CN107097478A - A kind of Ceramic Tiles with heating function and preparation method thereof - Google Patents
A kind of Ceramic Tiles with heating function and preparation method thereof Download PDFInfo
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- CN107097478A CN107097478A CN201710228995.0A CN201710228995A CN107097478A CN 107097478 A CN107097478 A CN 107097478A CN 201710228995 A CN201710228995 A CN 201710228995A CN 107097478 A CN107097478 A CN 107097478A
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- ceramic tiles
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- heat
- cavity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/20—Layered products comprising a layer of natural or synthetic rubber comprising silicone rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/043—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/28—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
- H05B3/286—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material the insulating material being an organic material, e.g. plastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
- B32B2419/04—Tiles for floors or walls
Abstract
The invention discloses a kind of Ceramic Tiles with heating function, its by ceramic brick layer and with cavity Ceramic Tiles basalis laminating form, the cavity is located at binding face side, filled with insulation heat preservation layer, heating layer and the insulated enclosure heat-conducting layer stacked gradually from bottom to top in cavity, metal electrode and temperature sensor are provided with the heating layer.Cavity of the invention by being provided for filling heating function composite bed in the binding face side of ceramic brick layer and Ceramic Tiles basalis, further limit the Rotating fields of composite bed, including setting up the inorganic heat-reflecting layer of near-infrared, the heat that heating layer is distributed is efficiently transfer to ceramic brick layer while effectively preventing heat from transmitting downwards, greatly improves the heating efficiency and heat-insulating property of the Ceramic Tiles.The invention also discloses its preparation method, its preparation technology is simple, production cost is low, strong operability, is conducive to industrialization to mass produce.
Description
Technical field
The present invention relates to feature architectural pottery field, more particularly to a kind of Ceramic Tiles and its preparation with heating function
Method.
Background technology
Ceramic Tiles turn into a kind of conventional Household ornament material, quilt by the excellent properties of itself and unique decorative effect
It is widely used in the decoration of ground and metope.In recent years, there are some Ceramic Tiles that can be heated, can be room in cold weather
Interior heating, area of dissipation is big, great application prospect.Ceramic Tiles with heating function are typically by electric heating material such as electric heating
Silk, electrothermal tube etc. are embedded under Ceramic Tiles matrix, realize that ceramic matrix is heated by way of electrical heating and heat transfer.But electricity
Heated filament class mode of heating contact area is smaller, and overall electrothermal efficiency is very low, and the heating wire life-span is shorter.
Electric radiant Heating Film is that, using the face of generating heat as thermal source, because its contact area is big, the thermal efficiency is higher, gradually instead of heating wire
Class heating source.
Chinese patent CN205918049U discloses a kind of electrothermal heating Ceramic Tiles and its paving arranging system, its Electric radiant Heating Film
Using one kind in the composite membrane of metal oxide film, metal film or metal oxide and metal.
Chinese patent CN205857573U discloses a kind of graphene heating ceramic tile, is produced by being powered to graphite ene coatings
Heat realizes the heating function of Ceramic Tiles.But the invention lacks necessary heat-insulation layer so that heating brick heat in actual applications
Not only it is communicated up, while can also transmit cement layer downwards, has had a strong impact on the thermal efficiency of heating ceramic brick.
Chinese patent CN105318398A discloses a kind of electrical heating ceramic tile and electrical heating ceramic tile heating system, by that will adopt
Warm sandwich layer is arranged at below ceramic tile and required heat dissipating layer, and has insulating later.But heat insulation layer is moulded for foaming
Expect material, to realize preferable heat insulation effect, foamed plastic thickness must be thick, and actual finishing can take larger space, together
When the easy aging of foamed plastic in the environment heated for a long time.
