CN107090210A - A kind of ink of high stability and preparation method thereof - Google Patents
A kind of ink of high stability and preparation method thereof Download PDFInfo
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- CN107090210A CN107090210A CN201710328612.7A CN201710328612A CN107090210A CN 107090210 A CN107090210 A CN 107090210A CN 201710328612 A CN201710328612 A CN 201710328612A CN 107090210 A CN107090210 A CN 107090210A
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- parts
- stabilizer
- ink
- high stability
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
Abstract
The invention discloses a kind of ink of high stability and preparation method thereof, the ink of this kind of high stability is made up of the raw material below according to parts by weight：3 ~ 10 parts of 30 ~ 40 parts of cigarette material, 20 ~ 30 parts of Arabic gum, 10 ~ 15 parts of palm oil, 5 ~ 12 parts of glycerine, 12 ~ 20 parts of stabilizer, 0.1 ~ 1.5 part of graft acrylamide and vinyl acetate, stabilizer is by polypropylene, CNT, silane coupler according to 2:5:3 are prepared from.The black hardness of this kind of high stability is high, non-friable, and safety non-toxic, raw material is cheap and easy to get, and production cost is low, has used stabilizer, effectively improves the stability of ink.The black preparation method of this kind of high stability, simple production process, flow are short, suitable for industrialized production.
Description
Technical field
The present invention relates to the black technical field of system, and in particular to a kind of ink of high stability and preparation method thereof.
Background technology
Ink is the china ink stick that ancient Chinese writing and drawing are used.The primary raw material of ink is carbon black, pine soot, glue etc., is carbon member
Element is with the presence of noncrystalline kenel.Prepared Chinese ink for brush writing can be produced by the grinding of inkstone water, with colloid in water
Solution is present.Wherein Huizhou inkstick be using pine soot, tung oil cigarette, paint cigarette, glue be primary raw material be made it is a kind of mainly for conventional book
The special pigment that method, drawing are used.Through light a cigarette and expect, press mill, dry, frustrate side, paint in gold, the process such as mounted box is refined forms, finished product
With the black profit of color and luster, it is hard and have light, enter that paper is not dizzy, lick pen not glue, it is prolonged do not move back, fragrance is strong the features such as.However, traditional ink
Preserve more difficult, now retain a small amount of Gu Mo, mostly broken or breakage, only few small ink-stick is able to intact guarantor
Deposit.
The content of the invention
Present invention aims at a kind of ink of high stability and preparation method thereof is provided, to solve what is mentioned in above-mentioned background
Problem.
To achieve the above object, the present invention provides following technical scheme：
A kind of ink of high stability, is made up of the raw material below according to parts by weight：30 ~ 40 parts of cigarette material, 20 ~ 30 parts of Arabic gum,
3 ~ 10 parts of 10 ~ 15 parts of palm oil, 5 ~ 12 parts of glycerine, 12 ~ 20 parts of stabilizer, 0.1 ~ 1.5 part of graft acrylamide and vinyl acetate.
It is used as further scheme of the invention：The ink of the high stability, is made up of the raw material below according to parts by weight：Cigarette
32 ~ 38 parts of material, 22 ~ 27 parts of Arabic gum, 11 ~ 14 parts of palm oil, 7 ~ 10 parts of glycerine, 14 ~ 18 parts of stabilizer, graft acrylamide
0.2 ~ 1.1 part and 5 ~ 8 parts of vinyl acetate.
It is used as further scheme of the invention：The ink of the high stability, is made up of the raw material below according to parts by weight：Cigarette
35 parts of material, 25 parts of Arabic gum, 12 parts of palm oil, 9 parts of glycerine, 16 parts of stabilizer, 0.4 part of graft acrylamide and vinyl acetate
6 parts.
It is used as further scheme of the invention：The black stabilizer of the high stability is even by polypropylene, CNT, silane
Join agent according to 2:5:3 are prepared from.
A kind of black preparation method of high stability, comprises the following steps：
1）Dispensing is carried out according to raw material composition and its parts by weight proportioning；
2）By in polypropylene, the well mixed addition silane coupler of CNT, 5h is stood at a temperature of 50 ~ 80 DEG C, is cooled to
Room temperature, obtains stabilizer；
3）Cigarette material, Arabic gum are added in palm oil, 15 ~ 20min is stirred at a temperature of 50 ~ 60 DEG C, mixture A is obtained；
4）Vinyl acetate, graft acrylamide are added in glycerine, work overtime 10 ~ 15min at a temperature of 30 ~ 50 DEG C, is mixed
Thing B；
5）Mixture A, mixture B are mixed, 30 ~ 45min is stirred at a temperature of 20 ~ 30 DEG C, stabilizer is added while stirring, with
After be cooled to room temperature, produce.
