG C through 27 minutes, nitrogen is removed, natural cooling after being incubated 60 minutes obtains black matrix erythema oil
Drip temmoku glaze ceramics.
Black matrix erythema droplet temmoku glaze ceramics that the present invention is provided and preparation method thereof, iron tire base is configured using raw ore raw material
Body and erythema oil droplet glaze, the ceramics burnt out have the carcass of atropurpureus, and its erythema oil droplet glaze is reflected from inside to outside
The speckle of kermesinus, and crystalline particle is remained with glaze layer, is seen with magnifying glass, when will be obvious glaze and being molded at high temperature
Sense of movement；When burning till, using reducing atmosphere and it is filled with nitrogen when burning till and is reacted, erythema oil droplet glaze and iron tire base
Element in body is extracted combustion-supporting, glaze raw material is changed and is recombinated, is reflected in iron compared with the place of enrichment dark red
The speckle of color, and in the place formation crystallization of other Biosorption of Metal Elements, this kind of black matrix erythema droplet temmoku glaze ceramic color essence
Beautiful, texture is gentle, with very high enjoying value and artistic value.
Three embodiments of the present invention are above are only, but the design concept of the present invention is not limited thereto, all profits
The change of unsubstantiality is carried out to the present invention with this design, the behavior for invading the scope of the present invention all should be belonged to.
Claims (10)
1. black matrix erythema droplet temmoku glaze is ceramic, it is characterised in that including iron tire base substrate and erythema oil droplet glaze,
The iron tire base substrate, its raw material and parts by weight are as follows：Water Ji 40-50 parts of clay, 20-30 parts of black mud, 10-20 parts of laterite,
10-20 parts of sericite, 1-5 parts of calcite, 1-3 parts of feldspar, wherein the iron oxide total amount in iron tire blank raw material are 5-8%；
The erythema oil droplet glaze, its parts by weight of raw materials is as follows：20-30 parts of clay of water Ji, 20-30 parts of quartz, feldspar 20-30
Part, 5-10 parts of talcum, 5-10 parts of andalusite, 1-5 parts of wollastonite, 1-5 parts of bloodstone, 1-5 parts of kaolin, and erythema oil droplet glaze
Iron oxide total amount in raw material is 10-13%.
2. black matrix erythema droplet temmoku glaze ceramics according to claim 1, it is characterised in that the iron tire base substrate, it is former
Material and parts by weight are as follows：43 parts of clay of water Ji, 23 parts of black mud, 18 parts of laterite, 11 parts of sericite, 3 parts of calcite, 2 parts of feldspar, its
Iron oxide total amount in middle iron tire blank raw material is 7%.
3. black matrix erythema droplet temmoku glaze ceramics according to claim 1 or 2, it is characterised in that：The erythema oil-spot glaze
Material, its parts by weight of raw materials is as follows：28 parts of clay of water Ji, 24 parts of quartz, 27 parts of feldspar, 6 parts of talcum, 7 parts of andalusite, wollastonite 4
Iron oxide total amount in part, bloodstone 2, kaolin 2, and erythema oil droplet glaze raw material is 12%.
4. black matrix erythema droplet temmoku glaze ceramics according to claim 3, it is characterised in that：The iron tire base substrate, it is former
Material and parts by weight are as follows：48 parts of clay of water Ji, black mud 21, laterite 14,12 parts of sericite, calcite 2, wherein 3 parts of feldspar, iron tire
Iron oxide total amount in blank raw material is 6%.
5. black matrix erythema droplet temmoku glaze ceramics according to claim 1 or 2, it is characterised in that：The erythema oil-spot glaze
Material, its parts by weight of raw materials is as follows：24 parts of clay of water Ji, 29 parts of quartz, 23 parts of feldspar, 8 parts of talcum, 6 parts of andalusite, wollastonite 2
Iron oxide total amount in part, bloodstone 5, kaolin 3, and erythema oil droplet glaze raw material is 11%.