Chinese patent CN105025598A discloses a kind of electric composite ceramic brick and preparation method thereof, the Ceramic Tiles be
Ceramic bases without being coated with electro-thermal coatings, draw link electrode, coating insulation-encapsulated waterproof layer, apply foamed ceramic successively on glaze
Layer.But foamed ceramic layer thermal conductivity factor 0.15 watt/（Meter Du）Left and right, only relies on foamed ceramic layer as heat-insulation layer, insulation
Effect is not good, and heat is easily lost in, and the thermal efficiency is relatively low.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art there is provided a kind of Ceramic Tiles with heating function and
Its preparation method.
The technical solution used in the present invention is：A kind of Ceramic Tiles with heating function, it is by ceramic brick layer and carries
The Ceramic Tiles basalis laminating of cavity is formed, and the cavity, which is located in binding face side, cavity, is filled with from bottom to top layer successively
Metal electrode and temperature sensor are provided with folded insulation heat preservation layer, heating layer and insulated enclosure heat-conducting layer, the heating layer.
Specifically, the lamination layer structure stacked gradually by insulation heat preservation layer, heating layer and insulated enclosure conductive layer so that can
Direction is distributed to the heat of heating layer to regulate and control, that is, prevents heat transmission downwards that heating layer is distributed and to be oriented to it efficiently upward
Transmission.
In fact, the Ceramic Tiles basalis of the present invention is light porous Ceramic Tiles basalis, which ensure that whole ceramics
Brick has excellent mechanical property and aft-loaded airfoil performance.Further, the thickness of light porous ceramic brick basalis be 1.8 ~
2.4cm, its constitution density is not higher than 1g/cm3, thermal conductivity factor be not higher than 0.2 watt/（Meter Du）.
As the further improvement of such scheme, it is additionally provided between the bottom surface of the insulated enclosure heat-conducting layer and cavity near red
Outer inorganic heat-reflecting layer, its thickness is 0.2 ~ 0.3mm, so as to further strengthen the heat insulation effect of whole Ceramic Tiles.
As the further improvement of such scheme, the heating layer is graphite ene coatings.Specifically, using graphene conduct
Generate heat layer material, with heating is uniform, heat conduction is fast, zero attenuation, long lifespan the features such as.Further, the thickness of the heating layer
Spend for 0.2 ~ 0.4mm.
As the further improvement of such scheme, the insulation heat preservation layer is aerogel layer.Further, the aeroge
One of which in aerosil, alumina aerogels or zirconia aerogels.The present invention uses thermal conductivity factor
Extremely low aeroge can effectively improve the thermal efficiency of whole Ceramic Tiles, effectively prevent heat from passing downwards as heat-insulating material
Pass, while the aeroge selected is inorganic material, it is respectively provided with excellent anti-ageing performance.The thickness of insulation heat preservation layer of the present invention
For 0.6 ~ 0.8mm, its thermal conductivity factor be not higher than 0.08 watt/（Meter Du）.
As the further improvement of such scheme, the insulated enclosure heat-conducting layer is heat conduction organosilicon glue-line, and it has close
The characteristics of sealing good effect and fast heat transfer, greatly improves the firing rate of Ceramic Tiles layer surface temperature.Insulated enclosure of the present invention
The thickness of heat-conducting layer is 0.3 ~ 0.5mm, and its specific insulation is not less than 1 × 1015Ohmcm.
A kind of preparation method of the Ceramic Tiles as described above with heating function, it is comprised the technical steps that：
1）Process to form the high cavity of middle low edge in Ceramic Tiles basalis binding face side using blasting craft, at cavity bottom
Portion's spray insulation heat-insulation layer；
2）After after insulation heat preservation layer solidification by way of silk-screen printing heating layer in charity, while installing metal electrode and temperature
Sensor, then uses the tape casting charity insulated enclosure heat-conducting layer on heating layer；
3）In Ceramic Tiles basalis raised brim charity adhesive glue, ceramic brick layer is fitted with Ceramic Tiles basalis, glue to be bonded
The Ceramic Tiles finished product with heating function is produced after solidification.
It is that preferably composite bed of the filling with heating function is combined, on Ceramic Tiles basalis of the present invention in actual production
Cavity bottom than the raised low 1.2 ~ 1.8mm in marginal portion.
It is near in the spraying of cavity bottom before being additionally included in spray insulation heat-insulation layer as the further improvement of such scheme
Infrared inorganic heat-reflecting layer.
As the further improvement of such scheme, the series-parallel connection texture row that the heating layer is combined in parallel and serial by presenting
The graphite ene coatings composition of cloth.
As the further improvement of such scheme, the temperature sensor scope of the temperature sensor is -10 ~ 80 DEG C.
The beneficial effects of the invention are as follows：
（1）The present invention is combined by being provided for filling heating function in the binding face side of ceramic brick layer and Ceramic Tiles basalis
The cavity of layer, further limits the Rotating fields of composite bed, including sets up the inorganic heat-reflecting layer of near-infrared so that what heating layer was distributed
Heat can be efficiently transfer to ceramic brick layer while effectively preventing heat from transmitting downwards, greatly improve the heating efficiency of the Ceramic Tiles
And heat-insulating property.
（2）The present invention carries out particular determination to the material of heating layer, insulated enclosure heat-conducting layer and insulation heat preservation layer, further
Improve the efficiency of heating surface and heat-insulating property of whole Ceramic Tiles.
（3）Preparation technology of the invention is simple, production cost is low, strong operability, is conducive to industrialization to mass produce.
Brief description of the drawings
Accompanying drawing 1 is Rotating fields schematic diagram of the invention；
Accompanying drawing 2 is the texture arrangement schematic diagram of the graphite ene coatings of the present invention.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Referring to the drawings 1, a kind of Ceramic Tiles with heating function, it is by ceramic brick layer 4 and the Ceramic Tiles base with cavity
The laminating of bottom 1 is formed, and the cavity is located in binding face side, cavity filled with the insulation heat preservation layer stacked gradually from bottom to top
21st, metal electrode 31 and temperature sensor 32 are provided with heating layer 22 and insulated enclosure heat-conducting layer 23, the heating layer 22.
It is inorganic that near-infrared is additionally provided with as further embodiment, between the bottom surface of the insulated enclosure heat-conducting layer and cavity
Heat-reflecting layer 24.
As further embodiment, the Ceramic Tiles basalis 1 is light porous Ceramic Tiles basalis, and its constitution is close
Degree is not higher than 1g/cm3, thermal conductivity factor be not higher than 0.2 watt/（Meter Du）, thickness is 1.8 ~ 2.4cm；The heating layer 22 is graphite
Ene coatings, its thickness is 0.2 ~ 0.4mm；The insulation heat preservation layer 21 be aerogel layer, its thermal conductivity factor be not higher than 0.08 watt/
（Meter Du）, thickness is 0.6 ~ 0.8mm；The insulated enclosure heat-conducting layer 23 is heat conduction organosilicon glue-line, and its specific insulation is not low
In 1 × 1015Ohmcm, thickness is 0.3 ~ 0.5mm.
Preparation method：
1）Process to form high recessed of middle low edge in light porous Ceramic Tiles basalis binding face side using blasting craft
Chamber, wherein cavity bottom than the raised low 1.2 ~ 1.8mm in marginal portion, after in the first coating thickness in cavity bottom be 0.2 ~ 0.3mm
The inorganic heat-reflecting layer of near-infrared again coating thickness be 0.6 ~ 0.8mm insulation heat preservation layer or direct spraying insulation heat preservation layer, its
One of which of the material of insulation heat preservation layer in aerosil, alumina aerogels or zirconia aerogels；
2）Thickness is 0.2 ~ 0.4mm's and parallel connection is presented in charity by way of silk-screen printing after insulation heat preservation layer solidifies
The graphene heating layer for the series-parallel connection texture arrangement being combined with series connection（As shown in Figure 2）, while installing metal electrode and temperature
Sensor, specific metal electrode selects conductive copper sheet interface, then use the tape casting on heating layer charity thickness for 0.3 ~
0.5mm insulated enclosure heat-conducting layer；
3）In Ceramic Tiles basalis raised brim charity adhesive glue, ceramic brick layer is fitted with Ceramic Tiles basalis, glue to be bonded
The Ceramic Tiles finished product with heating function is produced after solidification.