The black hardness of the high stability of the present invention is high, non-friable, and safety non-toxic, raw material is cheap and easy to get, and production cost is low, makes
With stabilizer, the stability of ink is effectively improved.The black preparation method of this kind of high stability, simple production process, flow are short,
Suitable for industrialized production.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of ink of high stability is made up of the raw material below according to parts by weight：30 parts of cigarette material, I
3 parts of primary 20 parts of glue, 10 parts of palm oil, 5 parts of glycerine, 12 parts of stabilizer, 0.1 part of graft acrylamide and vinyl acetate.
The black stabilizer of high stability is by polypropylene, CNT, silane coupler according to 2:5:3 are prepared from.
A kind of black preparation method of high stability, comprises the following steps：
1）Dispensing is carried out according to raw material composition and its parts by weight proportioning；
2）By in polypropylene, the well mixed addition silane coupler of CNT, 5h is stood at a temperature of 50 ~ 80 DEG C, is cooled to
Room temperature, obtains stabilizer；
3）Cigarette material, Arabic gum are added in palm oil, 15 ~ 20min is stirred at a temperature of 50 ~ 60 DEG C, mixture A is obtained；
4）Vinyl acetate, graft acrylamide are added in glycerine, work overtime 10 ~ 15min at a temperature of 30 ~ 50 DEG C, is mixed
Thing B；
5）Mixture A, mixture B are mixed, 30 ~ 45min is stirred at a temperature of 20 ~ 30 DEG C, stabilizer is added while stirring, with
After be cooled to room temperature, produce.
Embodiment 2
In the embodiment of the present invention, a kind of ink of high stability is made up of the raw material below according to parts by weight：40 parts of cigarette material, I
10 parts of primary 30 parts of glue, 15 parts of palm oil, 12 parts of glycerine, 20 parts of stabilizer, 1.5 parts of graft acrylamide and vinyl acetate.
The black stabilizer of high stability is by polypropylene, CNT, silane coupler according to 2:5:3 are prepared from.
Preparation method be the same as Example 1.
Embodiment 3
In the embodiment of the present invention, a kind of ink of high stability is made up of the raw material below according to parts by weight：35 parts of cigarette material, I
6 parts of primary 25 parts of glue, 12 parts of palm oil, 9 parts of glycerine, 16 parts of stabilizer, 0.4 part of graft acrylamide and vinyl acetate.
The black stabilizer of high stability is by polypropylene, CNT, silane coupler according to 2:5:3 are prepared from.
Preparation method be the same as Example 1.
Comparative example 1
In the embodiment of the present invention, Yi Zhongmo is made up of the raw material below according to parts by weight：35 parts of cigarette material, 25 parts of Arabic gum, palm fibre
6 parts of 12 parts of palmitic acid oil, 9 parts of glycerine and vinyl acetate.
A kind of black preparation method, comprises the following steps：
1）Dispensing is carried out according to raw material composition and its parts by weight proportioning；
2）Cigarette material, Arabic gum are added in palm oil, 15 ~ 20min is stirred at a temperature of 50 ~ 60 DEG C, mixture A is obtained；
3）Vinyl acetate is added in glycerine, work overtime 10 ~ 15min at a temperature of 30 ~ 50 DEG C, obtains mixture B；
4）Mixture A, mixture B are mixed, 30 ~ 45min is stirred at a temperature of 20 ~ 30 DEG C, room temperature is then cooled to, produces.
Examine the black stability approach of above-mentioned high stability as follows.
According to the formula of embodiment 1 ~ 3 and comparative example 1, the ink of phase homogenous quantities is prepared, ink is measured using dynamic light scattering method
The particle diameter distribution of pigment.Ink is preserved 15 days at 90 DEG C, the particle diameter distribution of black pigment, measurement result are determined by the same way
It is shown in Table 1.
Table 1
| 0.1~0.3mm | 0.3~0.5mm | 0.5~0.7mm | 0.8~1.0mm | |
| Embodiment 1 | 18% | 25% | 25% | 32% |
| Embodiment 2 | 15% | 25% | 36% | 24% |
| Embodiment 3 | 20% | 24% | 28% | 28% |
| Comparative example 1 | 40% | 10% | 6% | 44% |
Particle diameter distribution is still more uniform after high-temperature process in embodiment 1 ~ 3 knowable to data in table, i.e., stability is preferable.Therefore
The stabilizer and graft acrylamide of addition can effectively lift the stability of ink, and according to the proportioning effect in embodiment 3
Most preferably.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It may be appreciated other embodiment.