6. the preparation technology of black matrix erythema droplet temmoku glaze ceramics, it is characterised in that the black matrix prepared described in claim 1-5 is red
Spot droplet temmoku glaze ceramics, are comprised the following steps that：
Step 1, by the composition of raw materials composition difference dispensing of iron tire base substrate, iron tire base is made in raw material wet grinding in ball mill
Somaplasm material；
Step 2, the sieving of iron tire base substrate slurry, the dehydration after grinding, dry, iron tire base substrate are made；
Step 3, by dispensing, the raw material sieving after wet grinding in ball mill respectively of erythema oil droplet glaze composition of raw materials composition, make
Into erythema oil droplet glaze；
Step 4, iron tire biscuit is made through biscuiting in the iron tire base substrate in step 2, and erythema oil made from step 3 is applied on iron tire biscuit
Drip glaze；
Step 5, the ceramic body after step 4 glazing is put into kiln, kiln rose to 900 under oxidation atmosphere through 1-2 hours
DEG C, turn reducing atmosphere, when being warming up to 1000 DEG C through 1-2 hours, be incubated 1-2 hours, be passed through nitrogen, continue on through under reducing atmosphere
Firing temperature being reached when rising to 1280-1310 DEG C within 20-30 minutes, removing nitrogen, natural cooling after being incubated 50-60 minutes is obtained
Black matrix erythema droplet temmoku glaze ceramics.
7. the preparation technology of black matrix erythema droplet temmoku glaze ceramics according to claim 6, it is characterised in that：The step
Iron tire base substrate slurry in 2 crosses 150 mesh sieves.
8. the preparation technology of black matrix erythema droplet temmoku glaze ceramics according to claim 7, it is characterised in that：In step 3
Erythema oil droplet glaze crosses 180 mesh sieves.
9. the preparation technology of black matrix erythema droplet temmoku glaze ceramics according to claim 6, it is characterised in that：Step 4 iron
The temperature of biscuiting I 600-630 DEG C, the moisture content of iron tire biscuit is 1.5-2%.
10. the preparation technology of the black matrix erythema droplet temmoku glaze ceramics according to claim 6 or 9, it is characterised in that：Step
The glazing thickness of 4 erythema oil-spot glaze is 2-4mm, and the B concentration of erythema oil-spot glaze is 55-60 degree.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710397617.5A CN107098677B (en) | 2017-05-31 | 2017-05-31 | Black-bottom red-spot oil-drop temmoku glaze ceramic and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710397617.5A CN107098677B (en) | 2017-05-31 | 2017-05-31 | Black-bottom red-spot oil-drop temmoku glaze ceramic and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107098677A true CN107098677A (en) | 2017-08-29 |
| CN107098677B CN107098677B (en) | 2020-07-21 |
Family
ID=59660060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710397617.5A Active CN107098677B (en) | 2017-05-31 | 2017-05-31 | Black-bottom red-spot oil-drop temmoku glaze ceramic and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107098677B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095893A (en) * | 2018-10-25 | 2018-12-28 | 福建省德化县冠鸿陶瓷有限公司 | A kind of acid and alkali-resistance ceramic ware for daily use and preparation method thereof |
| CN111499339A (en) * | 2020-03-13 | 2020-08-07 | 魏宝华 | Firing method of color-bottom color-drop golden-edge building cup |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
| CN115849866A (en) * | 2022-11-17 | 2023-03-28 | 福建省德化县华达陶瓷有限公司 | Tianmu ceramic and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020015538A (en) * | 2000-08-22 | 2002-02-28 | 김대진 | The method of preparing glaze for chinaware and its application method |
| CN1724477A (en) * | 2005-05-25 | 2006-01-25 | 广东全福陶瓷实业有限公司 | Manufacturing method of redyohen tenmoku ceramic and ceramic glaze used therefor |
| CN103172406A (en) * | 2013-04-12 | 2013-06-26 | 徐维茂 | Gold spot temmoku glaze and preparation technology thereof |
| CN105906335A (en) * | 2016-04-20 | 2016-08-31 | 河南天目瓷文化有限公司 | Raw material formula of oil-drop temmoku porcelain and preparation method of same |
| CN106277785A (en) * | 2016-08-18 | 2017-01-04 | 温书强 | A kind of black matrix erythema pottery glaze |
-
2017