The Ceramic Tiles that the present invention is prepared are made test sample and carry out correlated performance detection, and testing result shows it not
Ceramic Tiles excellent mechanical property and aft-loaded airfoil performance are only maintained, while its surface has efficient heating function, and entirely
Ceramic Tiles have good heat-insulating property.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (10)
1. a kind of Ceramic Tiles with heating function, it is characterised in that：By ceramic brick layer（4）With the Ceramic Tiles substrate with cavity
Layer（1）Laminating is formed, and the cavity is located in binding face side, cavity filled with the insulation heat preservation layer stacked gradually from bottom to top
（21）, heating layer（22）With insulated enclosure heat-conducting layer（23）, the heating layer（22）In be provided with metal electrode（31）Passed with temperature
Sensor（32）.
2. a kind of Ceramic Tiles with heating function according to claim 1, it is characterised in that：The insulated enclosure heat conduction
Layer（23）The inorganic heat-reflecting layer of near-infrared is additionally provided between the bottom surface of cavity（24）.
3. a kind of Ceramic Tiles with heating function according to claim 1, it is characterised in that：The heating layer（22）For
Graphite ene coatings.
4. a kind of Ceramic Tiles with heating function according to claim 1 or 3, it is characterised in that：The heating layer
（22）Thickness be 0.2 ~ 0.4mm.
5. a kind of Ceramic Tiles with heating function according to claim 1, it is characterised in that：The insulation heat preservation layer
（21）For aerogel layer.
6. a kind of Ceramic Tiles with heating function according to claim 5, it is characterised in that：The aeroge is selected from two
One of which in silica aerogel, alumina aerogels or zirconia aerogels.
7. a kind of Ceramic Tiles with heating function according to claim 1, it is characterised in that：The insulated enclosure heat conduction
Layer（23）For heat conduction organosilicon glue-line.
8. a kind of preparation method of Ceramic Tiles with heating function as described in any one of claim 1 ~ 7, it is characterised in that
Comprise the technical steps that：
1）Process to form the high cavity of middle low edge in Ceramic Tiles basalis binding face side using blasting craft, at cavity bottom
Portion's spray insulation heat-insulation layer（21）；
2）After after insulation heat preservation layer solidification by way of silk-screen printing heating layer in charity（22）, while installing metal electrode
（31）And temperature sensor（32）, then use the tape casting charity insulated enclosure heat-conducting layer on heating layer（23）；
3）In Ceramic Tiles basalis raised brim charity adhesive glue, ceramic brick layer is fitted with Ceramic Tiles basalis, glue to be bonded
The Ceramic Tiles finished product with heating function is produced after solidification.
9. a kind of preparation method of Ceramic Tiles with heating function according to claim 8, it is characterised in that：Also include
In spray insulation heat-insulation layer（21）The inorganic heat-reflecting layer of near-infrared is sprayed in cavity bottom before（24）.
10. a kind of preparation method of Ceramic Tiles with heating function according to claim 8, it is characterised in that：It is described
Heating layer（22）The graphite ene coatings for the series-parallel connection texture arrangement being combined in parallel and serial by presenting are constituted.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710228995.0A CN107097478A (en) | 2017-04-10 | 2017-04-10 | A kind of Ceramic Tiles with heating function and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710228995.0A CN107097478A (en) | 2017-04-10 | 2017-04-10 | A kind of Ceramic Tiles with heating function and preparation method thereof |
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| Publication Number | Publication Date |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108360789A (en) * | 2018-04-16 | 2018-08-03 | 广东金意陶陶瓷集团有限公司 | A kind of electric heating ceramic tile with long service life and production method |
| CN108590098A (en) * | 2018-04-16 | 2018-09-28 | 广东金意陶陶瓷集团有限公司 | The electric heating ceramic tile and production method of a kind of high heat conduction and consistent heat generation |
| CN108620299A (en) * | 2018-02-27 | 2018-10-09 | 古（广东）建材有限公司 | A kind of method for making decorative plate with Heated by Far-Infrared Radiation function |
| CN109348554A (en) * | 2018-10-16 | 2019-02-15 | 浙江云墨绿能科技有限公司 | A kind of electric heating film and preparation method thereof of nano ceramics graphene composite structure |
| CN109501328A (en) * | 2018-11-29 | 2019-03-22 | 江苏科强新材料股份有限公司 | The preparation process of fever offset plate |
| CN110056163A (en) * | 2019-05-29 | 2019-07-26 | 上海热丽科技集团有限公司 | A kind of spontaneous heating ceramic tile, preparation process and its method for paving |
| GB2571292A (en) * | 2018-02-22 | 2019-08-28 | Graphene Composites Ltd | Composite structure and method of manufacture |
| CN111688316A (en) * | 2020-07-24 | 2020-09-22 | 武汉联维新材料科技有限公司 | Graphene multilayer composite heat insulation film and preparation method and application thereof |
| GB2587889A (en) * | 2018-02-22 | 2021-04-14 | Graphene Composites Ltd | Composite structure and method of manufacture |
| CN112878620A (en) * | 2021-03-04 | 2021-06-01 | 季华实验室 | Preparation method of heating ceramic tile and heating ceramic tile |
| CN113914577A (en) * | 2021-09-22 | 2022-01-11 | 江苏齐盛热能科技有限公司 | Anti-skid stain-resistant far infrared electric heating ceramic tile |
| US11635280B2 (en) | 2018-05-18 | 2023-04-25 | Graphene Composites Limited | Protective shield, shield wall and shield wall assembly |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2587889A (en) * | 2018-02-22 | 2021-04-14 | Graphene Composites Ltd | Composite structure and method of manufacture |
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| CN108590098A (en) * | 2018-04-16 | 2018-09-28 | 广东金意陶陶瓷集团有限公司 | The electric heating ceramic tile and production method of a kind of high heat conduction and consistent heat generation |
| CN108360789A (en) * | 2018-04-16 | 2018-08-03 | 广东金意陶陶瓷集团有限公司 | A kind of electric heating ceramic tile with long service life and production method |
| US11635280B2 (en) | 2018-05-18 | 2023-04-25 | Graphene Composites Limited | Protective shield, shield wall and shield wall assembly |
| CN109348554A (en) * | 2018-10-16 | 2019-02-15 | 浙江云墨绿能科技有限公司 | A kind of electric heating film and preparation method thereof of nano ceramics graphene composite structure |
| CN109501328A (en) * | 2018-11-29 | 2019-03-22 | 江苏科强新材料股份有限公司 | The preparation process of fever offset plate |
| CN110056163A (en) * | 2019-05-29 | 2019-07-26 | 上海热丽科技集团有限公司 | A kind of spontaneous heating ceramic tile, preparation process and its method for paving |
| CN111688316A (en) * | 2020-07-24 | 2020-09-22 | 武汉联维新材料科技有限公司 | Graphene multilayer composite heat insulation film and preparation method and application thereof |
| CN112878620B (en) * | 2021-03-04 | 2022-07-22 | 季华实验室 | Preparation method of heating ceramic tile and heating ceramic tile |
| CN112878620A (en) * | 2021-03-04 | 2021-06-01 | 季华实验室 | Preparation method of heating ceramic tile and heating ceramic tile |
| CN113914577A (en) * | 2021-09-22 | 2022-01-11 | 江苏齐盛热能科技有限公司 | Anti-skid stain-resistant far infrared electric heating ceramic tile |
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Address after: 528137 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan Applicant after: Foshan Oushennuo Ceramic Co., Ltd. Address before: 528000 fan Lake Industrial Park, Leping Town, Sanshui District, Foshan, Guangdong Applicant before: Foshan Oceano Ceramic Co., Ltd. |
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