Claims (5)
1. a kind of ink of high stability, it is characterised in that be made up of the raw material below according to parts by weight：30 ~ 40 parts of cigarette material, I
Primary 20 ~ 30 parts of glue, 10 ~ 15 parts of palm oil, 5 ~ 12 parts of glycerine, 12 ~ 20 parts of stabilizer, 0.1 ~ 1.5 part of graft acrylamide and vinegar
Sour 3 ~ 10 parts of ethene.
2. the ink of high stability according to claim 1, it is characterised in that be made up of the raw material below according to parts by weight：
32 ~ 38 parts of cigarette material, 22 ~ 27 parts of Arabic gum, 11 ~ 14 parts of palm oil, 7 ~ 10 parts of glycerine, 14 ~ 18 parts of stabilizer, grafted propylene acyl
5 ~ 8 parts of 0.2 ~ 1.1 part of amine and vinyl acetate.
3. the ink of high stability according to claim 1, it is characterised in that be made up of the raw material below according to parts by weight：
35 parts of cigarette material, 25 parts of Arabic gum, 12 parts of palm oil, 9 parts of glycerine, 16 parts of stabilizer, 0.4 part of graft acrylamide and acetic acid second
6 parts of alkene.
4. according to the ink of any described high stabilities of claim 1-3, it is characterised in that stabilizer is by polypropylene, carbon nanometer
Pipe, silane coupler are according to 2:5:3 are prepared from.
5. the black preparation method of a kind of high stability as described in claim 1-3 is any, it is characterised in that including following step
Suddenly：
1）Dispensing is carried out according to raw material composition and its parts by weight proportioning；
2）By in polypropylene, the well mixed addition silane coupler of CNT, 5h is stood at a temperature of 50 ~ 80 DEG C, is cooled to
Room temperature, obtains stabilizer；
3）Cigarette material, Arabic gum are added in palm oil, 15 ~ 20min is stirred at a temperature of 50 ~ 60 DEG C, mixture A is obtained；
4）Vinyl acetate, graft acrylamide are added in glycerine, work overtime 10 ~ 15min at a temperature of 30 ~ 50 DEG C, is mixed
Thing B；
5）Mixture A, mixture B are mixed, 30 ~ 45min is stirred at a temperature of 20 ~ 30 DEG C, stabilizer is added while stirring, with
After be cooled to room temperature, produce.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710328612.7A CN107090210A (en) | 2017-05-11 | 2017-05-11 | A kind of ink of high stability and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710328612.7A CN107090210A (en) | 2017-05-11 | 2017-05-11 | A kind of ink of high stability and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107090210A true CN107090210A (en) | 2017-08-25 |
Family
ID=59637793
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110210601A (en) * | 2019-07-05 | 2019-09-06 | 江瑞祥 | The method of china ink stick, production china ink stick with electronic tag and black product |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100096596A1 (en) * | 2008-10-17 | 2010-04-22 | Lewis Jennifer A | Biphasic inks |
| CN102875742A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Manufacturing method of high branching degree acrylamide graft copolymer taking amylopectin as framework |
| CN104804552A (en) * | 2015-04-14 | 2015-07-29 | 陈良伢 | Glass ink with high adhesion and preparation method of glass ink |
| CN105778622A (en) * | 2016-03-31 | 2016-07-20 | 黄山市古城歙砚有限公司 | High-performance ink and preparation method thereof |
-
2017
- 2017-05-11 CN CN201710328612.7A patent/CN107090210A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100096596A1 (en) * | 2008-10-17 | 2010-04-22 | Lewis Jennifer A | Biphasic inks |
| CN102875742A (en) * | 2012-09-05 | 2013-01-16 | 喻小琦 | Manufacturing method of high branching degree acrylamide graft copolymer taking amylopectin as framework |
| CN104804552A (en) * | 2015-04-14 | 2015-07-29 | 陈良伢 | Glass ink with high adhesion and preparation method of glass ink |
| CN105778622A (en) * | 2016-03-31 | 2016-07-20 | 黄山市古城歙砚有限公司 | High-performance ink and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110210601A (en) * | 2019-07-05 | 2019-09-06 | 江瑞祥 | The method of china ink stick, production china ink stick with electronic tag and black product |
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Application publication date: 20170825 |
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