- 2017-05-31 CN CN201710397617.5A patent/CN107098677B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020015538A (en) * | 2000-08-22 | 2002-02-28 | 김대진 | The method of preparing glaze for chinaware and its application method |
| CN1724477A (en) * | 2005-05-25 | 2006-01-25 | 广东全福陶瓷实业有限公司 | Manufacturing method of redyohen tenmoku ceramic and ceramic glaze used therefor |
| CN103172406A (en) * | 2013-04-12 | 2013-06-26 | 徐维茂 | Gold spot temmoku glaze and preparation technology thereof |
| CN105906335A (en) * | 2016-04-20 | 2016-08-31 | 河南天目瓷文化有限公司 | Raw material formula of oil-drop temmoku porcelain and preparation method of same |
| CN106277785A (en) * | 2016-08-18 | 2017-01-04 | 温书强 | A kind of black matrix erythema pottery glaze |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095893A (en) * | 2018-10-25 | 2018-12-28 | 福建省德化县冠鸿陶瓷有限公司 | A kind of acid and alkali-resistance ceramic ware for daily use and preparation method thereof |
| CN111499339A (en) * | 2020-03-13 | 2020-08-07 | 魏宝华 | Firing method of color-bottom color-drop golden-edge building cup |
| CN111499339B (en) * | 2020-03-13 | 2022-06-07 | 南平市曜变陶瓷研究院 | Firing method of color-bottom color-drop golden-edge building cup |
| CN112479589A (en) * | 2020-12-24 | 2021-03-12 | 湖州海程塑业有限公司 | Light pink glaze and preparation method thereof |
| CN115849866A (en) * | 2022-11-17 | 2023-03-28 | 福建省德化县华达陶瓷有限公司 | Tianmu ceramic and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107098677B (en) | 2020-07-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107098677A (en) | Black matrix erythema droplet temmoku glaze ceramics and its preparation technology | |
| CN105924230B (en) | Portoro glaze and production method with Portoro glaze ceramics | |
| CN105693207B (en) | A kind of preparation method of tea dust artistic porcelain | |
| CN102219561B (en) | Production method of streaked glaze with leopard spots | |
| CN107602152B (en) | Green and white glaze for Jun porcelain and process for preparing Jun porcelain by using green and white glaze for Jun porcelain | |
| CN104150965A (en) | Copper red glaze formula and manufacturing process of copper red glaze porcelain | |
| CN102898121A (en) | Ru-kiln celadon ware and preparation process thereof | |
| CN105884197A (en) | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze | |
| CN100360462C (en) | Glaze coloured decoration daily use poocelain and its production method | |
| CN105036810A (en) | Black-base mottled composite Tang jun glaze and process for preparing jun porcelain through black-base mottled composite Tang jun glaze | |
| CN105036809A (en) | Blue background and mottled spot composite Tang jun glaze and technology for preparing jun porcelain through same | |
| CN104496555B (en) | Imitative ceramic metal artistic glaze and preparation and application thereof | |
| CN105175020A (en) | Complex Tang-dynasty jun glaze with blue spots in black and process for preparing jun porcelain by use of complex Tang-dynasty jun glaze | |
| CN102173737B (en) | Manufacturing process of colored kiln-transformation ceramic product | |
| CN105175017A (en) | Complex Tang-dynasty jun glaze with white spots in blue and process for preparing jun porcelain by use of complex Tang-dynasty jun glaze | |
| KR20180123308A (en) | Method for manufacturing a heat-resistant ceramic using a multi-colored high-strength pigment composition for ceramics and a multi-colored high-strength pigment composition for ceramics and a heat-resistant ceramic | |
| CN106517781A (en) | Purple and golden glaze and preparation method thereof | |
| CN104788079A (en) | Slip casting preparation method for high-whiteness earthenware | |
| CN107010922B (en) | Preparation method of transmutation glaze purple sand fine pottery | |
| CN100417619C (en) | Method for manufacturing Yao Country porcelain with red body and jade lines | |
| CN102515864A (en) | Gold crystal glaze domestic ceramic glaze material | |
| CN105924007A (en) | Fancy glaze and preparing method thereof | |
| CN105175019A (en) | Complex Tang-dynasty jun glaze with red spots in black and process for preparing jun porcelain by use of complex Tang-dynasty jun glaze | |
| CN107586038B (en) | Process for preparing jun porcelain from green and white glaze for jun porcelain | |
| CN105254275A (en) | Ge kiln porcelain formula and manufacturing process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |